Keys to gully formation processes on Mars: Relation to climate cycles and sources of meltwater     

Samuel C. Schon  James W. Head 《Icarus》2011,213(1):428-432

Advances in dating gullies on Mars using superposition relationships and a stratigraphic marker horizon link gully chronostratigraphy to recent climate cycles. New observations of gully morphology show the close association of gully source regions, channels, and fan deposits with well-documented ice-rich latitude-dependent mantle deposits, the deposition of which is interpreted to be coincident with recent ice ages. On the basis of these close correlations, we interpret the formative processes for mid-latitude gullies to involve melting of these ice-rich mantling deposits and the generation of an aqueous phase leading to fluvial activity. Continued monitoring of gullies by spacecraft in the current “interglacial” climate period (∼0.4 Ma to the present) will permit assessment of changing rates and styles of gully activity in the now largely depleted source areas.  相似文献   

Quantum chemical calculation on the potential energy surface of H₂CO₃ and its implication for martian chemistry     

Yu-Jong Wu  C.Y. Robert Wu 《Icarus》2011,214(1):228-235

A detailed theoretical study of the potential energy surface of H₂CO₃ is explored at the CCSD(T)//B3LYP/aug-cc-pVTZ level. On the potential energy surface, 12 isomers of H₂CO₃ are located. Their molecular properties such as geometries, vibrational frequencies, rotational constants, dipole moments, gas-phase acidities, and relative energies are calculated. Various reaction pathways and decomposition products have also been discussed. Among these products, CO₂ and H₂O are definitely the most favorable products with predominant abundance. Large energy barriers are predicted for other dissociation channels leading to the formation of oxygen, formaldehyde, and so on. These high energy channels are not important thermodynamically and kinetically, but they might occur in the presence of cosmic rays in astronomic environments. From the present work we suggest that chemical reactions between CO₂ and H₂O at the polar ice caps could be a potential source of H₂CO and O₂, in addition to the previously proposed mechanisms, i.e., the oxidation of methane and cosmic-ray-mediated production through the intermediate H₂CO₃. The results of the present work may provide useful data to improve our understanding of icy chemistry at the polar caps on Mars.  相似文献   

Redefinition of the crater-density and absolute-age boundaries for the chronostratigraphic system of Mars     

S.C. Werner  K.L. Tanaka 《Icarus》2011,215(2):603-607

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The thermal evolution of Mars as constrained by paleo-heat flows     

Javier Ruiz  Patrick J. McGovern  Valle López  Jean-Pierre Williams  Rosa Tejero 《Icarus》2011,215(2):508-517

Lithospheric strength can be used to estimate the heat flow at the time when a given region was deformed, allowing us to constrain the thermal evolution of a planetary body. In this sense, the high (>300 km) effective elastic thickness of the lithosphere deduced from the very limited deflection caused by the north polar cap of Mars indicates a low surface heat flow for this region at the present time, a finding difficult to reconcile with thermal history models. This has started a debate on the current heat flow of Mars and the implications for the thermal evolution of the planet. Here we perform refined estimates of paleo-heat flow for 22 martian regions of different periods and geological context, derived from the effective elastic thickness of the lithosphere or from faulting depth beneath large thrust faults, by considering regional radioactive element abundances and realistic thermal conductivities for the crust and mantle lithosphere. For the calculations based on the effective elastic thickness of the lithosphere we also consider the respective contributions of crust and mantle lithosphere to the total lithospheric strength. The obtained surface heat flows are in general lower than the equivalent radioactive heat production of Mars at the corresponding times, suggesting a limited contribution from secular cooling to the heat flow during the majority of the history of Mars. This is contrary to the predictions from the majority of thermal history models, but is consistent with evidence suggesting a currently fluid core, limited secular contraction for Mars, and recent extensive volcanism. Moreover, the interior of Mars could even have been heating up during part of the thermal history of the planet.  相似文献   

The influence of multivariate analysis methods and target grain size on the accuracy of remote quantitative chemical analysis of rocks using laser induced breakdown spectroscopy     

