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21.
R.G. Mayne  J.M. Sunshine  S.J. Bus 《Icarus》2011,214(1):147-160
High quality VNIR spectra of 15 Vestoids, small asteroids that are believed to originate from Vesta, were collected and compared to laboratory spectra and compositional data for selected HED meteorites. A combination of spectral parameters such as band centers, and factors derived from Modified Gaussian Model fits (band centers, band strengths, calculation of the low to high-Ca pyroxene ratio) were used to establish if each Vestoid appeared most like eucrite or diogenite material, or a mixture of the two (howardite). This resulted in the identification of the first asteroid with a ferroan diogenite composition, 2511 Patterson. This asteroid can be used to constrain the size of diogenite magma chambers within the crust of Vesta. The Vestoids indicate that both large-scale homogeneous units (>5 km) and smaller-scale heterogeneity (<1 km) exist on the surface of Vesta, as both monomineralogic (eucrite or diogenite material alone) and mixed (both eucrite and diogenite) spectra are observed. The small-scale of the variation observed within the Vestoid population is predicted by the partial melting model, which has multiple intrusions penetrating into the crust of Vesta. It is much more difficult to reconcile the observations here with the magma ocean model, which would predict much more homogeneous layers on a large-scale both at the surface and with depth.  相似文献   
22.
Optical constants in a broad temperature and wavelength range are important input parameters in radiative transfer models used in studies of planetary atmospheres. In the laboratory, the refractive index values of ices at the HeNe laser wavelength (632.8 nm) are often used to monitor the growth rate and thickness of ice films. In this report we present laboratory measurements determining the refractive index at 632.8 nm of ammonia and hydrocarbon ices in the temperature range 80-100 K. Thin ice films are vapor-deposited on a cryogenically cooled mirror located inside a high-vacuum apparatus. The real component of the refractive index of these ice films is determined by a two-angle interferometric technique. Optical modeling calculations of the transmittance and reflectance through the thin ice films assist in the interpretation of the experimental results. We discuss our results and compare them with other measurements available in the literature. The results reported here are relevant to the spectroscopy of icy objects in the solar system; they are needed to perform laboratory characterization of ices, derive optical constants, and model spectra.  相似文献   
23.
The surface composition of Europa is of great importance for understanding both the internal evolution of Europa and its putative ocean. The Near Infrared Mapping Spectrometer (NIMS) investigation on Galileo observed Europa and the other Galilean satellites from 0.7 to 5.2 μm with spatial resolution down to a few kilometers during flybys by the spacecraft as it orbited Jupiter. These data have been analyzed and results published over the life of the Galileo mission and afterward. One result was the discovery of hydrated minerals at some locations on Europa and Ganymede. The data are noisy, especially for Europa, due to radiation affecting the NIMS electronics and detectors, and other artifacts are also present. The NIMS data are now being reprocessed using the accumulated knowledge gained over the entire missions to remove noise spikes and compensate for some other defects in the data. We are analyzing these reprocessed data in an attempt to defined better the nature of the hydrate spectral features and improve their interpretation. We report here on analyses of two NIMS reprocessed observations for the 0.7-3-μm region. A revised hydrate spectrum is calculated and mapped in detail across two lineaments. The spectrum shows the expected distorted water features but little or no spectral structure in these features. A narrow, weak spectral feature appears at 1.344 μm, which is weakly correlated with lower albedo. Several other weak features may be present but are difficult to confirm in these limited data sets. The hydrate signature shows the greatest strength within and toward the center of the lineaments, confirming and strengthening the association of the hydrate with these endogenic features. This trend may indicate that the material in the lineaments is youngest toward the center and has more water frost coverage toward the edge. A small, visually dark, circular feature has a spectrum that shows both hydrate and crystalline water ice features and perhaps contains a hydrate different in spectral characteristics and perhaps composition than found in the lineament.  相似文献   
24.
The region surrounding the Mawrth Vallis outflow channel on Mars hosts thick layered deposits containing diverse phyllosilicate minerals. Here we report detection of the Ca-sulfate bassanite on the outflow channel floor, requiring a more complex aqueous chemistry than previously inferred for this region. The sulfate-bearing materials underlie phyllosilicate-bearing strata, and provide an opportunity for testing proposed models of martian geochemical evolution with a future landed mission.  相似文献   
25.
