基于关键路径和响应时间约束的空间信息服务优化组合算法   总被引：1，自引：0，他引：1  

朱庆  杨晓霞  李海峰 《武汉大学学报(信息科学版)》2007,32(11):1042-1045

空间信息服务的响应时间是网络信息服务和分布式空间信息处理等关心的核心问题之一。针对空间信息服务链的自动生成,基于关键路径法思想,定义了服务链关键路径、关键服务和服务时间余量的概念,建立了确定型和概率型响应时间计算模型,提出了顾及关键路径响应时间的服务优化组合算法,保证服务链的组合结果更好地满足响应时间约束。仿真实验结果证明了本文方法的有效性。  相似文献   

Chemical reaction diversity of geofluids revealed by hydrothermal experiments under sub- and supercritical states     

Noriyoshi  Tsuchiya  Nobuo  Hirano 《Island Arc》2007,16(1):6-15

Abstract   Hydrothermal experiments of dissolution of granite and quartz with pure water up to 600°C and 60 MPa were carried out in order to evaluate chemical reaction under sub- and supercritical conditions. The supercritical region beyond the critical point for water has been inferred to be a homogeneous state, which does not correspond to either a true liquid phase, or a true vapor phase. Results of dissolution experiments of granite and quartz in a supercritical state (artificially defined as higher pressures and temperatures than the critical point), show this fluid can be subdivided into two apparent phases comprising a 'liquid-like' region and a 'vapor-like' region. Chemical phenomena with respect to dissolution reactions in the 'liquid-like' region are more similar to those of subcritical water, whilst those reactions in the 'vapor-like' region even in the supercritical state are considered to be weak. The critical point of various kinds of geofluids, composed of solutions in the H₂O-CO₂-NaCl system was experimentally determined using a visible type autoclave. Chemical reaction diversity, depending on location of the critical point for a given solution and apparent phase boundary in terms of chemical reaction within the supercritical state, was recognized by hydrothermal experiments.  相似文献   

Chemical mass balance in a reaction zone between serpentinite and metapelites in the Nishisonogi metamorphic rocks, Kyushu, Japan: Implications for devolatilization   总被引：1，自引：0，他引：1  

Yasushi  Mori  Tadao  Nishiyama  Takeru  Yanagi 《Island Arc》2007,16(1):28-39

Abstract   Reaction zones of 0.5–10.0 m thick are commonly observed between serpentinite and pelitic schist in the Nishisonogi metamorphic rocks, Kyushu, Japan. Each reaction zone consists of almost monomineralic or bimineralic layers of talc + carbonates, actinolite (or carbonates + quartz), chlorite, muscovite and albite from serpentinite to pelitic schist. Magnesite + quartz veins extend into the serpentinite from the talc + carbonates layer, while dolomite veins extend into the pelitic schist from the muscovite layer. These veins are filled by subhedral minerals with oriented growth features. Primary fluid inclusions yield the same homogenization temperatures (145–150°C) both in the reaction zone and in the veins, suggesting their simultaneous formation. Mass-balance calculations using the isocon method indicate that SiO₂, MgO, H₂O and K₂O are depleted in the reaction zone relative to the protoliths. These components were probably extracted from the reaction zone as fluids during the formation of the reaction zone.  相似文献   

Origin and evolution of FeAl-granulite in the thermal aureole of the Chilka Lake anorthosite, Eastern Ghats Province, India     

Michael M. Raith 《Proceedings of the Geologists' Association. Geologists' Association》2007,118(1):87-100

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Middle to Late Holocene glacial variations, periglacial processes and alluvial sedimentation on the higher Apennine massifs (Italy)   总被引：1，自引：0，他引：1  

Carlo Giraudi 《Quaternary Research》2005,64(2):176-184

The major climatic variations that have affected the summit slopes of the higher Apennine massifs in the last 6000 yr are shown in alternating layers of organic matter-rich soils and alluvial, glacial and periglacial sediments. The burial of the soils, triggered by environmental-climatic variations, took place in several phases. For the last 3000 yr chronological correlations can be drawn between phases of glacial advance, scree and alluvial sedimentation and development of periglacial features. During some periods, the slopes were covered by vegetation up to 2700 m and beyond, while in other phases the same slopes were subject to glacial advances and periglacial processes, and alluvial sediments were deposited on the high plateaus. Around 5740-5590, 1560-1370 and 1300-970 cal yr B.P., organic matter-rich soils formed on slopes currently subject to periglacial and glacial processes; the mean annual temperature must therefore have been higher than at present. Furthermore, on the basis of the variations in the elevation of the lower limit reached by gelifraction, it can be concluded that the oscillations in the minimum winter temperatures could have ranged between 3.0°C lower (ca. 790-150 cal yr B.P.) and 1.2°C higher (ca. 5740-5590 cal yr B.P.) than present minimum winter temperatures. During the last 3000 yr the cold phases recorded by the Calderone Glacier advance in the Apennines essentially match basically the phases of glacial advance in the Alps.  相似文献   