Ryan B. Anderson  Richard V. Morris 《Icarus》2011,215(2):608-627

Laser-induced breakdown spectroscopy (LIBS) was used to quantitatively analyze 195 rock slab samples with known bulk chemical compositions, 90 pressed-powder samples derived from a subset of those rocks, and 31 pressed-powder geostandards under conditions that simulate the ChemCam instrument on the Mars Science Laboratory Rover (MSL), Curiosity. The low-volatile (<2 wt.%) silicate samples (90 rock slabs, corresponding powders, and 22 geostandards) were split into training, validation, and test sets. The LIBS spectra and chemical compositions of the training set were used with three multivariate methods to predict the chemical compositions of the test set. The methods were partial least squares (PLS), multilayer perceptron artificial neural networks (MLP ANNs) and cascade correlation (CC) ANNs. Both the full LIBS spectrum and the intensity at five pre-selected spectral channels per major element (feature selection) were used as input data for the multivariate calculations. The training spectra were supplied to the algorithms without averaging (i.e. five spectra per target) and with averaging (i.e. all spectra from the same target averaged and treated as one spectrum). In most cases neural networks did not perform better than PLS for our samples. PLS2 without spectral averaging outperformed all other procedures on the basis of lowest quadrature root mean squared error (RMSE) for both the full test set and the igneous rocks test set. The RMSE for PLS2 using the igneous rock slab test set is: 3.07 wt.% SiO₂, 0.87 wt.% TiO₂, 2.36 wt.% Al₂O₃, 2.20 wt.% Fe₂O₃, 0.08 wt.% MnO, 1.74 wt.% MgO, 1.14 wt.% CaO, 0.85 wt.% Na₂O, 0.81 wt.% K₂O. PLS1 with feature selection and averaging had a higher quadrature RMSE than PLS2, but merits further investigation as a method of reducing data volume and computation time and potentially improving prediction accuracy, particularly for samples that differ significantly from the training set. Precision and accuracy were influenced by the ratio of laser beam diameter (∼490 μm) to grain size, with coarse-grained rocks often resulting in lower accuracy and precision than analyses of fine-grained rocks and powders. The number of analysis spots that were normally required to produce a chemical analysis within one standard deviation of the true bulk composition ranged from ∼10 for fine-grained rocks to >20 for some coarse-grained rocks.  相似文献   

On the statistical distribution of dust devil diameters     

Ralph Lorenz 《Icarus》2011,215(1):381-390

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The deep interior of Venus, Mars, and the Earth: A brief review and the need for planetary surface-based measurements     

Antoine Mocquet  Pascal Rosenblatt 《Planetary and Space Science》2011,59(10):1048-1061

A comparison of the internal structure of Earth-like planets is unavoidable to understand the formation and evolution of the solar system, and the differences between Earth’s, Mars’, and Venus’ atmospheres, surfaces and tectonic behaviors. Recent studies point at the role of core structure and dynamics in the evolution of the atmosphere, mantle and crust. On Earth, the crust thickness and the radius and physical state of the cores are known for almost one century, since the advent of seismological observations, but the lack of long-term surface-based geodetic, electromagnetic and seismological observations on the other planets, results in very large uncertainties on the crust thickness, on the temperature and composition of their mantle, and on the size and physical state of their cores. According to the currently available geodetic data, Mars’ dimensionless mean-moment-of-inertia ratio is equal to 0.3653±0.0008. When combined with geochemical observations and with the inputs of laboratory experiments on planetary materials at high pressure and high temperature, this result constrains a narrow range of density values for Mars’ mantle and favors a light [6200-6765 kg m⁻³] sulfur-rich core, but it still allows for a 1600-1750 km range for the core radius, i.e. an uncertainty at least ten times larger than the precision obtained in 1913 by Gutenberg for the Earth’s core. Mars’ mantle density distribution may be explained by a large range of temperatures and mineralogical compositions, either olivine- or pyroxene-rich. The unknown mean thickness of Mars’ crust makes necessary a number of working assumptions for the interpretation of gravimetric and magnetic data. The situation is worse for Venus, and the most conservative model of its deep interior is a transposition of the Earth’s structure scaled to Venus’ radius and mass. The temperature conditions at the surface of this planet hardly make possible long-term ground-based measurements, but this is indeed feasible at the surface of Mars. Precise measurements of Mars’ crust thickness, core radius and structure, and the proof of the existence or absence of an inner core, would put tight constraints on mantle dynamics and thermal evolution, and on possible scenarios leading to the extinction of Mars’ magnetic field about 4.0 Ga ago. Long-lasting surface-based geodetic, seismological and magnetic observations would provide this information, as well as the distributions as a function of depth of the density, elastic and anelastic parameters, and electrical conductivity. Current studies on the structure of Earth’s deep interior demonstrate that the latter data set, when constrained by laboratory experiments, may be inverted in terms of temperature, chemical, and mineralogical compositions.  相似文献   

