Microstructure Evolution of Organic Matter and Clay Minerals in Shales with Increasing Thermal Maturity     

GU Yuantao  LI Xiaoxi  YANG Shuguang  WAN Quan 《《地质学报》英文版》2020,94(2):280-289

As the two important components of shale, organic matter(OM) and clay minerals are usually thought to strongly influence the hydrocarbon generation, enrichment and exploitation. The evolution process of OM and clay minerals as well as their interrelationship over a wide range of thermal maturities are not completely clear. Taking Yanchang(T_3y), Longmaxi(S_1l) and Niutitang(?_1n) shales as examples, we have studied the microstructure characteristics of OM and clay minerals in shales with different thermal maturities. The effects of clay minerals and OM on pores were reinforced through sedimentation experiments. Using a combination of field emission scanning electron microscopy(FESEM) and low-pressure N_2 adsorption, we investigated the microstructure differences among the three shales. The results showed that both OM and clay minerals have strong effects on pores, and small mesopore(2–20 nm) is the dominant pore component for all three samples. However, the differences between the three samples are embodied in the distribution of pore size and the location. For the T_3y shale, clay minerals are loosely arranged and develop large amounts of pores, and fine OM grains often fill in intergranular minerals or fractures. Widespread OM pores distribute irregularly in S_1l shale, and most of the pores are elliptical and nondirectional. The ?_1n shale is characterized by the preferred orientational OM-clay aggregates, and lots of pores in the composites are in the mesopore range, suggesting that over maturity lead to the collapse and compaction of pores under huge pressure of strata. The results of the current research imply that with increasing thermal maturity, OM pores are absent at low maturity(T_3y), are maximized at high maturity(S_1l) and are destroyed or compacted at over-mature stage(?_1n). Meanwhile, clay minerals have gone through mineral transformation and orientational evolution. The interaction of the two processes makes a significant difference to the microstructure evolution of OM and clay minerals in shale, and the findings provide scientific foundation in better understanding diagenetic evolution and hydrocarbon generation of shale.  相似文献   

硅灰加固宁波软土的试验研究     

王泽平  王常明  江南  张在恒 《岩土工程技术》2020,(2):111-116,121

为探索硅灰对软土的力学性质的影响,以宁波鄞州地区一种淤泥质黏土为试样,掺入不同量的硅灰,对硅灰加固土的力学性质和结构特征进行了测试。采用三轴不固结不排水剪切试验,测试分析了不同掺入量的硅灰加固土的应力应变关系,通过扫描电镜SEM照片分析了不同硅灰掺入量的硅灰加固土的结构特征。结果表明:(1)硅灰可以提高软土的黏聚力,黏聚力随着硅灰掺入量的增加而增大;(2)随着硅灰掺入量的增加,硅灰加固土的抗变形能力呈先增加后减小的趋势;(3)同一围压条件下,随着硅灰掺入量的增加,硅灰加固土的破坏偏应力逐渐增加;(4)随着硅灰掺入量的增加,硅灰加固土中大孔隙逐渐减少,小孔隙逐渐数量增加,孔径<1μm的小孔隙组分逐渐占优。  相似文献   

Effect of microstructure on stress–strain and pore-pressure response of sabarmati sand under the influence of mica     

P. Seethalakshmi 《Geomechanics and Geoengineering》2020,15(2):123-139

ABSTRACT

Micaceous soil is believed to be detrimental for civil engineering constructions due to the effect of high compressibility, low compacted density and low shear strength. Individual mica particle has numerous intact mica flakes foliated over each other making it flexible upon loading and rebound upon unloading due to its low hardness and resilient nature. Hence, micaceous soils with mica content more than 10% are considered undesirable for highway pavements, embankments and railway track constructions. When platy mica particles are sufficiently numerous to interact with spherical sand particles, bridging and ordering phenomena are augmented within the soil mass creating unique sand-mica particle orientation (MS microstructure) unlike sand-sand particle orientation (PS microstructure). The current experimental research was conducted to evaluate the variation in stress–strain, pore pressure and effective stress path response of Sabarmati sand under the influence of mica (sand with 30% mica and pure sand) with MS and PS microstructure respectively. Effect of particle crushing on stress–strain and pore pressure response was also studied on Sabarmati sand with MS and PS microstructure. Distinctive macroscopic response was observed in Sabarmati sand with MS microstructure under the influence of mica as well as mica particle crushing.  相似文献   

