Elastic collisions in ion irradiation experiments: A mechanism for space weathering of silicates   总被引：1，自引：0，他引：1  

Rosario Brunetto  Giovanni Strazzulla 《Icarus》2005,179(1):265-273

Ion irradiation experiments have been performed on silicates (bulk samples) rich of olivine, pyroxene, and serpentine to simulate the effects of space weathering induced on asteroids by solar wind ions. We have used different ions (H⁺, He⁺, Ar⁺, Ar²⁺) having different energies (from 60 to 400 keV) to weather the samples, probed by Raman spectroscopy and UV-vis-NIR reflectance spectroscopy. All the irradiated materials have shown reddening and darkening of reflectance spectra in the 0.25-2.7 μm spectral range. We have found that the increase of the spectral slope of the continuum across the 1-μm band is strongly related with the number of displacements caused by colliding ions because of elastic collisions with the target nuclei. The spectral slopes have been compared, at increasing ion fluence, with those from irradiated Epinal meteorite. We show that formation of nuclear displacements by solar wind ion irradiation is a physical mechanism that reddens the asteroidal surfaces on a time-scale lower than 10⁶ years.  相似文献   

Sulfurous acid (H₂SO₃) on Io?     

Andreas F. Voegele  Christofer S. Tautermann  Andreas Hallbrucker  Erwin Mayer  Klaus R. Liedl 《Icarus》2004,169(1):242-249

Sulfurous acid (H₂SO₃) has never been characterized or isolated on Earth. This is caused by the unfavorable conditions for H₂SO₃ within Earth's atmosphere due to the high temperatures, the high water content and the oxidizing environment. Kinetic investigations by means of transition state theory showed that the half-life of H₂SO₃ at 300 K is 1 day but at 100 K it is increased to 2.7 billion years. Natural conditions to form H₂SO₃ presumably require cryogenic SO₂ or SO₂/H₂O mixtures and high energy proton irradiation at temperatures around 100 K. Such conditions can be found on the Jupiter moons Io and Europa. Therefore, we calculated IR-spectra of H₂SO₃ which we compared with Galileo's spectra of Io and Europa. From the available data we surmise that H₂SO₃ is present on Io and probably but to a smaller extent on Europa.  相似文献   

The atmospheric signature of Io's Prometheus plume and anti-jovian hemisphere: evidence for a sublimation atmosphere     

Kandis Lea Jessup  John R. Spencer  Robert R. Howell  Miquela Vigel 《Icarus》2004,169(1):197-215

Using the Hubble Space Telescope's Space Telescope Imaging Spectrograph we have obtained for the first time spatially resolved 2000-3000 Å spectra of Io's Prometheus plume and adjoining regions on Io's anti-jovian hemisphere in the latitude range 60° N-60° S, using a 0.1″ slit centered on Prometheus and tilted roughly 45° to the spin axis. The SO₂ column density peaked at 1.25×10¹⁷ cm⁻² near the equator, with an additional 5×10¹⁶ cm⁻² enhancement over Prometheus corresponding to a model volcanic SO₂ output of 10⁵ kg s⁻¹. Apart from the Prometheus peak, the SO₂ column density dropped fairly smoothly away from the subsolar point, even over regions that included potential volcanic sources. At latitudes less than ±30°, the dropoff rate was consistent with control by vapor pressure equilibrium with surface frost with subsolar temperature 117.3±0.6 K, though SO₂ abundance was higher than predicted by vapor pressure control at mid-latitudes, especially in the northern hemisphere. We conclude that, at least at low latitudes on the anti-jovian hemisphere where there are extensive deposits of optically-thick SO₂ frost, the atmosphere is probably primarily supported by sublimation of surface frost. Although the 45° tilt of our slit prevents us from separating the dependence of atmospheric density on solar zenith angle from its dependence on latitude, the pattern is consistent with a sublimation atmosphere regardless of which parameter is the dominant control. The observed drop in gas abundance towards higher latitudes is consistent with the interpretation of previous Lyman alpha images of Io as indicating an atmosphere concentrated at low latitudes. Comparison with previous disk-resolved UV spectroscopy, Lyman-alpha images, and mid-infrared spectroscopy suggests that Io's atmosphere is denser and more widespread on the anti-jovian hemisphere than at other longitudes. SO₂ gas temperatures were in the range of 150-250 K over the majority of the anti-jovian hemisphere, consistent with previous observations. SO was not definitively detected in our spectra, with upper limits to the SO/SO₂ ratio in the range 1-10%, roughly consistent with previous observations. S₂ gas was not seen anywhere, with an upper limit of 7.5×10¹⁴ cm⁻² for the Prometheus plume, confirming that this plume is significantly poorer in S₂ than the Pele plume (S₂ /SO₂<0.005, compared to 0.08-0.3 at Pele). In addition to the gas absorption signatures, we have observed continuum emission in the near ultraviolet (near 2800 Å) for the first time. The brightness of the observed emission was directly correlated with the SO₂ abundance, strongly peaking in the equatorial region over Prometheus. Emission brightness was modestly anti-correlated with the jovian magnetic latitude, decreasing when Io intersected the torus centrifugal equator.  相似文献   

