Mass movements in cave sediments: investigation of a ∼40,000-year-old guano mudflow inside the entrance of the Great Cave of Niah, Sarawak, Borneo     

A. P. Dykes 《Landslides》2007,4(3):279-290

The West Mouth of the Great Cave at Niah in Sarawak, northwest Borneo and the North Passage that leads to the West Mouth contain large deposits of guano. The main deposit, several metres thick in places, forms the sloping floor of the entire North Passage. A mass movement deposit identified in the West Mouth, having a volume of 600 m³, originated as a guano mudflow up the North Passage in the order of 40,000 years ago. This failure of the guano slope was investigated to determine whether particular conditions or events could be identified as the most likely causes. The physical, hydrological and geotechnical properties of samples of the material were determined so that the stability of the slope could be assessed. Stability analyses showed that shearing failure of the slope would require inputs of water to the slope in quantities for which no feasible explanation can be suggested. However, the properties of the guano are similar to those of loess, indicating a high susceptibility to ‘hydrocollapse’. Very shallow failure of the slope, possibly as several smaller mudflows, could therefore have occurred due to additional water in quantities that could realistically be supplied as rainwater spray, possibly with a seismic trigger. The climate must therefore have been wetter than it is at present. These findings have implications for the interpretation of sediment deposits in other relict caves.  相似文献   

Effective macroscopic transport parameters between parallel plates with constant concentration boundaries     

D.R. Webster  D.S. FeltonJ. Luo 《Advances in water resources》2007

A macroscopic transport model is developed, following the Taylor shear dispersion analysis procedure, for a 2D laminar shear flow between parallel plates possessing a constant specified concentration. This idealized geometry models flow with contaminant dissolution at pore-scale in a contaminant source zone and flow in a rock fracture with dissolving walls. We upscale a macroscopic transient transport model with effective transport coefficients of mean velocity, macroscopic dispersion, and first-order mass transfer rate. To validate the macroscopic model the mean concentration, covariance, and wall concentration gradient are compared to the results of numerical simulations of the advection–diffusion equation and the Graetz solution. Results indicate that in the presence of local-scale variations and constant concentration boundaries, the upscaled mean velocity and macrodispersion coefficient differ from those of the Taylor–Aris dispersion, and the mass transfer flux described by the first-order mass transfer model is larger than the diffusive mass flux from the constant wall. In addition, the upscaled first-order mass transfer coefficient in the macroscopic model depends only on the plate gap and diffusion coefficient. Therefore, the upscaled first-order mass transfer coefficient is independent of the mean velocity and travel distance, leading to a constant pore-scale Sherwood number of 12. By contrast, the effective Sherwood number determined by the diffusive mass flux is a function of the Peclet number for small Peclet number, and approaches a constant of 10.3 for large Peclet number.  相似文献   

Capillary pressure for the sand–CO₂–water system under various pressure conditions. Application to CO₂ sequestration     

W.-J. Plug  J. Bruining 《Advances in water resources》2007

Accurate modeling of storage of carbon dioxide (CO₂) in heterogeneous aquifers requires experiments of the capillary pressure as function of temperature and pressure. We present a method with which static drainage and imbibition capillary pressures can be measured continuously as a function of saturation at various temperature (T) and pressure (P) conditions. The measurements are carried out at (T, P) conditions of practical interest. Static conditions can be assumed as small injection rates are applied. The capillary pressure curves are obtained for the unconsolidated sand–distilled water–CO₂ system. The experimental results show a decrease of drainage and imbibition capillary pressure for increasing CO₂ pressures and pronounced dissolution rate effects for gaseous CO₂. Significant capillary pressure fluctuations and negative values during imbibition are observed at near critical conditions. The measurement procedure is validated by a numerical model that simulates the experiments.  相似文献   

黑龙江盘古-碧水韧性剪切带中段构造地球化学特征   总被引：3，自引：0，他引：3       下载免费PDF全文

李仰春  赵寒冬  韩伟民  李永秀  朱春艳 《地质科学》2001,36(2):144-151

盘古-碧水韧性剪切带中段糜棱岩的叠加强度和质量平衡分析表明:剪切带在变形过程中组分发生了显著的交换。糜棱岩类总体CaO、K₂O、SiO₂大量带入,TiO₂、MnO、FeO是带出的。随着糜棱岩化程度的提高,SiO₂、K₂O、MnO明显带入,CaO少量带出。以Al₂O₃守恒为限制条件,整个剪切带质量和体积增加了16.87%。大规模的物质带入带出发生在糜棱岩阶段。  相似文献   

质量平衡法——定量恢复新生代青藏高原造山作用   总被引：2，自引：0，他引：2  

向芳  王成善 《地球科学进展》2001,16(2):279-283

青藏高原的形成演化及其对东亚地形，水文分布，季风起源，全球气候变化，海洋化学组分改变等的影响，一直是全球地质学家关注的热点，然而由于定量研究方法的缺乏，一些关键性的问题一直悬而未决，质量平衡法的提出为解决这一困境提供了新思路，阐述了质量平衡法的原理，并以Metivier等对西藏高原地区，东亚，印度支那和印度板块地区的研究为例，介绍了质量平衡法的应用，同时对存在的问题进行了较为详细的讨论，为进一步研究指明了重点。  相似文献   

