快速城镇化进程中珠江三角洲高铵地下水赋存环境及驱动因素          下载免费PDF全文

吕晓立  刘景涛  韩占涛  朱亮  杨明楠  李海军 《中国地质》2021,48(6):1770-1780

地下水中高浓度的铵态氮对生活饮用水安全及生态环境存在潜在威胁。相比较硝态氮，高浓度的铵态氮不仅有各种人为来源，天然沉积环境更是造成高铵地下水的主要成因。本文以城镇化快速发展的珠江三角洲为研究区，运用数理统计、主成分分析等方法深入探讨了研究区高铵地下水的赋存环境特征及驱动因素。结果表明，研究区地下水中NH₄⁺质量浓度介于未检出~180 mg/L。研究区1539组地下水样品中，NH₄⁺质量浓度大于10 mg/L的高铵地下水69组，其中含NH₄⁺质量浓度大于30 mg/L的高铵"肥水"23组。对比2005-2008年历史水化学数据，2009-2018年新增建设用地孔隙含水层高铵地下水样品比例增加25%。高铵地下水呈斑块状分布于三角洲平原区第四系底部低洼的基底、洼地等退积层序发育的淤泥质含水层中。淤泥层等富含有机质和总有机碳的沉积层是珠江三角洲地区的"生铵层"，有机氮的矿化是三角洲平原区城市化孔隙含水层中高铵地下水的主要驱动力。城镇化扩张引起生活污水及富铵工业废水的泄漏入渗是城乡结合部高铵地下水铵氮的重要来源。三角洲平原区中性至弱碱性富含有机质的还原环境是高铵地下水的主要成因。风化溶滤、阳离子交换吸附、海陆交互作用是珠江三角洲高铵地下水质演变的主要水文地球化学过程。  相似文献   

论四川盆地三叠系地下水水文地质条件   总被引：3，自引：0，他引：3       下载免费PDF全文

林耀庭 《盐湖研究》2006,14(1):1-8

四川盆地三叠系地下水可划分出碎屑岩孔隙裂隙和碳酸盐岩岩溶裂隙两大储集类型。按此处构造开启程度和埋深条件等的不同,下中三叠统地下水有沉积变质水和渗入淋滤水两种基本成因类型,水动力特征各异。沉积变质水处于深埋封闭条件,受地静压力驱动控制;渗入淋滤水分布于背斜露头区和浅部地区,受静水压力驱动控制。并由此控制了盆地三叠系盐类的保存条件。  相似文献   

XANES analysis of the mechanisms of arsenic removal in biological iron and manganese treatment unit     

Yoko Fujikawa Daisuke Yoneda Atushi Minami Hiroshi Yashima Toshio Tonokai Sotoji Tani Masami Fukui Tatuhide Hamasaki Masataka Sugahara 《中国地球化学学报》2006,25(B08):113-113

Biological iron and manganese removal utilizing indigenous iron and manganese oxidizing bacteria （IRB hereafter） in groundwater can also be applied to arsenic removal according to our pilot-scale test. The arsenic removal probably occurred through sorption and complexation of arsenic to iron and manganese oxides formed by enzymic action of IRB. We investigated the chemical properties of iron and manganese oxides in IRB floc and the valence state of arsenic sorbed to the floc to clarify the mechanisms of the arsenic [especially As （Ⅲ）] removal. The floc samples were collected from two drinking water plants using IRB （Jyoyo and Yamatokoriyama, Japan）, and our pilot - scale test site where arsenic and iron removal using IRB is under way （Mukoh, Japan）. The Jyoyo and Yamatokoriyama IRB floc samples were subjected to As （Ⅲ） and As（Ⅴ） sorption experiments. The elemental composition of the floc samples was measured. XANES spectra were collected on As, Fe and Mn K-edges at synchrotron radiation facility Spring 8 （Hyogo, Japan）. FT-IR and the X-ray diffraction spectra of the samples were also obtained. The IRB floc contained ca. 35 % Fe, 0.3%-3.5% Mn and 2%-6% P. The samples were highly amorphous and contained ferrihidrites and hydrated iron phosphate. According to XANES analyses of IRB, As associated with IRB was in ＋5 valence state when As （Ⅲ） （or As （Ⅴ）） was added in laboratory sorption test, Fe in ＋3 valence state, and Mn a mixture of＋3 and ＋4 valence states. Small shift was observed in the XANES spectra of IRB on As K-edge as the equilibration time of the sorption experiment was increased. Gradual oxidation of a small amount of As （Ⅲ） associated with IRB or change in arsenic binding with sorption site were the probable mechanism.  相似文献   

