Discussion on “The action of elemental sulfur plus water on 1-octene at low temperatures” by Said-Ahmad et al. (Organic Geochemistry 59, 82–86)     

《Organic Geochemistry》2015

A recent article (Said-Ahmad, W., Amrani, A., Aizenshtat, Z., 2013. The action of elemental sulfur plus water on 1-octene at low temperatures. Organic Geochemistry 59, 82–86) is commented on in this discussion. Radical mechanisms proposed by Said-Ahmad et al. (2013) for the formation of sulfurized and oxidized organic compounds in experiments involving elemental sulfur and 1-octene under aqueous conditions, aimed at investigating the interaction of organic matter and sulfur compounds under geological conditions, are not compatible with their experimental results and other studies. In addition, results from the experiments aimed at demonstrating the role of HO radicals in the formation of oxidized organic compounds were incorrectly interpreted by the authors. In this discussion, alternative mechanisms for the formation of the sulfurized and oxygenated products reported by Said-Ahmad et al. (2013) are proposed.  相似文献   

Computer experiments to investigate complex fibre patterns in natural antitaxial strain fringes     

D. Koehn  D. G. A. M. Aerden  P. D. Bons  C. W. Passchier 《Journal of Metamorphic Geology》2001,19(2):217-231

Antitaxial non‐deforming strain fringes from Lourdes, France, show complex quartz, calcite and chlorite fibre patterns that grew around pyrite in a slate during non‐coaxial progressive deformation. Development of these fringes was modelled using a computer program ‘Fringe Growth 2.0’ which can simulate incremental growth of crystal fibres around core‐objects of variable shape. It uses object‐centre paths as input, which are obtained from fibre patterns in thin section. The numerical experiments produced fibre patterns that show complex intergrowth of displacement‐controlled, face‐controlled and intermediate fibres similar to those in the natural examples. The direction of displacement‐controlled growth is only dependent on the relative movement between core‐object and fringe, so that core‐object rotation with respect to the fringe influences the fibre patterns and produces characteristic asymmetric fibre curvature. Object‐centre paths should be used for kinematic analysis of strain fringes instead of single fibres since these paths represent the fringe as a whole. The length along the path can be interpreted in terms of finite strain and path curvature in terms of rigid body rotation of fringes with respect to an external reference frame.  相似文献   

InFOCμS Hard X-ray Imaging Telescope     

J. Tueller  H. A. Krimm  T. Okajima  S. D. Barthelmy  S. M. Owens  P. J. Serlemitsos  Y. Soong  K.-W. Chan  Y. Ogasaka  R. Shibata  K. Tamura  A. Furuzawa  Y. Tawara  H. Kunieda  K. Yamashita 《Experimental Astronomy》2005,20(1-3):121-129

InFOCμS is a new generation balloon-borne hard X-ray telescope with focusing optics and spectroscopy. We had a successful 22.5-hour flight from Fort Sumner, NM on September 16,17, 2004. In this paper, we present the performance of the hard X-ray telescope, which consists of a depth-graded platinum/carbon multilayer mirror and a CdZnTe detector. The telescope has an effective area of 49 cm² at 30 keV, an angular resolution of 2.4 arcmin (HPD), and a field of view of 11 arcmin (FWHM) depending on energies. The CdZnTe detector is configured with a 12 × 12 segmented array of detector pixels. The pixels are 2 mm square, and are placed on 2.1 mm centers. An averaged energy resolution is 4.4 keV at 60 keV and its standard deviation is 0.36 keV over 128 pixels. The detector is surrounded by a 3-cm thick CsI anti coincidence shield to reduce background from particles and photons not incident along the mirror focal direction. The inflight background is 2.9 × 10⁻⁴ cts cm⁻² sec⁻¹ keV⁻¹ in the 20–50 keV band.  相似文献   

A Simple Model for the Movement of Fire Smoke in a Confined Tunnel     

M.?K.-A.?NeophytouEmail author  R.?E.?Britter 《Pure and Applied Geophysics》2005,162(10):1941-1954