五氯苯酚在矿物表面吸附——实验、表面反应模式及其环境意义   总被引：4，自引：0，他引：4  

吴大清  刁桂仪袁鹏 彭金莲 《岩石矿物学杂志》2005,24(6):556-562

利用批量平衡技术研究了石英、高岭石、伊利石、蒙脱石和铁氧化物对五氯苯酚(PCP)吸附的pH关系等温线和浓度关系等温线,发现所有矿物的pH关系等温线都表现出典型的峰形曲线特征,峰位在pH=5～6之间,依矿物不同而不同。基于矿物表面羟基位化合态和PCP的化合态考虑,提出一种包含表面络合反应和表面静电吸附反应的模式,对pH关系等温线计算拟合发现有很好的相关性。模式计算还表明,石英和层状硅酸盐矿物对PCP吸附以表面络合反应为主,而氧化铁矿物则包含表面络合反应和表面静电吸附反应,但以后者占主导,其反应平衡常数比前者大1～3个数量级。高岭石和氧化铁矿物的浓度吸附等温线可用Langmuir方程很好拟合,最大吸附量的大小顺序是赤铁矿>纤铁矿>针铁矿>高岭石>石英>蒙脱石≈伊利石,并可以用矿物表面羟基位浓度和反应机制加以解释。PCP在矿物表面可观的吸附量说明矿物表面吸附对憎水性可离解有机化合物(HIOCs)在天然水相体系和沉积中的迁移转化过程起着相当重要的作用。  相似文献   

Pressure, temperature and cooling rates of granulite facies migmatitic pelites from the southern Adirondack Highlands, New York   总被引：4，自引：1，他引：4  

L. C. STORM  F. S. SPEAR 《Journal of Metamorphic Geology》2005,23(2):107-130

Detailed petrographic analysis was performed on samples from five localities within the southern Adirondacks. Textures and zoning patterns in garnet from all samples provide evidence for dehydration melting of biotite. Zoning of grossular in garnet – providing a record of prograde growth – shows both increasing and decreasing trends in garnet from the same sample. However, Ca concentrations at the garnet rims of most samples are identical (grossular = 3.4%). These observations have been interpreted as evidence for the differential timing of garnet nucleation and growth. All Fe/(Fe + Mg) and some spessartine distributions are consistent between samples, displaying diffusive profiles established largely upon cooling. Only one sample, in which retrogression was minimal, contains garnet with flat Fe/(Fe + Mg) profiles. A general pelitic pseudosection constructed in the system MnNCKFMASH reveals a maximum for Ca in garnet where the plagioclase‐out isopleth intersects the solidus (muscovite = 0). The pseudosection predicts bell‐shaped core‐to‐rim profiles of grossular during anatexis, similar to those observed in the rocks. Garnet–biotite thermometry and GASP barometry indicate peak temperatures of at least 790 °C at about 7–9 kbar, similar to conditions determined for the central Adirondacks. Cooling rates determined from finite difference modelling of spessartine and Fe/(Fe + Mg) diffusional profiles indicate a multi‐stage cooling history in which some period of rapid cooling (>200 °C Myr^?1) is required.  相似文献   

Transport of low-aH₂O dehydration products to melt sites via reaction-zone networks, Milford Sound, New Zealand     

P. BLATTNER 《Journal of Metamorphic Geology》2005,23(7):569-578

The gabbroic/dioritic Pembroke Hornblende Granulite (PHG) of Milford Sound displays a geometrically simple mesoscopic network of sub‐planar garnet reaction zones (GRZ) in which the meta‐igneous hornblende granulite has been depleted of Na, Si, and H₂O, and c. 25 vol.% almandine‐rich garnet has formed. Some studies postulate the initial presence of melt along the centres of all GRZ, explaining the frequent absence of feldspathic veins by selective melt loss. A more parsimonious model is necessitated by structural evidence and, together with chemical data, suggests a relationship between mid‐range metasomatic transport and anatexis. The Pembroke outcrops show a process of incipient melting of gabbro/diorite in an environment of relatively low aH₂O in lithologies that have limited free quartz. A non‐equilibrium steady state is proposed, in which a sodic dehydration fluid moves some distance via the GRZ network towards areas of partial melting. Only in these areas are Na and Si reconstituted as albite, with more garnet as byproduct, having avoided the need for melt percolation. The combined structural and chemical evidence directs a focus on mass transport in low‐aH₂O gabbroic environments. In subsequent events of shearing and complete transposition, both sets of garnet – the atypical GRZ residue and partial melt melanosomes – were inherited by the Milford Gneiss ‘facies’ of the PHG.  相似文献   

