单道扫描电感耦合等离子体发射光谱法测定珊瑚礁中主量和微量元素   总被引：1，自引：0，他引：1       下载免费PDF全文

林学辉  刘昌岭 《岩矿测试》2003,22(3):225-227

建立了用单道扫描电感耦合等离子体发射光谱法测定珊瑚礁中主量和微量元素的方法。珊瑚礁样品经酸溶解后,直接进行Ca、Mg、K、Na、V、Sr、Ba、Co、Ni、Pb、Li、Rb的测定,方法检出限为0.0004～0.1mg/L,精密度RSD<5%(n=6),样品的加标回收率为97%～105%。测定w(CaO)为50%的样品,结果与传统的EDTA容量法相符。方法经碳酸盐岩石国家一级标准物质验证可行,已用于大批量的珊瑚礁样品的测定。  相似文献   

高温密闭溶样电感耦合等离子体质谱准确测定辉钼矿铼-锇地质年龄   总被引：176，自引：28，他引：176  

屈文俊  杜安道 《岩矿测试》2003,22(4):254-257262

采用Carius管高温密闭溶样,电感耦合等离子体质谱(ICP MS)法对采自两个不同金属矿床的辉钼矿样品的Re Os同位素地质年龄进行了准确测定。所得出的Re Os年龄的平均值分别为14.26±0.19Ma和34.39±0.81Ma,相对标准偏差分别为1.3%(以2s计算,n=6)和2.4%(以2s计算,n=7)。采用国际通用的ISOPLOT软件按Model1模式对这两组样品分别进行处理,所得Re Os等时线年龄分别为14.32±0.46Ma和34.52±0.38Ma(均为95%置信水平)。同批次样品中所带的内部管理样JDC的Re Os年龄与国际先进实验室采用负离子热表面电离质谱测量所得的结果吻合也较好。说明在严格的质量体系保证及有效地降低实验室空白水平的前提下,ICP MS完全可以准确地测定辉钼矿的Re Os年龄。  相似文献   

Low-Frequency Plasma Waves in the Outer Polar CUSP: A Review of Observations from Prognoz 8, Interball 1, Magion 4, and Cluster     

J. Blecki  R. Wronowski  S. Savin  N. Cornilleau-Wehrlin  M. Parrot  Z. Nemecek  J. Safrankova  O. Santolik  K. Kudela  J-A. Sauvaud 《Surveys in Geophysics》2005,26(1-3):177-191

This paper presents a review of the most interesting observations of low-frequency plasma waves together with plasma particles which were made by the Interball 1, Magion 4 and Prognoz 8 satellites in the outer polar cusp. Accelerated plasma particles, hot electron populations and very strong wave activity, particularly at low frequencies, are observed. A detailed study of the wave spectra together with the distribution function for electrons indicate the correlation between the presence of lower-hybrid waves and the population of the particles with higher energy than in the surrounding space. These experimental facts suggest that strong coupling between waves and particles is responsible for plasma heating. During polar cusp crossings by Interball 1 and Prognoz 8, FFT analysis of the wave form indicates many bursts of ULF emissions in both electric and magnetic components. These waves have highly non-stationary characteristics. To study the dynamics of changes in the spectral characteristics of the waves wavelet analysis has been used. Nonlinear interactions are studied using bispectral methods of analysis. This presentation gives the results of such an analysis for selected cusp crossings at different altitudes. An example of wave activity registered by the STAFF instrument onboard the CLUSTER spacecraft in the polar cusp is also presented.  相似文献   

利用微波等离子体炬四极杆质谱在线测定稀土矿样中的多种稀土元素     

初晨  张瑛  王尚贤  周润芝  蒋涛  朱志强  卢爱民 《岩矿测试》2016,35(5):468-474

随着稀土的应用越来越广泛,开发稀土元素的快速在线检测技术已日趋成为行业发展的需求。本文以微波等离子体炬(MPT)为离子源,以四极杆质谱仪(QMS)作为质量分析器建立了一种快速、直接检测水样中稀土元素的质谱检测方法,并将其应用于分析稀土矿样中的多种稀土元素。研究表明,应用MPT-QMS测定水样中的钇、镧、铈、钕、铕五种稀土元素,检出限(LOD)可达11.0~60.5μg/L,测定范围为50~1000μg/L。当分析固体稀土矿样时,样品经酸溶处理后通过气动雾化形成气溶胶,再进行冷却干燥,气溶胶由MPT的中心管道进入等离子体中,产生稀土元素复合离子,再引入QMS中进行分析,即可以定量地测定矿样中稀土元素的含量。同一样品用电感耦合等离子体质谱(ICP-MS)进行对比实验,两者的检测结果在数量级上接近,证明了MPTQMS方法在半定量的意义下是准确、可靠的,因而这种快速的检测方法可发展成为水体中金属元素的现场分析方法,应用于环境水、生活水质量在线监测等领域。  相似文献   

电感耦合等离子体质谱法(ICP-MS)测定水系沉积物中的铌钽锆铪   总被引：1，自引：0，他引：1  

胡家祯  于亚辉  吴娣  李小辉  吴葆存  刘春霞  钟盼 《矿产与地质》2016,(4):699-702

建立电感耦合等离子体质谱法(ICP-MS)测定水系沉积物中铌、钽、锆、铪四种元素的分析方法。将样品与氢氧化钠、过氧化钠混合物放入高温炉中,熔融分解完全,用热水提取,过滤后弃去滤液,将滤纸及沉淀用酒石酸-盐酸溶液溶解,稀释至刻度测定。方法检出限(3s)为:LD(Nb)=0.08μg/g,LD(Ta)=0.04μg/g,LD(Zr)=0.5μg/g,LD(Hf)=0.04μg/g,精密度(RSD%,n=6)为:0.84%~4.21%。该测定方法具有灵敏度高、精密度好、分析速度快、线性范围宽、操作性强等优势。采用该方法对国家一级标准物质进行测定表明,其结果与标准值吻合。此方法已在实际地质调查样品分析中得到应用。  相似文献   

