Estimation of the <Emphasis Type="Italic">in situ</Emphasis> Ultraviolet-A absorption of seawater by a simple irradiance inversion model     

Takafumi Hirata 《Journal of Oceanography》2008,64(4):561-566

An irradiance inversion model to estimate the in situ absorption coefficient of seawater has been developed for the Ultraviolet-A (UVA) wavelength domain. Input parameters are sun angle and the up-and downward planar irradiances measured for at least two depths. The present method does not require seawater to be sampled, and is a discrete wavelength method which returns the absorption coefficient at a given wavelength from the irradiances measured at that wavelength without assuming a spectral shape of any optical properties a priori. Comparison between the model results and spectrophotometric measurements shows that the model is practically useful when cloud cover in the atmosphere is ≤ 50%. According to the present method, measurements of the irradiances enable simultaneous observation of the in situ underwater UVA radiation level and the absorption capacity of bulk seawater using a radiometer.  相似文献   

用于太阳紫外辐射测量传感器的设计   总被引：1，自引：0，他引：1  

王晶  王项南  石建军  李超 《海洋技术学报》2008,27(4)

介绍了太阳紫外辐射的测量原理,为了提高入射光学系统的余弦响应特性而设计的余弦漫射器,以及等效辐射平面位置的计算方法。设计了适用于海滨浴场等场所的太阳紫外线辐射传感器的光学系统结构,研制了试验样机,开展了相应的试验,并对试验结果进行了分析。  相似文献   

Influence of rotational darkening on ultraviolet interstellar extinction     

C. Friedemann 《Astronomische Nachrichten》1989,310(4):289-293

Der Einfluß der Rotationsverdunklung schnell rotierender Sterne wird einer Neudiskussion unterzogen. Dafür werden filterphotometrische Helligkeiten vom Satelliten ANS herangezogen. Von schwach verfärbten B Sternen (E(B - V) 0.1 mag) wurden die Helligkeiten vom Einfluß der interstellaren Extinktion befreit. Die Verleilung der Sterne im Rotationsgeschwindigkeits-Farbenindex-Diagramm weist eine Streuung auf, die den Betrag der photometrischen Fehler übersteigt. Die Lage der Sterne im Rotationsgeschwindigkeits-Farbenindex-Diagramm befindet sich in qualitativer Übereinstimmung mit entsprechenden theoretischen Resultaten. Bei der Diskussion von individuell abweichenden Verläufen der interstellaren Extinktion vom durchschnittlichen Extinktionsgesetz sollte der Einfluß der Rotationsverdunklung als eine mögliche Quelle für die Abweichungen in Betracht gezogen und geprüft werden.  相似文献   

青岛地区太阳紫外线辐射研究   总被引：12，自引：0，他引：12  

王晶  侯红英 《中国海洋大学学报(自然科学版)》2006,36(4):671-676

通过对青岛地区2004年全年紫外线观测数据的分析,在预设局地纬度、海拔高度、大气中臭氧量及其分布、空气质量状况、地表反照率等因素基本不变的情况下,总结了青岛地区紫外辐射随与太阳天顶角相关的不同季节和时段、天气状况(云况)的统计性变化规律,以服务于该地区人们日常生活中对紫外线的防护,尤其是为调光生态膜的研制及改善提供参考。  相似文献   

Sunlight Degradation of Aquatic Humic Substances Abbau von Huminstoffen unter dem Einfluß von Sonnenlicht     

D. Hongve 《洁净——土壤、空气、水》1994,22(3):117-120

Coloured bog water and an aqueous solution of fulvic acid were exposed to natural sunlight. Up to 67% reduction in colour and 32% reduction in DOC concentration were measured after 12 days exposure. Colour bleaching and reduction in ultraviolet light absorbance were independent of added preservatives. The high molecular weight fraction of dissolved organic matter was most reduced in concentration while substances with low molecular weight increased. The reduction in absorbance (λ = 254 nm) per DOC was most significant for substances with high molecular weight. The final concentration of DOC was highest in samples where microbial activity was suppressed.  相似文献   

太阳紫外光谱及NO2光解系数的观测          下载免费PDF全文

范志华  毛节泰 《大气科学》1991,15(4):109-115

本文讨论了利用自动太阳光谱仪测量地面的紫外辐射光谱,并进一步计算了NO_2的光分解系数.光谱测量范围为310—375nm.测量结果表明,在北京地区秋季NO_2的光解系数变化在(1—4)×10~(-3)S~(-1),有明显的日变化.  相似文献   

