Behaviour of REE and mass balance calculations in a lateritic profile over chlorite schists in South Cameroon     

Veronique Kamgang Kabeyene Beyala  Estelle Ndome Effoudou Priso  Georges Emmanuel Ekodeck 《Chemie der Erde / Geochemistry》2009,69(1):61-13

An in situ weathering profile overlying chlorite schists in the Mbalmayo-Bengbis formations (South Cameroon) was chosen for the study of the behaviour of REE and the evaluation of geochemical mass balance. After physical and mineralogical studies, the chlorite schists and the undisturbed weathered materials were chemically analyzed for major elements (X-ray fluorescence and titrimetry) and REE (ICP-MS). The behaviour of the REE in the Mbalmayo weathering system was established in comparison with the REE of the reference parent rock. Mass balance calculations were applied to both major elements and REE. The mineralogy of the materials was determined with the aid of a Philips 1720, diffractometer. The chlorite schists of the Mbalmayo sector show low REE contents (Σ=153.44 ppm). These rocks are relatively rich in LREE (about 125 times the chondritic value) and relatively poor in HREE (about 20 times the chondritic value). The REE diagram normalized to chondrites shows a slightly split graph ((La/Yb)_N=6.18) with marked enrichment in LREE (LREE/HREE=9.50) in relation to HREE. Moreover, these spectra do not present any Ce anomaly, but a slightly positive Eu anomaly. The imperfectly evolved profile, whose materials are genetically linked, shows an atypical behaviour of REE. In effect, the LREE are more mobile than the HREE during weathering ((La/Yb)NASC<1) with weak Ce anomalies. This has been rarely reported in lateritic profiles characterized by higher HREE mobility than LREE during weathering processes with high Ce anomalies. This is either due to the difference in the stability of REE-bearing minerals, or to the weak acidic to basic pH conditions (6.70<pH<7.80), or even due to the average evolution of the weathering materials. The pathway of the REE along the profile is as follows: (1) leaching in the saprolites and summit of the profile, except for Ce, which precipitates very weakly in the nodular materials and the coarse saprolite materials, (2) at the base of the profile, solutions come in contact with chlorite schist formations, at this level, the pH increases (pH=7.79), HREE and a part of LREE partially void of Ce precipitate and (3) the other part of LREE precipitates further up in the profile. The geochemical mass balance calculations reveal that these elements are leached in the same phases as the relatively high Si, Al, K and Fe²⁺ contents.  相似文献   

Atlantic Water flow through the Barents and Kara Seas   总被引：2，自引：0，他引：2  

Ursula Schauer  Harald Loeng  Bert Rudels  Vladimir K. Ozhigin  Wolfgang Dieck 《Deep Sea Research Part I: Oceanographic Research Papers》2002,49(12)

The pathway and transformation of water from the Norwegian Sea across the Barents Sea and through the St. Anna Trough are documented from hydrographic and current measurements of the 1990s. The transport through an array of moorings in the north-eastern Barents Sea was between 0.6 Sv in summer and 2.6 Sv in winter towards the Kara Sea and between zero and 0.3 Sv towards the Barents Sea with a record mean net flow of 1.5 Sv. The westward flow originates in the Fram Strait branch of Atlantic Water at the Eurasian continental slope, while the eastward flow constitutes the Barents Sea branch, continuing from the western Barents Sea opening.About 75% of the eastward flow was colder than 0°C. The flow was strongly sheared, with the highest velocities close to the bottom. A deep layer with almost constant temperature of about −0.5°C throughout the year formed about 50% of the flow to the Kara Sea. This water was a mixture between warm saline Atlantic Water and cold, brine-enriched water generated through freezing and convection in polynyas west of Novaya Zemlya, and possibly also at the Central Bank. Its salinity is lower than that of the Atlantic Water at its entrance to the Barents Sea, because the ice formation occurs in a low salinity surface layer. The released brine increases the salinity and density of the surface layer sufficiently for it to convect, but not necessarily above the salinity of the Atlantic Water. The freshwater west of Novaya Zemlya primarily stems from continental runoff and at the Central Bank probably from ice melt. The amount of fresh water compares to about 22% of the terrestrial freshwater supply to the western Barents Sea. The deep layer continues to the Kara Sea without further change and enters the Nansen Basin at or below the core depth of the warm, saline Fram Strait branch. Because it is colder than 0°C it will not be addressed as Atlantic Water in the Arctic Ocean.In earlier decades, the Atlantic Water advected from Fram Strait was colder by almost 2 K as compared to the 1990s, while the dense Barents Sea water was colder by up to 1 K only in a thin layer at the bottom and the salinity varied significantly. However, also with the resulting higher densities, deep Eurasian Basin water properties were met only in the 1970s. The very low salinities of the Great Salinity Anomaly in 1980 were not discovered in the outflow data. We conclude that the thermal variability of inflowing Atlantic water is damped in the Barents Sea, while the salinity variation is strongly modified through the freshwater conditions and ice growth in the convective area off Novaya Zemlya.  相似文献   

