钽铌钨锡多金属矿分离加工废水处理工艺研究     

黄江波 《矿产与地质》2013,(4):347-352

研究了采用石灰中和＋化学絮凝沉淀、有机复合脱氮剂分质处理钽铌钨锡多金属矿分离加工产生的酸性和碱性废水,氟化物、氨氮去除率可达到99.9%以上,重金属离子去除率可达到99%以上,氨回收率可达到98%以上。该处理工艺可实现废水资源化,回收的稀氨水可返回生产工艺再利用,具有良好的环境效益和经济效益。  相似文献   

Decoding post-orogenic sediment recycling and dispersal using detrital zircon core and rim ages     

Li Liu  Jie Xu  Daniel F. Stockli  Timothy F. Lawton  Ronald C. Blakey 《Basin Research》2023,35(2):489-509

Detrital zircon (DZ) geochronology has become a popular tool in provenance studies during the past two decades. However, similar zircon crystallization ages from different source regions greatly hamper the interpretation of sediment dispersal and recycling processes. The Alleghenian–Ouachita–Marathon (AOM) foreland and vicinity in North America is a region where some dominant DZ age groups could come from both the southern Appalachians in the eastern United States and the Gondwanan terranes in Mexico. In this study, we present 1045 new DZ U–Pb ages and 81 DZ core–rim age pairs in lower Permian sandstone in the Permian Basin and Miocene sandstone in the eastern Gulf of Mexico (GOM). These new data were integrated with published DZ single U–Pb age and core–rim ages from syn- to post-orogenic strata in the Permian Basin, Marathon foldbelt, southern Appalachian foreland basin and eastern GOM to interpret the sediment-dispersal models in the AOM foreland and eastern GOM. Our models show that during the Leonardian Stage, sediments derived from the Appalachians were first delivered to the US midcontinent and then recycled to the Permian Basin; during the Miocene, sediment from the Appalachians fluxed to the eastern GOM, with no longshore mixing from the western GOM. These models based on the integration of single U–Pb and core–rim ages are consistent with published results that used other methods, including zircon single U–Pb age, zircon Hf isotopic data, zircon (U–Th)/He age, sedimentology and stratigraphy. Our results demonstrate that although some limitations exist, zircon core–rim age is a powerful tool, adding an extra constraint on the interpretation of sediment-dispersal systems. This tool is particularly applicable to the post-orogenic stage, during which the sediment pathways are more complicated because of the dominant input from distal sources. Insights gained in this study imply that this novel strategy of using core and rim ages could be integrated with other methods to better understand sediment dispersal.  相似文献   

Moisture transport and seasonal variations in the stable isotopic composition of rainfall in Central American and Andean Páramo during El Niño conditions (2015–2016)     

Germain Esquivel‐Hernndez  Giovanny M. Mosquera  Ricardo Snchez‐Murillo  Adolfo Quesada‐Romn  Christian Birkel  Patricio Crespo  Rolando Clleri  David Windhorst  Lutz Breuer  Jan Boll 《水文研究》2019,33(13):1802-1817

High‐elevation tropical grassland systems, called Páramo, provide essential ecosystem services such as water storage and supply for surrounding and lowland areas. Páramo systems are threatened by climate and land use changes. Rainfall generation processes and moisture transport pathways influencing precipitation in the Páramo are poorly understood but needed to estimate the impact of these changes, particularly during El Niño conditions, which largely affect hydrometeorological conditions in tropical regions. To fill this knowledge gap, we present a stable isotope analysis of rainfall samples collected on a daily to weekly basis between January 2015 and May 2016 during the strongest El Niño event recorded in history (2014–2016) in two Páramo regions of Central America (Chirripó, Costa Rica) and the northern Andes (Cajas, south Ecuador). Isotopic compositions were used to identify how rainfall generation processes (convective and orographic) change seasonally at each study site. Hybrid Single Particle Lagrangian Integrated Trajectory model (HYSPLIT) air mass back trajectory analysis was used to identify preferential moisture transport pathways to each Páramo site. Our results show the strong influence of north‐east trade winds to transport moisture from the Caribbean Sea to Chirripó and the South American low‐level jet to transport moisture from the Amazon forest to Cajas. These moisture contributions were also related to the formation of convective rainfall associated with the passage of the Intertropical Convergence Zone over Costa Rica and Ecuador during the wetter seasons and to orographic precipitation during the transition and drier seasons. Our findings provide essential baseline information for further research applications of water stable isotopes as tracers of rainfall generation processes and transport in the Páramo and other montane ecosystems in the tropics.  相似文献   

