塞曼石墨炉原子吸收法测定地球化学样品中银元素     

白志斌 《西部资源》2011,(5):55-56

对塞曼效应石墨炉原子吸收法对地质样中痕量银的测定进行了研究。简化了样品处理过程。对地质标样及实际样品分析获得了满意的结果加标回收率为96.2%-103.5%,相对标准偏差为3.04%-4.77%所采用的方法快速、简便,准确。  相似文献   

聚氨酯泡塑富集硫脲解脱-石墨炉原子吸收光谱法测定地质样品中金铂   总被引：5，自引：4，他引：1  

刘向磊  文田耀  孙文军  姚维利  王腾飞  吴俊文 《岩矿测试》2013,32(4):576-580

泡沫塑料常用于富集常规地质样品中的铂族元素,而富集后往往用高温灰化法解脱,此法操作繁琐,温度过高易使铂配合物分解为王水难以提取的不溶性残渣,导致测试结果不稳定、效率低;单独使用20 g/L硫脲溶液解脱,测试结果的重现性差。本文对此方法进行改进,采用50%王水封闭溶解试样,氯化亚锡还原,聚氨酯泡塑富集,20 g/L硫脲-20%盐酸溶液解脱,石墨炉原子吸收光谱法测定金和铂。在盐酸-氯化亚锡体系中,吸附温度为20℃,振荡时间为30 min时,金和铂的回收率均在95%以上,金和铂的检出限分别为0.23 ng/g和0.39 ng/g,精密度(RSD,n=10)分别为1.8%～10.3%和1.3%～13.3%。经国家一级标准物质验证,测定值和标准值基本相符。该方法泡塑解脱时无需高温灰化,用王水多次提取,在100℃沸水浴中即可一次完成,样品处理快捷。与高温灰化法相比,提取温度大为降低,分析流程简单,显著提高了单次测样量,且干扰小、空白值低,可以满足除王水难溶的铂矿种外大部分地质样品快速测定的需要。  相似文献   

中国北方石墨矿床及赋矿孔达岩系碳同位素特征及有关问题讨论   总被引：24，自引：10，他引：14  

陈衍景  刘丛强  陈华勇  张增杰  李超 《岩石学报》2000,16(2):233-244

本文综合了中国北方孔达岩系和石墨矿床的碳同位素数据 10 2件 ,发现片麻岩石墨 透辉岩石墨 <大理岩石墨 <石墨大理岩方解石 <大理岩方解石 ;混合岩化岩石中石墨δ1 3C总介于有机碳和无机碳之间 ;不同地体片麻岩石墨δ1 3C极为一致 ,变化于 - 2 2 .8‰～ - 2 1.48‰ ,略低于世界有机质平均值 - 2 6± 7‰ ;大理岩的原岩碳酸盐δ1 3C高于 2‰ ,与2 330～ 2 0 6 0 Ma期间全球性δ1 3Ccarb正向漂移事件一致。地质流体是碳同位素分馏、均一化的重要因素 ,是石墨矿床的 3种主要碳源之一 ,是碳的 5种存在形式之一 ,也是碳循环的重要媒介和方式 ;导致热液矿床δ1 3C=- 5‰左右的因素较多 ,依据δ1 3Ccalcite - 5‰得出成矿物质和流体来自地幔的结论值得怀疑 ;中国北方孔达岩系形成于古元古代 ,可能为 2 30 0～ 2 0 5 0 Ma。  相似文献   

Microtextural constraints on the interplay between fluid–rock reactions and deformation     

Alexis K. Ault  Jane Selverstone 《Contributions to Mineralogy and Petrology》2008,156(4):501-515

Schists from two mylonitic localities in the footwall of a low-angle normal fault in the eastern Alps record different degrees of embrittlement during exhumation, depending on the extent to which fluid–rock reactions proceeded. At one site, graphitic schists preserve textural evidence for two metamorphic reactions that modified and/or fluid volume: (1) reaction between graphite and aqueous fluid that increased without changing the molar amount of fluid, and (2) replacement of titanite by rutile, calcite, and quartz. The latter reaction involved net consumption of increasingly CO₂-rich fluid. Areas where the first reaction proceeded are associated with abundant Mode I microcracks. Fluid inclusion arrays within the microcracks show that increased from ∼0.1 to 0.6 during decompression from 4.75 to 2 kbar at a reference temperature of 500°C. Titanite consumption is most pronounced within transgranular Mode I microcracks, but microcracks do not crosscut products of this reaction; fluid consumption during reaction was coeval with the end of microcracking, at least on a local scale. At the other site, graphitic schists lack small-scale Mode I cracks as well as evidence for graphite consumption during decompression. SEM imaging shows that graphite is anhedral and pitted at the first site, but occurs in clusters of euhedral grains at the second site. Mass balance calculations demonstrate that rocks with partially consumed graphite were infiltrated by an externally derived, H₂O-rich fluid that drove subsequent graphite-fluid reaction. Evidence for similar fluid infiltration is absent at the second site. Variations in the degree of reaction progress indicate that fluid pathways and deformation style were heterogeneous on the scale of millimeters to kilometers during exhumation from mid-crustal depths.  相似文献   

山东平度闫村石墨矿岩石学特征及找矿标志          下载免费PDF全文

焦丽香  郭加朋  高树学  颜玲亚  欧阳友和 《山东国土资源》2020,36(11)

