利用AutoPrep技术抑制型电导离子色谱法检测土壤中碘     

刘肖  史亚利Archava Siriraks Mike Kinderman 《岩矿测试》2007,26(6):446-450

利用AutoPrep自动样品前处理技术，对土壤燃烧吸收液进行在线预浓缩，抑制型电导进行检测，建立了一种全新思路的检测土壤样品中碘的方法。选择亲水性非常强的氢氧化物选择性IonPac AS16阴离子交换色谱柱，淋洗液发生装置在线产生KOH进行等梯度淋洗，抑制型电导检测。结果表明，对于土壤燃烧吸收液中碘离子的测定，方法检出限（S／N=3）可达1．2μg/L，线性相关系数为0．9998，方法精密度（RSD，n=7）为1．161％～4．566％，回收率在90．6％～100．8％。采用AutoPrep电导检测和脉冲安培检测离子色谱法测定不同土壤样品中的碘，两种方法的检测结果基本一致。方法在提供了稳定的系统空白的同时，还具备自动化程度高、操作简单、重现性好、灵敏度高、系统稳定、节约时间、成本低廉和对环境友好等多方面特点，适合于大批量土壤普查中碘的分析。  相似文献   

锚定式方钢管混凝土柱与钢梁节点抗震性能试验研究     

王先铁  郝际平  王丰平  潘阳  任青青  李娜 《地震工程与工程振动》2007,27(5):95-102

通过低周反复加载试验对6个锚定式方钢管混凝土柱-H形钢梁节点进行了试验研究,研究了不同轴压比情况下节点的破坏模式、延性、耗能性能、强度及刚度退化等。试验结果表明,破坏之前节点具有良好的滞回性能、延性及耗能能力,满足现行抗震规范的要求。锚定式方钢管混凝土梁柱节点可以用于拉力较小的节点。文中提出了有关的设计建议。  相似文献   

用地面湿度参量计算我国整层大气可降水量及有效水汽含量方法的研究   总被引：56，自引：3，他引：56       下载免费PDF全文

杨景梅  邱金桓 《大气科学》2002,26(1):9-22

根据1993年我国28个台站地面及高空气象要素资料,拟合出这28个台站所在地区整层大气可降水量同地面湿度参量(地面水汽压、地面露点)关系的经验表达式,并且在此基础上,通过引进地理纬度ψ和海拔高度H两个参量,将经验系数参数化,建立起由地面湿度参量计算整层大气可降水量的经验计算模式.另外还拟合出这些地区整层大气有效水汽含量同可降水量关系的经验表达式,提出一个先由地面湿度参量计算整层大气可降水量,再由此计算出整层大气有效水汽含量的方法.  相似文献   

REMOTE SENSING OF THE SEASONAL VARIATION IN COLUMN ABUNDANCE OF ATMOSPHERIC CH₄^*          下载免费PDF全文

WEI Heli  LIU Qinghong  XU Qingshan  ZHAO Fengsheng  SONG Zhengfang 《Acta Meteorologica Sinica》2001,15(2):249-256

Infrared solar spectra on clear days were measured automatically by an infrared solar spectrometer(ISS) with 0.4 cm^-1 resolution developed by us.A line-by line(LBL) computation method was used to calculate theoretical atmospheric absorption.In the wavelength range of 3.410-3.438 μm.the absorption is mainly due to atmospheric methane and water vapor.Columnatmospheric methane was retrieved from the recorded infrared solar spectra.The seasonal variation of column atmospheric methane in Hefei has been obtained from the measuremental data of nearly 18 months since the April of 1997.and found that it is similar to that of background data.The instruments.principles of measurement and some of results were introduced,and the results are also discussed briefly in the paper.  相似文献   

中高层钢筋混凝土异形柱框架结构弹塑性时程分析   总被引：3，自引：2，他引：3  

王滋军  刘伟庆  蒋永生 《地震工程与工程振动》2001,21(3):60-64

用杆模型编制了钢筋混凝土异形柱框架结构的弹塑性时程分析程序FEANT。采用该程序对一中高层大开间钢筋混凝土异形柱框架结构振动台试验模型进行了计算分析，计算值与试验值吻合较好，能满足工程需要。  相似文献   

