原油族组分成气的化学动力学模型及其标定   总被引：27，自引：2，他引：27       下载免费PDF全文

卢双舫  付晓泰 《地质学报》1997,71(4):367-373

利用等温密封热解实验技术及恒速升温热解实验与PY—GC分析技术的结合,本文分别建立并标定了原油中各族组分,即饱和烃、芳烃、非烃和沥青质成气的化学动力学模型。结果表明,原油中不同族组分成气的过程均可用平行一级反应描述,但不同组分在平均活化能及活化能分布上有明显的差异。各族组分在地史过程中成气的过程可由各自的化学动力学模型来描述。这将使原油成气过程的定量、动态描述成为可能。  相似文献   

吉林六批叶沟金矿床绢云母⁴⁰Ar-³⁹Ar 快中子活化法定年研究   总被引：6，自引：0，他引：6  

侯树桓  桑海清 《矿床地质》2004,23(4):502-508

在六批叶沟金矿石中,精选出与金矿物同期生成的绢云母作为样品,采用40Ar-39Ar快中子活化法测年,获得8个一致相连的平坦型绢云母年龄谱,tp=(190.28±0.30) Ma,氩同位素计算得等时线年龄为(189.98±0.58) Ma,两者完全吻合.等时线截距为(296.9±10.0) Ma,与大气氩的该值(295.5 Ma)相比较,两者完全吻合,表明该样品出自未受明显后期热力作用影响的非扰动体系.锁定六批叶沟金矿床主要成矿年龄为190 Ma左右,属早侏罗世的燕山早期.  相似文献   

Foundations of petroleum prediction based on the activation of geochemical processes by direct current     

V.Yu. Shigaev 《Russian Geology and Geophysics》2018,59(11):1508-1513

Petroleum prediction in local objects and the applicability of geologic environment parameters in this regard are considered. The proposed guidelines for petroleum potential prediction are based on the analysis of the distribution of typomorphic epigenetic multivalent elements loosely fixed in rocks before and after electric current treatment. The advantage of geoelectrochemical methods providing data on the chemical composition of above-productive deposits is demonstrated.  相似文献   

Properties and organic activation of ocean clay in the East Pacific     

Huahua Lü 《世界地质(英文版)》2006,9(1)

In order to make use of ocean clay reasonably and excavate its potential applications the properties of ocean clay in Chinese investigating area of the East Pacific have been tested with the chemical analysis, XRFS, ICP/MAS, granulometry and SSA, etc. The results show that the clay sediments of this area are rich in clay minerals, fine granularity, bigger SSA, bigger water absorbability and lower ion changing ability etc. To improve the adaptability of ocean clay and macromolecule materials, using the dry milling method with silane, aluminate, stearic acid coupling agents etc the properties of ocean clay are improved. The effect has been evaluated by testing the water absorbing of the modified ocean clay and their dispersing in paraffin liquid. The result is that KH550 is better than any other active reagents, and the best activation technics is that 1.5% (volume) of KH550 quantity, 20min of milling time. The DTA, XRD, SEM and IR analyses and SSA testing show that the organic activation can not change the mineral structure but can densify the structure of clay, and activation mechanism is chemical covered mainly and chemical combined secondly.  相似文献   

矿物热敏参数测试仪及其在地质找矿中的应用     

赵亨达  王忠荣 《岩石矿物学杂志》1994,13(2):175-186

介绍了国内外第一台矿物热敏参数测试仪研制的原理、应用范围和对一些金属矿物、半导体矿物的测试情况以及仪器在浙江、赣南等地区金矿找矿中的初步应用。  相似文献   

A PRELIMINARY ANALYSIS ON THE CHARACTERISTICS OF THE KUROSHIO FRONTAL EDDY IN THE EAST CHINA SEA IN SPRING   总被引：3，自引：0，他引：3  