Orbital effects of non-isotropic mass depletion of the atmospheres of evaporating hot Jupiters in extrasolar systems     

Lorenzo Iorio 《New Astronomy》2012,17(3):356-361

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Further confirmations of mass transfer in Algol type binary U Sagittae     

Davood Manzoori 《Astrophysics and Space Science》2008,313(4):339-344

This paper describes how a new photometric V light curve solution of Algol type binary U Sge was obtained using Wilson–Devinney code. I also discuss how the physical and orbital parameters, along with absolute dimensions of the system, were determined. The Roche lobe configurations of the system indicate that the secondary component has filled its Roche lobe and therefore is losing mass at the rate of 6.15×10⁻⁷ M _sun yr⁻¹. The conservative mass flow is the most likely process in this system.  相似文献   

内蒙古东部春季三类沙尘天气气溶胶散射系数及其与PM10、能见度相关性分析   总被引：3，自引：0，他引：3  

王天舒  牛生杰 《大气科学》2017,41(1):121-131

利用内蒙古东胜、锡林浩特两站2004~2006年春季（3~5月）积分浊度计的观测资料,结合同期PM10质量浓度、大气能见度等资料,分析了背景、扬沙、沙尘暴、强沙尘暴等不同强度沙尘天气气溶胶散射系数的分布特征,讨论了不同强度沙尘天气过程中散射系数、PM10、能见度的日变化规律,以及不同强度沙尘天气过程中散射系数与PM10质量浓度、散射系数与能见度的相关关系。结果表明:散射系数能够很好地反映沙尘天气强度;随沙尘天气强度增强,散射系数日变化从双峰型向单峰型转变;沙尘天气强度较弱时,PM10与散射系数的日变化不相似,强沙尘暴过程中PM10与散射系数的日变化有一定的相似性;能见度与散射系数日变化趋势相反;散射系数与PM10质量浓度呈正相关性,沙尘天气越强,相关性越好,背景、扬沙、沙尘暴、强沙尘暴相关系数分别为0.201、0.809、0.898和0.953;散射系数与能见度有指数相关关系,随沙尘天气强度增强二者相关性逐渐增强,背景、扬沙、沙尘暴、强沙尘暴相关系数分别为-0.773、-0.870、-0.918和-0.940。  相似文献   