珠江三角洲软土微结构的定量研究   总被引：4，自引：0，他引：4  

李榴芬  彭元贵 《华东地质学院学报》2001,24(2):127-130

对用不同长度的PVC管在珠海和广州两地采得的淤泥样柱施于一定荷载，然后在扫描电镜下研究软土受压后在样柱垂深方向上的微结构变化，并将样品的微结构照片扫描，在计算机内进行量化处理。结果表明，样品的孔隙分布分维差随着离施压点距离的增加而逐渐减小，从而得到两者的关系方程。据此，可了解在一定荷载下应力在软土层中向下的衰减趋势。文章还对软土的天然含水量和围压对压缩变形的影响作了初步的讨论。  相似文献   

Evaluation of density in layer compaction using SASW method   总被引：1，自引：0，他引：1  

Dong-Soo Kim  Min-Kyun Shin  Hyung-Choon Park   《Soil Dynamics and Earthquake Engineering》2001,21(1)

SASW test, which is non-intrusive and rapid in the field application, was used to evaluate the layer density in the roller compaction without performing the complicated inversion process. The concept of normalized shear wave velocity was introduced to minimize the effect of confinement in the density evaluation. SASW test was performed to determine the shear wave velocity of the layer, and the free–free resonant column (FF–RC) test was adopted to determine the correlation between the normalized shear wave velocity and density of the site, which is almost unique independent of confinement. Testing and data reduction procedures of both tests were briefly discussed and an evaluation procedure of the field density was proposed by effectively combining in-situ shear wave velocity determined by the SASW test with the correlation between the normalized shear wave velocity and the density determined by the FF–RC test. Finally, the feasibility of the proposed method was verified by performing a field case study at Hoengsung road construction site. Field densities determined by the proposed method matched well with those determined by sand cone tests, showing the potential of applying the proposed method in the field density evaluation.  相似文献   

Routine Analyses of Trace Elements in Geological Samples using Flow Injection and Low Pressure On-Line Liquid Chromatography Coupled to ICP-MS: A Study of Geochemical Reference Materials BR, DR-N, UB-N, AN-G and GH   总被引：6，自引：0，他引：6  

Jean Carignan  Pascal Hild  Guy Mevelle  Jacques Morel  Delphine Yeghicheyan 《Geostandards and Geoanalytical Research》2001,25(2-3):187-198

  相似文献   

离子色谱法测定水样中S~(2-)、SO_3~(2-)、SO_4~(2-)、S_2O_3~(2-)     

时艳  刘江潮 《吉林地质》2001,(2)

该种方法利用离子色谱仪的电导检测器与电化学检测器串联 ,十几分钟即可连续完成水中S2 - 、SO2 - 3 、SO2 - 4、S2 O2 - 3 的测定 ,方法具有快速、高效、方便、灵敏、选择性好等特点。方法的检出限分别为 :S2 - 12 5 μg/L ;SO2 - 3 2 2 4 μg/L ;SO2 - 45 0 μg/L ;S2 O2 - 35 0 μg/L。相对标准偏差在 1 5 %～ 6 9%之间 ,能够满足水中S2 - 、SO2 - 3 、SO2 - 4、S2 O2 - 3四种阴离子分析测试的需要。  相似文献   

pH influence on sorption characteristics of heavy metal in the vadose zone   总被引：10，自引：0，他引：10  

M. Elzahabi  R. N. Yong 《Engineering Geology》2001,60(1-4):61-68

Sorption is an important process in the modelling and prediction of the movement of heavy metals in unsaturated clay barriers. This experimental study investigates the effect of pH changes in the acidic range on the sorption characteristics of heavy metals such as: lead, copper and zinc in an unsaturated soil. A series of one-dimensional coupled solute and moisture leaching column tests, using different heavy metal solutions, were conducted on an unsaturated illitic soil at varying pH values. Variations of volumetric water content (VWC) with distance were measured for different time durations, and concentrations of heavy metals in the liquid and solid phases were analysed. Partitioning coefficient profiles of contaminants along the soil column were determined for each individual layer in the soil.

Results from column leaching tests showed that the sorption characteristics of heavy metals are controlled by many factors which should be taken into consideration, i.e. the VWC, time of wetting, soil pH, and the influent heavy metal concentrations. Simplification of K_d as a constant and of the VWC as a linear function cannot be considered a good assumption and may lead to an improper evaluation of the sorption phenomena and also to serious errors in predicting contaminant transport through unsaturated soils.  相似文献