由膨润土提铝残渣直接合成五配位体有机硅化合物     

于少明  周爱萍  陆亚玲  李忠 《矿物学报》2003,23(4):355-358

研究了以膨润土提铝残渣为原料，采用低温加热法直接合成有机硅化合物新方法。由实验确定了最佳的合成条件。用红外光谱法和X射线衍射法分析了合成产物的结构。结果表明，当以碱金属氢氧化物为介质时，合成的产物为五配位体有机硅化合物；在最佳合成条件下，钠盐和锂盐的收率分别为63．0％和44．9％。  相似文献   

天然含钒金红石加热、淬火及电子辐射改性实验研究   总被引：4，自引：5，他引：4       下载免费PDF全文

刘娟鲁安怀  郭延军李宁  李巧荣郑佳 《岩石矿物学杂志》2003,22(4):339-344

天然含钒金红石样品经过1273K加热、淬火和高能电子辐照处理后性质发生不同程度的变化。XRD谱峰显示处理前后样品没有发生物相变化，显微IR图谱证明原样、加热、淬火样品的表面有少量吸附水存在，而辐射样品的显微IR图谱上没有检测到吸附水的吸收峰。用XPS分析比较了处理前后样品表面主要元素Ti、O和V的价态及含量，结果表明，原样经过处理后表面钒和氧的原子百分含量增加，其中淬火样品表面吸附水和钒的含量相对于原样增加最为明显，光催化活性相应较高；加热样品表面的吸附水和钒的含量比原样稍有增加，光催化活性与原样相当；电子辐射样品表面钒的原子百分含量相对原样增加不明显，而对水的吸附能力相对原样较低，光催化效率也略低。  相似文献   

1998年夏季青藏高原及其邻近地区地面总热源季节变化特征及其与西太平洋副热带地区对流的关系   总被引：3，自引：0，他引：3  

LI Wei  CHEN Longxun 《大气科学进展》2003,20(3):343-348

利用98’TIPEX实验资料、1998年5-8月青藏高原6个自动热量平衡站(AWS)资料、青藏高原常规观测资料、中国300多个站的逐日降水资料、国家卫星中心接收的1998年5-8月OLR和日本GMS的TBB资料,研究了1998年5-8月青藏高原及其邻近地区逐日地面总热源的季节变化特征及其与西太平洋副热带地区对流的关系。结果表明:高原地面总热源与高原雨季开始有密切关系,高原雨季开始以后,高原平均的地面总热源明显减小;高原平均的地面总热源与20—30°N附近的西太平洋副热带地区的TBB有很好的负相关关系,表明高原地面总热源可以通过某种机制影响副热带地区的对流。  相似文献   

A Laboratory Model for the Flow in Urban Street Canyons Induced by Bottom Heating   总被引：2，自引：2，他引：2  

LIU Huizhi  LIANG Bin  ZHU Fengrong  ZHANG Boyin  SANG Jianguo 《大气科学进展》2003,20(4):554-564

Water tank experiments are carried out to investigate the convection flow induced by bottom heating and the effects of the ambient wind on the flow in non-symmetrical urban street canyons based on the PIV (Particle Image Visualization) technique. Fluid experiments show that with calm ambient wind,the flows in the street canyon are completely driven by thermal force, and the convection can reach the upper atmosphere of the street canyon. Horizontal and vertical motions also appear above the roofs of the buildings. These are the conditions which favor the exchange of momentum and air mass between the street canyon and its environment. More than two vortices are induced by the convection, and the complex circulation pattern will vary with time in a wider street canyon. However， in a narrow street canyon， just one vortex appears. With a light ambient wind, the bottom heating and the associated convection result in just one main vortex. As the ambient wind speed increases, the vortex becomes more organized and its center shifts closer to the leeward building.  相似文献   

孟加拉湾季风爆发对南海季风爆发的影响Ⅰ:个例分析   总被引：11，自引：4，他引：11       下载免费PDF全文

刘屹岷  陈仲良  毛江玉  吴国雄 《气象学报》2003,61(1):1-9

利用南海季风试验分析场和NCAR向外长波辐射通量(OLR)资料研究了1998年孟加拉湾季风和南海季风爆发期间副热带环流的大尺度和天气尺度特征,探讨了孟加拉湾季风爆发与南海季风爆发之间的物理联系及孟加拉湾季风气旋的对流凝结潜热释放对副热带高压“撤出”南海的影响。结果表明,1998年5月爆发的东亚季风展现出典型的从孟加拉湾地区东传发展到南海地区的过程。随着孟加拉湾季风爆发和对流活动增强、北移,南海北部出现了低层西风和对流活动,领先于副热带高压在南海地区减弱和撤退。结果还显示南海北部地区的对流凝结加热有助于该地区经向温度梯度的反转,在热成风关系的制约下南海上空副热带高压脊面的垂直倾斜由冬季型转向夏季型,季风爆发。  相似文献   

经纬向热源（汇）异常对环流影响的数值试验     

姚日升  唐东升 《南京气象学院学报》1997,20(3):348-354

利用１９８３￣１９８８／１９８９年６年季平均全球加热场资料，分析了各年相对于６年平均的距平沿经、纬向非均匀分布的特征。并且，基于加热异常沿经向表现为正负相间分布和沿纬向有几个加热异常中心的特征，利用定常态初始方程三维谐模式进行了加热异常沿经、纬向非均匀分布对环流影响的数值试验。结果表明，加热异常的经向非均匀分布显著增强了经向环流的异常，所引起的环流异常与几个孤立热源（汇）作用的结果的线性叠加有较大  相似文献   

