江西牛形坝-柳木坑金银铅锌多金属矿床铋矿物类型及指示意义     

鲁麟  梁婷  陈郑辉  王登红  赵正  陈伟 《地质学报》2018,92(3):560-574

江西银坑矿田的牛形坝-柳木坑矿床是赣南于都-赣县矿集区典型的金银铅锌多金属矿床。根据野外调研、系统矿相学研究和电子探针成分分析,表明铋在牛形坝-柳木坑矿床中是一种重要的伴生矿化金属元素,呈独立矿物或呈微细矿物包体分布在早期硫化物内部或边缘。铋矿物种类丰富,主要包括块硫铋银矿、硫铋银矿、板硫铋铜铅矿、针硫铋铅矿、硫铜铋矿、库辉铋铜铅矿、辉碲铋矿等。与同一矿集区石英脉型盘古山钨铋矿床相比,两矿床铋矿物种类均出现Pb-Ag-Bi-S、Te-Bi-S元素组合,赋存形式和含量有所不同,Cu-Pb-Bi-S元素组合仅在牛形坝-柳木坑矿床出现。矿床属于Au-Bi-(低Te)-S体系,铋盐矿物形成于中低温、中高密度、低盐度的成矿环境。从岩浆中分馏出来的成矿流体发生减压沸腾迫使大量蒸汽相逸散,硫逸度增加,铋主要以硫络合物形式运移,随着黄铁矿等硫化物沉淀,硫被大量消耗形成金矿物和碲化物(碲银矿)。成矿流体演化过程中由于温度和硫逸度进一步降低导致在成矿后期沉淀出大量铋硫盐矿物。成矿过程中的Bi促进金的迁移富集。铋矿物在两矿床中的赋存特征、化学成分、形成环境以及沉淀机制等表现出差异,说明铋具有成矿选择性,起到对成矿物质示踪的作用。  相似文献   

Metallogeny of the Baiyangping Lead‐Zinc Polymetallic Ore Concentration Area,Northern Lanping Basin of Yunnan Province,China     

WANG Xiaohu  SONG Yucai  ZHANG Hongrui  LIU Yingchao  PAN Xiaofei  GUO Tao 《《地质学报》英文版》2018,92(4):1486-1507

The Lanping Basin in the Nujiang‐Lancangjiang‐Jinshajiang (the Sanjiang) area of northeastern margin of the Tibetan Plateau is an important part of eastern Tethyan metallogenic domain. This basin hosts a number of large unique sediment‐hosted Pb‐Zn polymetallic deposits or ore districts, such as the Baiyangping ore concentration area which is one of the representative ore district. The Baiyangping ore concentration area can be divided into the east and west ore belts, which were formed in a folded tectogene of the India‐Asia continental collisional setting and was controlled by a large reverse fault. Field observations reveal that the Mesozoic and Cenozoic sedimentary strata were outcropped in the mining area, and that the orebodies are obviously controlled by faults and hosted in sandstone and carbonate rocks. However, the ore‐forming elements in the east ore belt are mainly Pb‐Zn‐Sr‐Ag, while Pb‐Zn‐Ag‐Cu‐Co elements are dominant in the west ore belt. Comparative analysis of the C‐O‐Sr‐S‐Pb isotopic compositions suggest that both ore belts had a homogeneous carbon source, and the carbon in hydrothermal calcite is derived from the dissolution of carbonate rock strata; the ore‐forming fluids were originated from formation water and precipitate water, which belonged to basin brine fluid system; sulfur was from organic thermal chemical sulfate reduction and biological sulfate reduction; the metal mineralization material was from sedimentary strata and basement, but the difference of the material source of the basement and the strata and the superimposed mineralization of the west ore belt resulted in the difference of metallogenic elements between the eastern and western metallogenic belts. The Pb‐Zn mineralization age of both ore belts was contemporary and formed in the same metallogenetic event. Both thrust formed at the same time and occurred at the Early Oligocene, which is consistent with the age constrained by field geological relationship.  相似文献   

The source of sulfur in sulfide deposits in the Siberian Platform traps (from isotope data)     

V.V. Ryabov  O.N. Simonov  S.G. Snisar  A.A. Borovikov 《Russian Geology and Geophysics》2018,59(8):945-961