The Viking missions to Mars failed to detect any organic material in regolith samples. Since then, several removal mechanisms of organic material have been proposed. Two of these proposed methods are removal due to exposure to plasmas created in dust devils and exposure to UV irradiation. The experiments presented here were performed to identify similarities between the two potential removal mechanisms and to identify any compounds produced from these mechanisms that would have been difficult for the Viking instruments to detect. Five organic compounds, phenanthrene, octadecane, octadecanoic acid, decanophenone and benzoic acid, were exposed to a glow discharge plasma created in simulated martian atmospheres as might be present in dust devils, and to UV irradiation similar to that found at the surface of Mars. Glow discharge exposure was carried out in a chamber with 6.9 mbar pressure of a Mars like gas composed mostly of carbon dioxide. The plasma was characterized using emission spectroscopy and found to contain cations and excited neutral species including carbon dioxide, carbon monoxide, and nitrogen. UV irradiation experiments were performed in a Mars chamber which simulates the temperature, pressure, atmospheric composition, and UV fluence rates of equatorial Mars. The non-volatile residues left after each exposure were characterized by mass loss, infrared spectroscopy and high resolution mass spectrometry. Oxidized, higher molecular weight versions of the parent compounds containing carbonyl, hydroxyl and alkenyl functional groups were identified. The presence of these oxidized compounds suggests that searches for organic material in soils on Mars use instrumentation suitable for detection of compounds which contain the above functional groups. Discussions of possible reaction mechanisms are given.  相似文献   
26.
The Thermal Emission Imaging System (THEMIS) has provided the highest spatial resolution (100 m/pixel) thermal infrared (TIR) data of the surface of Mars to date. These data have enabled the discovery of many small-scale compositional units and helped to better constrain surface processes operating at these scales. However, with higher-resolution visible (VIS) instruments revealing smaller-scale surficial differences, there exists a need to detect and map compositional variability using TIR data at scales below 100 m. Because it is unlikely there will be a higher-resolution TIR instrument sent to Mars in the near future, creative image processing techniques commonly classified under the umbrella of “super-resolution” can be employed to improve or enhance the spatial resolution of the THEMIS TIR data. These approaches typically integrate another higher-resolution dataset and can either be qualitative for visual appeal, quantitative for data accuracy, or some combination of both. The super-resolution approach presented here produces enhanced TIR images that are radiometrically accurate, but also visually appealing. For the technique to be successfully applied, multi- to hyper-spectral data from two different spectral regions are required (e.g., the THEMIS TIR and VIS datasets). The focus here is to introduce this new super-resolution methodology and demonstrate its ability using existing THEMIS IR and VIS data. The quartzofeldspathic deposit in northern Syrtis Major was selected because of the spectral variability detected using the original IR resolution data and to better constrain the relationship between the small-scale surface morphology and areal extent of the deposit as well as its formation process. Despite being associated with the central peaks of two craters, the results here show no positive correlation between the small rocky outcrops and the quartzofeldspathic unit. A gradational contact exists between the unit and basaltic sands within the intercrater eolian material. The super-resolution approach offers an alternative approach to traditional sub-pixel deconvolution identification and provides a higher-resolution IR dataset for thermophysical and spectral analysis on Mars.  相似文献   
27.
Extensive regions of low-density cometary comae are characterized by important deviations from the Maxwell-Boltzmann velocity distribution, i.e. breakdown of thermodynamic equilibrium. The consequences of this on the shapes of emission and absorption lines, and for the acceleration of solid bodies due to gas drag, have rarely been investigated.These problems are studied here to aid in the development of future coma models, and in preparation for observations of Comet 67P/Churyumov-Gerasimenko from the ESA Rosetta spacecraft. Two topics in particular, related to Rosetta, are preparation for in situ observations of water, carbon monoxide, ammonia, and methanol emission lines by the mm/sub-mm spectrometer MIRO, as well as gas drag forces on dust grains and on the Rosetta spacecraft itself.Direct Simulation Monte Carlo (DSMC) modeling of H2O/CO mixtures in spherically symmetric geometries at various heliocentric distances are used to study the evolution of the (generally non-Maxwellian) velocity distribution function throughout the coma. Such distribution functions are then used to calculate Doppler broadening profiles and drag forces.It is found that deviation from thermodynamic equilibrium indeed is commonplace, and already at 2.5 AU from the Sun the entire comet coma displays manifestations of such breakdown, e.g., non-equal partitioning of energy between kinetic and rotational modes, causing substantial differences between translational and rotational temperatures. We exemplify how deviations from thermodynamic equilibrium affect the properties of Doppler broadened line profiles. Upper limits on the size of liftable dust grains as well as terminal grain velocities are presented. Furthermore, it is demonstrated that the drag-to-gravity force ratio is likely to decrease with decreasing cometocentric distance, which may be of relevance both for Rosetta and for the lander probe Philae.  相似文献   
28.
