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131.
The early diagenetic environment of intertidal sandy sediments (sands) and muddy sediments (muds) is described and compared from two cores taken from an unpolluted part of the Manukau Harbour, New Zealand. Extraction techniques characterized the form of the trace elements (Fe, Mn, S, C, Pb, Zn, Cu) at different depths in the sediment. Dissolved forms of Fe, Mn, and S were measured in interstitial water. Nonresidual metal concentrations, humic acid, FeS, and FeS2 are an order of magnitude higher in the muds than in the sands because of dilution by unreactive sand particles. Muds contain a larger proportion of metals in the mobile fractions; exchangeable (Mn), carbonate (Mn, Fe, Zn), and easily-reducible oxide (Fe, Mn, Zn, Pb). This is due to greater surface area (for Mn adsorption); the favorable conditions for MnCO3, FeCO3, and FeS precipitation; and higher concentrations of easily reducible iron oxide and humic acid. Therefore, compared to the sands, muds are more important as reservoirs for toxic metals, both in terms of quantity and availability. At either site there was very little difference between the forms of Zn, Pb or Cu identified by sequential extraction as sediments changed from oxic to anoxic conditions. One reason for this is that the amounts and proportions of some of the important components that bind metals, viz., amorphous iron hydrous oxides, humic acids, and FeS2, do not change much. Other components that do change with redox conditions, for example, manganese phases and FeS, are only minor components of the sediment. Redox conditions, then, have relatively little effect on trace-metal partitioning in the sediment matrix of these unpolluted sediments. 相似文献
132.
Stefan Keller 《Surveys in Geophysics》1995,16(5-6):661-670
Laboratory simulation of powder snow avalanches serves for the validation of numerical models and as a tool in its own right for consulting and research purposes. Two-phase gravity currents are simulated in water with quartz powder or glass spheres as the particle phase. Particle-phase velocity profiles and particle-phase volume fraction profiles are measured with an ultrasonic device. The experimental setup and the current state of the measurement technique are described and preliminary results are presented. 相似文献
133.
Christine Franke Thomas Frederichs Mark J. Dekkers 《Geophysical Journal International》2007,170(3):1053-1066
Low-temperature rock magnetic measurements have distinct diagnostic value. However, in most bulk marine sediments the concentration of ferrimagnetic and antiferromagnetic minerals is extremely low, so even sensitive instrumentation often responds to the paramagnetic contribution of the silicate matrix in the residual field of the magnetometer. Analysis of magnetic extracts is usually performed to solve the problems raised by low magnetic concentrations. Additionally magnetic extracts can be used for several other analyses, for example electron microscopy or X-ray diffraction. The magnetic extraction technique is generally sufficient for sediments dominated by magnetite. In this study however, we show that high-coercivity components are rather underrepresented in magnetic extracts of sediments with a more complex magnetic mineralogy. We test heavy liquid separation, using hydrophilic sodium polytungstenate solution Na6 [H2 W12 O40 ], to demonstrate the efficiencies of both concentration techniques. Low-temperature cycling of zero-field-cooled, field-cooled and saturation isothermal remanent magnetization acquired at room temperature was performed on dry bulk sediments, magnetic extracts, and heavy liquid separates of clay-rich pelagic sediments originating from the Equatorial Atlantic. The results of the thermomagnetic measurements clarify that magnetic extraction favours components with high spontaneous magnetization, such as magnetite and titanomagnetite. The heavy liquid separation is unbiased with respect to high- and low-coercive minerals, thus it represents the entire magnetic assemblage. 相似文献
134.
将碳酸钙试样用盐酸溶解后,在0.6mol/L的盐酸介质中,用KI-MIBK萃取试样中微量的铅和镉,有机相用原子吸收分光光度法测定。该方法测定铅的相对标准偏差为2.38%-6.31%,回收率为96.5%-97.0%;测定镉的相对标准偏差为4.50%-5.52%,回收率为96%-102.8%。结果可靠,具有灵敏、准确、快速、选择性好等优点。适用于碳酸钙中铅、镉的测定。 相似文献
135.