The source of sulfur in giant Norilsk-type sulfide deposits is discussed. A review of the state of the problem and a critical analysis of existing hypotheses are made. The distribution of δ³⁴S in sulfides of ore occurrences and small and large deposits and in normal sedimentary, metamorphogenic, and hypogene sulfates is considered. A large number of new δ³⁴S data for sulfides and sulfates in various deposits, volcanic and terrigenous rocks, coals, graphites, and metasomatites are presented. The main attention is focused on the objects of the Norilsk and Kureika ore districts. The δ³⁴S value varies from -14 to + 22.5‰ in sulfides of rocks and ores and from 15.3 to 33‰ in anhydrites. In sulfide-sulfate intergrowths and assemblages, δ³⁴S is within 4.2-14.6‰ in sulfides and within 15.3-21.3‰ in anhydrites. The most isotopically heavy sulfur was found in pyrrhotite veins in basalts (δ³⁴S = 21.6‰), in sulfate veins cutting dolomites (δ³⁴S = 33‰), and in subsidence caldera sulfates in basalts (δ³⁴S = 23.2-25.2‰). Sulfide ores of the Tsentral’naya Shilki intrusion have a heavy sulfur isotope composition (δ³⁴S = + 17.7‰ (n = 15)). Thermobarogeochemical studies of anhydrites have revealed inclusions of different types with homogenization temperatures ranging from 685 °C to 80 °C. Metamorphogenic and hypogene anhydrites are associated with a carbonaceous substance, and hypogene anhydrites have inclusions of chloride-containing salt melts. We assume that sulfur in the trap sulfide deposits was introduced with sulfates of sedimentary rocks (δ³⁴S = 22-24‰). No assimilation of sulfates by basaltic melt took place. The sedimentary anhydrites were “steamed” by hydrocarbons, which led to sulfate reduction and δ³⁴S fractionation. As a result, isotopically light sulfur accumulated in sulfides and hydrogen sulfide, isotopically heavy sulfur was removed by aqueous calcium sulfate solution, and “residual” metamorphogenic anhydrite acquired a lighter sulfur isotope composition as compared with the sedimentary one. The wide variations in δ³⁴S in sulfides and sulfates are due to changes in the physicochemical parameters of the ore-forming system (first of all, temperature and P_ch4) during the sulfate reduction. The regional hydrocarbon resources were sufficient for large-scale ore formation.  相似文献   

内蒙古兴和县曹四夭超大型斑岩钼铅锌金成矿系统年代学及其地质意义     

范海洋  李铁刚  武文恒  张明玉  黄凡  赵正  张彤  许立权  李香资  权知心 《矿床地质》2018,37(2):355-370

曹四夭斑岩钼矿床位于内蒙古兴和县,是华北克拉通北缘最大的钼矿床。该矿床中部发育斑岩型钼矿体,外围和上部产出热液脉型铅锌金矿体。文章选取1件与斑岩钼矿化共生的绢云母样品进行了40Ar-39Ar定年,获得40Ar-39Ar坪年龄为(144.4±1.2)Ma,相应的39Ar/36Ar-40Ar/39Ar等时线年龄为(146.4±2.2)Ma(MSWD=0.31),将等时线年龄认作绢云母的Ar封闭年龄,表明曹四夭斑岩钼矿化发生在约146 Ma前。选取14件脉型铅锌矿石中的闪锌矿、黄铁矿和磁黄铁矿样品开展了Rb-Sr定年,获得4件闪锌矿的Rb-Sr等时线年龄为(145.1±3.0)Ma(MSWD=0.63);5件黄铁矿的Rb-Sr等时线年龄为(145.2±1.3)Ma(MSWD=0.53);4件闪锌矿、5件黄铁矿和1件磁黄铁矿的Rb-Sr等时线年龄为(145.3±1.0)Ma(MSWD=0.43)。硫化物Rb-Sr定年结果表明曹四夭矿床脉型铅锌矿化形成于约145 Ma前。本次绢云母40Ar-39Ar和硫化物Rb-Sr定年结果表明,曹四夭矿床斑岩型钼矿化和脉型铅锌金矿化为同期产物,两者均形成于晚侏罗世末期,属于同一个斑岩成矿系统。曹四夭矿床硫化物的w(Rb)和w(Sr)分别为0.1867×10~(-6)~1.305×10~(-6)和0.3175×10~(-6)~6.935×10~(-6),Sr同位素初始比值(87Sr/86Sr)i介于0.709 919~0.711 951之间,平均值0.710 952,结合前人获得的辉钼矿Re含量,认为曹四夭矿床的成矿物质主要来源于地壳。  相似文献   