Ultraviolet absorption spectra of some Br-containing haloalkanes     

V. L. Orkin  E. E. Kasimovskaya 《Journal of Atmospheric Chemistry》1995,21(1):1-11

The ultraviolet absorption cross sections were measured for CF₃Br, CF₂ClBr, CF₂Br-CF₂Br, CF₂Br₂, CHF₂Br, CHFBr-CF₃, CH₂Br-CF₃, CHClBr-CF₃ in the wavelength range 190–320 nm at 295 K. The photolysis is concluded to be the minor atmospheric sink for CHF₂Br, CHFBr-CF₃, CH₂Br-CF₃, CHClBr-CF₃.  相似文献   

紫外线辐射增加对大豆的影响及其估算   总被引：8，自引：0，他引：8       下载免费PDF全文

郑有飞  颜景义 《应用气象学报》1995,6(4):442-448

在田间及盆栽试验中观测到经超量紫外线（UV280～400 nm）辐射处理的大豆作物，其株型、生理活动及产量均受到不同程度的影响，其影响量随UV辐射强度，大豆品种以及环境条件不同而异。文章还给出了计算紫外线辐射对大豆影响程度的公式，该计算方法效果较好。  相似文献   

Analysis of Physical and Chemical Parameters for Discrimination of Water Origin in a Hydroelectric Reservoir     

Wagner José Barreto  Ieda Scarminio  Maria Cristina Solci  Dílson Norio Ishikawa  Melissa Tiemi Ogasawara  Sônia Naomi Nomi  Sônia Regina Giancoli Barreto 《洁净——土壤、空气、水》2007,35(3):239-245

Seventeen physical and chemical parameters were obtained from a hydroelectric reservoir located in a tropical region in the south of Brazil. Multivariate Principal Component Analysis (PCA) and Hierarchical Group Analysis (HGA) were used to identify the parameters discriminating the origin of water from the Tibagi and the Primeiro de Maio River, after it has passed the mixing region. The study was conducted during the dry and rainy seasons in July 2002 and February 2003 at three depths and three sampling sites located 0, 5, and 10 km away from the mixing region. The statistical methods showed to be appropriate for identifying the contribution of each tributary in the water mixing site of a complex water system. The most important discriminating parameter was the absorbance relation A(253 nm)/A(203 nm), followed by the concentrations of Fe(III), Mn(III), and Ni(II). An anthropogenic interference was found in the reservoir due to high Ni(II) and orthophosphate concentrations caused by a nearby town sewage discharge. The interference was more important during the dry periods due to the lower dispersion of the pollutants. Urgent initiatives should be taken from the state government to build treatment stations for the wastewater of the small cities around the Capivara hydroelectric reservoir to prevent the drinking water quality from deteriorating.  相似文献   

Calculation of the UV Absorption Spectra of As(III) Oxo- and Thio- Acids and Anions in Aqueous Solution and of PF3 in the Gas-phase     

J. A. Tossell 《Aquatic Geochemistry》2001,7(4):239-254

Changes in the UV spectra of As(OH)₃ solutions with variations in pH and temperature have recently been used to determine the temperature dependence of the pK_a of the acid. In previous studies I used quantum mechanical techniques to study changes in structure and vibrational spectra as a function of pH for arsenites and thioarsenites. I previously calculated UV spectra for ``molecular' minerals, like realgar As₄S₄. Here I use a number of different quantum mechanical methods, both Hartree-Fock and density functional theory based, to calculate the UV spectra for both a related simple well-characterized gas-phase molecule PF₃ and for As(OH)₃ and As(SH)₃ and their conjugate anions and some neutral and anionic oligomers in aqueous solution. For the monomeric species small numbers of water molecules have been explicitly included, in a supermolecule or microsolvation approach. I find that UV absorption energies accurate to a few tenths of an eV can be obtained both for gas- phase PF₃ and for neutral arsenious acid in aqueous solution, for which the UV absorption maximum is calculated to occur around 6.5 eV, consistent with experiment. Accurate calculation of the UV energies for arsenite anions in aqueous solution is much more difficult, since basis set size and solvation effects are considerably larger than for the neutral molecules, but fairly reliable results can still be obtained. Deprotonation is found to reduce the lowest calculated UV transition energy by about half an eV. Oligomerization also reduces the lowest calculated UV energy by at least half an eV. Replacement of one or all the –OH groups by –SH groups reduces the lowest calculated UV energies by about 2 eV. UV excitation energies have been calculated for oligomeric species as large as As₃E₃(EH)₃ and As₄E₆, where E = O, S, and may be useful for identifying such species in solution.  相似文献