SOS: the visible spectroscopic survey of 820 asteroids     

D. Lazzaro  C.A. Angeli  T. Mothé-Diniz  M. Florczak 《Icarus》2004,172(1):179-220

We present the results of a visible spectroscopic survey of 820 asteroids carried on between November 1996 and September 2001 at the 1.52 m telescope at ESO (La Silla). The instrumental set-up allowed an useful spectral range of about 4900 Å<λ<9200 Å. The global spatial distribution of the observed asteroids covers quite well all the region between 2.2 and 3.3 AU though some concentrations are apparent. These are due to the fact that several sub-sets of asteroids, such as families and groups, have been selected and studied during the development of the survey. The observed asteroids have been classified using the Tholen and the Bus taxonomies which, in general, agree quite well.  相似文献   

Near-infrared laboratory spectra of solid H₂O/CO₂ and CH₃OH/CO₂ ice mixtures     

Max P. Bernstein  Dale P. Cruikshank  Scott A. Sandford 《Icarus》2005,179(2):527-534

We present near-IR spectra of solid CO₂ in H₂O and CH₃OH, and find they are significantly different from that of pure solid CO₂. Peaks not present in either pure H₂O or pure CO₂ spectra become evident when the two are mixed. First, the putative theoretically forbidden CO₂ (2ν₃) overtone near 2.134 μm (4685 cm⁻¹), that is absent from our spectrum of pure solid CO₂, is prominent in the spectra of H₂O/CO₂=5 and 25 mixtures. Second, a 2.74-μm (3650 cm⁻¹) dangling OH feature of H₂O (and a potentially related peak at 1.89 μm) appear in the spectra of CO₂-H₂O ice mixtures, but are probably not diagnostic of the presence of CO₂. Other CO₂ peaks display shifts in position and increased width because of intermolecular interactions with H₂O. Warming causes some peak positions and profiles in the spectrum of a H₂O/CO₂=5 mixture to take on the appearance of pure CO₂. Absolute strengths for absorptions of CO₂ in solid H₂O are estimated. Similar results are observed for CO₂ in solid CH₃OH. Since the CO₂ (2ν₃) overtone near 2.134 μm (4685 cm⁻¹) is not present in pure CO₂ but prominent in mixtures, it may be a good observational (spectral) indicator of whether solid CO₂ is a pure material or intimately mixed with other molecules. These observations may be applicable to Mars polar caps as well as outer Solar System bodies.  相似文献   

Spectral observations of 19 weathered and 23 fresh NEAs and their correlations with orbital parameters     

