The Atmospheric Oxidation of the HS Radical: Reaction with NO2     

Stella M. Resende 《Journal of Atmospheric Chemistry》2007,56(1):21-32

The atmospheric reaction between HS and NO₂ was theoretically investigated at 298 K and 1 atm of pressure. Our results show that the first reaction step will lead to the formation of HSNO₂ or HSONO, spontaneously and exothermically. HSONO easily decomposes into HSO + NO. On the other hand, HSNO₂ can hardly dissociate in the reactants, and its isomerization to other adducts is much hindered. Production of HNO + SO and SNO + OH was found to be unfavorable. Thus, the main products would be HSO + NO and HSNO₂, and new investigations focusing on the atmospheric fate of HSNO₂ are suggested. A general discussion of the fate of HS under atmospheric conditions is presented. Recent investigations indicate that NO₂, O₂ and N₂O should be the most important oxidants of HS, while the O₃ influence will not be significant.  相似文献   

拱星OH脉泽辐射频谱的双峰结构和多重分离的膨胀拱星壳     

俞志尧 《天文学报》1998,39(3):237-243

对一些OH／IR星的拱星OH脉泽的观测结果表明,在双峰结构谱线轮廓上常常可以发现一些小峰叠加在双峰上,即在谱线轮廓的双峰结构中的每个峰是由几个小峰叠加而成的．从脉泽的辐射转移方程和拱星包层的速度结构出发,研究拱星OH脉泽辐射频谱的轮廓特征,提出多重分离的膨胀拱星亮模型,很好地解释了双峰结构的奇特观测现象．  相似文献   

X-ray emission of OH megamaser galaxies     

R. A. Kandalyan  V. V. Hambaryan  H. A. Sabat 《Astrophysics》2007,50(2):135-143

The properties of OH megamaser galaxies in the x-ray region are discussed. Observational data from the XMM-Newton x-ray satellite are presented for three megamasers, IRAS 01418+1651, IRAS 11010+4107, and IRAS 13218+0552. Based on a sample of OH megamaser galaxies it is shown that the x-ray and OH emission are closely coupled. Megamaser emission also correlates with the column density of the medium and the OH emissivity increases as the square of the column density. The results of this study indicate that in OH megamaser galaxies an active nucleus, x-ray heating of molecules, and saturation of the maser emission can play an important role. In some megamasers, active star formation may be the dominant source. __________ Translated from Astrofizika, Vol. 50, No. 2, pp. 171–182 (May 2007).  相似文献   

Spatial variability of snowmelt timing from AMSR‐E and SSM/I passive microwave sensors,Pelly River,Yukon Territory,Canada     

Joan M. Ramage  Jeremy D. Apgar  Rose A. McKenney  Wade Hanna 《水文研究》2007,21(12):1548-1560

Spring snow melt run‐off in high latitude and snow‐dominated drainage basins is generally the most significant annual hydrological event. Melt timing, duration, and flow magnitude are highly variable and influence regional climate, geomorphology, and hydrology. Arctic and sub‐arctic regions have sparse long‐term ground observations and these snow‐dominated hydrologic regimes are sensitive to the rapidly warming climate trends that characterize much of the northern latitudes. Passive microwave brightness temperatures are sensitive to changes in the liquid water content of the snow pack and make it possible to detect incipient melt, diurnal melt‐refreeze cycles, and the approximate end of snow cover on the ground over large regions. Special Sensor Microwave Imager (SSM/I) and Advanced Microwave Scanning Radiometer for EOS (AMSR‐E) passive microwave brightness temperatures (T_b) and diurnal amplitude variations (DAV) are used to investigate the spatial variability of snowmelt onset timing (in two stages, ‘DAV onset’ and ‘melt onset’) and duration for a complex sub‐arctic landscape during 2005. The satellites are sensitive to small percentages of liquid water, and therefore represent ‘incipient melt’, a condition somewhat earlier than a traditional definition of a melting snowpack. Incipient melt dates and duration are compared to topography, land cover, and hydrology to investigate the strength and significance of melt timing in heterogeneous landscapes in the Pelly River, a major tributary to the Yukon River. Microwave‐derived melt onset in this region in 2005 occurred from late February to late April. Upland areas melt 1–2 weeks later than lowland areas and have shorter transition periods. Melt timing and duration appear to be influenced by pixel elevation, aspect, and uniformity as well as other factors such as weather and snow mass distribution. The end of the transition season is uniform across sensors and across the basin in spite of a wide variety of pixel characteristics. Copyright © 2007 John Wiley & Sons, Ltd.  相似文献   

3D Numerical Simulation Analysis of Passive Drag near Free Surface in Swimming     

詹杰民  李天赠  陈学彬  李毓湘  韦永康 《海洋工程》2015,29(2):265-273

The aim of this work is to build a 3D numerical model to study the characteristics of passive drag on competitive swimmers taking into account the impact of the free surface. This model solves the 3D incompressible Navier-Stokes equations using RNG k?ε turbulence closure. The volume of fluid (VOF) method is used to locate the free surface. The 3D virtual model is created by Computer Aided Industrial Design (CAID) software, Rhinoceros. Firstly, a specific posture of swimming is studied. The simulation results are in good agreement with the data from mannequin towing experiments. The effects of a swimmer’s arms and legs positions on swimming performance are then studied. Finally, it is demonstrated that the present method is capable of simulating gliding near the free surface.  相似文献   

