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2.
1 IntroductionAnicecoreobtainedfrom polarglaciersoricesheetsisoneofthemostimportantarchivestoreconstructpaleoclimaticandpaleoatmosphericcondition .Informationonpale o environmentcanbeextractedfromicecoresaschemicaland/orphysicalsignals.Amongthechemicalsignals,heavymetalsarenotedassignalsofterrestrialenvironmentalchangeandanthropogenicpollution (e.g .Murozumietal.1 969;NgandPatterson 1 981 ;Hongetal.1 994) .SinceconcentrationsofmostofthemetalsinpolarsnowincentralGreen landareatorbelowthepptl…  相似文献   
3.
We have observed the eclipsing low-mass X-ray binary MS 1603.6+2600 with Chandra for 7 ks. The X-ray spectrum is well fit with a single absorbed power law with an index of ∼2. We find a clear sinusoidal modulation in the X-ray light curve with a period of  1.7 ± 0.2 h  , consistent with the period of 1.85 h found before. However, no (partial) eclipses were found. We argue that if the X-ray flare observed in earlier X-ray observations was a type I X-ray burst, then the source can only be an accretion disc corona source at a distance of ∼11–24 kpc (implying a height above the Galactic disc of ∼8–17 kpc). It has also been proposed in the literature that MS 1603.76+2600 is a dipper at ∼75 kpc. We argue that, in this dipper scenario, the observed optical properties of MS 1603.6+2600 are difficult to reconcile with the optical properties one would expect on the basis of comparisons with other high-inclination, low-mass X-ray binaries, unless the X-ray flare was not a type I X-ray burst. In that case, the source can be a nearby soft X-ray transient accreting at a quiescent rate, as was proposed by Hakala et al., or a high-inclination source at ∼15–20 kpc.  相似文献   
4.
1 INTRODUCTION One of the most intriguing phenomena in the late Neoproterozoic (~750 to 543 Ma) is the globa occurrence of thin carbonates that directly overlie glacial deposits in almost every continent (Kennedy 1996; Hoffman et al., 1998; Hoffman and Schrag 2002; Brasier and Shields, 2000; James et al., 2001 Jiang et al., 2003; Nogueira et al., 2003). These “cap carbonates”, commonly several to tens of meters thick, have attracted enormous interests because o their unusually negati…  相似文献   
5.
Chemical structure of Jurassic vitrinites isolated from the coals in basins in NW China have been checked using solid state 13C NMR and flash pyrolysis-GC/MS. Study shows some Jurassic collodetrinites are rich in aliphatic products in pyrolysates, consisting with the high amount of methylene carbon in 13C NMR spectra. In contrast, pyrolysates of Jurassic collotelinites are rich in phenols and alkylbenzenes. Also one Pennsylvanian and one Permian vitrinite selected from the Ordos basin, NW China have been checked for comparison. The proportion of aliphatics is low in pyrolysates, and aliphatic carbon peak in 13C NMR spectrum of Permian vitrinite is mostly composed of gas-prone carbons compared with collodetrinites in those Jurassic basins. But both pyrolysis and 13C NMR data shows the Pennsylvanian vitrinite is not only gas-prone but also oil-prone. Relatively high proportion of long chain aliphatic structure of some Jurassic vitrinite in Junggar, Turpan-Hami basins may be due to the contribution of liptodetrinites, which may be included during the formation of vitrinites. And it seems that suberinite is the most possible precursor of long chain aliphatics in the structure of Jurassic collodetrinite.  相似文献   
6.