土壤中钙形态的连续浸提方法 总被引:4,自引:0,他引:4
通过改进的连续浸提技术,把土壤钙的赋存形态划分为5个类型:水溶态、交换态、酸溶态、有机结合态及残渣态,用原子吸收光谱法测定各形态钙含量及总钙量,各形态钙的加和值与测得的总钙量基本相符,且各形态钙8次浸提的相对标准偏差基本在10%以内。探讨了改进的连续浸提方法提取条件(包括浸提剂、水土比、提取时间、离心速率及离心时间等)对提取效果的影响。结果表明,土壤中各形态钙可以满足生态地球化学土壤样品评价需要。 相似文献
136.
高分辨率遥感影像在岩墙地质体信息提取中的应用 总被引:5,自引:0,他引:5
高分辨率遥感影像可明显表现地物的几何结构和纹理特征,从而使得在较小空间尺度上观察地物细节变化、进行大比例尺遥感制图成为可能。利用高分辨率QuickBird遥感影像,对新疆巴楚县麻扎尔塔格山地区的岩墙进行计算机辅助地质解译,共获得1227条岩墙。结合GIS空间分析方法获得了解译岩墙长度、走向分布等特征。结果表明:该地区76%的解译岩墙走向为NNW(135°~180°);QuickBird能够满足1∶2.5万地质调查的要求;通过地质分析综合解译结果获得了麻扎尔塔格岩体内部存在发育岩墙、岩墙形成应晚于内部的正长岩体的新认识。探讨并验证了高分辨率遥感影像在中小规模地质体解译中的可行性和有效性。 相似文献
137.
利用GVG线采样技术提取农作物种植面积及其精度分析 总被引:5,自引:0,他引:5
GVG(GIS&Video&GPS)线采样系统提出以线状样区代替以往成数抽样中的点样区与面积样区概念,通过统计线状样区内作物种植面积成数来反映区域总体农作物种植面积成数。通过 GVG实地采样,将其结果与解译遥感影像提取的作物种植面积成数结果进行了对比分析,结果显示采用GVG线采样方式精确度较高,其采样系统具有实用性和推广价值。 相似文献
138.
铼—锇同位素分析中试样化学预处理方法进展 总被引:4,自引:0,他引:4
评述了用于Re-Os同位素体系分析的化学前处理技术的发展。简要介绍了卡洛斯管熔样法、Os的CCl4提取、溴提取和微蒸馏方法。卡洛斯管封闭熔样方法,有效地防止了Os的挥发损失和保证了Os同位素平衡,是一种很有发展前景的熔样方法。蒸馏法仍是分离和纯化Os的有效方法,溶剂(CCl4)提取和溴提取法在许多实验室里应用,而微蒸馏则是Os的二次纯化的主要方法。Re的化学分离和纯化仍是离子交换和萃取法。引用主要文献29篇。 相似文献
139.
Peter Doucette Peggy Agouris Anthony Stefanidis Mohamad Musavi 《ISPRS Journal of Photogrammetry and Remote Sensing》2001,55(5-6)
The extraction of road networks from digital imagery is a fundamental image analysis operation. Common problems encountered in automated road extraction include high sensitivity to typical scene clutter in high-resolution imagery, and inefficiency to meaningfully exploit multispectral imagery (MSI). With a ground sample distance (GSD) of less than 2 m per pixel, roads can be broadly described as elongated regions. We propose an approach of elongated region-based analysis for 2D road extraction from high-resolution imagery, which is suitable for MSI, and is insensitive to conventional edge definition. A self-organising road map (SORM) algorithm is presented, inspired from a specialised variation of Kohonen's self-organising map (SOM) neural network algorithm. A spectrally classified high-resolution image is assumed to be the input for our analysis. Our approach proceeds by performing spatial cluster analysis as a mid-level processing technique. This allows us to improve tolerance to road clutter in high-resolution images, and to minimise the effect on road extraction of common classification errors. This approach is designed in consideration of the emerging trend towards high-resolution multispectral sensors. Preliminary results demonstrate robust road extraction ability due to the non-local approach, when presented with noisy input. 相似文献
140.