The NO2 absorption spectrum. III: The 200–300 nm region at ambient temperature     

A. Jenouvrier  B. Coquart  M. F. Merienne 《Journal of Atmospheric Chemistry》1996,25(1):21-32

Absorption cross-section measurements of NO₂ performed in our laboratory have been extended to the 200–300 nm region at ambient temperature. Low pressures have been used, limiting the effects of the dimer N₂O₄ which has an absorption cross-section from one to two orders of magnitude larger than that of NO₂ in this region. The results have been compared to those of previous authors and are now available for atmospheric purposes at 0.01 nm intervals.Unité de Recherche Associée au CNRS.  相似文献   

Solar ultraviolet transfer in the Martian atmosphere: biological and geological implications     

C Córdoba-Jabonero  L.M LaraA.M Mancho  A MárquezR Rodrigo 《Planetary and Space Science》2003,51(6):399-410

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大气臭氧总量的经验计算方法   总被引：1，自引：0，他引：1  

白建辉 《南京气象学院学报》2006,29(6):799-805

依据臭氧生消与紫外辐射(UV)能量利用相互作用的观点,考虑与臭氧有关的主要因子UV、大气中物质在化学和光化学反应中对UV能量的吸收、气溶胶粒子的散射等,在分析1990—1992年臭氧总量、太阳辐射、气象资料的基础上,建立了计算臭氧总量的经验模式,其优点是所用资料均可由常规气象站获得。结果表明,计算值与观测值符合得比较好。利用该经验模式计算了北京地区1979年1月—1996年6月的臭氧总量,计算值与观测值同样比较一致,二者相对偏差的最大值、最小值、平均值分别为15.2%、0.05%和4.9%,相对偏差在±10%之内的比例为91.4%,因而该经验模式是合理、可行的。1991年之后北京地区臭氧的下降与Pinatubo火山气溶胶的影响有关。  相似文献   

Seasonality in UV transparency of an alpine lake is associated to changes in phytoplankton biomass   总被引：1，自引：0，他引：1  

Ruben Sommaruga  Günther Augustin 《Aquatic Sciences - Research Across Boundaries》2006,68(2):129-141

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Parameterization of Ozone Photolysis Frequency in the Lower Troposphere Using Data from Photodiode Array Detector Spectrometers     

Evelyn Jäkel  Manfred Wendisch  Barry L. Lefer 《Journal of Atmospheric Chemistry》2006,54(1):67-87

Spectroradiometers using photodiode array detectors (PDAs) are increasingly applied for airborne and ground-based atmospheric measurements of spectral actinic flux densities due to their high time resolution (less than one second). However they have limited sensitivity of ultraviolet (UV) radiation for wavelengths less than about 305 nm. This results in uncertainties of ozone photolysis frequencies derived from spectral actinic flux density measurements using PDA spectrometers. To overcome this limitation a parameterization method is introduced which extrapolates the data towards the wavelength range of limited sensitivity of the PDA spectrometers (less than about 305 nm). The parameterization is based on radiative transfer simulations and is valid for measurements in the lower troposphere. The components of the suggested parameterization are the lower threshold wavelength of the PDA spectrometer, the slant ozone column (ratio of the total ozone column and the cosine of the solar zenith angle), and the ambient temperature. Tests of the parameterization with simulated actinic flux density spectra have revealed an uncertainty of the derived ozone photolysis frequency of ±5%. Field comparisons of the parameterization results with independent measurements of the ozone photolysis frequency were within ±10% for solar zenith angles less than 70^∘. Finally the parameterization was applied to airborne measurements to emphasize the advantage of high time resolution of PDA spectrometers to study ozone photolysis frequency fields in inhomogeneous cloud condtitions.  相似文献   

SSBUV and NOAA-11 SBUV/2 Solar Variability Measurements     

Matthew T. DeLand  Richard P. Cebula  Ernest Hilsenrath 《Studia Geophysica et Geodaetica》1998,42(2):83-91

The Shuttle SBUV (SSBUV) and NOAA-11 SBUV/2 instruments measured solar spectral UV irradiance during the maximum and declining phase of solar cycle 22. The SSBUV data accurately represent the absolute solar UV irradiance between 200–405 nm, and also show the long-term variations during eight flights between October 1989 and January 1996. These data have been used to correct long-term sensitivity changes in the NOAA-11 SBUV/2 data, which provide a near-daily record of solar UV variations over the 170–400 nm region between December 1988 and October 1994. The NOAA-11 data demonstrate the evolution of short-term solar UV activity during solar cycle 22.  相似文献   

Europa’s disk-resolved ultraviolet spectra: Relationships with plasma flux and surface terrains     

Amanda R. Hendrix  Timothy A. Cassidy  Chris Paranicas 《Icarus》2011,212(2):736-743