Ronald A. Fevig  Uwe Fink 《Icarus》2007,188(1):175-188

Results of our visible to near-infrared spectrophotometric observations of 41 near-Earth asteroids (NEAs) are reported. These moderate-resolution spectra, along with 14 previously published spectra from our earlier survey [Hicks, M.D., Fink, U., Grundy, W.M., 1998. Icarus 133, 69-78] show a preponderance of spectra consistent with ordinary chondrites (23 NEAs with this type of spectrum, along with 19 S-types and 13 in other taxonomic groups). There exists statistically significant evidence for orbit-dependent trends in our data. While S-type NEAs from our survey reside primarily in (1) Amor orbits or (2) Aten or Apollo orbits which do not cross the asteroid main-belt, the majority of objects with spectra consistent with ordinary chondrites in our survey are in highly eccentric Apollo orbits which enter the asteroid main-belt. This trend toward fresh, relatively unweathered NEAs with ordinary chondrite type spectra in highly eccentric Apollo orbits is attributed to one or a combination of three possible causes: (1) the chaotic nature of NEA orbits can easily result in high eccentricity orbits/large aphelion distances so that they can enter the collisionally enhanced environment in the main-belt, exposing fresh surfaces, (2) they have recently been injected into such orbits after a collision in the main-belt, or (3) such objects cross the orbits of several terrestrial planets, causing tidal disruption events that expose fresh surfaces.  相似文献   

Thermal emission spectroscopy (5.2-38 μm) of three Trojan asteroids with the Spitzer Space Telescope: Detection of fine-grained silicates     

J.P. Emery  D.P. Cruikshank 《Icarus》2006,182(2):496-512

We present thermal emission spectra (5.2-38 μm) of the Trojan asteroids 624 Hektor, 911 Agamemnon, and 1172 Aneas. The observations used the Infrared Spectrograph (IRS) on board the Spitzer Space Telescope. Emissivity spectra are created by dividing the measured Spectral Energy Distribution (SED) by a model of the thermal continuum. We employ the Standard Thermal Model (STM), allowing physical parameters (e.g., radius and albedo) to vary in order to find the best thermal continuum fit to the SED. The best-fit effective radius (R) and visible geometric albedo (pv) for Hektor (R=110.0±7.3, ) and Aneas (R=69.1±5.1, ) agree very well with previous estimates, and for Agamemnon (R=71.5±5.2, ) we find slightly a smaller size and higher albedo than previously derived. Other thermal models (e.g., thermophysical) result in estimates of R and pv that vary a few percent from the STM, but the resulting emissivity spectra are identical. The emissivity spectra of all three asteroids display an emissivity plateau near 10-μm and another broader rise from ∼18 to 28 μm. We interpret these as indications of fine-grained silicates on the surfaces of these asteroids. The emissivity spectra more closely resemble emission spectra from cometary comae than those from solid surfaces and measured in the laboratory for powdered meteorites and regolith analogs. We hypothesize that the coma-like emission from the solid surfaces of trojans may be due to small silicate grains being imbedded in a relatively transparent matrix, or to a very under-dense (fairy-castle) surface structure. These hypotheses need to be tested by further laboratory and theoretical scattering work as well as continued thermal emission observations of asteroids.  相似文献   

Titan at 3 microns: Newly identified spectral features and an improved analysis of haze opacity     

Haingja Seo  Joo Hyeon Kim  Régis Courtin 《Icarus》2009,199(2):449-457

We have reanalyzed the high-resolution spectrum of Titan between 2.87 and 3.12 μm observed with NIRSPEC/Keck II on 2001 Nov. 21 in southern summer, using updated CH₃D and C₂H₆ line-by-line models. From new synthetic spectra, we identify all but a few of the previously unidentified significant absorption spectral features in this wavelength range as due to these two species, both of which had been previously detected by Voyager and ground-based observations at other wavelengths. We also derive opacities and reflectivities of haze particles as functions of altitude for the 2.87-2.92 μm wavelength range, where Titan's atmosphere is partially transparent down to the surface. The extinction per unit altitude is observed to increase from 100 km (∼8 mbar) toward lower altitude. The derived total optical depth is approximately 1.1 for the 2.87-2.92 μm range. At wavelengths increasing beyond 2.92 μm the haze layers become much more optically thick, and the surface is rapidly hidden from view. These conclusions apply to equatorial and southern-temperate regions on Titan, excluding polar regions. We also find it unlikely that there is a large enhancement of the tropospheric CH₄ mole fraction over the value reported from analysis of the Huygens/GCMS observations.  相似文献   

