Rotationally-resolved spectroscopy of Vesta I: 2-4 μm region     

A.S. Rivkin  L.A. McFadden  M. Sykes 《Icarus》2006,180(2):464-472

We present new infrared (2-4 μm) spectroscopic observations of Vesta obtained in 2001, 2003, and 2004. Together with previously published work, these present a picture of how Vesta's spectrum changes with sub-Earth latitude and longitude. Vesta's albedo and 2-μm band vary regularly with its rotational phase. While establishing the continuum level for Vesta in the 3-μm region is not straightforward, Vesta appears to have a spectrum consistent with the HED meteorites and not requiring a 3-μm water of hydration band. We cannot formally rule out a shallow (∼1%) band, however. We place limits on the extent to which solar-wind implantation and contamination by CM-like impactors has changed the surface spectrum of Vesta.  相似文献   

Latitudinal variations of CO and OCS in the lower atmosphere of Venus from near-infrared nightside spectro-imaging     

Emmanuel Marcq  Bruno Bézard  Mirel Birlan 《Icarus》2005,179(2):375-386

Spectro-imaging of Venus' nightside in the 2.3-μm window provides a powerful means of probing the lower atmosphere in the 25-40 km altitude range. We present observations recorded at the NASA/IRTF in February 2003 and August 2004, using the SpeX spectro-imager in the 2.1-2.5-μm region. Abundances of CO and OCS have been derived as a function of latitude for different longitudes. The CO abundance increases by about 15% between the equatorial region and higher latitudes (±40°). No longitudinal or temporal variations are observed. The OCS abundance shows the opposite variation in observational sets with sufficient S/N. These variations and anticorrelation are consistent with upwelling motions in the equatorial region and downwelling at higher latitudes.  相似文献   

应用FTIR-XRD-XRF分析测试技术研究新型仿制绿松石的矿物学特征   总被引：4，自引：3，他引：1  

严俊  刘晓波  王巨安  方飚  刘培钧  杨彬彬 《岩矿测试》2015,34(5):544-549

近年来绿松石及其仿制品的鉴定工作较多局限于应用傅里叶变换红外光谱对仿制品进行简单的筛选,前人报道的仿制绿松石的矿物组成主要为单一的矿物相(如异极矿、三水铝石、磷铝石、羟硅硼钙石、菱镁矿等)。本文应用傅里叶变换红外光谱(FTIR)、X射线粉晶衍射(XRD)与X射线荧光光谱(XRF)对当前珠宝市场上几种新型仿制绿松石进行了初步分类,并对不同类别的仿制绿松石的具体矿物组成、物相及晶型特征作了对比研究。结果表明,这些新型仿制绿松石可分为三大类:一类主要由硅酸盐(斜硅钙石)与碳酸盐(方解石)两种矿物组成;另一类为白云石与方解石两种碳酸盐矿物的混合相;第三类以硅酸盐类为主要矿物,并含有钡长石、辉石与石英。显然,新型仿制绿松石的矿物组成明显相异于传统仿制品,可见仿制绿松石的矿物组成日趋多样性、复杂化,该现状必然对新型仿制样品的物相鉴定提出了更高的要求。  相似文献   

激光拉曼光谱法在单个流体包裹体研究中的应用进展   总被引：2，自引：2，他引：0  

何佳乐  潘忠习  冉敬 《岩矿测试》2015,34(4):383-391

激光拉曼光谱法以其非破坏性、高灵敏度和高分辨率等特性,一直以来都是研究流体包裹体的重要方法之一。近年来,围绕激光拉曼光谱在流体包裹体中的应用而展开的研究主要集中在半定量-定量测试方面,即在准确定性的基础上,采用高斯-洛仑兹去卷积分峰、低温原位等定量方法获取流体包裹体的成分和含量,从而克服了激光拉曼光谱法应用于溶液中阳离子的定量分析的灵敏度、准确度较低的问题,不仅能获得流体包裹体中一些常温下不具拉曼活性的盐类物质拉曼特征峰信息,还能根据特征峰与浓度、内压之间的线性关系,进一步对盐度和压力等性质进行测定,从而拓展了激光拉曼光谱法在流体包裹体中的应用范围。本文对激光拉曼光谱法应用于分析流体包裹体成分、盐度、同位素和压力所取得的最新进展进行了评述,并认为随着分析测试技术的不断进步,激光拉曼光谱法未来的分析方向也将继续围绕多元复杂体系及其定量方面的研究展开。  相似文献   