The full set of high-resolution observations from the Galileo Ultraviolet Spectrometer (UVS) is analyzed to look for spectral trends across the surface of Europa. We provide the first disk-resolved map of the 280 nm SO₂ absorption feature and investigate its relationship with sulfur and electron flux distributions as well as with surface features and relative surface ages. Our results have implications for exogenic and endogenic sources. The large-scale pattern in SO₂ absorption band depth is again shown to be similar to the pattern of sulfur ion implantation, but with strong variations in band depth based on terrain. In particular, the young chaos units show stronger SO₂ absorption bands than expected from the average pattern of sulfur ion flux, suggesting a local source of SO₂ in those regions, or diapiric heating that leads to a sulfur-rich lag deposit.While the SO₂ absorption feature is confined to the trailing hemisphere, the near UV albedo (300-310 nm) has a global pattern with a minimum at the center of the trailing hemisphere and a maximum at the center of the leading hemisphere. The global nature of the albedo pattern is suggestive of an exogenic source, and several possibilities are discussed. Like the SO₂ absorption, the near UV albedo also has local variations that depend on terrain type and age.  相似文献   

太阳大气中氢原子的赖曼谱线     

田晖  夏利东  何建森 《天文学进展》2010,28(1)

氢是太阳大气中最主要的元素。氢原子的赖曼(Lyman)谱线,尤其是赖曼阿尔法(Ly-α)谱线的辐射,是太阳色球和低过渡区能量损失的主要形式。在太阳的赖曼α像中,网络组织的辐射比较强,而辐射最强的地方是活动区。由于存在辐射转移效应,在宁静区,低阶赖曼谱线的谱形中央一般会形成一个凹陷,而在中央两侧则形成两个峰,两峰往往呈现出一定的不对称性。数值模拟和观测研究表明,赖曼谱线双峰的不对称性与高层大气中各种系统性流动有关。在太阳活动区,赖曼谱形在谱斑区与在宁静区类似;而在黑子区,赖曼谱形几乎没有中央凹陷。赖曼谱形也可用于诊断日珥、耀斑和日冕物质抛射等结构和现象的等离子体特性。该文回顾了赖曼谱线的观测历史,阐明了观测与模拟结果所揭示的物理过程,并结合笔者的认识进行了相应的评论。  相似文献   

Combined experimental and theoretical studies on methane photolysis at 121.6 and 248 nm—implications on a program of laboratory simulations of Titan’s atmosphere     

C. Romanzin  Y. Bénilan 《Planetary and Space Science》2010,58(13):1748-1757

Methane is, together with N₂, the main precursor of Titan’s atmospheric chemistry. In our laboratory, we are currently developing a program of laboratory simulations of Titan’s atmosphere, where methane is intended to be dissociated by multiphotonic photolysis at 248 nm. A preliminary study has shown that multiphotonic absorption of methane at 248 nm is efficient and leads to the production of hydrocarbons such as C₂H₂ (Romanzin et al., 2008). Yet, at this wavelength, little is known about the branching ratios of the hydrocarbon radicals (CH₃, CH₂ and CH) and their following photochemistry. This paper thus aims at investigating methane photochemistry at 248 nm by comparing the chemical evolution observed after irradiation of CH₄ at 248 and at 121.6 nm (Ly-α). It is indeed important to see if the chemistry is driven the same way at both wavelengths in particular because, on Titan, methane photolysis mainly involves Ly-α photons. An approach combining experiments and theoretical analysis by means of a specifically adapted 0-D model has thus been developed and is presented in this paper. The results obtained clearly indicate that the chemistry is different depending on the wavelength. They also suggest that at 248 nm, methane dissociation is in competition with ionisation, which could occur through a three-photon absorption process. As a consequence, 248 nm photolysis appears to be unsuitable to study methane neutral photochemistry alone. The implications of this result on our laboratory simulation program and new experimental developments are discussed. Additional information on methane photochemistry at 121.6 nm are also obtained.  相似文献   

菏泽市紫外线辐射变化特征及月预报方程     

孙翠凤  ;窦坤  ;程德海  ;李瑛  ;吴雷柱 《干旱气象》2014,(4):677-682

利用2008年4月至2012年12月菏泽市紫外线观测资料以及地面常规气象观测资料和空气质量资料,分析了该地区太阳紫外线辐射的变化特征及其与各因子的相关关系,并建立逐月预报方程。结果表明:菏泽紫外线辐射年总量达到187.98 W/m2,春夏两季明显高于秋冬两季,5月达到全年的最大值,1月为全年的最小值;3~9月紫外线辐射极大值均可达到5级,其他月份均可达到4级。不同天气条件下紫外线辐射强度存在明显差异,其中晴天紫外线辐射强且稳定,呈抛物线变化;多云天紫外线辐射波动较大,时强时弱;阴天紫外线辐射相对较弱。紫外线辐射强度与风速、能见度、气温呈正相关,与总云量、低云量、相对湿度呈负相关,与SO2、PM10、NO2、PM2.5多呈负相关。基于多元线性回归分析向后剔除变量方法得出的逐月预报方程,经检验总体预报效果较好,对当地紫外线等级预报工作具有参考意义。  相似文献