Palaeoenvironmental and diagenetic reconstruction of a closed‐lacustrine carbonate system – the challenging marginal setting of the Miocene Ries Crater Lake (Germany)     

《Sedimentology》2018,65(1):235-262

Chemostratigraphic studies on lacustrine sedimentary sequences provide essential insights on past cyclic climatic events, on their repetition and prediction through time. Diagenetic overprint of primary features often hinders the use of such studies for palaeoenvironmental reconstruction. Here the potential of integrated geochemical and petrographic methods is evaluated to record freshwater to saline oscillations within the ancient marginal lacustrine carbonates of the Miocene Ries Crater Lake (Germany). This area is critical because it represents the transition from shoreline to proximal domains of a hydrologically closed system, affected by recurrent emergent events, representing the boundaries of successive sedimentary cycles. Chemostratigraphy targets shifts related to subaerial exposure and/or climatic fluctuations. Methods combine facies changes with δ ¹³C–δ ¹⁸O chemostratigraphy from matrix carbonates across five closely spaced, temporally equivalent stratigraphic sections. Isotope composition of ostracod shells, gastropods and cements is provided for comparison. Cathodoluminescence and back‐scatter electron microscopy were performed to discriminate primary (syn‐)depositional, from secondary diagenetic features. Meteoric diagenesis is expressed by substantial early dissolution and dark blue luminescent sparry cements carrying negative δ ¹³C and δ ¹⁸O. Sedimentary cycles are not correlated by isotope chemostratigraphy. Both matrix δ ¹³C and δ ¹⁸O range from ca −7·5 to +4·0‰ and show clear positive covariance (R  = 0·97) whose nature differs from that of previous basin‐oriented studies on the lake: negative values are here unconnected to original freshwater lacustrine conditions but reflect extensive meteoric diagenesis, while positive values probably represent primary saline lake water chemistry. Noisy geochemical curves relate to heterogeneities in (primary) porosity, resulting in selective carbonate diagenesis. This study exemplifies that ancient lacustrine carbonates, despite extensive meteoric weathering, are able to retain key information for both palaeoenvironmental reconstruction and the understanding of diagenetic processes in relation to those primary conditions. Also, it emphasizes the limitation of chemostratigraphy in fossil carbonates, and specifically in settings that are sensitive for the preservation of primary environmental signals, such as lake margins prone to meteoric diagenesis.  相似文献   

Responses of nutrient biogeochemistry and nitrogen cycle to seasonal upwelling in coastal waters of the eastern Hainan Island     

Nan Zhou  Sumei Liu  Guodong Song  Yunyan Zhang  Lingyan Wang  Xiaoyan Ning 《海洋学报(英文版)》2022,41(6):99-113

The coastal upwelling has profound influence on the surrounding ecosystem by supplying the nutrient-replete water to the euphotic zone. Nutrient biogeochemistry was investigated in coastal waters of the eastern Hainan Island in summer 2015 and autumn 2016. From perspectives of nutrient dynamics and physical transport, the nutrient fluxes entered the upper 50 m water depth（between the mixed layer and the euphotic zone） arisen from the upwelling were estimated to be 2.5-5.4 mmol/（m²·d）,...  相似文献   

4个代表站点的珊瑚δ18O数据对热带印度洋气候变率的反演能力分析*     

陈云帆  陈天然  龙上敏  陈泽生  杜岩 《热带海洋学报》2022,41(1):82-93

珊瑚中的δ¹⁸O含量可以高精度地记录热带海洋中的气候变率及气候变化信息, 从而弥补器测观测时间长度有限的缺陷, 为反演过去长期的气候状况提供了可能。热带印度洋的气候模态通过海气相互作用影响周边区域甚至全球的气候, 具有重要的研究意义。本文对比分析了1880—1999年间热带印度洋4个站点(肯尼亚、坦桑尼亚、塞舌尔、明打威)的珊瑚δ¹⁸O数据, 研究了其对热带印度洋气候的反演情况。结果显示, 珊瑚δ¹⁸O对海表温度(sea surface temperature, SST)的长期变化趋势反演良好, 珊瑚δ¹⁸O与局地SST在季节循环中保持一致, 且在低温季节对SST的变化更为敏感。此外, 4个站点的珊瑚δ¹⁸O对印度洋海盆模态(Indian Ocean Basin Mode, IOBM)和印度洋偶极子模态(Indian Ocean Dipple Mode, IODM)有一定的表征能力, 并且δ¹⁸O记录的热带印度洋年际变率受年代际变率调制。本文的研究结果表明, 珊瑚δ¹⁸O数据对于了解古气候时期热带印度洋气候变率具有重要的指示意义, 但同时也需要综合考虑不同站点的信息来完整地反映印度洋在历史时期的气候变化情况。  相似文献   