雷暴大风过程中对流层中低层动量通量和动能通量输送特征研究   总被引：2，自引：0，他引：2  

张琳娜  冉令坤  李娜  杜佳  周璇  孟悦 《大气科学》2018,42(1):178-191

2014年5月31日北京发生一次雷暴大风过程。以雷达资料同化结果为初始场,对此次过程进行高分辨率数值模拟。采用非静力平衡和非地转平衡的经向动量方程和质量权重动能方程,利用模拟资料,对雷暴大风过程中经向动量和质量权重动能进行收支分析,以此来研究雷暴过程中对流层中低层动量通量和动能通量输送特征,讨论地面大风的可能成因。分析结果表明,在对流层中低层,经向动量通量散度是影响经向动量局地变化的主要强迫项。雷暴系统后部的入流把中低层的经向动量倾斜向下输送,系统前部对流云区中低层的下沉气流也向下输送经向动量。这两支下传动量通量先后与近地面经向动量的水平通量汇合,向系统前沿输送经向动量。在北京西北部地形阻挡作用下,经向动量通量在系统前端近地面辐合,促进那里的经向动量局地增长,有利于增强那里的南风。质量动能收支的特征与经向动量收支类似,在近地面层质量动能的局地变化主要是由质量动能通量散度引起的。系统后部入流把中层质量动能向下传输到近地面层,然后与近地面质量动能的水平通量汇合,向系统前沿输送质量动能。相对来说,近地面层经向动量和质量动能的水平通量比下传通量更重要,这主要与低层较强的东南急流有关。  相似文献   

Inferring Glacier Mass Balance Using Radarsat: Results From Peyto Glacier, Canada     

Michael Demuth  & Alain Pietroniro 《Geografiska Annaler: Series A, Physical Geography》1999,81(4):521-540

The capability of RADARSAT synthetic aperture radar (SAR) for the purpose of snow-line/accumulation area mapping for a temperate alpine glacier is examined. In agreement with other orbital C-band SAR studies, RADARSAT can discriminate between firn and bare ice facies. Limited observations are reported with respect to the electromagnetic variability of the ice facies in the ablation area, but they are inconclusive. Operational considerations are discussed with respect to reconciling the uncertainties of late-summer weather and their possible impact on the dielectric and scattering properties of the glacier surface. Vagaries associated with other glacier settings, mass balance states and their associated facies configurations are discussed including the difficulty of using the transient snow-line to define the equilibrium line and the lower extent of the accumulation area for glaciers where superimposed ice may form.
The radar remote-sensing reconnaissance of equilibrium line altitude (ELA) and accumulation area ratio (AAR) for estimating glacier mass balance requires serious consideration in those instances where traditional ground measurements used in the direct glaciological method are absent. However, with respect to the ELA, such estimates can vary depending on the accuracy of the reference digital elevation information. Moreover, for many glacier configurations, where mass balance variations due to altitude are influenced or in some cases completely masked by local balance variations, defining the ELA may be an irreconcilable problem. Using the AAR may be more robust in this regard. It is further determined that the total error inherent in the reconnaissance method would have serious implications for the confident estimation of mass balance normals and climate-related trends if the method were to be utilized over the longer term.  相似文献   

Annual Mass Balance of Blue Glacier, USA: 1955–97     

H. Conway  L.A. Rasmussen  & H.-P. Marshall 《Geografiska Annaler: Series A, Physical Geography》1999,81(4):509-520

Mass changes of Blue Glacier, USA are calculated from topographic maps made from vertical aerial photography in late summer of 1939, 1952, 1957, and 1987, along with laser altimetry flown in June 1996. Changes in elevation between maps were adjusted for seasonal variations in the snow cover, and to account for the ablation between the date of photography and 1 October. Topography obtained from the laser altimetry was adjusted for snow thickness and glacier motion to estimate topography of 1 October 1995. The mass of Blue Glacier has changed less than 7 m (water equivalent) during this 56 year period which is minor compared with other glaciers in the region and elsewhere in the world. Glacier-average annual mass balances, beginning in 1956, have been calculated either from stake measurements and probing of late-season snow, or from a regression analysis using late-season measurements of the equilibrium line altitude. A comparison with the changes derived from surface maps shows values obtained from field measurements are too positive by about 0.4 m a^?1 , indicating that considerable caution is needed when interpreting time series of mass balance. Two alternative time series of mass balance consistent with the long-term mass changes are created by making simple adjustments: (1) a single constant is subtracted from each value so that the series is consistent with the 1957–95 mass change; (2) one constant is subtracted from each value over 1957–87 and another is subtracted from each value over 1987-95 so that the series is consistent with both the 1957–87 and 1987–95 mass changes. The mass balance of Blue Glacier was generally positive until the mid-1970s and negative since. The fluctuations of mass balance closely resemble those of snowfall on the glacier as estimated from the joint distribution of temperature and precipitation. The climate in western Washington was cooler and wetter during the decade before the mid-1970s, but the trend since has been towards warmer and drier conditions.  相似文献   