砂土高压蠕变微观机理分析          下载免费PDF全文

尹建华  顾凯  姜洪涛  刘春  施斌  刘兵 《高校地质学报》2018,24(1):116

砂土层在地面沉降过程中呈现一定的蠕变特性。文章采用一维压缩试验对4 MPa 下砂土的变形特征进行了研究,并 采用改进的试验装置对砂土的微观结构进行了提取。通过对8 组不同级配砂土样的蠕变特性和微观结构分析,得到如下结 论：粒径单一的砂土在蠕变过程中更容易出现突变,砂粒受力后更容易发生破碎,产生滑移错动;砂土蠕变的蠕变量与砂 粒级配密切相关,砂土的粒径越单一且粒径越大时,砂土的蠕变量也越大;采用表征砂土颗粒形状复杂程度的形状系数, 从微观上定量分析了砂土在蠕变过程中发生破碎的情况和蠕变量大小,且形状系数越小,表明该种砂土形状越复杂,在蠕 变过程中砂土的破碎性越高,蠕变量越大。  相似文献   

微生物沉积碳酸钙固化珊瑚砂的试验研究   总被引：1，自引：0，他引：1  

方祥位  申春妮  楚剑  吴仕帆  李依珊 《岩土力学》2015,36(10):2773-2779

向珊瑚砂中注入巴斯德芽孢杆菌菌液、氯化钙和尿素的混合液,利用微生物沉积碳酸钙固化珊瑚砂;并对珊瑚砂固化体进行了渗透、强度及微观结构等试验。试验结果表明,巴斯德芽孢杆菌的活性随时间呈衰减趋势,但衰减速度缓慢,能较好地满足珊瑚砂固化的需要。随着菌液、氯化钙和尿素的混合液注入次数的增加,珊瑚砂柱渗透性逐步降低,最终渗透性降低了1～2个数量级。微生物固化后的珊瑚砂柱应力-应变曲线大致可分为3段,即应力随应变缓慢增加段、快速增加段以及突降段。试样发生压裂脆性破坏,无侧限抗压强度最高达到14 MPa左右。抗压强度随干密度增加而增大,随渗透性降低而增大。微生物固化后珊瑚砂颗粒被生成的碳酸钙完整的包裹,孔隙间极少见生成的碳酸钙,与普通硅砂微生物固化后的微观结构不同,较好地解释了渗透性降低不多的原因。  相似文献   

在CorelDRAW平台上进行Fry法有限应变测量的新技术     

韩阳光  颜丹平  李政林 《现代地质》2015,29(3):494-500

有限应变测量是韧性变形定量估算的主要手段。Fry法有限应变测量以变形颗粒,如变形砾石、鲕粒、近等轴矿物等为应变标志体,地质实践中较容易获得,是岩石有限应变测量的最普遍手段。其传统测量过程极为繁琐,难以满足大范围应变测量的要求,数据精度也较低,限制了Fry法的应用。前人曾根据Fry法原理设计了计算机程序,但其程序相关编程语言如今已基本不能使用。本研究基于目前地质上较普遍使用的制图软件CorelDRAW平台的VBA编程,设计出一个基于CorelDRAW平台的Fry法应变测量宏程序FRY-1。在新图层上将所有变形颗粒的中心点标出后,运行FRY-1宏程序即可快速得到精确的Fry图解,并计算出相对精确的R值。通过实例与“最邻近心对心法”的测量结果进行的对比,证明该方法简便易操作,并可大幅提高有限应变测量的效率和有效减小误差。  相似文献   

Evolution of the ductile shear zone of the Paishanlou gold deposits,western Liaoning,China     

NI JinLong  LIU JunLai  TANG XiaoLing  ZHAO ChunQiang & ZENG QingDong 《中国科学:地球科学(英文版)》2014,57(4):600-613

The combination of field surveys with analysis of microstructure of tectonite and Electron Backscatter Diffraction (EBSD) on quartz fabric indicated that three periods of ductile shear events developed in the Paishanlou gold deposits and the E-W and NE-striking ductile shear zones were formed during each event. The E-W-striking ductile shear zone, accompanied by compressional and dextral shear slip, was shear-cut by the NE-striking shear zones, accompanied by compressional-sinistral shear slip and sinistral-normal shear slip, successively. An E-W-striking ductile shear zone developed at a deeper tectonic level and at middle- to high-temperatures, accompanied by abundant microstructures, including microlayering between a polycrystal quartz belt and mica, and quartz deformation was depended on cylinder (10-10) 〈a〉 or 〈c〉 glide. The development of an E-W-striking shear zone can be seen as a tectonic pattern in the region of the Paishanlou gold deposits of the collision between the Mongolian tectonic belt and the North Archean Craton from Suolun to the Linxi suture zone during the Indosinian. The NE-striking ductile shear zone developed approximately 160 Ma during the early Yianshanian at middle to shallow tectonic levels and at middle- to low-temperatures, accompanied by typical microstructures, including polycrystal quartz aggregation and quartz subgrain rotation recrystallization, etc., and quartz deformation was depended on prismatic (1011) 〈a〉 glide. The last ductile shear event around the NE-striking shear zone developed at low temperatures and shallow tectonic levels, yielding to a pre-existing NE-striking shear zone, accompanied by abundant microstructures, including low-temperature quartz grain boundary migration and bulging recrystallization. The last ductile shear movement may be related to lithosphere thinning and the destruction of the North China Craton from approximately 130-120 Ma, and this shear event resulted directly in the mineralization in the Paishanlou region.  相似文献   