Ore-forming Fluid Characteristics of the Saishitang Cu-polymetallic Deposit in Qinghai Province, China     

LAI Jianqing  JU Peijiao  MAO Yin  AN Jianghu  WANG Xiongjun 《《地质学报》英文版》2015,89(2):485-504

Saishitang Cu-polymetallic deposit is located in the southeast section of Late Paleozoic arcfold in the southeastern margin of Qaidam platform. Accoring to the geological process of the deposit,four mineralization episodes were identified: melt/fluid coexisting period(O),skarn period(A),first sulfide period(B) and second sulfide period(C),and 10 stages were finally subdivided. Three types of inclusions were classified in seven stages,namely crystal bearing inclusions(type I),aqueous inclusions(type II) and pure liquid inclusions(type III). Type I and II inclusions were observed in stage O1,having homogenization temperature from 252 to 431°C,and salinities ranging from 24.3% to 48.0%. Type I inclusion was present in stage A1,having homogenization temperature from 506 to 548°C,and salinities ranging from 39.4% to 44.6%. In stage B1,type II and III inclusions were observed,with homogenization temperature concentrating between 300–400°C,and salinities from 0.4% to 4.3%. Type II inclusions were present in stage B2,with homogenization temperature varying from 403 to 550°C. In stage C1,type I and II inclusion commonly coexisted,and constituted a boiling inclusion group,having homogenization temperatures at 187–463°C,and salinities in a range of 29.4%–46.8% and 2.2%–11.0%. Type II and III inclusions were developed in stage C2,having homogenization temperature at 124–350°C,and salinities ranging between 1.6% and 15.4%. In stage C3,type II and III inclusions were presented,with a homogenization temperature range of 164–360°C,and salinities varying from 4.0% to 11.0%. The results of micro-thermal analysis show that fluids are characterized by high temperature and high salinity in stage O1 and A1,and experienced slight decrease in temperature and dramatic decrease in salinity in stage B1 and B2. In stage C1,the salinity of fluid increased greatly and a further decrease of temperature and salinity occurred in stage C2 and C3. Fluids boiled in stage C1. With calculated pressure of 22 MPa from the trapping temperature of 284–289°C,a mineralization depth of 2.2 km was inferred. Results of Laser Raman Spectroscopy show high density of H2 O,CH4 and CO2 were found as gas composition. H-O isotope study indicates the oreforming fluids were the mixture of magmatic water and meteoric water. Physicochemical parameters of fluids show oxygen and sulfur fugacity experienced a decrease,and redox state is weakly reducing. Along with fluid evolution,oxidation has increased slightly. Comprehensive analysis shows that melt exsolution occurred during the formation of quartz diorite and that metal elements existed and migrated in the form of chlorine complex. Immiscible fluid separation and boiling widely occurred after addition of new fluids,bringing about dissociation of chlorine-complex,resulting in a great deal of copper precipitation. In conclusion,Saishitang deposit,controlled by regional tectonics,is formed by metasomatism between highly fractionated mineralization rock body and wall rock,and belongs to banded skarn Cu-polymetallic deposit.  相似文献   

H2 in molecular shocks: observations from 2 to 12 microns     

M. J. Richter  J. R. Graham  G. S. Wright  D. M. Kelly  J. H. Lacy 《Astrophysics and Space Science》1995,233(1-2):67-70

We present spectroscopy of the molecular shock in the supernova remnant IC 443. The H₂ level populations in IC 443 are nearly identical to Orion Peak 1 (Brand et al. 1988; Parmar et al. 1994) and are consistent with a partially dissociative J-shock. The similarity with Orion suggests the shock processes which dominate the emission in both regions are essentially identical.  相似文献   

A high-resolution infrared spectral survey of Comet C/1999 H1 Lee     

Neil Dello Russo  Michael J. Mumma  Karen Magee-Sauer  Boncho P. Bonev  I.S. McLean 《Icarus》2006,184(1):255-276