华北地区煤的显微组分结焦性热台试验   总被引：1，自引：0，他引：1       下载免费PDF全文

康西栋  潘银苗 《地球科学》1997,22(2):181-184

为探讨煤的显微组分的结焦性，对不同变质程度煤的镜质组、壳质组和惰性组分别进行了显微镜热台加热试验．在加热过程中，活性组分经历了３个明显不同的变化阶段，即变形阶段、胶质体形成阶段以及固化阶段．随煤变质程度的增加，镜质组的初变温度和胶质体形成时的温度逐渐增大，而固结温度变化规律不明显；壳质组在低变质阶段因受热而挥发掉，但随煤级增高其变形程度减弱；半镜质组在受热过程中也有变形和少量胶质体形成，而惰性组只发生微弱变化．在低变质阶段，活性显微组分形成的焦炭显微结构以各向同性为主；随变质程度的增高，焦炭显微结构中各向异性成分比例增大  相似文献   

Influence of the zone of weakness on dip angle and shear heating of subducted slabs     

Martin Kuka?ka  Ctirad Matyska 《Physics of the Earth and Planetary Interiors》2004,141(4):243-252

We study the importance of the zones of weakness and the pattern of downgoing flow in steady-state models of subducting lithosphere, which interacts mechanically and thermally with the ambient mantle. The non-linear system of governing equations consists of (i) the momentum equation in stream function formulation and (ii) the steady-state heat transfer equation including conduction and advection of heat and dissipation. A finite element method has been applied to this system. We consider the viscosity to be a non-linear function of both the temperature and the stream function. In steady-state two-dimensional (2D) flow, the stream function isolines follow material trajectories. They are used to follow the top of the subducting slab, which because of its possible increase in water content, is assumed to have a lower viscosity. The zone of weakness has been thus obtained in the self-consistent fashion since the stream function as well as the temperature are the output from our modeling and no a priori assumptions about the shape of the bending lithosphere are taken into account. It was shown that several orders decrease of viscosity in the zone of weakness is required to obtain the dip angle of about 45°. If the decrease of viscosity is not sufficient enough, the subducted slab either sinks almost vertically or does not exhibit a plate-like behavior. We have also demonstrated that shear heating can unrealistically increase at the zone of weakness for fast subductions if decrease of viscosity is underestimated.  相似文献   

Seasonal Variation of the East Asian Subtropical Westerly Jet and Its Association with the Heating Field over East Asia   总被引：3，自引：0，他引：3  

KUANG Xueyuan  ZHANG Yaocun 《大气科学进展》2005,22(6):831-840

The structure and seasonal variation of the East Asian Subtropical Westerly Jet （EAWJ） and associations with heating fields over East Asia are examined by using NCEP/NCAR reanalysis data. Obvious differences exist in the westerly jet intensity and location in different regions and seasons due to the ocean-land distribution and seasonal thermal contrast, as well as the dynamic and thermodynamic impacts of the Tibetan Plateau. In winter, the EAWJ center is situated over the western Pacific Ocean and the intensity is reduced gradually from east to west over the East Asian region. In summer, the EAWJ center is located over the north of the Tibetan Plateau and the jet intensity is reduced evidently compared with that in winter. The EAWJ seasonal evolution is characterized by the obvious longitudinal inconsistency of the northward migration and in-phase southward retreat of the EAWJ axis. A good correspondence between the seasonal variations of EAWJ and the meridional differences of air temperature （MDT） in the mid-upper troposphere demonstrates that the MDT is the basic reason for the seasonal variation of EAWJ. Correlation analyses indicate that the Kuroshio Current region to the south of Japan and the Tibetan Plateau are the key areas for the variations of the EAWJ intensities in winter and in summer, respectively. The strong sensible and latent heating in the Kuroshio Current region is closely related to the intensification of EAWJ in winter. In summer, strong sensible heating in the Tibetan Plateau corresponds to the EAWJ strengthening and southward shift, while the weak sensible heating in the Tibetan Plateau is consistent with the EAWJ weakening and northward migration.  相似文献   

浓硫酸钠水溶液中的离子对          下载免费PDF全文

刘元会  房春晖 《盐湖研究》2005,13(4):42-46

不同浓度的Na2SO4水溶液的拉曼光谱显示了SO42-的四个拉曼活性带:980 cm-1处的SO42-的对称伸缩振动模式v1带,1 106 cm-1处的反对称伸缩振动模式v3带,448 cm-1处的变形振动模式v2带和617 cm-1处的变形振动模式v4带。482 cm-1处的肩膀峰是由于NaSO4-离子对的形成对448 cm-1的v2带的影响而形成的SO42-的一个新的振动峰。浓Na2SO4水溶液中,水共享离子对[Na+.H2O.SO42-]-是主要的离子对物种。随着Na2SO4水溶液浓度的增加,Na+和SO42-的相互作用增强,NaSO4-离子对所占的摩尔分数增加。  相似文献