基于微观结构的青藏高原风积沙导热系数变化机理研究   总被引：1，自引：0，他引：1  

陈琳  喻文兵  杨成松  易鑫  刘伟博 《冰川冻土》2014,36(5):1220-1226

风积沙作为青藏高原一种重要的局地因素, 改变了多年冻土的赋存条件. 风积沙的导热系数特征对预报分析其对冻土赋存有利或者不利具有重要作用. 采用非稳态法对青藏高原红梁河风积沙进行了导热系数测试, 并结合电镜扫描/能谱分析, 从微观结构的角度探讨了风积沙的导热系数变化机理. 结果表明: 研究区风积沙平均粒度为242.427 μm; 标准偏差值为0.125, 分选极好; 偏度为0.359, 接近对称; 峰度值为1.086, 峰态中等; 颗粒粒径主要分布在75～500 μm之间, 沙粒均匀, 不含黏土及砾石成分, 自然堆积状态下其孔隙率为0.391. 天然状态下的风积沙颗粒呈类球形, 颗粒磨圆度高, 点与点接触, 颗粒间孔隙较大; 表面有明显撞击坑和擦痕, 这导致颗粒的比表面积增大, 连通性增强, 孔隙率增加. 干燥状态下风积沙颗粒的相互接触面积较小, 孔隙由空气填充, 导热系数较低; 而在湿润状态下, 正温时孔隙中的水间接增大了风积沙的接触面积, 导致其导热系数增大; 负温时, 孔隙内的水变成冰, 从而导致导热系数进一步增大. 天然状态下, 暖季地表风积沙含水量较低, 导热系数较低, 而冷季地表风积沙含水量较大, 导热系数较大. 此外, 风积沙为颗粒物质, 表面光滑, 颗粒之间粘性小, 孔隙未被填堵, 结构松散, 这些因素导致自然堆积状态下其渗透系数较一般细砂大, 透水性良好, 保水性差, 是防冻胀较好的换填材料.  相似文献   

石碑塬滑坡黄土液化特征及其影响因素研究   总被引：1，自引：0，他引：1  

张晓超  黄润秋  许模  裴向军  韩祥森  宋丽娟  张帆宇 《岩土力学》2014,35(3):801-810

石碑塬滑坡是1920年海原地震触发的大型黄土流滑,认识其破坏特征与发生机制对于黄土边坡长距离液化失稳机制的研究非常重要。对石碑塬黄土滑坡的调查和研究表明,饱和黄土或高含水率黄土具有很高的液化势和流态破坏势,在强震作用下,饱和黄土易发生液化或流滑。对石碑塬滑坡的7组原状黄土样品进行振动三轴剪切试验,并结合其微观特征分析,探讨了循环振动荷载作用下的饱和黄土孔隙水压力-应变增长模型,分析了振动液化过程中液化应力比与黄土粒度组成、土体微观结构参数及饱和度之间的关系。结果表明：黏粒含量越低,振动作用下饱和黄土孔隙水压力响应越快,液化应力比越低;黄土孔隙比越大,孔隙结构分形维数越大,液化应力比越低,振动液化后黄土孔隙分形维数降低,结构较液化之前更为致密;饱和度对黄土粒间胶结物质的赋存状态及黄土结构强度影响很大,同一土体饱和度越高,溶滤于孔隙水中的离子浓度越高,土体粒间接触点（或胶结点）越容易发生断裂,使得黄土结构强度降低,液化应力比降低。  相似文献   

总氮对土物理力学性能影响的试验研究     

伍艳  任海平  王玮屏  兰雁  沈细中 《岩土力学》2014,35(8):2278-2285

通过室内试验,考察了去离子水及不同浓度总氮溶液对土体物理力学性能的影响,并通过土体矿物成分含量及微观形貌分析,对总氮溶液与土体作用机制进行了初步探讨。结果表明,总氮对土体物理力学性能影响明显：（1）土体塑性指数、相对密度和有效黏聚力随总氮溶液浓度增大而减小,有效内摩擦角随溶液浓度的增大而增大;（2）各浸泡条件下,土体应力-应变关系曲线变化规律基本一致,均呈应变硬化现象,土体剪切峰值随总氮溶液浓度的增大先减小后增大;（3）孔隙水压力随轴向应变的增加先增加,然后缓慢降低,最后曲线逐渐趋于水平,表现出较大的剪胀性;（4）总氮溶液与土体间相互作用主要包括离子交换作用、微生物分解作用和溶蚀及胶结作用,这些作用通过改变土体的矿物成分含量,使其微观形貌及孔隙特征发生明显变化,最终导致土体的宏观力学特性改变。  相似文献