An Investigation of Digestion Methods for Trace Elements in Bauxite and Their Determination in Ten Bauxite Reference Materials Using Inductively Coupled Plasma‐Mass Spectrometry          下载免费PDF全文

Wen Zhang  Liang Qi  Zhaochu Hu  Cunjiang Zheng  Yongsheng Liu  Haihong Chen  Shan Gao  Shenghong Hu 《Geostandards and Geoanalytical Research》2016,40(2):195-216

Trace elements from samples of bauxite deposits can provide useful information relevant to the exploration of the ore‐forming process. Sample digestion is a fundamental and critical stage in the process of geochemical analysis, which enables the acquisition of accurate trace element data by ICP‐MS. However, the conventional bomb digestion method with HF/HNO₃ results in a significant loss of rare earth elements (REEs) due to the formation of insoluble AlF₃ precipitates during the digestion of bauxite samples. In this study, the digestion capability of the following methods was investigated: (a) ‘Mg‐addition’ bomb digestion, (b) NH₄HF₂ open vessel digestion and (c) NH₄F open vessel digestion. ‘Mg‐addition’ bomb digestion can effectively suppress the formation of AlF₃ and simultaneously ensure the complete decomposition of resistant minerals in bauxite samples. The addition of MgO to the bauxite samples resulted in (Mg + Ca)/Al ratios ≥ 1. However, adding a large amount of MgO leads to significant blank contamination for some transition elements (V, Cr, Ni and Zn). The NH₄HF₂ or NH₄F open vessel digestion methods can also completely digest resistant minerals in bauxite samples in a short period of time (5 hr). Unlike conventional bomb digestion with HF/HNO₃, the white precipitates and the semi‐transparent gels present in the NH₄HF₂ and NH₄F digestion methods could be efficiently dissolved by evaporation with HClO₄. Based on these three optimised digestion methods, thirty‐seven trace elements including REEs in ten bauxite reference materials (RMs) were determined by ICP‐MS. The data obtained showed excellent inter‐method reproducibility (agreement within 5% for REEs). The relative standard deviation (% RSD) for most elements was < 6%. The concentrations of trace elements in the ten bauxite RMs showed agreement with the limited certified (Li, V, Cr, Cu, Zn, Ga, Sr, Zr and Pb) and information values (Co, Ba, Ce and Hf) available. New trace element data for the ten RMs are provided, some of which for the first time.  相似文献   

Characteristics and evolution of a coastal mesoscale eddy in the Western Bay of Bengal monitored by high-frequency radars     

《Dynamics of Atmospheres and Oceans》2019

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微波等离子体炬原子发射光谱法测定铁和铝的研究   总被引：2，自引：0，他引：2  

董德凡  叶冬梅 《岩矿测试》1994,13(1):41-44

研究了低功率微波等离子体炬原子发射光谱法（ＭＰＴ－ＡＥＳ）对Ｆｅ，Ａｌ的测定。样品经气动雾化后，分别以流动注射与连续式两种方式引入ＭＰＴ。考察了用这两种进样方式时ＭＰＴ－ＡＥＳ的分析性能，证明低功率ＭＰＴ－ＡＥＳ具有良好的分析特性。  相似文献   

Eolian deposition determined by the oxygen plasma furnace     

P. S. A. Jones 《地球表面变化过程与地形》1984,9(5):479-484

The oxygen plasma furnace enables small samples of clastic sediment to be separated from filter papers at low temperatures without physical or chemical alteration of the sediment. This technique provides a suitable treatment for processing very small samples of alpine eolian sediment, enabling their grain size distribution, mineralogy, and origin to be determined.  相似文献   

Type Ia supernovae: An explosion in the regime of a convergent delayed detonation wave     

N. V. Dunina-Barkovskaya  V. S. Imshennik  S. I. Blinnikov 《Astronomy Letters》2001,27(6):353-362

The model of a presupernova’s carbon-oxygen (C-O) core with an initial mass of 1.33 M _⊙, an initial carbon abundance X _C ⁽⁰⁾ =0.27, and a mean rate of increase in mass of 5 × 10^?7 M _⊙ yr^?1 through accretion in a binary system evolved from the central density and temperature ρ_c=10⁹ g cm^?3 and T _c=2.05 × 10⁸K, respectively, by forming a convective core and its subsequent expansion to an explosive fuel ignition at the center. The evolution and explosion equations included only the carbon burning reaction ¹²C+¹²C with energy release corresponding to the complete conversion of carbon and oxygen (at the same rate as that of carbon) into ⁵⁶Ni. The ratio of mixing length to convection-zone size α_c was chosen as the parameter. Although the model assumptions were crude, we obtained an acceptable (for the theory of supernovae) pattern of explosion with a strong dependence of its duration on α_c. In our calculations with sufficiently large values of this parameter, α_c=4.0 × 10^?3 and 3.0×10^?3, fuel burned in the regime of prompt detonation. In the range 2.0×10^?3≥α_c≥3.0×10^?4, there was initially a deflagration with the generation of model pulsations whose amplitude gradually increased. Eventually, the detonation regime of burning arose, which was triggered from the model surface layers (with m ? 1.33 M _⊙) and propagated deep into the model up to the deflagration front. The generation of model pulsations and the formation of a detonation front are described in detail for α_c=1.0 × 10^?3.  相似文献