This paper presents an example of application of the double solid reactant method (DSRM) of Accornero and Marini (Environmental Geology, 2007a), an effective way for modeling the fate of several dissolved trace elements during water–rock interaction. The EQ3/6 software package was used for simulating the irreversible water–rock mass transfer accompanying the generation of the groundwaters of the Porto Plain shallow aquifer, starting from a degassed diluted crateric steam condensate. Reaction path modeling was performed in reaction progress mode and under closed-system conditions. The simulations assumed: (1) bulk dissolution (i.e., without any constraint on the kinetics of dissolution/precipitation reactions) of a single solid phase, a leucite-latitic glass, and (2) precipitation of amorphous silica, barite, alunite, jarosite, anhydrite, kaolinite, a solid mixture of smectites, fluorite, a solid mixture of hydroxides, illite-K, a solid mixture of saponites, a solid mixture of trigonal carbonates and a solid mixture of orthorhombic carbonates. Analytical concentrations of major chemical elements and several trace elements (Cr, Mn, Fe, Ni, Cu, Zn, As, Sr and Ba) in groundwaters were satisfactorily reproduced. In addition to these simulations, similar runs for a rhyolite, a latite and a trachyte permitted to calculate major oxide contents for the authigenic paragenesis which are comparable, to a first approximation, with the corresponding data measured for local altered rocks belonging to the silicic, advanced argillic and intermediate argillic alteration facies. The important role played by both the solid mixture of trigonal carbonates as sequestrator of Mn, Zn, Cu and Ni and the solid mixture of orthorhombic carbonates as scavenger of Sr and Ba is emphasized.
Luigi Marini (Corresponding author)Email:
  相似文献   
7.
以1,4—苯二酚和不同的短链脂肪酸为基本原料,经溴代、加成、形成酰卤和酰化等反应,合成了六种新的溴化脂肪酸—2,3,5,6—四溴—1,4—苯二酯。通过对产物的碳、氢、溴等元素的定量分析,以及红外吸收光谱和氢核磁共振谱的研究,验证了化合物的结构。  相似文献   
8.
Molecular-level characterization of natural organic matter (NOM) has been elusive due to the inherent complexity of natural organic mixtures and to the fact that individual components are often polar and macromolecular. Electrospray ionization (ESI) is a “soft” ionization technique that ionizes polar compounds from aqueous solution prior to injection into a mass spectrometer. The highest resolution and mass accuracy of compounds within NOM have been achieved when ESI is combined with an ultrahigh-resolution mass spectrometer such as the Fourier transform ion cyclotron resonance mass spectrometer (FT-ICR MS). With this technique, individual molecules within a variety of natural organic mixtures can be detected and their elemental composition can be determined. At low mass-to-charge (m/z) ratio, the resolution is high enough to assign exact molecular formulas allowing specific components of these mixtures to be identified. In addition to molecular identification, we can now use ESI FT-ICR MS to examine molecular-level changes in different organic mixtures as a function of relevant geo-processes, such as microbial alterations and photochemistry. Here we present the results from the application of ESI FT-ICR MS to two geochemical questions: (1) the effect of photoirradiation on the molecular composition of fulvic acids and (2) the role of protozoan grazers in the modification of DOM in aquatic systems.  相似文献   
9.
用6-DMAP抑制受精卵第二极体排放的方法诱导缢蛏三倍体的试验.结果表明:6-DMAP在100~500μmol/dm^3处理浓度范围内均可以诱导出三倍体,随着药物处理浓度和处理时间的提高,三倍体倍化率和D形幼虫畸形率有不同程度的提高,而D形幼虫孵化率会随之下降.综合来看,在30%卵子受精并出现第一极体,6-DMAP浓度为300μmol/dm^3和处理持续时间为20min时的处理组的处理效果优于其他处理组组合.  相似文献   
10.
不同生长期坛紫菜多糖中组分含量的变化   总被引:3,自引:0,他引:3  
于1990-1991年,运用^13C-NMR和化学分析方法研究南方产和移植北方养殖的不同生长发育阶段坛紫菜多糖的组分变化,结果表明,随着藻体生长发育,坛紫菜琼胶中3,6-内醚-L-半乳糖和6-OCH3-D-半乳糖的含量逐渐增加,而硫酸基的含量呈现先增加后减少的规律;北移坛紫菜琼胶中3,6-内醚-L-半乳糖的含量高于南方坛紫菜,而硫酸基和6-OCH3-D-半乳糖的含量低于南方坛紫菜。  相似文献   
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