赣南狮吼山硫铁-钨多金属矿床H-O-S同位素组成特征     

李伟  于长琦  曾载淋  刘翠辉  贺根文  陈伟  邬思涛 《岩矿测试》2018,37(6):713-720

狮吼山硫铁-钨多金属矿床位于银坑-青塘整装勘查区北部,是赣南地区唯一大型硫铁矿床。磁黄铁矿-黄铁矿(-黄铜矿-白钨矿)矿体赋存于石炭系梓山组上段地层中含铁、含钙层位,主要形成于石英-硫化物阶段。本文通过分析原生矿石矿物中H-O-S同位素组成特征,结合Pb同位素和成矿年代测试结果,探讨成矿流体来源及成矿演化过程。矿石硫化物中δ~(34)S组成特征(-5. 50‰～-0. 20‰,集中于-3. 0‰～0. 0‰)显示,硫源以岩浆硫为主,较宽的变化范围预示成矿流体遭受了叠加和改造作用。δD-δ~(18)O同位素组成主要集中于岩浆水与变质水重叠区域(δD=-74. 4‰～-48. 0‰,δ~(18)O_(H_2O)=3. 76‰～10. 86‰),说明成矿流体以岩浆水和变质水为主,后期有少量的天水混入。综合分析认为,该矿床成矿流体主要来自深部岩浆水,岩浆热液与含钙地层的接触交代作用形成大规模变质流体,再加上少量的天水混入,流体间的不混溶作用使成矿物质在岩体与含钙层位接触部位富集沉淀,形成热液充填交代型矿床。  相似文献   

现代海底块状硫化物矿床储量估算方法探讨     

张柏松 《地质与勘探》2018,54(4):723-734

海底块状硫化物矿床具有巨大的经济价值和良好的开发前景。但是由于勘探难度和技术手段的限制,在全球已经发现的600多个海底热液喷口和硫化物矿床中,不到5%的矿床进行了详细的勘探,进行资源量计算的矿床更是屈指可数。选择适当的方法估算储量对于深海资源开发意义重大。本文系统总结了前人估算海底硫化物储量的方法,并以勘探程度相对较高、数据资料相对丰富的Atlantis-II-Deep矿床和Solwara 1矿床为例,评析了前人采用不同储量计算方法得到的结果和各种方法计算的准确性;针对有一定钻孔数据的TAG硫化物堆丘,采用距离反比法重新计算了储量,并和块段法估算的结果进行对比。得到以下结论:(1)海底硫化物矿体形态是制约储量估算方法适用性的一个重要因素;(2)传统几何法可以在极低勘探条件下估算海底硫化物储量量级;(3)对于海底硫化物储量估算,地质统计学的精度高于传统几何法;(4)较高勘探条件下距离反比法可以与地质统计学相互对照、验证;(5)在一定钻孔数量的条件下,可以应用距离反比法进行海底硫化物储量估算。  相似文献   

综合物探方法在广西妙皇隐伏多金属矿勘查中的应用     

刘星  杨秋访 《江苏地质》2018,42(4):668-674

妙皇多金属矿区位于来宾凹陷东缘与大瑶山隆起西侧交接部位,广西大瑶山及其西侧铅锌成矿带中部成矿条件优越,历年来开展过多种研究和找矿方法,但找矿效果不佳。通过研究妙皇铜铅锌银矿区的地质条件和成矿背景,运用综合物探方法,对区内部分地质问题及矿产特征进行了推断和预测。2012年,依据地质物探综合成果布置了ZK22701号验证孔,取得了突破性的进展。同时,依据物探成果推测了矿区成矿机理和成矿模式,在找矿方向和找矿潜力方面进行了分析探讨,对中深部找矿具有很好的指导意义。  相似文献   