辉石岩：高压结晶还是再循环洋壳？     

张亚玲  徐义刚 《高校地质学报》2012,18(1):74-87

        辉石岩有三种不同的成因：（1）堆晶成因（Ⅰ类辉石岩） ;（2）再循环洋壳变质成因（Ⅱ类辉石岩） ;（3）交代成 因。 I 类辉石岩由橄榄岩部分熔融产生的熔体在岩浆通道内上升过程中,在1.5~2.5 GPa 压力范围内结晶形成。常具有堆晶 结构或火成结构,在 CaO/MgO-SiO2/MgO 图解中无明显的线性关系,无Eu 异常,其 Sr-Nd-O 同位素组成与幔源岩浆相似。 II 类辉石岩多数为再循环洋壳的变质产物,常具变晶结构,在CaO/MgO-SiO2/MgO 图解中形成明显的线性关系,具Eu 正异常, 其εNd 值与MORB 相似,而Sr 同位素比值变化范围大;其O 同位素组成与原岩有关,如原岩是洋壳下部,δ18O < 地幔值; 如原岩是洋壳上部,则δ18O > 地幔值。交代成因辉石岩是熔体- 橄榄岩相互反应的结果,常被方辉橄榄岩或纯橄岩包围, 矿物种类相对其他两类辉石岩单一,在CaO/MgO-SiO2/MgO 图解中较分散,其εNd 值较II 类辉石岩低,而Sr 同位素比值变 化较小,δ18O 值低于、高于、近似于地幔值都存在。再循环洋壳在俯冲到地幔深部和随超基性岩体上升的过程中由流体萃 取作用和部分熔融作用形成化学成分丰富的流体和熔体,这些熔/ 流体或交代围岩橄榄岩将其转化为辉石岩,或直接高压 结晶形成辉石岩,或者由洋壳变质形成的榴辉岩经退变质形成Ⅱ类辉石岩。上述过程导致了在同一超基性岩体中各类成分、 成因不同辉石岩共存的现象。  相似文献   

废雷尼镍催化剂的组成分析     

盛东  梅少博  练鸿振 《岩矿测试》2009,28(4):321-324

运用红外光谱、X射线粉末衍射、等离子体发射光谱、X射线光电子能谱、扫描电镜、元素分析等多种仪器分析手段,对一种废雷尼镍催化剂的组成进行全面分析,该废催化剂中镍元素的含量较高,具有较高的回收利用价值;通过实验得到其中组分镍、铝、钙、铁、钼、铜、硅的定量信息和部分定性信息,建立了废雷尼镍催化剂中镍回收利用的技术方案。  相似文献   

我国凹凸棒石黏土开发利用研究中实行循环经济的途径          下载免费PDF全文

陈月源  张旺强  王国有  高宏  毛振才 《甘肃地质》2009,18(4):41-44

针对我国凹凸棒石黏土开发利用现状、存在的主要问题和循环经济的要求,分析探讨了我国凹凸棒石黏土开发利用研究中实行循环经济的途径。结果表明,重视凹凸棒石黏土物化性能和有益有害元素的检测、表征与评价,实行绿色设计、清洁生产,提高科技含量,开发环境友好产品,加强和重视矿山综合性开采与资源的合理化利用技术、环境无害化技术、废弃物综合利用技术、矿山复垦生态环境技术等是实行循环经济的重要途径。  相似文献   

Some Key Problems on the Petrogenesis of Seafloor Basalts,Abyssal Peridotites and Geodynamics—A Non-traditional Isotope Approach     

Niu Yaoling  Gong Hongmei  Wang Xiaohong  Xiao Yuanyuan  Guo Pengyuan  Shao Fengli  Sun Pu  Chen Shuo  Duan Meng  Kong Juanjuan  Wang Guodong  Xue Qiqi  Gao Yajie  Hong Di 《地球科学进展》2017,32(2):111-127