应用微波遥感数据的东北地区地表温度反演     

满浩然  臧淑英  李苗  张鑫 《测绘科学》2021,46(3):124-132

针对无源微波遥感时间分辨率高可以克服云层影响获取地表温度的问题,该文应用AMSR-E微波亮度温度数据,分别选取了基于发射率估计的单通道反演法和多通道线性拟合法反演东北地区地表温度。在原有方法的基础上提出算法改进:对单通道反演法按照植被生长周期在生长季与非生长季分别建立发射率估计方程,探究各微波通道在每种地表覆被类型的反演能力并组合反演精度最高的通道,将微波极化差异指数作为表征发射率参数加入多通道拟合方程。结果显示,获取的地表温度剔除水体和冰雪无效像元后可用性达到100%,改进后的单通道反演法均方根误差由3.58~4.6降低至2.0~3.1,在75%的区域的误差小于2 K;多通道拟合法的最终均方根误差为2.6~3.5,同样有较高精度且只使用微波亮温数据就能获取地表温度。  相似文献   

应用于被动氢钟的简单滤波器实现     

徐文  李玉莹  刘铁新 《中国科学院上海天文台年刊》2011,(0)

在被动型氢原子钟数字伺服电路中,使用FPGA对误差信号进行数字信号处理。设计了一种简单的低通滤波器,与传统的FIR滤波器相比,节省了FPGA的使用资源,并且性能优于传统滤波器,能够很好地应用于被动型氢钟。  相似文献   

海南福基田幔源辉石结构OH与氢氧同位素     

张保民  张晓黎  狄敬茹  叶德隆 《地质科技情报》2010,29(3)

采用IR光谱和质谱技术分析了海南福基田幔源巨晶和包体中辉石的结构羟基红外光谱和氢氧同位素。测试的所有巨晶普通辉石和包体中透辉石及顽火辉石均含结构OH,对比印证了国内外同类矿物的红外光谱特征。结构水质量分数分别是:普通辉石87×10-6~389×10-6;透辉石127×10-6~273×10-6;顽火辉石69×10-6~207×10-6。包体中结构水质量分数为1 811×10-6~5 377×10-6,平均为3 133×10-6。包体中辉石的氢氧同位素特征如下:透辉石的δ(D)为-123.17‰,顽火辉石的δ(D)为-132.04‰;透辉石的δ(18O)为5.96‰,顽火辉石的δ(18O)为5.60‰。实验和对比表明,辉石是海南福基田上地幔重要的"水储库",包体未受地壳成分污染,继承和保持了上地幔"富水贫氘"的特征。上述结果为该地区上地幔研究提供了结构水和氢氧同位素的基础资料。  相似文献   

运用H、O同位素资料分析地下热水的补给来源——以鲁西北阳谷-齐河凸起为例   总被引：1，自引：0，他引：1  

张保建  徐军祥  马振民  沈照理  亓麟 《地质通报》2010,29(4):603-609

通过对阳谷-齐河凸起地下热水的化学成分、同位素及其地热地质条件的分析,对这一地区的地下热水的补给来源进行了研究。本区地下热水的δD为-65‰～-80.67‰,δ18O为-9.2‰～-10.2‰,均分布在全球雨水线的附近,说明该区地下热水主要为大气降水成因。济南北地热田地下热水的补给高程为256m,此范围大致相当于济南南部山区及其以南的泰山北麓;聊城东地热田地下热水的补给高程为411m,此范围大致相当于泰山山脉及其周边的中山区。聊城东地热田地下热水的2H过量参数d明显低于济南北地热田,说明聊城东地热田地下热水的补给区比后者更远。  相似文献   

壳聚糖/纳米铜复合微球的制备及其对刚果红染料的脱色性能     

李瑞明  李瑾  钟莲  朱巧雅 《中国海洋大学学报(自然科学版)》2022,52(2):77-86

以壳聚糖和CuCl₂·2H₂O为原料,分别采用直接负载法和吸附法成功制备了壳聚糖/纳米铜复合微球,运用傅里叶变换红外光谱(FT-IR)、X-射线衍射(XDR)和扫描电镜(SEM)对催化剂结构进行了表征。以刚果红(CR)染料为目标污染物,评价了催化剂的制备方法、制备条件及氢转移催化反应条件对其催化性能的影响。结果表明,由直接负载法(CS/CuNPs)和吸附法(CS/CuNPs-X)制备的壳聚糖/纳米铜复合微球在CR染料浓度为100 mg/L,催化剂投加量为0.05 g,供氢体浓度为0.05 mol/L的氢转移催化反应条件下,催化反应进行180和60 min时CR脱色率可分别达95.8%和96.8%。CS/CuNPs-X比CS/CuNPs表现了更高的对CR氢转移催化反应的催化速率。两种催化剂催化还原CR染料的反应均符合准一级动力学模型。在连续循环使用10次后,CS/CuNPs和CS/CuNPs-X对CR的脱色率分别为93.9%和89.4%,表明催化剂具有良好的重复使用性能。  相似文献