甘肃省明舒井地区高光谱蚀变异常及找矿分析     

王瑞军  张春雷  王诜  孙永彬  王永军 《地质论评》2021,67(Z1):67z1167-67z1168

正明舒井地区位于甘肃省北西侧,敦煌市北侧、瓜州县北西侧。前人在该区及周边区域开展了区调、矿调及相关多金属矿的勘查工作(王瑞军等,2014,2017),在遥感地质方面,仅开展了多光谱遥感的应用工作,而针对高光谱遥感的研究工作还未开展。明舒井地区基岩出露好、地形起伏小、切割弱,地表蚀变发育,矿床、矿点分布较多,具备开展高光谱遥感技术的地质和自然地理条件,有利于发挥高光谱的技术优势。  相似文献   

桂西北丹池成矿带He、Ar同位素特征及其矿床成因指示     

蔡明海  李晔  彭振安  胡志戍  胡鹏飞  肖俊杰 《地质学报》2021,95(12):3758-3767

桂西北丹池成矿带是我国南方重要的有色金属矿业基地.本文对成矿带内芒场矿田马鞍山Pb-Zn矿和大山Sn-Zn矿、大厂矿田铜坑Sn多金属矿、五圩矿田箭猪坡Pb-Zn多金属矿等4个主要矿床矿石黄铁矿流体包裹体He、Ar同位素进行了研究.结果 表明,丹池成矿带内典型矿床成矿流体的3He/4He=0.79～5.32 Ra,介于地壳流体(0.01～0.05 Ra)与地幔流体(6～9 Ra)特征值之间,40Ar/36 Ar=273～351,接近或略高于大气40 Ar/36 Ar特征值(295.5),不同矿床成矿流体中均有幔源组分的参与,地幔流体参与成矿作用是一个区域性事件.结合区内泥盆纪喷流沉积作用、燕山晚期花岗质岩体及构造特征等综合研究认为,参与成矿作用的地幔组分主要来自壳幔相互作用过程中沿NW向深大断裂上升的深源地幔流体,丹池成矿带内成岩、成矿作用是燕山晚期同一构造-热事件产物,矿床成因属后生热液充填交代成矿.  相似文献   

应用电子探针-扫描电镜研究陕西华阳川铀稀有多金属矿床稀土矿物特征     

万建军  潘春蓉  严杰  康清清  洪斌跃  钟福军  黄卉  杜景勇  严兆彬  潘家永 《岩矿测试》2021,(1):145-155

陕西华阳川铀稀有多金属矿床伴生大量的稀土资源,其矿石类型独特、组分复杂,系统的稀土矿物学工作将揭示矿石主要稀土矿物类型、稀土元素赋存状态,进而对矿床开发中稀土元素综合利用及选冶技术提供重要参考。本文在岩相学基础上,利用电子探针、扫描电镜对陕西华阳川铀稀有多金属矿床矿石中的稀土独立矿物与含稀土矿物进行系统研究,在矿石中发现了褐帘石（La₂O₃ 6.49%～7.61%,Ce₂O₃ 11.50%～14.00%）、磷铈镧矿（La₂O₃ 16.30%～21.21%,Ce₂O₃ 32.06%～39.18%）、磷钇矿（La₂O₃ 2.29%～3.58%,Ce₂O₃ 1.89%～2.37%,Y₂O₃ 39.77%～42.80%）、氟碳铈镧矿（La₂O₃ 12.86%～14.20%,Ce₂O₃ 36.67%～39.90%）、褐钇铌矿（La₂O₃ 1.19%～2.11%,Ce₂O₃ 1.29%～2.30%,Y₂O₃ 22.67%～25.88%）等5种稀土独立矿物;同时发现磷灰石、贝塔石、榍石等矿物中稀土元素含量较高。研究表明,该矿床稀土元素以独立矿物（褐帘石、磷铈镧矿、磷钇矿、氟碳铈镧矿、褐钇铌矿）与类质同象（磷灰石、贝塔石、榍石等矿物）两种形式存在,稀土资源以La、Ce轻稀土元素为主,并富含重稀土元素Y。  相似文献