夏季楚科奇海河水与海冰融化水组分的空间变化特征   总被引：2，自引：1，他引：1  

童金炉  陈敏  潘红  杨伟锋  张润  郑敏芳  邱雨生 《海洋学报》2014,36(10):90-102

通过对2008年夏季楚科奇海水氧同位素组成的分析,运用S、δ18 O的质量平衡关系计算出河水组分和海冰融化水组分的份额,揭示出楚科奇海河水和海冰融化水组分的空间变化规律,并探讨其影响因素。楚科奇海河水组分的份额介于1.9%~18.4%之间,呈现随深度增加而降低的趋势;河水组分积分高度的变化范围为1.3~16.6m,平均为(4.8±4.0)m。河水组分份额与积分高度均呈现东高西低、北强南弱的特征,与太平洋入流东侧为富含河水组分的阿拉斯加沿岸流、西侧为低河水组分的白令海陆架水,以及北部海域受波弗特流涡埃克曼辐聚作用的影响有关。海冰融化水份额呈现随深度增加而降低的趋势,20~30m以深受到冬季海冰形成时所释放盐卤水的明显影响。海冰融化水积分高度的变化范围为-3.2~1.7m,平均值为(-0.3±1.2)m,其空间分布呈现东低西高、南强北弱的特征,与太平洋入流输入通量的时间变化以及输入路径的西偏有关。  相似文献   

Channelized fluids in subducted continental crust: constraints from δD–δ18O of quartz and fluid inclusions in quartz veins from the Chinese Continental Scientific Drilling Project     

《International Geology Review》2012,54(13):1443-1463

Fluid inclusions hosted by quartz veins in high-pressure to ultrahigh-pressure (HP-UHP) metamorphic rocks from the Chinese Continental Scientific Drilling (CCSD) Project main drillhole have low, varied hydrogen isotopic compositions (δD?=??97‰ to??69‰). Quartz δ¹⁸O values range from??2.5‰ to 9.6‰; fluid inclusions hosted in quartz have correspondingly low δ¹⁸O values of??11.66‰ to 0.93‰ (T _h?=?171.2～318.8°C). The low δD and δ¹⁸O isotopic data indicate that protoliths of some CCSD HP-UHP metamorphic rocks reacted with meteoric water at high latitude near the surface before being subducted to great depth. In addition, the δ¹⁸O of the quartz veins and fluid inclusions vary greatly with the drillhole depth. Lower δ¹⁸O values occur at depths of ～900–1000 m and ～2700 m, whereas higher values characterize rocks at depths of about 1770 m and 4000 m, correlating roughly with those of wall-rock minerals. Given that the peak metamorphic temperature of the Dabie-Sulu UHP metamorphic rocks was about 800°C or higher, much higher than the closure temperature of oxygen isotopes in quartz under wet conditions, such synchronous variations can be explained by re-equilibration. In contrast, δD values of fluid inclusions show a different relationship with depth. This is probably because oxygen is a major element of both fluids and silicates and is much more abundant in the quartz veins and silicate minerals than is hydrogen. The oxygen isotope composition of fluid inclusions is evidently more susceptible to late-stage re-equilibration with silicate minerals than is the hydrogen isotope composition. Therefore, different δD and δ¹⁸O patterns imply that dramatic fluid migration occurred, whereas the co-variation of oxygen isotopes in fluid inclusions, quartz veins, and wall-rock minerals can be better interpreted by re-equilibration during exhumation.