Fires in tunnels are unfortunately frequent occurrences often with tragic outcomes. A recent example is the fire on the funicular train at the ski resort in Kaprun (Austria), which caused nearly 160 deaths. Design engineers and risk analysts require knowledge of the fluid dynamics of the fire and smoke movement to answer questions such as how much oxygen can access and feed the fire, and what concentration of smoke will the people be exposed to. As an example in the Austrian accident the geometry was a long tunnel with fire doors closed at one end, and with a fire initiated near the closed (lower) end. The hot smoke from the fire is a source of buoyancy; the smoke reaches the ceiling of the tunnel, and then develops along the ceiling as a wall-bounded plume. The motion of the smoke is driven by a buoyancy force, but at the same time, mechanisms of turbulent heat and mass transfer act as a brake to this motion. In this paper we present how a generic model describing a semi-enclosed buoyancy-driven flow can be interpreted and used in the modelling of fire smoke movement in a confined tunnel. A consideration of the net pollutant volume flux through the tunnel leads to predictions for the variation of concentrations along the tunnel. The smoke concentrations near the fire smoke source scale linearly with the length of the tunnel, with higher concentrations at the lower section of the tunnel, as could be expected. Similarly the concentration of oxygen making its way through to the fire source decreases linearly with the length of the tunnel. A lower bound estimate of the smoke residence time can be obtained based on smoke concentration predictions from the model.  相似文献   

LABORATORY OBSERVATIONS OF SEDIMENT ENTRAINMENT BY FREEZING SUPERCOOLED WATER     

SIMON J. COOK  PETER G. KNIGHT  DEBORAH A. KNIGHT  RICHARD I. WALLER 《Geografiska Annaler: Series A, Physical Geography》2012,94(3):351-362

Debris in basal ice produced by glaciohydraulic supercooling is typically characterized by high proportions of silt. A prominent hypothesis for this silt‐dominance is that frazil ice growing in supercooled water preferentially traps silt from sediment‐laden water percolating through it. It has therefore been suggested that silt‐dominance may be diagnostic of glaciohydraulic supercooling. The aim of our work is to test this hypothesis that freezing sediment‐laden supercooled water necessarily produces ice dominated by silt. We do this by simulating two freezing processes under laboratory conditions: (1) percolation of sediment‐laden water through frazil ice; (2) turbulent supercooling and subsequent freezing of sediment‐laden water. In experiments repeated using different particle sizes (sand, silt and clay in individual experiments) both processes entrained sand most effectively and silt least effectively. In experiments using a sediment mixture dominated by medium to coarse silt, both processes produced ice facies dominated by particle sizes between fine sand and coarse silt. These results suggest that silt‐dominance should therefore not be expected for supercooled freeze‐on, and is not a reliable diagnostic signature for supercooling. The silt‐dominated character of basal ice types associated with supercooling may result from other controls such as a silt‐dominated sediment supply or subglacial water flow rates, rather than the freezing process.  相似文献   

Effects of the low-frequency zonal wind variation on the high frequency atmospheric variability over the tropics     

K. P. Sooraj  Daehyun Kim  Jong-Seong Kug  Sang-Wook Yeh  Fei-Fei Jin  In-Sik Kang 《Climate Dynamics》2009,33(4):495-507

Recently, there is increasing evidence on the interaction of atmospheric high-frequency (HF) variability with climatic low-frequency (LF) variability. In this study, we examine this relationship of HF variability with large scale circulation using idealized experiments with an aqua-planet Atmospheric GCM (with zonally uniform SST), run in different zonal momentum forcing scenarios. The effect of large scale circulation changes to the HF variability is demonstrated here. The HF atmospheric variability is enhanced over the westerly forced region, through easterly vertical shear. Our study also manifests that apart from the vertical wind shear, strong low-level convergence and horizontal zonal wind shear are also important for enhancing the HF variance. This is clearly seen in the eastern part of the forcing, where the HF activity shows relatively maximum increase, in spite of similar vertical shear over the forced regions. The possible implications for multi-scale interaction (e.g. MJO–ENSO interaction) are also discussed.  相似文献   