This paper discusses some major research to be carried out in the next five years in the newly established Laboratory of Ocean Lithosphere and Mantle Geodynamics. By using our existing sample collections of global mid-ocean ridge basalts, gabbros and abyssal peridotites from the Pacific, Atlantic and Indian oceans, the research includes: ①Using Ti-Zr-Hf stable isotope methods to test the hypothesis that the observed huge Nb-Ta and Zr-Hf fractionations result from mass-dependent fractionation under mantle magmatic conditions; ②Using a MORB sample suite of uniform ratios of incompatible elements and Sr-Nd-Pb isotopes with large major element compositional variation to test the common hypothesis of iron isotope fractionation, i.e, the affinity of heavy Fe with ferric Fe (Fe³⁺), and both heavy Fe and ferric Fe (Fe³⁺) being more incompatible than light Fe and ferrous Fe (Fe²⁺) during magma evolution; while using an incompatible trace element and Sr-Nd-Pb isotope highly variable MORB suite to test the same hypothesis during low-degree mantle melting (i.e, the effect of mantle metasomatism); ③Proposing and testing the hypothesis that the high oxygen fugacity of the Earth’s mantle is a consequence of plate tectonics by subducting partially serpentinized oceanic mantle lithosphere with abundant ferric Fe (e.g. Fe³⁺/SFe>2); ④The recent work by Andersen et al. (Nature, 2015) is a milestone contribution by using U isotope variation in oceanic basalts to hypothesize that the O₂-rich atmosphere since the late Archean (abont 2.4 Ga) mobilized the water soluble U (6+ vs. 4+) from continents, transported to the ocean and subducted with sediments to the upper mantle, which explains the low Th/U in MORB (<2.5) and the high Th/U (>3.5) ocean island basalts (OIB) do not see such U addition effect probably because OIB source materials are all ancient (> abont 2.4 Ga) if there were subducted component. The Cenozoic alkali basalts from eastern China are ideal materials for evaluating the significance of the subducted seafloor materials for the petrogenesis of OIB and enriched MORB by using the U isotope approach, which is expected to revise and improve the Andersen et al hypothesis.  相似文献   

Impact of tectonic erosion by subduction processes on intensity of arc volcanism     

Serge E.  Lallemand 《Island Arc》1996,5(1):16-24

Abstract According to new estimates, more than 2 km³ of terrestrial material is transported every year with the subducting lithospheric plates to depths greater than 20-30 km. A comparable amount of subducted material is partly restored to the nearby margins through underplating, diapirism or forearc volcanism; partly rejuvenated through arc and back-arc magmatism; and the rest is recycled into the deep mantle. This study emphasizes the connection between the consumption of some arcs and the intensity of arc volcanism. In many cases (Japan, Peru, Izu-Bonin, Guatemala), interruption in tectonic erosion of the margin is followed by a hiatus of arc volcanism. The delay between the presumed cause (i.e. absence of subducted arc-type crust) and the response (i.e. lack of explosive volcanism) corresponds to the time required for the subducting slab to reach the melting depth (i.e. 2-4 million years). Alternately, intense tectonic erosion of the margin is followed by paroxysms of arc volcanism. Crustal contamination of volcanic rocks may be caused directly by magma sources which may contain arc material derived from the subcrustal erosion of the margin.  相似文献   

桐柏北部黄岗侵入杂岩岛弧构造环境的厘定   总被引：1，自引：0，他引：1  

张利  周炼  王林森  凌文黎 《矿物岩石地球化学通报》2001,20(4):245-247

出露于北秦岭桐柏北部的黄岗侵入杂岩形成于早古生代 ,有超基性、基性和中酸性岩石产出 ,以中酸性岩石为主。主量元素和微量元素地球化学特征显示 ,黄岗侵入杂岩是同源岩浆分异结晶的产物 ,同位素示踪反映岩浆中含有一定比例的陆壳物质。分析表明 ,黄岗侵入杂岩形成于类似大洋板块俯冲的岛弧构造环境 ,与二郎坪弧后盆地向北的俯冲消减有密切联系 ,其中的陆壳物质来自俯冲板上陆壳沉积物的再循环。  相似文献   

大别山榴辉岩的密度和波速及其对壳—幔循环的启示   总被引：7，自引：0，他引：7  

赵志丹  谢鸿森  周文戈  朱茂旭  郭捷 《矿物岩石地球化学通报》2001,20(1):6-10

测定了大别山地区榴辉岩和麻粒岩的密度和高温高压 (至 5 .0GPa和 130 0℃ )的纵波速度 (Vp)。超高压榴辉岩具有较高的密度和Vp 及较弱的各向异性。榴辉岩的压力系数为 0 .2 2～ 0 .33km/s·GPa ,超高压榴辉岩的温度系数为 - 3.41× 10 -4 km/s·℃。榴辉岩的密度和波速的分析表明 ,地幔深部的超高压榴辉岩形成后可能包含了两个过程 ,即一部分榴辉岩通过拆沉作用进入深部地幔 ,另一部分快速折返至地壳内或地表 ,榴辉岩的形成过程代表了壳幔物质循环。现今的大别山深部可能只存在少量榴辉岩。  相似文献