Quartz veins in the Dabie-Sulu UHP metamorphic terrane are the product of high-Si fluids. Given that channelized fluid migration is much faster than pervasive flow, and that the veins formed through precipitation of quartz from high-Si fluids, the abundant veins indicate significant fluid mobilization and migration within this subducted continental slab. Many mineral reactions can produce high-Si fluids. For UHP metamorphic rocks, major dehydration during subduction occurred when pressure–temperature conditions exceeded the stability of lawsonite. In contrast, for low-temperature eclogites and other HP metamorphic rocks with peak metamorphic P–T conditions within the stability field of lawsonite, dehydration and associated high-Si fluid release may have occurred as hydrous minerals were destabilized at lower pressure during exhumation. Because subduction is a continuous process whereas only a minor fraction of the subducted slabs returns to the surface, dehydration during underflow is more prevalent than exhumation even in subducted continental crust, which is considerably drier than altered oceanic crust.  相似文献   

2006～2008年重庆大气降水δD和δ18O特征初步分析   总被引：6，自引：0，他引：6       下载免费PDF全文

李廷勇  李红春  沈川洲  杨朝秀  李俊云  衣成城  袁道先  王建力  谢世友 《水科学进展》2010,21(6):757-764

大气降水稳定同位素组成受到温度、蒸发、水汽源地等多种因素的复杂影响,在不同时间和不同地区具有很大差异.通过分析2006~2008年间重庆雨水样品的δD和δ18O,初步建立了当地的大气降水线方程.当地的大气降水稳定同位素组成在不同季节变化明显:夏季降水中的稳定同位素值普遍偏轻,而冬季降水中稳定同位素值普遍偏重.水汽来源是控制当地大气降水稳定同位素组成的最重要原因,而蒸发作用等是控制短期次降水事件中雨水稳定同位素组成的重要影响因素.  相似文献   

新月细柱藻的分离培养及形态和分子鉴定     

李海涛  杨官品  张秀芳  张健 《中国海洋大学学报(自然科学版)》2007,37(4):627-630,620

自胶州湾分离培养2株微藻(MGB0401和MGB0402)。经形态学鉴定为新月细柱藻(Cylindrotheca closterium)。MGB0401和MGB0402的18S核糖体RNA基因(rDNA)扩增片段长度为1775 bp,存在10个碱基差异。MGB0401和MGB0402的rbcL基因扩增片段长度为1190 bp,有45个碱基差异,对应的氨基酸序列存在4个氨基酸残基差异。系统学分析表明,2株微藻与已知新月细柱藻相应序列亲缘关系最近。微藻常用系统学分析用基因的序列不仅是分类鉴定的补充指标,也是不同研究结果相互比较的重要基础。  相似文献   

基于氢氧稳定同位素的武汉北部新城地表水-地下水转换关系研究          下载免费PDF全文

杨艳林  靖晶  赵永波  何军  杜小锋 《中国地质》2022,49(3):706-715

【研究目的】揭示武汉北部新城地表水、地下水的氢氧稳定同位素特征及其相互作用。【研究方法】2019年，采集、测定了降水样7件、河水样6件、水库样14件、民井样98件、泉水样3件和钻孔样11件，并收集到武汉站1986—1998年的监测数据50件，以空间分析和流域分析为基础，氢氧稳定同位素分析为手段。【研究结果】（1）武汉降水氢氧同位素随季节变化，并表现出“降雨效应”明显、“温度效应”不明显的特点；（2）地表水在枯水期受到强烈的蒸散发，表现出一定的“地貌效应”与“干支流效应”的特征；（3）民井、泉和钻孔等地下水均源于大气降水，表现出“含水层埋深效应”与“山区平原效应”的特点；（4）枯水期，界河流域中界河获得了上游水库和地下水的补给，夏家寺水库流域中夏家寺水库得到了地下水补给。【结论】氢氧同位素能显著提高武汉北部新城地表水-地下水相互转换规律的认识。创新点：利用各类水体氢氧同位素组成及空间分布特征，揭示了武汉北部新城降水、地表水和地下水相互转换的规律  相似文献