沙尘输送模式的不确定性分析   总被引：4，自引：1，他引：3  

林彩燕  朱江  王自发 《大气科学》2009,33(2):232-240

利用一个远距离输送的沙尘模式估计了由于参数化过程 (干沉降速度) 和输入资料 (源强和水平风场) 的误差造成沙尘模拟的不确定性。通过对以上参数分别进行敏感性试验, 分析了模式对2002年3月15～24日期间中国东部地区两次主要沙尘过程模拟的不确定性。结果显示, 源区的潜在源强和气象水平风场的不确定性对模拟结果的影响最大, 而干沉降速度的影响相对较小。同时, 对不同区域 ［西部 (＜95°E)、中部 (95°E～110°E) 和东部 (＞110°E)］ 的潜在源强和干沉降速度参数进行敏感性试验发现, 中部区域的参数设置对模拟结果的影响最大, 而西部和东部区域的参数变化对模拟结果的影响很小。此外, 不同高度的风场影响也不一样: 地面风速影响最大, 中层的影响较小, 而高层 (约6 km高度以上) 的风场几乎没有影响。  相似文献   

Subfilter-scale Fluxes over a Surface Roughness Transition. Part I: Measured Fluxes and Energy Transfer Rates     

Matthew A. Carper  Fernando Porté-Agel 《Boundary-Layer Meteorology》2008,126(1):157-179

A wind-tunnel experiment was designed and carried out to study the effect of a surface roughness transition on subfilter-scale (SFS) physics in a turbulent boundary layer. Specifically, subfilter-scale stresses are evaluated that require parameterizations and are key to improving the accuracy of large-eddy simulations of the atmospheric boundary layer. The surface transition considered in this study consists of a sharp change from a rough, wire-mesh covered surface to a smooth surface. The resulting magnitude jump in aerodynamic roughnesses, M = ln(z ₀₁/z ₀₂), where z ₀₁ and z ₀₂ are the upwind and downwind aerodynamic surface roughnesses respectively, is similar to that of past experimental studies in the atmospheric boundary layer. The two-dimensional velocity fields used in this study are measured using particle image velocimetry and are acquired at several positions downwind of the roughness transition as well as over a homogeneous smooth surface. Results show that the SFS stress, resolved strain rate and SFS transfer rate of resolved kinetic energy are dependent on the position within the boundary layer relative to the surface roughness transition. A mismatch is found in the downwind trend of the SFS stress and resolved strain rate with distance from the transition. This difference of behaviour may not be captured by some eddy-viscosity type models that parameterize the SFS stress tensor as proportional to the resolved strain rate tensor. These results can be used as a benchmark to test the ability of existing and new SFS models to capture the spatial variability SFS physics associated with surface roughness heterogeneities.  相似文献   

风暴尺度天气下利用集合卡尔曼滤波模拟多普勒雷达资料同化试验I.不考虑模式误差的情形   总被引：11，自引：8，他引：3  

兰伟仁  朱江  Ming XUE 《大气科学》2010,34(3):640-652

本文在假定模式无偏差的情况下, 利用一次风暴过程的模拟多普勒雷达资料进行一系列风暴天气尺度的集合卡尔曼滤波资料同化试验, 检验集合卡尔曼滤波在风暴天气尺度资料同化方面的效果, 并验证各集合卡尔曼滤波参数对同化效果的影响。试验结果表明, 集合卡尔曼滤波能有效地应用于风暴尺度的资料同化; 40个集合成员以及6 km的局地化尺度能较好地滤除采样误差造成的虚假相关, 同时可以将观测信息传递到无观测的模式格点; 利用背景场加上空间平滑的高斯型随机扰动生成初始成员的方式较未经过平滑的方式有更好的分析效果; 背景场扰动方法能够提高样本的离散度; 只同化反射率的同化试验表明, 反射率的同化效果较明显, 也证明了集合卡尔曼滤波在非常规资料同化中的作用; 增加径向风资料同化的效果优于只进行反射率同化的结果。  相似文献   

Collisional disruption experiments of porous targets     

Akiko M. Nakamura  Kensuke Hiraoka  Nagisa Machii 《Planetary and Space Science》2009,57(2):111-118

More and more small bodies are found to be porous. Laboratory impact experiments of various porous materials have been performed, which increased our understanding of the impact process of porous bodies. In this review, we classify porous targets according to the internal structure, describe the physical properties that characterize these materials, and summarize some results of impact strength and the general tendency upon impact condition and material properties. The material property presented here includes a relation between applied load and distension although measured in static condition. Further investigation is required to clarify the role of crack growth and compaction in the time evolution of physical properties of porous materials upon impact. Laboratory experiments with detailed material properties will be useful as a database that can serve as a reference for numerical modeling and theoretical scaling considerations.  相似文献