不同方案求解非线性化学动力学方程组的比较   总被引：1，自引：0，他引：1       下载免费PDF全文

王体健  李宗恺 《应用气象学报》1996,7(4):466-472

在一个简化的气相化学模式的基础上，比较了Ｈｙｂｒｉｄ、ＱＳＳＡ、Ｓｋｌａｒｅｗ三种计算方案求解非线性化学动力学方程组的差异，并引入误差分配和线性组合两种质量守恒技术，分析它们对模拟结果的影响．研究结果表明：不同方案对有机烃类浓度的计算几乎没有影响，但对其它气态物浓度有一定的影响．用ＱＳＳＡ和Ｓｌａｒｅｗ方案预测的结果更为相近，而采用Ｈｙｂｒｉｄ方案得到的气态物浓度的平衡时间略为提前．从计算效率来看，ＱＳＳＡ方案优于其它两种方案，两种质量守恒技术均能改善模拟结果．  相似文献   

The transformation and export of phosphorus from Wetlands     

Jim Gehrels  George Mulamoottil 《水文研究》1989,3(4):365-370

There is widespread acceptance of the phosphorus retention capability of wetlands even though research findings are often inconclusive and contradictory. The results of a one year phosphorus budget study indicate that internal wetland processes may transform sediment bound phosphorus to plant available orthophosphorus. While total phosphorus imports were nearly double the total phosphorus exports for the study wetland, orthophosphorus exports were 22 per cent greater than imports. This study supports the recent finding that wetlands have limited capability to retain orthophosphorus and indicates that wetlands may even increase the export of orthophosphorus. The generally accepted nutrient retention function of wetlands and their possible role in eutrophication is thus questionable.  相似文献   

Meso-scale testing and development of test procedures to maintain mass balance     

Bonner J  Page C  Fuller C 《Marine pollution bulletin》2003,47(9-12):406-414

The Conrad Blucher Institute for Surveying and Science (Texas A&M University––Corpus Christi) has conducted numerous petroleum experiments at the Shoreline Environmental Research Facility (Corpus Christi, Texas, USA). The meso-scale facility has multiple wave tanks, permitting some control in experimental design of the investigations, but allowing for real-world conditions. This paper outlines the evolution of a materials balance approach in conducting petroleum experiments at the facility. The first attempt at a materials balance was during a 1998 study on the fate/effects of dispersant use on crude oil. Both water column and beach sediment samples were collected. For the materials balance, the defined environmental compartments for oil accumulation were sediments, water column, and the water surface, while the discharge from the tanks was presumed to be the primary sink. The “lessons learned” included a need to quantify oil adhesion to the tank surfaces. This was resolved by adhering strips of the polymer tank lining to the tank sides that could be later removed and extracted for oil. Also, a protocol was needed to quantify any floating oil on the water surface. A water surface (oil slick) quantification protocol was developed, involving the use of solid-phase extraction disks. This protocol was first tested during a shoreline cleaner experiment, and later refined in subsequent dispersant effectiveness studies. The effectiveness tests were designed to simulate shallow embayments which created the need for additional adjustments in the tanks. Since dispersant efficacy is largely affected by hydrodynamics, it was necessary to scale the hydrodynamic conditions of the tanks to those expected in our prototype system (Corpus Christi Bay, Texas). The use of a scaled model permits the experiment to be reproduced and/or evaluated under different conditions. To minimize wave reflection in the tank, a parabolic wave dissipater was built. In terms of materials balance, this design reduced available surface area as a sink for oil adsorption.  相似文献   

Characteristics and formation causes of Qingdao Cold Water Mass   总被引：2，自引：0，他引：2  

张启龙  刘兴泉  程明华  于新胜 《中国海洋湖沼学报》2002,20(4):303-308

In this work,the main characteristics of the Qingdao Cold Water Mass were studied by using“the comparison analysis method”based on 1980 temperature,salinity and dissolved oxygen data on the western South Yellow Sea.The formation cause of the water mass was analyzed based on February of 1959 temperature and salinity data for this area and on some other authors’studies.The results showed that the Qingdao Cold Water Mass has growing and vanishing processes：appears in the last ten days of March;has stable pattern in April;is biggest in its area in May;becomes small in its area in June;vanishes in July.It comes from the northem Shandong Coastal Water and is characterized by low temperature and salinity and high disolved oxygen.The mass is formed under the joint effects of anticyclonic circulation and solar radiation.  相似文献   

Alternative Validation of a LC-MS/MS-Multi-Method for Pesticides in Drinking Water     

Alexander Müller  Dirk Flottmann  Wolfgang Schulz  Wolfram Seitz  Walter H. Weber 《洁净——土壤、空气、水》2007,35(4):329-338

The development of instrumental analytics such as the LC-MS/MS has made it possible to quickly determine many component concentrations in a single chromatogram. However, the validation of such multi-methods needs new strategies for robustness and optimization. Statistical execution of analytical tests is one tool that can be utilized to meet this requirement. A Central Composite Design (CCD) was utilized for the validation of an LC-MS/MS multi-method for 84 analytes. The experimental design includes six design variables and two non-design variables (response variables). Concentration, ionization temperature, dwell time, gradient, flow (of eluent), and spraying/curtain gas (continuous design variables) were varied on five different levels; the whole design encompassed 91 runs. To investigate the robustness of a LC-MS/MS method both peak sensitivity and chromatographic separation had to be verified. Therefore, two non-design variables were necessary. The distribution of the peaks over analysis time was applied to describe the quality of the chromatographic separation. The sensitivity was described with the signal to noise ratio (S/N). The evaluation of the measured data was accomplished with the Analysis of Variance (ANOVA) and the Response Surface Methodology (RSM). Three main effects (concentration, ionization temperature, dwell time) and no significant interaction effect were found for the response variable “S/N”. The variables of concentration, ionization temperature, and dwell time had no significant effects for the response variable “S/N”. The ANOVA of the response variable chromatographic separation abandoned no significant effects as well. Therefore, robustness of the method can be guaranteed for all non significant design variables.  相似文献