Experimental Study on Treatment of High-concentrated Sulfur Wastewater by Process of Depositing Natrojarosite and Its Environmental Significance     

MA Shengfeng WANG Changqiu LU Anhuai GUO Yanjun HE Hongliao 《《地质学报》英文版》2007,81(2):330-334

High-concentrated sulfur wastewater with sodium and COD （chemical oxygen demand） up to 26000 mg/L from a chemical plant, Jiangsu Province of China has been treated by deposition of natrojarosite in lab. The results indicated that the COD of the wastewater was decreased sharply from 26000 mg/L to 1001 mg/L, with removal rate of COD up to 96% by twice precipitations of natrojarosite and twice oxidation of H202. The treated sulfur wastewater reached the requirement of subsequent biochemical treatment to water quality. The optimal operational parameters should be controlled on pH value between 2.50 and 3.20 and 50 g FeCly6H2O solid added in per liter wastewater. The study provided an experimental basis for pretreatment of high-concentrated sulfur wastewater and proposed a new mineralogical method on treatment of other wastewaters. Depositing process of jarosite and its analogs should be able to be used to treat wastewater from mine and other industries to remove S, Fe and other toxic and harmful elements, such as As, Cr, Hg, Pb, etc. in the water.  相似文献   

Study on numerical simulation of organic pollutant transport in groundwater northwest of Laixi          下载免费PDF全文

ZHU Heng-hua  JIA Chao  XU Yu-liang  YU Ze-min  YU Wei-jiang 《地下水科学与工程》2018,6(4):293-305

The construction and hydrogeological area in the low hill, which is northwest of Laixi City and in the east of Shandong Province more precisely, is one of Dagu River’s groundwater source. Regarding COD as the typical pollutant according to general situation of groundwater pollution in aforementioned area, a three-dimensional advection-dispersion model was established to simulate the transport of organic pollutants under two accident conditions. In addition, the effect of corresponding dispersity was analyzed. The results show that COD transport is mainly in accordance with the direction of groundwater flow, pollutant concentration and its gradient as well as the rule of narrower pollution range in deeper stratum. Moreover, COD is mainly transported and diffused in groundwater of sandy soil in the first and second layers. However, under accident condition II, the pollutant concentration begins to decay gradually after its transport and diffusion tends to be stable. Besides, in terms of dominance, dispersion is to transverse transport of pollutants what advection is to longitudinal transport. If considering random dispersion, the final results see higher peak concentration of COD and longer transverse distance from pollution center compared to transport route. What’s more, the pollution plume changes and concentration isocline becomes slightly irregular.  相似文献   

钦州湾海域COD 时空分布及对富营养化贡献分析   总被引：5，自引：0，他引：5  

杨斌  钟秋平  鲁栋梁  林美芳  李尚平 《海洋科学》2014,38(3):20-25

根据2010年4月(春季)和9月(秋季)钦州湾海域现场调查资料,对表层海水中化学需氧量(COD)的时空分布特征进行研究,评价其污染水平,分析COD对该海域富营养化的贡献,并探讨了COD的主要来源及与环境因子之间的关系。研究结果表明,钦州湾海域表层COD的平均浓度为(1.21±0.55)mg/L,浓度范围为0.57~2.38 mg/L,水平分布呈现由湾内向湾外逐渐递减的趋势;秋季研究海域COD污染水平高于春季;COD对富营养化的贡献范围为42.1%~64.7%,平均贡献为(50.3±6.7)%,贡献随着富营养化指数的增加而减小;COD与盐度、pH存在显著负相关,而与DIN、SiO-23Si存在显著正相关。COD时空分布主要受陆地径流、陆源输入和水动力过程的影响,COD是影响钦州湾海域富营养化的重要因素,但并非决定性因子,富营养化程度加重时来自营养盐的贡献表现更为突出。  相似文献   

Biodegradability Assessment and Treatability of High Strength Complex Industrial Park Wastewater     

Ahmet Baban 《洁净——土壤、空气、水》2013,41(10):976-983

Industrial park wastewater (IPWW) includes complex non‐biodegradable organic compounds. A wastewater treatability study using biodegradability assessment approach was carried out for an industrial park housing mainly textile and machinery sectors. Biodegradable and inert chemical oxygen demand (COD) fractions with soluble and particulate counterparts were experimentally estimated by implementing respirometric methods. Aerobic batch test methods and oxygen uptake rate profiles were used to map kinetic parameters and COD fractions. Denitrification potential was also determined by application of anoxic batch tests. Relevant kinetic constants, stoichiometric, and design parameters were determined for biological processes. Tests were carried out for raw and physico‐chemically pre‐treated IPWW. Hence, it was aimed to assess the effects and necessity of pre‐treatment on biological processes. Biological mineralization, nitrification, and denitrification processes were also designed and tested using a bench scale continuous treatment model for pre‐treated IPWW. The sum of initial inert soluble COD fraction and production of soluble microbial products decreased about 25% for the case of pre‐treated IPWW as compared to raw IPWW. Eighty‐three percent total COD and 89% total Kjeldahl nitrogen removal efficiencies were attained for the modeling experiments of pre‐treated IPWW. Results showed the significance of pre‐treatment if complex strength industrial wastewaters are to be biologically treated.  相似文献   