A simulating experiment on the geochemical variation trend at the initial period of meteoric waters converting to underground waters and ore fluids     

ZHU Xiaoqing 《中国地球化学学报》2005,24(4):306-315

Experimental studies were undertaken on leaching of sedimentary rocks （ dolomite and sandstone） and Hg, Sb ores by distilled water under the condition of a completely open system （room temperature and room pressure）. The aim is to find whether the halogen elements or metal elements first enter the solution at the early stage of meteoric waters converting to groundwaters and ore fluids, and, at the same time, to understand how and when they enter distilled water solutions from the rocks. The experimental resuhs have shown that F and Cl began to enter the fluids in the initial period of thirty days. With increasing leaching duration, the amounts of the elements that entered the fluids increased steadily. During the period from 120 days to 150 days the amounts increased more drastically, followed a slow increase. It is found that the capability of Cl entering the solutions is much greater than that of F. Hg and Sb were found not to have entered the solutions till 120 days later. During this period of time the pH value of the solutions began to drop. As for Hg and Sb ores, Hg and Sb began to enter the solutions on the 60th or 90th day, greatly ahead of schedule, but the two metallic elements in the rock samples began to enter the solutions 150 days later. Relatively speaking, Hg is more easily leached out than Sb from the rocks. In some rock samples, Sb could be detected in the solutions at the end of the experiment. However, Cu, Pb and Zn had not been detected in the leaching solutions from the beginning to the end of the experiment. In the whole leaching process the pH value of the solutions tend to decrease slowly from 7.1 at the beginning to 6.5 at the end. That is to say, in the interaction between pure water and rock the halogen elements in the rocks were preferentially leached out and then entered the fluids. With increasing water/rock reaction duration and amount of halogen-group elements in the solution and with decreasing pH value of the solution, some active metallic elements began to release in small amounts. This experimental result can explain the source and mechanism of volatile components and trace metals in underground waters. Meanwhile, as for those ore deposits produced by ore fluids derived from meteoric waters, the experimental result is also helpful to the understanding of the geochemical variation trend at the initial stage of conversion of meteoric waters to ore fluids.  相似文献   

Does sediment resuspension by storms affect the fate of polychlorobiphenyls (PCBs) in the benthic food chain? Interactions between changes in POM characteristics, adsorption and absorption by the mussel Mytilus galloprovincialis   总被引：1，自引：0，他引：1  

Franois Charles  Susanna Lopez-Legentil  Antoine Grmare  Jean Michel Amouroux  Martin Desmalades  Gilles Vtion  Karine Escoubeyrou 《Continental Shelf Research》2005,25(19-20):2533

Environmental parameters and gross sedimentation rates (GSR) were monitored at a fixed site located in the Bay of Banyuls-sur-Mer (NW Mediterranean), between March 1997 and April 1998, together with the main biochemical characteristics of both sedimenting and sedimented particulate organic matter (POM). Three storms which occurred during this time period resulted in natural sediment resuspension. This is indicated by the corresponding increase in GSR and a decrease in the enzymatically hydrolysable amino acids/totally hydrolysable amino acids ratio (EHAA/THAA), within the sedimenting POM. Only the strongest storm resulted in (1) a transitory increase in fine-grained particles, (2) concomitant increases in organic carbon, carbohydrates, lipids and THAA, and (3) a decrease in the EHAA/THAA ratio in surficial sediments. For most of the assayed parameters, the values recorded after the December 1997 storm corresponded to extremes for the whole period under study. This emphasises the role of storms in controlling the characteristics of sedimented and sedimenting POM.Ten sediment types, with contrasting biochemical characteristics, were selected for experiments; these were based on the results of the monitoring survey and were used during adsorption and absorption experiments involving ¹⁴C tetrachlorobiphenyl (TCB). Adsorption rates differed significantly between the sediment types, but did not correlate with any of the assayed biochemical parameters. Absorption efficiency by the mussel Mytilus galloprovincialis also differed between the sediment types; it correlated positively with all the assayed biochemical parameters, except lipids. Comparison between the magnitudes of the increase in GSR, together with the decrease in absorption efficiency during resuspension events, suggests that resuspension tends to enhance the transfer of organic pollutants in the benthic food chain.  相似文献