稠油油藏井间泥岩夹层对双水平井SAGD开发效果的影响     

唐帅  刘鹏程  潘莉莉  吴永彬  张金川 《现代地质》2016,30(2):388-393

为定量描述稠油油藏蒸汽辅助重力泄油(SAGD)开采过程中注采井间夹层对双水平井泄油通道与开发效果的影响,针对新疆油田A区块,利用CMG数值模拟软件建立了表征SAGD注采井间夹层的数值模拟模型,对注采井间存在不同大小、间距及物性夹层情况下的SAGD蒸汽腔发育形态与开发效果进行对比,得到了稠油油藏夹层非均质影响SAGD开发的临界特征参数。矿场实际的非均质SAGD井组夹层展布特征、蒸汽腔发育特征及生产效果对比结果表明,得到的结论与矿场实践一致,因此可用于指导并实现经济、高效的稠油油藏双水平井SAGD开发。  相似文献   

四川攀西地区钒钛磁铁矿成矿元素富集过程模拟与资源潜力评价     

刘才泽  秦建华  李明雄  张启明 《吉林大学学报(地球科学版)》2013,43(3):758-764,775

根据层状含钒钛磁铁矿岩体的韵律特征及其铁质量分数变化规律,探索性地应用瑞利分馏模型模拟四川攀西地区攀枝花、红格、白马、太和等岩体成矿元素富集过程,分别建立了各岩体的统计模型和理想模型,并据此估算了铁矿石以及伴生钒、钛资源量。其中:攀枝花、红格、太和等岩体的数学模型比较一致,可能与这些岩体岩浆结晶分异比较彻底、成矿性好有关;而白马岩体的模型参数有较大差异,充分体现了该岩体结晶分异不彻底、成矿性相对较差的特点。  相似文献   

天然海水硝酸盐氮同位素组成的蒸馏法测定     

杨志  陈敏  曹建平  邱雨生 《海洋学报》2012,34(3):72-79

建立了测定天然海水中硝酸盐氮同位素组成的蒸馏法,该方法主要是在碱性条件下利用戴氏合金将海水中的硝酸盐还原为氨,后利用稀盐酸吸收生产的氨,将得到的氨吸收液浓缩后干燥结晶,利用同位素比值质谱仪测定所得晶体的氮同位素组成。研究中开展了戴氏合金添加量及氨吸收溶液在不同条件下干燥结晶对氮同位素测值的影响研究。结果表明,戴氏合金添加量为3.0 g及60 ℃下直接干燥结晶为最佳的实验条件。所建立的氨蒸馏法氮空白值仅为(0.90±0.19) μmol,低于此前文献报道的氮空白值;氮同位素组成(δ15N)空白值为(-14.7±4.1)×10-3。运用所建立的氨蒸馏法实测得到的硝酸盐δ15N值与氨扩散法、硝酸盐直接测定法得到的数值非常吻合,进一步证明所建立氨蒸馏法的可靠性。改进后的氨蒸馏法适用于硝酸盐浓度在2~50 μmol/dm3内的天然海水硝酸盐氮同位素组成的测定,方法的标准偏差为±0.3×10-3。  相似文献   

Quantitative Recovery of Elemental Sulfur and Improved Selectivity in a Chromium-Reducible Sulfur Distillation     

Jens Gröger  Jennifer Franke  Kay Hamer  Horst D. Schulz 《Geostandards and Geoanalytical Research》2009,33(1):17-27

Chromium-reducible sulfur (CRS) distillations are intended to recover only reduced inorganic sulfur compounds (RIS) including elemental sulfur. However, the quantitative recovery of elemental sulfur is not ensured in common CRS-distillations. The new method presented here was designed to remedy this deficiency. An increase in ethanol concentration assured the quantitative recovery of elemental sulfur in various forms and, in addition, all other RIS-compounds were quantitatively recovered. Furthermore, the selectivity of the procedure was improved by an additional filtration step to eliminate zinc particles from the Cr(II)-solution. Thus, the recovery of sulfates and organic sulfur compounds was significantly decreased by a factor of up to 35, depending on the compound analysed. Exhaustive testing with a variety of pure phases, rock and soil samples demonstrated the precision and accuracy of the new method. The new protocol eliminated the constraints of previous procedures. The improved distillation efficiency for elemental sulfur ensured the quantitative recovery of all RIS-compounds in a single-step distillation.  相似文献   

Refinement of the Micro‐Distillation Technique for Isotopic Analysis of Geological Samples with pg‐Level Osmium Contents     

Nao Nakanishi  Tetsuya Yokoyama  Akira Ishikawa 《Geostandards and Geoanalytical Research》2019,43(2):231-243

