Hydrometallurgical processing and recovery of molybdenum trioxide from spent catalyst   总被引：5，自引：0，他引：5  

Kyung Ho Park  B. Ramachandra Reddy  D. Mohapatra  Chul-Woo Nam 《International Journal of Mineral Processing》2006,80(2-4):261-265

Hydrometallurgical processing of spent hydrodesulphurisation (HDS) catalyst for the recovery of molybdenum using sodium carbonate and hydrogen peroxide mixtures was investigated. The results indicated that the recovery of molybdenum was largely dependent on the concentrations of Na₂CO₃ and H₂O₂ in the reaction medium, which controls the acidity of the leach liquor and carry over of impurities such as Al, Ni, P, Si and V. Leaching process was exothermic and leaching efficiency of molybdenum decreased with increasing solid to liquid ratio. Large scale leaching of spent catalyst, under optimum conditions: 20% pulp density, 85 g/L Na₂CO₃, 10 vol.% H₂O₂ and 1 h reaction, resulted a leaching efficiency of 84% Mo. The obtained leach liquor contained (g/L): Mo — 22.0, Ni — 0.015 and Al — 0.82, P — 1.1, Si — 0.094 and minor quantities of V — 8 mg/L, As and Co — < 1 mg/L. Recovery of Mo from leach solution as MoO₃ of 97.30% purity was achieved by ammonium molybdate precipitation method.  相似文献   

Water–rock interaction during the process of steam stimulation exploitation of viscous crude oil in Liaohe Shuguang Oil Field, Liaoning, China     

Qian Hui  Yang Zhenghua  Li Yunfeng  Xu Wancai  Sun Yaqiao 《Environmental Geology》2006,50(2):229-236

In the process of steam stimulation exploitation of viscous crude oil, the injected water, at high temperature and under high pressure, reacts intensively with the host rock. This kind of water–rock interaction in Liaohe Shuguang Oil Field was studied on the basis of analysis of water composition changes, laboratory experiments, mineral saturation indices analysis, and mass balance calculation. Compared with the injected water, the changes of the composition of discharged water are mainly the distinct decrease of pH, Na⁺, SiO₂ and Cl⁻, as well as the increase of K⁺, Ca²⁺, Mg²⁺, SO ₄ ²⁻ and HCO ₃ ⁻ . Laboratory experiments under field conditions showed: the dissolution sequence of minerals quantitatively is quartz>potassium feldspar>albite, and the main change of clay minerals is the conversion of kaolinite to analcime. Mass balance calculation indicated during the process of steam stimulation, large quantities of analcime are precipitated with the dissolution of large amounts of quartz, kaolinite, potassium feldspar, and CO₂. These results correlated very well with the experimental results. The calculated results of Liaohe Shuguang Oil Field showed that during the steam stimulation for viscous crude oil, the amounts of minerals dissolved (precipitated) are huge. To control the clogging of pore spaces of oil reservoirs, increased study of water–rock interaction is needed.  相似文献   

油页岩综合利用对周围环境的影响——以抚顺矿区为例   总被引：3，自引：0，他引：3  

张丽萍曾荣树  徐文东金福杰 《中国煤田地质》2006,18(2):46-48,51

世界能源日益减少的局面为油页岩的开发应用带来广阔的前景，但油页岩工业所带来的环境影响亦不容忽视。以抚顺油页岩为例，从油页岩综合利用和油页岩工业对环境的影响等方面系统讨论了在我国发展油页岩工业时，如何本着节约能源、保护环境、实现可持续发展的观念，利用现有先进技术，科学发展油页岩工业，降低生产过程中的固、液、气污染物对环境的危害。  相似文献   

酶法催化餐饮废油制备生物柴油的研究     

安永磊  唐唯森  高松 《吉林大学学报(地球科学版)》2006,(Z1)

以废物资源转化为宗旨,利用固定化脂肪酶催化餐饮废油与乙醇反应制备生物柴油,通过实验获得最佳酯化反应条件:反应温度47℃、有机溶剂为正己烷、醇油比3∶1,5次投加乙醇,酶用量为0.3g,反应时间32h时,生物柴油产率可达81%。  相似文献   

大洋粘土制备白炭黑后的铝回收实验研究     

刘娟娟  张培萍  石学法  吕华华  王宝君  邵冬梅 《吉林大学学报(地球科学版)》2006,(Z1)

为了回收大洋粘土制备白炭黑后残液中的Al3 ,并获得氧化铝超细粉体,实验选用NH3.H2O为沉淀剂,在常温下采用沉淀法使残液中Al3 以氢氧化铝形式沉淀并去除其它杂质离子,然后将得到的沉淀在1200℃灼烧,保温1h。利用IR和XRD测试了产物的物相组成和结构,证实实验可以获得纯度较高的α-Al2O3;而SEM和粒度分析结果显示产物粒度细小,部分颗粒可以达到纳米级;BET结果显示Al2O3的比表面积可达32m2/g。根据氧化铝结构和性能等优选的实验条件为大洋粘土的进一步开发利用提供了参考依据。  相似文献   

