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41.
Based on a self-consistent solution of the equations of gas dynamics, kinetics of hydrogen atomic level populations, and radiative transfer, we analyze the structure of a shock wave that propagates in a partially ionized hydrogen gas. We consider the radiative transfer at the frequencies of spectral lines by taking into account the effects of a moving medium in the observer's frame of reference. The flux in Balmer lines is shown to be formed behind the shock discontinuity at the initial hydrogen recombination stage. The Doppler shift of the emission-line profile is approximately one and a half times smaller than the gas flow velocity in the Balmer emission region, because the radiation field of the shock wave is anisotropic. At Mach numbers M1?10 and unperturbed gas densities σ1=10?10 g cm?3, the Doppler shift is approximately one third of the shock velocity U1. The FWHM of the emission-line profile δ ? is related to the shock velocity by δ ? k ? U1, where k ? = 1, 0.6, and 0.65 for the Hα, Hβ, and Hγ lines, respectively.  相似文献   
42.
We analyse long-lasting (several hours) Pc1 pearl pulsations with decreasing, increasing or constant central frequencies. We show that nonstationary pearl events (those with either decreasing or increasing central frequency) are observed simultaneously with increasing auroral magnetic activity at the nightside magnetosphere while the stationary events (constant central frequency) correspond to quiet magnetic conditions. Events with decreasing central frequency are observed mostly in the late morning and daytime whereas events with increasing central frequency appear either early in the morning or in the afternoon. We explain the diurnal distribution of the nonstationary pearl pulsations in terms of proton drifts depending on magnetic activity, and evaluate the magnetospheric electric field based on the variation of the central frequency of pearl pulsations.  相似文献   
43.
In usual incoherent scatter data analysis, the plasma distribution function is assumed to be Maxwellian. In space plasmas, however, distribution functions with a high energy tail which can be well modeled by a generalized Lorentzian distribution function with spectral index kappa (kappa distribution) have been observed. We have theoretically calculated incoherent scatter spectra for a plasma that consists of electrons with kappa distribution function and ions with Maxwellian neglecting the effects of the magnetic field and collisions. The ion line spectra have a double-humped shape similar to those from a Maxwellian plasma. The electron temperatures are underestimated, however, by up to 40% when interpreted assuming Maxwellian distribution. Ion temperatures and electron densities are affected little. Accordingly, actual electron temperatures might be underestimated when an energy input maintaining a high energy tail exists. We have also calculated plasma lines with the kappa distribution function. They are enhanced in total strength, and the peak frequencies appear to be slightly shifted to the transmitter frequency compared to the peak frequencies for a Maxwellian distribution. The damping rate depends on the electron temperature. For lower electron temperatures, plasma lines for electrons with a distribution function are more strongly damped than for a Maxwellian distribution. For higher electron temperatures, however, they have a relatively sharp peak.  相似文献   
44.
采用AGMP-1阴离子交换树脂,分别以7mol/L HCl、2mol/L HCl、0.5mol/L HNO3作为淋洗剂,可有效分离Cu、Fe、Zn。介绍了方法的基本原理、化学分离过程及混合标准溶液与地质标样的分离结果。结果表明,Cu、Fe、Zn回收率均接近100%,标准溶液在离子交换分离前后同位素组成一致,可以满足多接收器等离子体质谱对Cu、Fe、Zn同位素高精度分析的要求。  相似文献   
45.
宋小年  冯天培 《岩矿测试》2006,25(2):189-190196
采用电感耦合等离子体发射光谱法测定硅铝丝(Al—1%Si)中Si及杂质元素Fe和Cu。确定了最少取样量和样品溶解方法,优化了元素分析谱线和仪器的测量条件。实验表明,方法的加标回收率为99%~1叭%,相对标准偏差(n=6)低于1.4%,Si、Fe、Cu的检出限分别为8.5、1.0和0.4μg/L。该方法应用于快速测定键合硅铝丝中的各种元素,结果满意。  相似文献   
46.