Spectral properties of simulated impact glasses produced from martian soil analogue JSC Mars-1     

L.V. Moroz  A.T. Basilevsky  S.S. Rout  C.H. van der Bogert  A.V. Fisenko  V.S. Rusakov  N.G. Zinovieva  C.M. Pieters 《Icarus》2009,202(1):336-353

To simulate the formation of impact glasses on Mars, an analogue of martian bright soil (altered volcanic soil JSC Mars-1) was melted at relevant oxygen fugacities using a pulsed laser and a resistance furnace. Reduction of Fe³⁺ to Fe²⁺ and in some cases formation of nanophase Fe⁰ in the glasses were documented by Mössbauer spectroscopy and TEM studies. Reflectance spectra for several size fractions of the JSC Mars-1 sample and the glasses were acquired between 0.3 and 25 μm. The glasses produced from the JSC Mars-1 soil show significant spectral variability depending on the method of production and the cooling rate. In general, they are dark and less red in the visible compared to the original JSC Mars-1 soil. Their spectra do not have absorption bands due to bound water and structural OH, have positive spectral slopes in the near-infrared range, and show two broad bands centered near 1.05 and 1.9 μm, typical of glasses rich in ferrous iron. The latter bands and low albedo partly mimic the spectral properties of martian dark regions, and may easily be confused with mafic materials containing olivine and low-Ca pyroxene. Due to their disordered structures and vesicular textures, the glasses show relatively weak absorption features from the visible to the thermal infrared. These weak absorption bands may be masked by the stronger bands of mafic minerals. Positive near-infrared spectral slopes typical of fresh iron-bearing impact or volcanic glasses may be masked either by oxide/dust coatings or by aerosols in the Mars' atmosphere. As a result, impact glasses may be present on the surface of Mars in significant quantities that have been either misidentified as other phases or masked by phases with stronger infrared features. Spectrometers with sufficient spatial resolution and wavelength coverage may detect impact glasses at certain locations, e.g., in the vicinity of fresh impact craters. Such dark materials are usually interpreted as accumulations of mafic volcanic sand, but the possibility of an impact melt origin of such materials also should be considered. In addition, our data suggest that high contents of feldspars or zeolites are not necessary to produce the transparency feature at 12.1 μm typical of martian dust spectra.  相似文献   

Jupiter's hydrocarbon polar brightening: Discovery of 3-micron line emission from south polar CH₄, C₂H₂, and C₂H₆     

Sang J. Kim  T.R. Geballe  J.H. Kim 《Icarus》2009,202(1):354-357

Jupiter exhibits bright H⁺₃ auroral arcs at 3-4 microns that cool the hot (>1000 K) ionosphere above the ∼¹⁰−7 bar level through the infrared bands of this trace constituent. Below the ¹⁰−7 bar level significant cooling proceeds through infrared active bands of CH₄, C₂H₂, and C₂H₆. We report the discovery of 3-micron line emission from these hydrocarbon species in spectra of the jovian south polar region obtained on April 18 and 20, 2006 (UT) with CGS4 on the United Kingdom Infrared Telescope. Estimated cooling rates through these molecules are 7.5×¹⁰−3, 1.4×¹⁰−3, and , respectively, for a total nearly half that of H⁺₃. We derive a temperature of 450 ± 50 K in the ¹⁰−7-¹⁰−5 bar region from the C₂H₂ lines.  相似文献