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421.
Several different trans-neptunian objects have been studied in order to investigate their physical and chemical properties. New observations in the 1.1-1.4 μm range, obtained with the ISAAC instrument, are presented in order to complete previous observations carried out with FORS1 in the visible and SINFONI in the near infrared. All of the observations have been performed at the ESO/Very Large Telescope. We analyze the spectra of six different objects (2003 AZ83, Echeclus, Ixion, 2002 AW197, 1999 DE9 and 2003 FY128) in the 0.45-2.3 μm range with the model of Hapke (Hapke, B. [1981]. J. Geophys. Res. 86, 4571-4586) and the method of Shkuratov et al. (Shkuratov, Y., Starukhina, L., Hoffmann, H., Arnold, G. [1999]. Icarus 137, 235-246). Water ice is found on two objects, and in particular it is confirmed in its amorphous and crystalline states on 2003 AZ84 surface. Upper limits on the water ice content are given for the other four TNOs investigated, confirming previous results (Barkume, K.M., Brown, M.E., Schaller, E.L. [2008]. Astron. J. 135, 55-67; Guilbert, A., Alvarez-Candal, A., Merlin, F., Barucci, M.A., Dumas, C., de Bergh, C., Delsanti, A. [2009]. Icarus 201, 272-283). Whatever the absorption features in the near infrared, all objects but one exhibit a moderate red slope in the visible, as most TNOs and Centaurs. We discuss the implications of the presence of water ice and the probable sources of the red slope.  相似文献   
422.
The Eurybates family is a compact core inside the Menelaus clan, located in the L4 swarm of Jupiter Trojans. Fornasier et al. (Fornasier, S., Dotto, E., Hainaut, O., Marzari, F., Boehnhardt, H., De Luise, F., Barucci, M.A. [2007]. Icarus 190, 622-642) found that this family exhibits a peculiar abundance of spectrally flat objects, similar to Chiron-like Centaurs and C-type main belt asteroids. On the basis of the visible spectra available in literature, Eurybates family’s members seemed to be good candidates for having on their surfaces water/water ice or aqueous altered materials.To improve our knowledge of the surface composition of this peculiar family, we carried out an observational campaign at the Telescopio Nazionale Galileo (TNG), obtaining near-infrared spectra of 7 members. Our data show a surprisingly absence of any spectral feature referable to the presence of water, ices or aqueous altered materials on the surface of the observed objects. Models of the surface composition are attempted, evidencing that amorphous carbon seems to dominate the surface composition of the observed bodies and some amount of silicates (olivine) could be present.  相似文献   
423.
Sang J. Kim  T.R. Geballe  A. Jung  Y.C. Minh 《Icarus》2010,208(2):837-849
We present latitudinally-resolved high-resolution (R = 37,000) pole-to-pole spectra of Jupiter in various narrow longitudinal ranges, in spectral intervals covering roughly half of the spectral range 2.86-3.53 μm. We have analyzed the data with the aid of synthetic spectra generated from a model jovian atmosphere that included lines of CH4, CH3D, NH3, C2H2, C2H6, PH3, and HCN, as well as clouds and haze. Numerous spectral features of many of these molecular species are present and are individually identified for the first time, as are many lines of and a few unidentified spectral features. In both polar regions the 2.86-3.10-μm continuum is more than 10 times weaker than in spectra at lower latitudes, implying that in this wavelength range the single-scattering albedos of polar haze particles are very low. In contrast, the 3.24-3.53 μm the weak polar and equatorial continua are of comparable intensity. We derive vertical distributions of NH3, C2H2 and C2H6, and find that the mixing ratios of NH3 and C2H6 show little variation between equatorial and polar regions. However, the mixing ratios of C2H2 in the northern and southern polar regions are ∼6 and ∼3 times, respectively, less than those in the equatorial regions. The derived mixing ratio curves of C2H2 and C2H6 extend up to the 10−6 bar level, a significantly higher altitude than most previous results in the literature. Further ground-based observations covering other longitudes are needed to test if these mixing ratios are representative values for the equatorial and polar regions.  相似文献   
424.
Lunar olivines typically contain inclusions of Cr-spinel (chromite) that influence their measured optical properties. These altered optical properties complicate modeled predictions of olivine composition from reflectance spectra. Approaches developed for inclusion-free terrestrial olivine spectra must be modified to be applied to chromite-bearing lunar olivine spectra. We present a revised approach for predicting the compositions of chromite-bearing lunar olivines using the Modified Gaussian Model (MGM). The results of this revised approach for chromite-bearing lunar olivines are consistent with previous results for terrestrial olivine reflectance spectra, and successfully predict the olivine’s composition. These results are an important step in compositional assessment of remotely-sensed olivine spectra, and are essential to ongoing investigations of that topic. Our results are based on a limited set of available lunar olivine separates, and would be strengthened by the inclusion of additional compositions.  相似文献   
425.