Atmospheric chemistry on Venus, Earth, and Mars: Main features and comparison     

Vladimir A. Krasnopolsky 《Planetary and Space Science》2011,59(10):952-964

This paper deals with two common problems and then considers major aspects of chemistry in the atmospheres of Mars and Venus. (1) The atmospheres of the terrestrial planets have similar origins but different evolutionary pathways because of the different masses and distances to the Sun. Venus lost its water by hydrodynamic escape, Earth lost CO₂ that formed carbonates and is strongly affected by life, Mars lost water in the reaction with iron and then most of the atmosphere by the intense meteorite impacts. (2) In spite of the higher solar radiation on Venus, its thermospheric temperatures are similar to those on Mars because of the greater gravity acceleration and the higher production of O by photolysis of CO₂. O stimulates cooling by the emission at 15 μm in the collisions with CO₂. (3) There is a great progress in the observations of photochemical tracers and minor constituents on Mars in the current decade. This progress is supported by progress in photochemical modeling, especially by photochemical GCMs. Main results in these areas are briefly discussed. The problem of methane presents the controversial aspects of its variations and origin. The reported variations of methane cannot be explained by the existing data on gas-phase and heterogeneous chemistry. The lack of current volcanism, SO₂, and warm spots on Mars favor the biological origin of methane. (4) Venus’ chemistry is rich and covers a wide range of temperatures and pressures and many species. Photochemical models for the middle atmosphere (58-112 km), for the nighttime atmosphere and night airglow at 80-130 km, and the kinetic model for the lower atmosphere are briefly discussed.  相似文献   

Lidar atmospheric measurements on Mars and Earth     

C. Dickinson  J.A. Whiteway  M. Illnicki  W. Junkermann  J. Hacker 《Planetary and Space Science》2011,59(10):942-951

The LIDAR instrument operating from the surface of Mars on the Phoenix Mission measured vertical profiles of atmospheric dust and water ice clouds at temperatures around −65 °C. An equivalent lidar system was utilized for measurements in the atmosphere of Earth where dust and cloud conditions are similar to Mars. Coordinated aircraft in situ sampling provided a verification of lidar measurement and analysis methods and also insight for interpretation of lidar derived optical parameters in terms of the dust and cloud microphysical properties. It was found that the vertical distribution of airborne dust above the Australian desert is quite similar to what is observed in the planetary boundary layer above Mars. Comparison with the in situ sampling is used to demonstrate how the lidar derived optical extinction coefficient is related to the dust particle size distribution. The lidar measurement placed a constraint on the model size distribution that has been used for Mars. Airborne lidar measurements were also conducted to study cirrus clouds that form in the Earth’s atmosphere at a similar temperature and humidity as the clouds observed with the lidar on Mars. Comparison with the in situ sampling provides a method to derive the cloud ice water content (IWC) from the Mars lidar measurements.  相似文献   

Soil simulant sourcing for the ExoMars rover testbed     

Thibault P. Gouache  Nildeep Patel  Gregory P. Scott  Marcus Matthews 《Planetary and Space Science》2011,59(8):779-787

ExoMars is the European Space Agency (ESA) mission to Mars planned for launch in 2018, focusing on exobiology with the primary objective of searching for any traces of extant or extinct carbon-based micro-organisms. The on-surface mission is performed by a near-autonomous mobile robotic vehicle (also referred to as the rover) with a mission design life of 180 sols (Patel et al., 2010). In order to obtain useful data on the tractive performance of the ExoMars rover before flight, it is necessary to perform mobility tests on representative soil simulant materials producing a Martian terrain analogue under terrestrial laboratory conditions. Three individual types of regolith shown to be found extensively on the Martian surface were identified for replication using commercially available terrestrial materials, sourced from UK sites in order to ensure easy supply and reduce lead times for delivery. These materials (also referred to as the Engineering Soil (ES-x) simulants) are: a fine dust analogue (ES-1); a fine aeolian sand analogue (ES-2); and a coarse sand analogue (ES-3). Following a detailed analysis, three fine sand regolith types were identified from commercially available products. Each material was used in its off-the-shelf state, except for ES-2, where further processing methods were used to reduce the particle size range. These materials were tested to determine their physical characteristics, including the particle size distribution, particle density, particle shape (including angularity/sphericity) and moisture content. The results are analysed to allow comparative analysis with existing soil simulants and the published results regarding in situ analysis of Martian soil on previous NASA (National Aeronautics and Space Administration) missions. The findings have shown that in some cases material properties vary significantly from the specifications provided by material suppliers. This has confirmed the need for laboratory testing to determine the actual parameters to prove that standard geotechnical processes are indeed suitable. The outcomes have allowed the confirmation of each simulant material as suitable for replicating their respective regolith types.  相似文献