Analytical perspective on trace element species of interest in exploration   总被引:1,自引:0,他引:1  
Analysis of soil and sediment samples, using selective extraction methods to distinguish different phases, is of particular interest in exploration geochemistry to locate deeply buried mineral deposits. There are various mechanisms of binding labile elements in the secondary environment, including physical and chemical sorption, precipitation, chelation and complexation. Phases present in soils and sediments which are likely to scavenge ‘free' elements include amorphous Mn and Fe oxides, the humic and fulvic components of humus, and clays. This paper reviews these forms of trace elements and the methods in current use to quantify them. Examples of precision data, both for control and survey samples, are given with respect to trace elements dissolved from the ‘soluble organic' component of humus, Mn oxides and amorphous Fe oxides. The high sensitivity of inductively coupled plasma mass spectrometry (ICP–MS) is required to measure accurately and precisely a large suite of trace elements, especially where only small fractions of elements are dissolved by such leaches as the commercially available Enzyme and MMI (Mobile Metal Ion) extractions. The relative standard deviations (RSD) obtained for 33 elements (e.g. Ag, Cd, In, I) in the standard reference sample (SRM), TILL-2, are in the range 0.5–8% for the hydroxylamine hydrochloride (NH2OH·HCl) leach designed to extract hydrous Fe and Mn oxides. The corresponding RSDs for elements in the reactive Mn oxide phase extracted by the Enzyme leach are in the range 3–19% except for some trace elements at levels close to detection limit (e.g. Cd, Bi). The RSDs obtained for field duplicates are inferior to those for analytical replicates (i.e. sample splits), probably a reflection of different concentrations of the host phase. In one soil survey, the Fe extracted by a 0.25 M NH2OH·HCl leach ranged conservatively from 0.2 to 1.7% whereas the Mn extracted by the Enzyme leach varied extensively, from 0.3 to >999 ppm. In contrast, precision, at 1–7% RSD, for field duplicates was found to be comparable with that for both analytical duplicates and the SRM, LKSD-4, for elements associated with the humic and fulvic component of humus samples sieved to <177 μm.  相似文献   
47.
For studying the auroral electrojet and for examining the effects it can produce in power systems on the ground, it is useful to be able to calculate the magnetic and electric fields that the electrojet produces at the surface of the Earth. Including the effects of currents induced in the Earth leads to a set of integral expressions, the numerical computation of which is complicated and demanding of computer resources. An approximate solution can be achieved by representing the induced currents by an image current at a complex depth. We present a simple derivation of the complex-image expressions and use them to calculate the fields produced by the auroral electrojet at the surface of an earth represented by layered conductivity models. Comparison of these results with ones obtained using the exact integral solution show that the errors introduced are insignificant compared to the uncertainties in the parameters used. The complex-image method thus provides a simple, fast and accurate means of calculating the magnetic and electric fields.  相似文献   
48.
Intense auroral kilometric radiation (AKR) is being frequently observed with POLRAD from the Auroral Probe (Interball-2). Observations of the abrupt upper frequency cutoffs (UFCs) in the spectra of AKR are reported. The UFCs can be observed at a frequency range from 300 to 700 kHz, corresponding to AKR generation altitudes from approximately 4800 to 2100 km, and are distributed in magnetic local time (MLT) hours similarly to the AKR events, with a maximum at 1 h MLT. The observed frequency extent of the UFCs is 12 kHz, and is often determined by the instrumental resolution (4 kHz). It is suggested that the UFC may be associated with an abrupt switching on of the generation mechanism, when the electron density becomes sufficiently low inside a plasma depletion at an altitude where the ratio of fpe/fce crosses some threshold value. The steepness of the UFCs can imply a non-linear process of generation. The estimated distance of the e-folding field aligned wave amplification is between 3 and 8 km. The UFCs are sometimes, though very seldom (10%), accompanied by narrow band (less than 4 kHz) ridges of radiation observed at the cutoff frequency. They are smoothly drifting in frequncy for several minutes. The power density of radiation in the ridge can be up to 2 orders of magnitude stronger than in the accompanying wide band emission of AKR. The ridge at UFC can imply either energy concentration at the source bottom, or focusing, if specific conditions for the escape of the radiation are assumed.  相似文献   
49.
EISCAT observations of the interplanetary scintillation of a single source were made over an extended period of time, during which the orientation of the baselines between the two observing sites changed significantly. Assuming that maximum correlation between the scintillations observed at the two sites occurs when the projected baseline is parallel to the direction of plasma flow, this technique can be used to make a unique determination of the direction of the solar wind. In the past it has usually been assumed that the plasma flow is radial, but measurements of eleven sources using this technique have indicated conclusively that in at least six cases observed at mid or high heliocentric latitude there is a significant non-radial component directed in four cases towards the heliocentric equator and in two cases towards the pole.  相似文献   
50.
The drift velocity of an auroral arc is compared with the component of F-region plasma velocity in the same direction for ten cases where the arc is seen to move steadily equatorward for several minutes without any major change in appearance or orientation. In most cases the two velocities are close, but on two occasions the drift velocity of the arc is much higher than the plasma velocity. From the cases studied it appears that during the growth and recovery phase of the substorm cycle the arc moves with a velocity close to the convection velocity, but during the expansion phase this is not the case.  相似文献   
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