We obtained high-resolution (λ/Δλ∼25,000) spectra of Comet C/1999 H1 (Lee) on UT 1999 August 19.6 and 21.6 using the cross-dispersed Near InfraRed SPECtrometer (NIRSPEC) at the Keck Observatory atop Mauna Kea, HI. Here we present spectra of Comet Lee between 2.874 and 3.701 μm (3479-2702 cm⁻¹) representing the most complete high-resolution infrared survey of a comet to date in this wavelength region. Using published line lists and laboratory spectra we have identified 444 of the 545 distinct emission features present in these spectra. We have tabulated the rest frequencies, assignments, relative intensities, and signal-to-noise ratios of all detected emissions. In addition to gaining insights into the chemistry of Comet Lee, this survey provides a valuable tool for planning future high-resolution infrared observations of comets and other astronomical targets, and for retrospective comparison to existing high-resolution infrared datasets.  相似文献   

Getting SMARTS on Novae: Highlights of the Early Evolution of Nova V475 Sct     

Guy S. Stringfellow  Frederich M. Walter 《Astrophysics and Space Science》2006,304(1-4):401-403

There is a disconcerting global trend of retiring telescopes of modest aperture, supplanting them instead with fewer expensive telescopes of quite large aperture. As a consequence, the available time and feasibility of following transient objects in astrophysics is diminishing. We show the utility of having a suite of small to moderate aperture telescopes capable of conducting imaging and spectroscopic observations in a service queue mode. The example we provide is the high-cadence early observations of the classical nova V475 Scuti (2003) carried out with the SMARTS suite of telescopes located at CTIO.  相似文献   

The surface composition of Trojan asteroids: constraints set by scattering theory     

J.P. Emery  R.H. Brown 《Icarus》2004,170(1):131-152

We present the results of spectral modeling of 17 Trojan asteroids. The surface composition of this group of objects (located just beyond the main belt, trapped in Jupiter's stable Lagrange points) remains uncertain due to an absence of diagnostic absorption features in their spectra. We quantitatively analyze spectra of these objects covering the range 0.3-4.0 μm using the formulation for scattering in a particulate medium developed by Hapke. Since the widest spectral range possible is desired to provide the most robust results, recently measured near-IR spectra are combined with previously published visible and near-IR data. These composite spectra are converted to and modeled in terms of geometric albedo to provide the additional constraint of the absolute brightness of the asteroids. It is important that this modeling is performed for a large number of objects, and results are derived based on trends among best-fit models. Under this rigorous examination, we find that it is unlikely that the red spectral slope is a result of organics on the surfaces, due mainly to the lack of absorptions in the L-band. Instead, anhydrous silicates adequately describe the spectral characteristics of this group of objects. A significant fraction of carbonaceous material is also likely present, but is not responsible for the red spectral slope in these models. Also, using these models, we estimate that these surfaces contain at most a few wt% of H₂O ice and no more than 10-30 wt% of hydrated silicates.  相似文献   

Distribution of hydrate on Europa: Further evidence for sulfuric acid hydrate     

R.W. Carlson  M.S. Anderson  R.E. Johnson 《Icarus》2005,177(2):461-471

Sulfuric acid hydrate has been proposed as an important species on Europa's surface, the acid being produced by radiolysis of surficial sulfur compounds. We investigated the spectral properties of disordered and crystalline forms of sulfuric acid and suggest that the hydration properties of Europa's hypothesized sulfuric acid lie between two end members: liquid sulfuric acid and its higher crystalline hydrates. The spectra of these end members are similar except for spectral shifts at the band edges. We measured the optical constants of sulfuric acid octahydrate and used these with simple radiative transfer calculations to fit Europa spectra obtained by Galileo's Near Infrared Mapping Spectrometer (NIMS). The global distribution of the hydrate that we associate here with hydrated sulfuric acid shows a strong trailing-side enhancement with a maximum fractional hydrate abundance of 90% by volume, corresponding to a sulfur atom to water molecule ratio of 10%. The hydrate concentration spatially correlates with the ultraviolet and visible absorption of the surface and with the sulfur dioxide concentration. The asymmetric global distribution is consistent with Iogenic plasma ion implantation as the source of the sulfur, possibly modified by electron irradiation and sputtering effects. The variegated distribution also correlates with geologic forms. A high spatial resolution image shows resolved lineae with less hydrate appearing within the lineae than in nearby crustal material. The low concentration of hydrated material in these lineae argues against their conveying sulfurous material to the surface from the putative ocean.  相似文献