郑义芳  黄卫民  Nakamura Yasuaki 《中国海洋湖沼学报》1993,11(3):276-284

The Kuroshi'o front eddy's surface and sectional isothermal distribution characteristics were analyzed on the basis of observation data obtained in April 13-16 of 1989 in the East China Sea. It was found from the similarity between these isothermal distributions with those in January and beginning of June for the years 1986-1990 that the Kuroshio front eddy often occurred from March to the beginning of June. The Kuroshio front eddy movement in the East China Sea in spring was along two routes: the Okinawa Trough route, and the continental shelf slope route. The two moving routes both in the surface layer and in the section are described, their causes are discussed, and differences are compared.  相似文献   

微型堆仪器中子活化分析测定水系沉积物中多个元素     

张卫华  曹传儒 《岩矿测试》1991,10(2):107-110

本实验以微型核反应堆为中子源用仪器中子活化分析对水系沉积物中的30个元素常规测定进行了研究。样品在长照射后从第四天开始直到第八天进行每天一次的跟踪测试。研究了有关元素的最佳冷却时间,从而得到了最佳探测限。以GSD-11和GSD-8为标准监控样品,对实验结果的精密度和近似检测限进行了计算。长照测试元素La、Sc、As、Sb、Na、W、Gd和Sm的相对标准偏差小于5％,Th、U、Yb、Ta、Rb、K、Fe小于10％,Ho、Ce、Ga、Lu、Br小于15％,Eu、Cs小于20％。短照测试元素为Mg、Al、Mn、In、Ca、V、Dy和Ti。  相似文献   

A combined pyrolysis mass spectrometric and light microscopic study of peatified Calluna wood isolated from raised bog peat deposits     

Edwin van der Heijden  Jaap J. Boon 《Organic Geochemistry》1994,22(6)

Stem wood of the Angiosperm Calluna vulgaris (Scotch heather), isolated at different depths from a selection of raised bog peat deposits, was chemically characterized using in-source pyrolysis mass spectrometry (Py-MS) and Curie-point pyrolysis gas chromatography mass spectrometry (Py-GC-MS). Light microscopy was performed to relate mass spectrometric characteristics with anatomical features. Peatified wood samples, isolated from increasing depth show a gradual decrease in carbohydrate content. This decrease in anatomically reflected in a selective removal of secondary cell wall material from the fibre-tracheids and wood parenchyma. During prolonged peatification a selective removal of hemicellulose sugars is observed, while a part of the cellulose fraction is preserved. This highly resistant cellulose is mainly located in the secondary cell walls of the vessels. The lignin macromolecule is preserved, but a gradual decrease in syringyl to guaiacyl ratio (S/G) is observed during peatification. Because no increase in catechol and phenolic compounds is observed, we conclude that S/G shifts are due to removal the of syringyl-rich secondary cell wall material and the retention of guaiacyl-rich compound middle lamella. Small chemical changes in the lignin macromolecule involve shifts in oxygen substitutions on the aliphatic side chains of the methoxyphenolics and the occurrence of aromatic acids.  相似文献   

人工合成硅灰石的发光性质与发光机理的初步研究   总被引：2，自引：0，他引：2  

袁曦明  何应律 《地球科学》1994,19(2):175-180

在２５４ｎｍ紫外光照激发条件下，对人工合成掺入不同激活离子的低温ＴＣ型和高温型假硅灰石的发光性质进行了实验测定，从微观原子能量谱项讨论了在全的硅灰石基质中Ｅｕ＾３＋和Ｇｄ＾３＋的发光机理，分析了Ｂｉ＾３＋对Ｅｕ＾３＋与Ｐｂ＾２＋对Ｍｎ＾２＋的敏化发光条件，初步探讨了掺放Ｅｕ＾３＋的高温型假硅灰石发光强度减弱的原因。  相似文献   

BP网络在位场解释中的应用     

朱晓军  申宁华 《吉林大学学报(地球科学版)》1995,(1)

介绍了ＢＰ网络的特点，阐述了它在位场资料解释中应用的方法、特点和可行性。通过模型计算证实了该方法在位场异常识别中的效果，正确率达９７％。此外，通过修改网络单元的激发函数，增强网络的稳定性和内插功能，使ＢＰ网络在多层密度界面反演中得到满意的结果，模型和实例计算证明了该方法的有效性。  相似文献