Radio occultations of Saturn’s main rings by spacecraft suggest a power law particle size-distribution down to sizes of the order of 1 cm (Marouf, E.A., Tyler, G.L., Zebker, H.A., Simpson, R.A., Eshleman, V.R. [1983]. Icarus 54, 189–211; Zebker, H.A., Marouf, E.A., Tyler, G.L. [1985]. Icarus 64, 531–548.). The lack of optical depth variations between ultraviolet and near-IR wavelengths indicate a lack of micron-sized particles. Between these two regimes, the particle-size distribution is largely unknown. A cutoff where the particle-size distribution turns over must exist, but the position and shape of it is not clear from existing studies.  相似文献   
426.
Martian equatorial dark regions are dominated by unweathered materials and it has often been assumed that they have not been significantly altered from their source lithology. The suite of minerals present is consistent with a basaltic composition and there has been no need to invoke additional processes to explain the origin of these compositions. We have begun to question this result based on detailed observations using a variety of datasets. Locally derived dark soils have a mineralogy distinct from that of adjacent rocky surfaces; most notably a lower olivine content. This pattern is common for many surfaces across the planet. Previous work using detailed measurements acquired within the Gusev Plains has shown that olivine dissolution via acidic weathering may explain chemical trends observed between rock rinds and interiors. Mineralogical trends obtained from rocks and soils within the Gusev Plains are more prominent than the elemental trends and support previous results that indicate that dissolution of olivine has occurred. However, clear differences are also present in elemental abundances that indicate a variety of inputs and processes are likely responsible for the formation of martian dark soils. Despite the potential complexity of source materials and processes, it appears that most martian dark regions have likely experienced aqueous alteration and chemical weathering appears to be closely linked to the mechanical breakdown of materials. Regardless of the responsible mechanism, there appears to be a general, though not perfect, correlation between elevated olivine abundance and high-thermal inertia surfaces on Mars.  相似文献   
427.
A Late Noachian-aged alluvial fan complex within Harris Crater in far western Terra Tyrrhena, Mars, is comprised of two well-defined source regions and associated discrete depositional lobes. Three fan units were recognized based on common morphological characteristics, thermal properties and spectral signatures. Although the entire fan complex has been subjected to extensive erosional degradation, the preserved morphologies record episodic fan formation and indicate the type of flow processes that occurred; the bulk of the fan surface has morphology consistent with fluvial emplacement while one fan unit exhibits a rugged surface texture with boulders consistent with a debris flow. This transition from fluvial to late-stage debris flow(s) suggests a decline in available water and/or change in sediment supply. The thermal inertia values obtained for all three fan surface units (mean values ranged from 318 to 344 J m−2 K−1 s−1/2) are typical for coarse-grained and/or well-indurated materials on Mars, but subtle variations point to important distinctions. Variations in aeolian bedform coverage as well as the density of ridges (inferred inverted channels) and boulders contribute to these subtle fan thermophysical differences and likely reflect changes in the fan depositional mechanisms and variations in post-depositional modification histories. The majority of the alluvial fan surface has a spectral signature that is broadly similar to TES “Surface Type 2” (ST2), with some important exceptions at long wavelengths. However, a unique spectral component was identified in one of the fan units (unit 3), that likely reflects lithological differences from other fan materials. This spectral attribute of unit 3 matched locations within the western catchment providing confirmation of provenance and supporting the contention that sediment supply changed over time as the fan developed. Finally, we applied simple modeling to a well preserved subsection of the fan complex to quantify the developmental history. Using the computed eastern fan volume (32 km3), significant water, likely from precipitation, was involved in fan construction (>50 km3) and an extensive period of fan formation occurred over millennia or longer.  相似文献   
428.
E. Dartois 《Icarus》2011,212(2):950-956
Carbon monoxide is the second most abundant molecule after H2 in the molecular universe, and as such an abundant constituent of interstellar and Solar System ices. To trace the possibility of this molecule to be found in a clathrate hydrate inclusion compound, its pure phase FTIR spectrum is investigated. We confirm the formation of a type I clathrate structure whereas simple guest size estimates would favour a type II clathrate hydrate, revealing interactions of this molecule with its water network during clathrate formation. The observed cage vibrational downshift with respect to pure CO ice is within 5 cm−1. The temperature dependent wavenumber separation between the two enclathrated CO vibrational transitions in the two distinct type I clathrate cages is less than a wavenumber below 140 K, implying that the spectral simplification for detailed spectroscopic analysis of the individual profiles is a difficult task. The dynamics of the CO molecules in its cage change considerably from 5 K to 140 K. At temperatures above 30 K, the molecule is extremely mobile in the cages, as revealed by the infrared profile, significantly different from CO entrapped in water ice and different from observed profiles in astrophysical objects.  相似文献   
429.