We present values from the Cassini Visual and Infrared Mapping Spectrometer (VIMS) of four fundamental disk-integrated spectrophotometric properties (bolometric Bond albedo, solar phase curve, phase integral, and geometric albedo at 7-15 different wavelengths in the λ = 0.35-5.1 μm range) for five mid-sized saturnian icy satellites: Rhea, Dione, Tethys, Mimas, and Enceladus. These values, which include data from the period 2004-2008 and add to past VIMS phase curves, include opposition surge effects at down to fractions of a degree in solar phase angle for several moons and extend to over double the solar phase angle coverage of the Voyager mission. We also present new rotational light curves for Rhea and Dione at 7 near-infrared bands not previously available in ground-based or spacecraft studies. The bolometric Bond albedos we derive are as follows: 0.48 ± 0.09 (Rhea), 0.52 ± 0.08 (Dione), 0.61 ± 0.09 (Tethys), 0.67 ± 0.10 (Mimas), and 0.85 ± 0.11 (Enceladus). We also provide breakdowns of the major photometric quantities in both leading and trailing hemispheres. These refined parameters can be used to construct future bolometric Bond albedo maps that will contribute to surface composition identification studies, as well as models of volatile transport and sublimation. Through such applications, these data will help to determine the physical properties of surface particles, how the E-ring affects the inner saturnian moons, what is responsible for the dark albedo patterns seen on Tethys, and if these moons (e.g., Dione) are geologically active.  相似文献   
29.
J. Warell  B.J.R. Davidsson 《Icarus》2010,209(1):164-178
An implementation of Hapke’s radiative transfer-based photometric model for light scattering in semi-transparent porous media is presented with special emphasis on the analysis of reflectance spectra of Mercury. The model allows intimate mixing of an arbitrary number of regolith components with varying modal abundances, modal chemistries and grain sizes, matured by microphase iron. Reflectance spectra of suites of silicates of varying grain sizes and chemistries are used to calculate the imaginary coefficient of the complex index of refraction as a function of chemistry, thus limiting the modeling effects of chemically atypical laboratory samples, and allowing controlled modeling of minerals with varying chemical compositions. The performance of the model in the visual to near-infrared wavelength range is evaluated for a range of chemically characterized silicate mixtures of terrestrial powders, meteorite powders, matured lunar return samples, and remotely sensed lunar spectra.  相似文献   
30.
We apply a multivariate statistical method to Titan data acquired by different instruments onboard the Cassini spacecraft. We have searched through Cassini/VIMS hyperspectral cubes, selecting those data with convenient viewing geometry and that overlap with Cassini/RADAR scatterometry footprints with a comparable spatial resolution. We look for correlations between the infrared and microwave ranges the two instruments cover. Where found, the normalized backscatter cross-section obtained from the scatterometer measurement, corrected for incidence angle, and the calibrated antenna temperature measured along with the scatterometry echoes, are combined with the infrared reflectances, with estimated errors, to produce an aggregate data set, that we process using a multivariate classification method to identify homogeneous taxonomic units in the multivariate space of the samples.In medium resolution data (from 20 to 100 km/pixel), sampling relatively large portions of the satellite’s surface, we find regional geophysical units matching both the major dark and bright features seen in the optical mosaic. Given the VIMS cubes and RADAR scatterometer passes considered in this work, the largest homogeneous type is associated with the dark equatorial basins, showing similar characteristics as each other on the basis of all the considered parameters.On the other hand, the major bright features seen in these data generally do not show the same characteristics as each other. Xanadu, the largest continental feature, is as bright as the other equatorial bright features, while showing the highest backscattering coefficient of the entire satellite. Tsegihi is very bright at 5 μm but it shows a low backscattering coefficient, so it could have a low roughness on a regional scale and/or a different composition. Another well-defined region, located southwest of Xanadu beyond the Tui Regio, seems to be detached from the surrounding terrains, being bright at 2.69, 2.78 and 5 μm but having a low radar brightness. In this way, other units can be found that show correlations or anti-correlations between the scatterometric response and the spectrophotometric behavior, not evident from the optical remote sensing data.  相似文献   
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