Metal contamination in southern Brazil vineyard softs     

《中国地球化学学报》2006,25(B08):120-120

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Analysis of the effect of geology, soil properties, and land use on groundwater quality using multivariate statistical and GIS methods     

Jin-Soo Lee Kyung-Seok Ko Tong-Kwon Kim Jae Gon Kim Seong-Hyun Cho In-Suk Oh 《中国地球化学学报》2006,25(B08):152-152

The regional survey of groundwater used as a small water supply system was performed to know the effect of geology, soil properties and land use on groundwater quality at Nonsan City, Korea. A total of 126 groundwater samples were collected and analyzed at the study area. The multivariate statistical methods, principal components analysis and discriminant analysis, and GIS technique were used for the quantitative interpretation of groundwater quality. The study area is mainly composed of Precambrian gneiss, Jurassic granite, and Cretaceous volcanics, and metasedimentary rocks of the Ogcheon zone. The land use was grouped as paddy, upland, grassland, resident, point source, industrial area, and water system. The soil properties were classified as 4 major groups, Entisols, Alfisols, Inceptisols, and Ultisols, by the degree of development, and reclassified as 11 subgroups. The modified and simplified geologic map, soil map, and land use map were made by using ARCGIS soft-ware. The area of geology, soil property, and land use affecting the groundwater quality for each well were also calculated by ARCGIS soft-ware to acquire the quantitative parameters for multivariate statistical analysis. The monitoring results of groundwater in the study area showed that 13%-21% of the groundwater samples exceeded the portable water guideline and the main causes were turbidity, bacteria, arsenic and nitrate-N. The spatial distribution of each component showed the close relationship between groundwater quality and geology reflecting the topography, land use.  相似文献   

Application of HCA and PCA in the discrimination of not polluted tubular wells from tubular wells with incidence of anthropogenic pollution in Western Amazon Region     

《中国地球化学学报》2006,25(B08):165-165

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A pronounced dry event recorded around 4.2 ka in brine sediments from the northern Red Sea     

Helge W. Arz  Frank Lamy  Jürgen Ptzold 《Quaternary Research》2006,66(3):432-441

Partly laminated sediments were sampled from the brine-filled, anoxic Shaban Deep basin in the northern Red Sea. At about 4200 cal yr BP more than two millennia of anoxic sedimentation is replaced by a sub-oxic facies strongly suggesting the episodic absence of the brine. At the same time stable oxygen isotopes from surface dwelling foraminifera show a sharp increase (within less than 100 yr) pointing to a strong positive salinity anomaly at the sea surface. This major evaporation event significantly enhanced the renewal of deep water and the subsequent ventilation of the small Shaban Deep basin. The timing and strength of the reconstructed environmental changes around 4200 cal yr BP suggest that this event is the regional expression of a major drought event, which is widely observed in the neighboring regions, and which strongly affected Middle East agricultural civilizations.  相似文献   

Non-volcanic deep low-frequency tremors accompanying slow slips in the southwest Japan subduction zone   总被引：5，自引：1，他引：5  