In recent years, the ¹⁸⁷Re–¹⁸⁷Os isotope system has been increasingly used to study samples containing very small quantities of Os. For such samples, optimisation of measurement procedures is essential to minimise the loss of Os before mass spectrometric measurements. Micro‐distillation is a necessary purification step that is applied after the main Os chemical separation procedure, prior to Os isotope ratio measurements by negative‐thermal ionisation mass spectrometry (N‐TIMS). However, unlike the other separation steps, this procedure has not yet been optimised for small samples. In this study, we present a refined micro‐distillation method that achieved higher yields and allowed high‐precision R(¹⁸⁷Os/¹⁸⁸Os) expressed as ¹⁸⁷Os/¹⁸⁸Os measurements for small‐sized geological samples that contain only a few pg Os. The Os recovery in the micro‐distillation step was tested by changing the operating conditions including heating time and temperature, and amounts of oxidant and reductant. Recoveries were measured by the isotope dilution ICP‐MS method after the addition of ¹⁹⁰Os‐enriched spike solution. We found that the most critical factor controlling the chemical yield of Os during micro‐distillation is the extent of dilution of the reductant (HBr) by H₂O evaporated from the oxidant. A refined micro‐distillation method, in which the amount of oxidant solution is reduced from the conventional method, achieved an improved chemical yield of Os (~ 90%). This refined method was applied to the measurement of ¹⁸⁷Os/¹⁸⁸Os by N‐TIMS of varying test portions of the geological reference material BIR‐1a. The resulting ¹⁸⁷Os/¹⁸⁸Os ratios of BIR‐1a matched the literature data, with propagated uncertainties of 0.2, 1.1 and 11% digested sample quantities containing 150, 10 and 1 pg of Os, respectively.  相似文献   

Carius管溶样-负离子热表面电离质谱准确测定辉钼矿铼-锇同位素地质年龄   总被引：175，自引：30，他引：175  

杜安道赵敦敏  王淑贤孙德忠　刘敦一 《岩矿测试》2001,20(4):247-252

将样品、混合稀释剂和逆王水加入到Carius管中,于230℃溶样10h.利用蒸馏法分离Os,萃取和阴离子交换法分离Re.采用负离子热表面电离质谱精确测定了所研制的年龄标准参考物辉钼矿(HLP)的Re-Os年龄.对取自12个小瓶中17个样品所测平均年龄为221.3±0.3Ma,置信度95%.中值年龄和平均绝对偏差为221.34±0.12Ma.美国克罗拉多州立大学AIRIE小组19次单独取样所测HLP的平均年龄为221.3±1.0Ma,置信度95%.中值年龄和平均绝对偏差为221.34±0.24Ma.  相似文献   

Noble gases in a section across the vapor dominated geothermal field of Larderello,Italy     

Emanuel Mazor 《Pure and Applied Geophysics》1978,117(1-2):262-275

Noble gases were studied in six wells, located on a 4.5 km south to north section across the Larderello field. Depth of wells, flow and gas/steam ratios are known to increase from south to north. Exploitation progressed in the same direction. The following noble gas patterns are observable: (a) Atmospheric Ar, Kr and Xe reflect productions of gas-depleted water at Colombaia 2 and progressively more gas-enriched steam towards the Gabbro wells. (b) Radiogenic⁴He and⁴⁰Ar are observed in increasing concentrations from south to north. (c) The radiogenic and atmospheric gases reveal a positive correlation, indicating that the recharging water enters deep into the system, and gets well mixed with the radiogenic gases prior to the steam separation. (d) Gas contents and relative abundances of radiogenic argon decrease with production, thus supplying markers for the degree of exploitation in a well and a guide for optimum well spacing. (e) Excess neon over argon is observed and discussed in terms of crustal origin versus possible fractionation of atmospheric noble gases due to pertial steam separation.  相似文献   

水体蒸发过程中稳定同位素的分形机制   总被引：1，自引：0，他引：1  

章新平  田立德  刘晶淼 《地理学报(英文版)》2005,15(3):375-384

The variations of stable isotopes in atm ospheric vapor and precipitation are caused by stableisotopic fractionation during phase changes in w ater cycle. The isotopic fractionation m ainlyhappens in the m ass transportation of stable isotopes from free w…  相似文献   

共沸蒸馏置换干燥法制备纳米氧化镁粉体的研究   总被引：2，自引：0，他引：2       下载免费PDF全文

王宝和  张伟  张文博  范方荣 《盐湖研究》2006,14(3):34-38

以六水氯化镁和尿素为原料,采用均匀沉淀法制备出氢氧化镁沉淀,利用不同共沸蒸馏置换干燥法除去沉淀中的湿分,再将干燥的氢氧化镁粉体经马弗炉煅烧得到纳米氧化镁粉体;通过透射电子显微镜和X射线衍射仪的表征与分析,研究不同共沸蒸馏置换干燥法对纳米氧化镁粉体形貌、颗粒尺寸和团聚情况的影响;探讨了共沸蒸馏置换干燥的基本原理、操作方法和置换剂的选择原则。  相似文献   

结晶膜蒸馏处理吸收炼矿烟气酸性废水的研究     

王鹤  李滦宁  张凤君  张孝生  王顺义  沙娜  戴宁 《吉林大学学报(地球科学版)》2006,(Z1)

采用天然碳酸钙中和烟气吸收酸性废水,研究中空纤维结晶膜蒸馏技术对中和后废水处理的效果。考察了料液温度、起始浓度、流速、pH值等因素对膜通量的影响。在选定的条件下对水样进行连续膜蒸馏处理。结果表明,在料液温度50℃,料液速度为18.5mL/min,pH值为7,运行18h后,浓缩溶液开始出现结晶,结晶效果较好。截留率均接近100%。  相似文献