天然水镁石及其煅烧产物对臭氧化降解水中苯酚的效果研究   总被引：1，自引：0，他引：1  

何坤  董玉明  李真  尹琳  张爱民 《矿物岩石地球化学通报》2007,26(2):155-159

为有效去除工业废水中的苯酚,本文结合臭氧化技术,引入天然碱性矿物水镁石及其煅烧产物氧化镁作为催化剂,进行了催化臭氧化处理水中苯酚的研究。结果表明,加入的两种碱性矿物对臭氧化降解苯酚都有显著的催化效果。同时,碱性矿物的加入明显的改变了臭氧化过程中水体的pH值,从而对促进苯酚的降解起到了主导作用;除此之外,吸附实验及改变催化剂加入量的实验表明,碱性矿物表面对羧酸的吸附作用在一定程度上也导致苯酚降解效率的提高。本文工作为臭氧化降解水中苯酚提供了一种简便实用的处理方法,同时为天然水镁石矿物找到了新的应用领域。  相似文献   

利用黄钾铁矾类矿物形成过程预处理高浓度含硫废水   总被引：1，自引：0，他引：1  

马生凤王长秋  鲁安怀郭延军　杨磊 《岩石矿物学杂志》2005,24(6):547-550

利用黄钾铁矾类矿物形成过程对某高浓度工业含硫废水进行预处理,除去一定量的SO42-,使溶液中低价态的硫继续转化成SO42-,再进行氧化处理。采取二次沉淀除去溶液中更多的SO42-,大大降低了该水样的COD值。通过实验得出沉淀的最佳工艺条件为pH值为2.50～3.20,氯化铁晶体(FeCl3.6H2O)最佳投入量为50g/L。经过两次黄钾铁矾类矿物沉淀过程,该废水COD的去除率达到85.29%,结合H2O2的氧化处理,COD去除率可达96%。为高浓度含硫废水进入生化处理前的预处理提供了实验依据。  相似文献   

重铬酸钾法测定废水COD条件改进的研究   总被引：3，自引：0，他引：3  

黄国柱  夏志奇 《华东地质学院学报》1996,19(3):295-299

本提出用ＣｕＳＯ４作催化剂，在Ｈ２ＳＯ４－Ｈ２ＰＯ４溶液中，重铬酸钾回流测定废水ＣＯＤ的方法，实验表明，最佳测定条件为：ＣｕＳＯ４浓度为７×１０＾－２ｍｏｌ．Ｌ＾－１（混酸溶液）：Ｈ２ＳＯ４：Ｈ３ＰＯ４＝５：１（体积比）回流时间２ｈ，通过与标准方法对比，测定结果满意，本方法的优点是：不需用贵重金试剂Ａｇ２ＳＯ４，改用ＣｕＳＯ４作催化剂，精密度高，准确性好，具有一定的实用价值。  相似文献   

垃圾渗滤液的特征污染组分在包气带中的迁移转化规律   总被引：1，自引：0，他引：1  

高秀花  朱锁  李海明 《地下水》2008,30(3):37-40

通过室内土柱实验,研究了垃圾渗滤液的特征污染组分氮、COD在包气带不同介质中的迁移转化特征。实验结果表明,岩性不同的包气带介质是影响氮素、COD迁移转化的重要因素之一,不同介质对氮、COD的净化能力不同;渗滤液对地下水不会造成氮素污染,但会造成有机污染。  相似文献   

Fenton 试剂降解壳聚糖废液的初步研究   总被引：1，自引：0，他引：1  

李玫  陈国华  侯进  汪学军 《中国海洋大学学报(自然科学版)》2004,34(1):84-90

通过单因素分析实验 ,研究了 Fenton试剂降解壳聚糖制备废液过程中各影响因子的作用机制 ,初步得出了其最佳作用范围。通过正交匹配实验 ,确定了最佳操作条件为 :初始 p H=2 .5,终了p H=1 0 ,1 0 g Fe/ L的 Fe2 溶液 1 5m L,30 % H2 O2 2 m L,t(搅拌 ) =80 min,t(静置 ) =8h,T=348K,经验证 COD去除率达到 58.91 %。在常温下 ,利用紫外扫描法简单分析了 Fenton试剂对醋酸钠难降解有机物的降解效率 ,达到了 1 6.39%。  相似文献   

秦山核电站邻近水域溶解氧和化学耗氧量的分布特征     

龚敏  王正方 《海洋学研究》1991,9(2):27-33

本文运用秦山核电站邻近水域零点生态调查四个航次中(春、夏、秋、冬)溶解氧和化学耗氧量两要素的检测数据,着重描述溶解氧和化学耗氧量的分布特征,并分析了环境因子对其变化的影响。  相似文献