闫村石墨矿为赋存于古元古代荆山群陡崖组徐村段含石墨变质岩系地层中的区域变质型矿床,属角闪岩相—麻粒岩相,是中深变质作用的产物。在系统采集石墨矿石样品的基础上,对石墨矿石样品进行了化学成分、矿物组成、结构构造、矿物共伴生关系、石墨结构等较为系统的研究。结果表明：矿石中有用组分固定碳含量2.74%～5.36%,平均3.34%,还含有SiO2,TiO2,Al2O3,Fe2O3,FeO,MnO,MgO,CaO等;矿石矿物为石墨,脉石矿物为石英、钾长石、白云母、透辉石、透闪石、黄铁矿、黄铜矿等。越靠近地表,矿石中黏土矿物含量越高,矿物组成越复杂;石墨片径一般在0.2～1.0mm,个别大径达1.2mm,片厚0.03～0.05mm。石墨片受力程度不同,局部有破碎和揉皱现象、泥化现象。闫村石墨矿属于区域变质型矿床,具有明显的找矿标志,赋矿层位、构造位置、岩性特征、岩石类型、地球物理特征,均是寻找该类石墨矿的良好标志。  相似文献   

石墨炉原子吸收法测定地质样品中痕量银     

王兵  唐良宝 《铀矿地质》1996,12(3):180-184

本文介绍了采用硝酸、氢氟酸、高氯酸溶解试样，在５％的盐酸介质中，不经分离，直接测定地质样品中痕量银。银的检出限为５ｎｇ／ｇ，方法灵敏度２．０×１０－１２，相对标准偏差为４％，回收率９５％－１１５％。  相似文献   

Geochemistry of late metamorphic hydrothermal alteration and graphitisation of host rock, Macraes gold mine, Otago Schist, New Zealand   总被引：4，自引：0，他引：4  

D Craw 《Chemical Geology》2002,191(4):257-275

The Macraes gold deposit in the Otago Schist, New Zealand, formed during late metamorphic fluid flow through a lower greenschist facies shear zone. Mineralisation occurred near to the brittle-ductile transition at about 300 °C. Large volumes of host rock in a shear zone up to 120 m thick have been hydrothermally altered by this fluid activity. Most alteration is not structurally controlled apart from proximity to the shear zone. Ductile and brittle microshears traverse the most mineralised rocks and some structural control of fluid flow occurred as well. Fluid flow was slow, similar to that in metamorphic rocks (mm/year) and diffusion through interconnected fluid was a significant chemical process. Localised extensional hydrofractures (m scale) are filled with mineralised quartz. Most alteration of the host rocks was isochemical with respect to the lithophile elements, and mineralised rocks have been variably enriched in As, Au, Sb, W, Mo and Bi, but not Co or Cd. Addition of sulphur has occurred to both host rocks and mineralised rocks, up to 1 wt.% above a background of 0.1 wt.%. Host rock sulphur is mainly pyritic and is not structurally controlled. Mineralised rocks have pyrite and arsenopyrite along microshears. Pyrite, chalcopyrite, sphalerite and galena have formed from sulphidation of silicates with no addition of metals. Graphite has been added to mineralised rocks along microshears, up to 3 wt.% locally, above a background of 0.1 wt.% noncarbonate carbon. Graphite deposition may have occurred as a result of mixing of two fluids, water+methane, and water+carbon dioxide. Graphitisation and sulphidation reactions released low δD water, which accumulated in the slow-moving mineralising fluid. Distinction between this low δD reaction water and meteoric water incursion is difficult.  相似文献   

石墨炉原子吸收法测定地质样品中的微量银     

姜云  王卿 《山东地质》2008,(7):98-100

研究了石墨炉原子吸收法测定地质样品中微量Ag的方法,探索了以NH4IrCl6做基体改进剂的最佳仪器工作条件。在取样0．2000g,定容25mL的情况下,方法检出限为0．010ug/g,用国家标准物质验证,其准确度（RE％）小于10％,10次测定的精密度（RSD％）小于10％。  相似文献   

基于中速-高速摩擦实验研究含碳断层带的电导率特征          下载免费PDF全文

韩明明  杨晓松  姚路  陈进宇  马胜利 《地球物理学报》2019,62(3):967-981

野外地质调查结果显示,断层带常富集碳质.断层带中碳的分布结构是影响断层带电导率特征的一种重要参数.本文在室温、室内湿度和2MPa正应力条件下,对不同石墨含量(3,5,6和7wt%)的石英-石墨混合断层泥模拟样品开展了滑动速率介于500μm·s-1～1m·s-1的摩擦实验及相应的电导率测量,以期研究断层运动对碳分布结构的影响以及断层带电性特征对碳含量及分布的响应情况.结果显示,摩擦滑动能够显著地改变样品的电性特征(电导率大小及其各向异性).在平行滑动面方向(径向),样品电导率随着滑动位移的增加快速增加,在滑动约数十厘米之后,其电导率基本达到稳定状态;在垂直滑动面方向(轴向),样品电导率基本不随摩擦滑动速率和滑动距离而变化.SEM显微结构观测显示,摩擦滑动所引起的电导率各向异性直接反映了石墨分布结构的变化.该研究结果深化了对地震断裂带浅部电性特征的认识,为野外断层带大地电磁测深资料的解释提供了约束,同时对于了解含碳断层的力学性质和弱矿物相在剪切变形中的分布特征及其演化过程等方面也具有重要意义.  相似文献   

Heavy Metals in Black Crabs in the Atlantic Coast (Tenerife,Spain) – Human Risk Assessment     

《洁净——土壤、空气、水》2017,45(1)

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