Analysis of Winter and Summer Glacier Mass Balances     

Mark B. Dyurgerov  & Mark F. Meier 《Geografiska Annaler: Series A, Physical Geography》1999,81(4):541-554

Seasonal mass balance components b_w (winter balance) and b_s (summer balance) as well as c_t (total accumulation) and a_t (total ablation), can be used directly to infer climate variables. In contrast, a_c (net balance of the accumulation area) and a_a (net balance of the ablation area), and b_a or b_n (annual or net balance) can not. The traditional Alpine system of observations of a_c and a_a , however, can be converted to true seasonal values b_w and b_s if both pairs of components are simultaneously observed for some years, because a correlation between the two pairs of components exists. We analyzed b_w and b_s data and their mean, standard deviations and ratios of these to the corresponding net or annual balances for 50 glaciers with relatively long records representing different regions in the northern hemisphere. We also investigated correlations between seasonal components. A negative correlation between b_w and b_s exists at many glaciers. About two-thirds of the glaciers show insignificant correlations (?0.3 < r < 0.3), implying independence of summer and winter balances. In a few unusual cases the correlations are positive. These different correlations, or lack thereof, may offer insight into feedback conditions that must exist in this climate-related system. The correspondence of the b_w and c_t , and b_s and a_t , appears to depend largely on the relative amounts of summer snowfall, a function of their climatic environment expressed as [α = (b_w+b_s)/2]. The contribution of variability of b_s to the net balance increases markedly with decreasing values of α. The variability of b_w and b_s , and therefore the net balance, has been increasing with time; whether this is due to an increase in climate variability or to other causes is not clear. It appears that b_w has been increasing with time at the highest altitudes, but b_s has been increasing more rapidly especially at low altitudes; the many-glacier average net balance is becoming more negative.  相似文献   

Modeling pollutant migration in the Upper Palar River Basin, Tamil Nadu, India     

M. Thangarajan 《Environmental Geology》1999,38(3):209-222

 Palar River Basin, a crystalline rock region in North Arcot District (Tamil Nadu), India, possesses vast groundwater potential along and near the river course and its lands are fertile. Serious contamination of both surface water and groundwater has been reported in this basin as a result of uncontrolled discharge of untreated effluents by the tanning industries for the last three decades. The health of the rural farming community and people working in the tanning industries has been seriously affected and they are suffering from occupational diseases such as asthma, chromium ulcers and skin diseases. About an 11000 hectares area of fertile land has lost its fertility. Total dissolved solids (TDS) concentration in groundwater at some pockets varies from 3000 to 10000 mg/l. As the discharge of effluents is continuing, a prognosis of further pollutant migration is carried out using a mathematical model. A numerical model of the Upper Palar River Basin was developed using the finite difference technique coupled with method of characteristics and used to predict TDS migration for the next 20 years. Sensitivity analysis was carried out to identify the parameters which are influencing the contaminant migration. Sensitivity analysis shows that advection and not dispersion is the predominant mode of solute migration in Palar Basin. Prognosis using the model confirms that the polluted area zone as well as the concentration of pollutants in the groundwater will continue to increase in future. The study also indicated that even if the pollutant sources are reduced to 25% of the present level, the TDS concentration level in the groundwater, even after 20 years, will not be reduced below 50% of its 1992 level. Received: 20 June 1998 · Accepted: 26 October 1998  相似文献