Application of membrane technology for water treatment： Ultrasound-associated cleaning of fouled microfiltration membranes     

Rui CHEN Xiaoli WANG Yonggang ZHANG Xueqi FU 《中国地球化学学报》2006,25(B08):128-129

The use of membranes is a widely employed, versatile, and effective separation process. One of the limiting aspects in applying microfiltration （MF） for wastewater treatment is that of problems with membrane fouling and consequent flux reduction. Membrane fouling occurs by the irreversible deposition of retained particles, colloids, macromolecules, salts, etc. at the membrane surface and/or inside the membrane. The predominant fouling mechanisms observed with MF membranes are classified as three categories： the build-up of a cake layer on the membrane surface, blocking of membrane pores, and adsorption of fouling material on the membrane surface or in the pore walls. Although many techniques have been developed to overcome fouling, studies on membrane cleaning still seem to be insufficient for practical membrane filtration systems. Current membrane cleaning technologies include hydraulic, chemical, and mechanical methods. Ultrasound （US） has been widely used as a method of cleaning materials because of the cavitation phenomenon. In this study, US cleaning technique was applied to removing the fouling of polyvinglidenefluoride （PVDF） MF membrane, which was used to treat yeast cell and isolated soybean protein （ISP） solution, respectively. The US employed 40 kHz frequency and the output power of 1.43-2.85 W/cm^2. The evolution of the cleaning effect is followed by the measurements of the flux recovery rate （FRstat） and the cleaning time cycle. Results showed that the membrane property, which was fouled by yeast cell solution, could be recovered by water cleaning with US irradiation. And the cleaning time with the same FRstat decreased with the increase of US intensity.  相似文献   

油气化探数据库系统     

赵跃伟  汤玉平  李沙园  任春 《物探与化探》2005,29(1):53-56

建立油气化探数据库是油气化探信息资源共享、科学管理、宏观决策的基础和依据,是油气化探数据处理及异常评价的基础。本系统采用动态自适应结构,收集、录入了几十年来我国油气化探数据,可以完成油气化探数据登录、管理、浏览、检索、报表、数据预处理。文章中论述了油气化探数据库的结构、特点及功能,反映了油气化探数据库研究领域的新进展和研究水平。  相似文献   

盐城凹陷朱家墩气田综合化探异常及其地质意义   总被引：1，自引：1，他引：1  

王国建  邓平  石美癸 《物探与化探》2005,29(2):131-134

用酸解烃、顶空气、吸附丝及甲烷碳同位素方法对盐城凹陷朱家墩气田进行了综合油气化探测量,建立了该区这几种方法指标的化探异常模式,在总结已知油气区异常规律的基础上,优化化探方法及指标组合并运用于未知区域,圈定了油气远景靶区。探讨了地表化探异常与石油地质特征的关系,为化探异常的地质解释提供了可借鉴的思路。  相似文献   

现阶段地表油气化探技术难题与发展对策   总被引：2，自引：1，他引：2  

姚俊梅 《物探与化探》2005,29(6):477-480,486

虽然地表油气化探方法技术已取得显著的应用效果, 但是由于成功率计算标准不同及方法技术本身的缺陷, 导致人们对方法的认同度较低。当前, 地表油气化探技术的发展, 一方面要以可靠的实验依据、严谨的数理推导及理论模型应对来自方法技术本身的挑战, 另一方面也要利用其快速、廉价和直接的优势, 加强与地质、遥感、非震物探等方法综合应用。  相似文献   

控制内蒙古二连盆地达尔其油田石油富集度的关键因素——不同油源原油的混合作用     

靳广兴  许书堂  侯读杰  田世澄  洪萍 《现代地质》2005,19(3):425-431

在对3套烃源岩的质量和成熟度描述基础上,通过对原油物理性质、族组成和生物标志化合物参数的研究,在达尔其油田内划分出成熟度有明显差异的低熟油和成熟油。油源对比结果认为它们分别由都红木组一段低熟烃源岩和阿尔善组二段成熟烃源岩所生。推测成熟度参数介于低熟和成熟之间的原油为混源油。通过原油混合试验和油砂连续抽提试验证实了混源油的推测。通过油藏剖面中不同性质油层的分布特征研究,结合断层发育史与油气运移关系分析认为不同油源原油的混合是控制该油田石油富集度较高的关键因素。此外,还分析了控制混源的断层组合特征。  相似文献