E.A. Cloutis  T. Hiroi 《Icarus》2011,212(1):180-209
Existing reflectance spectra of CI chondrites (18 spectra of 3 CIs) have been augmented with new (18 spectra of 2 CIs) reflectance spectra to ascertain the spectral variability of this meteorite class and provide insights into their spectral properties as a function of grain size, composition, particle packing, and viewing geometry. Particle packing and viewing geometry effects have not previously been examined for CI chondrites. The current analysis is focused on the 0.3-2.5 μm interval, as this region is available for the largest number of CI spectra. Reflectance spectra of powdered CI1 chondrites are uniformly dark (<10% maximum reflectance) but otherwise exhibit a high degree of spectral variability. Overall spectral slopes range from red (increasing reflectance with increasing wavelength) to blue (decreasing reflectance with increasing wavelength). A number of the CI spectra exhibit weak (<5% deep) absorption bands that can be attributed to both phyllosilicates and magnetite. Very weak absorption bands attributable to other CI phases, such as carbonates, sulfates, and organic matter may be present in one or a few spectra, but their identification is not robust. We found that darker spectra are generally correlated with bluer spectral slopes: a behavior most consistent with an increasing abundance of fine-grained magnetite and/or insoluble organic material (IOM), as no other CI opaque phase appears able to produce concurrent darkening and bluing. Magnetite can also explain the presence of an absorption feature near 1 μm in some CI spectra. The most blue-sloped spectra are generally associated with the larger grain size samples. For incidence and emission angles <60°, increasing phase angle results in darker and redder spectra, particularly below ∼1 μm. At high incidence angles (60°), increasing emission angle results in brighter and redder spectra. More densely packed samples and underdense (fluffed) samples show lower overall reflectance than normally packed and flat-surface powdered samples. Some B-class asteroids exhibit selected spectral properties consistent with CI chondrites, although perfect spectral matches have not been found. Because many CI chondrite spectra exhibit absorption features that can be related to specific mineral phases, the search for CI parent bodies can fruitfully be conducted using such parameters.  相似文献   
430.
E.A. Cloutis  P. Hudon  T. Hiroi 《Icarus》2011,216(1):309-346
We have examined the spectral reflectance properties and available modal mineralogies of 39 CM carbonaceous chondrites to determine their range of spectral variability and to diagnose their spectral features. We have also reviewed the published literature on CM mineralogy and subclassification, surveyed the published spectral literature and added new measurements of CM chondrites and relevant end members and mineral mixtures, and measured 11 parameters and searched pair-wise for correlations between all quantities. CM spectra are characterized by overall slopes that can range from modestly blue-sloped to red-sloped, with brighter spectra being generally more red-sloped. Spectral slopes, as measured by the 2.4:0.56 μm and 2.4 μm:visible region peak reflectance ratios, range from 0.90 to 2.32, and 0.81 to 2.24, respectively, with values <1 indicating blue-sloped spectra. Matrix-enriched CM spectra can be even more blue-sloped than bulk samples, with ratios as low as 0.85. There is no apparent correlation between spectral slope and grain size for CM chondrite spectra - both fine-grained powders and chips can exhibit blue-sloped spectra. Maximum reflectance across the 0.3-2.5 μm interval ranges from 2.9% to 20.0%, and from 2.8% to 14.0% at 0.56 μm. Matrix-enriched CM spectra can be darker than bulk samples, with maximum reflectance as low as 2.1%. CM spectra exhibit nearly ubiquitous absorption bands near 0.7, 0.9, and 1.1 μm, with depths up to 12%, and, less commonly, absorption bands in other wavelength regions (e.g., 0.4-0.5, 0.65, 2.2 μm). The depths of the 0.7, 0.9, and 1.1 μm absorption features vary largely in tandem, suggesting a single cause, specifically serpentine-group phyllosilicates. The generally high Fe content, high phyllosilicate abundance relative to mafic silicates, and dual Fe valence state in CM phyllosilicates, all suggest that the phyllosilicates will exhibit strong absorption bands in the 0.7 μm region (due to Fe3+-Fe2+ charge transfers), and the 0.9-1.2 μm region (due to Fe2+ crystal field transitions), and generally dominate over mafic silicates. CM petrologic subtypes exhibit a positive correlation between degree of aqueous alteration and depth of the 0.7 μm absorption band. This is consistent with the decrease in fine-grained opaques that accompanies aqueous alteration. There is no consistent relationship between degree of aqueous alteration and evidence for a 0.65 μm region saponite-group phyllosilicate absorption band. Spectra of different subsamples of a single CM can show large variations in absolute reflectance and overall slope. This is probably due to petrologic variations that likely exist within a single CM chondrite, as duplicate spectra for a single subsample show much less spectral variability. When the full suite of available CM spectra is considered, few clear spectral-compositional trends emerge. This indicates that multiple compositional and physical factors affect absolute reflectance, absorption band depths, and absorption band wavelength positions. Asteroids with reflectance spectra that exhibit absorption features consistent with CM spectra (i.e., absorption bands near 0.7 and 0.9 μm) include members from multiple taxonomic groups. This suggests that on CM parent bodies, aqueous alteration resulted in the consistent production of serpentine-group phyllosilicates, however resulting absolute reflectances and spectral shapes seen in CM reflectance spectra are highly variable, accounting for the presence of phyllosilicate features in reflectance spectra of asteroids across diverse taxonomic groups.  相似文献   
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