Kazushige Obara  Hitoshi Hirose 《Tectonophysics》2006,417(1-2):33

Non-volcanic deep low-frequency tremors in southwest Japan exhibit a strong temporal and spatial correlation with slow slip detected by the dense seismic network. The tremor signal is characterized by a low-frequency vibration with a predominant frequency of 0.5–5 Hz without distinct P- or S-wave onset. The tremors are located using the coherent pattern of envelopes over many stations, and are estimated to occur near the transition zone on the plate boundary on the forearc side along the strike of the descending Philippine Sea plate. The belt-like distribution of tremors consists of many clusters. In western Shikoku, the major tremor activity has a recurrence interval of approximately six months, with each episode lasting over a week. The tremor source area migrates during each episode along the strike of the subducting plate with a migration velocity of about 10 km/day. Slow slip events occur contemporaneously with this tremor activity, with a coincident estimated source area that also migrates during each episode. The coupling of tremor and slow slip in western Shikoku is very similar to the episodic tremor and slip phenomenon reported for the Cascadia margin in northwest North America. The duration and recurrence interval of these episodes varies between tremor clusters even on the same subduction zone, attributable to regional difference in the frictional properties of the plate interface.  相似文献   

Les failles récentes des Grands-Moulins (Savoie) : un Sackung (tassement gravitaire) majeur dans les Alpes françaises     

Jean-Claude Hippolyte  Marc Tardy  Gérard Nicoud 《Comptes Rendus Geoscience》2006,338(10):734-741

In Savoy, the Grands-Moulins recent fault scarps, previously interpreted as seismic fault ruptures, are in fact part of a major Sackung (deep seated gravitational spreading) of the French Alps (9 km long). We mapped more than 60 sackung scarps, some of them reaching 1330 m long and 30 m high. These antislope scarps stop the active screes and offset relict Dryassic rock glaciers by 16 m. We present geomorphologic observations attesting for their gravitational origin. This Sackung is primarily due to glacial debuttressing, while seismic shaking could be a triggering mechanism. To cite this article: J.-C. Hippolyte et al., C. R. Geoscience 338 (2006).  相似文献   

Weathering characteristics of arctic islands in northern Norway     

yvind Paasche  Jrund Raukleiv Strmse  Svein Olaf Dahl  Henriette Linge 《Geomorphology》2006,82(3-4):430-452

The arctic islands of the Lofoten-Vesterålen archipelago in northern Norway have a wide distribution of weathered land surfaces commonly located above 250 m with several apparent similarities. In order to investigate the characteristics of (deep) weathering in this region, northern Langøya and Hadseløya were chosen for in-depth analyses. Eight weathering profiles were excavated from various surfaces, and the stratigraphies were logged in detail. Material was collected throughout the weathering horizons, and all samples were subsequently analysed for clay mineralogy (< 63 μm fraction) and grain size distribution. The sampling strategy was complemented by samples from additional saprolites and other landforms such as moraines and rock glaciers. The XRD results indicate that the presence of secondary minerals, such as gibbsite (Al(OH)₃) and kaolinite (Al₂Si₂O₅(OH)₄), are very common throughout the profiles. Gibbsite is an extreme end product of silicate weathering and usually associated with a warmer and more humid climate, as found in Scandinavia during the Tertiary. The grain size analyses (< 63 μm) show that the finer silt fractions (< 8 μm) tend to be high in the profiles (20–40%), with significant amounts of clay (5–15%) demonstrating that the regolith itself is susceptible to frost sorting mechanisms.¹⁰Be exposure dates from in situ quartz knobs on tors and boulders of local origin suggest > 40,000 years of subaerial conditions. Considering the steady surface erosion, this figure should be viewed as an absolute minimum age estimate. Mapping of the superficial sediments and geomorphological features of the study areas has revealed several common morphological features, which indicate dominance of glacial and periglacial processes in the areas lying below the lower boundary of blockfields (c. 250 m). The weathering mantles are not a periglacial end product, but rather a relict tertiary landform that were modulated by permafrost processes as well as biological processes at later stages. The regolith cover constrain the vertical extension of warm-based Quaternary ice sheets challenging the notion of a parabolic ice mass consuming every mountain top of Lofoten and Vesterålen.  相似文献