Chloritoid–glaucophane schist in the north Qilian orogen, NW China: phase equilibria and P–T path from garnet zonation     

C. J. WEI  S. G. SONG 《Journal of Metamorphic Geology》2008,26(3):301-316

Chloritoid–glaucophane‐bearing rocks are widespread in the high‐pressure belt of the north Qilian orogen, NW China. They are interbedded and cofacial with felsic schists originated from greywackes, mafic garnet blueschists and low‐T eclogites. Two representative chloritoid–glaucophane‐bearing assemblages are chloritoid + glaucophane + garnet + talc + quartz (sample Q5‐49) and chloritoid + glaucophane + garnet + phengite + epidote + quartz (sample Q5‐12). Garnet in sample Q5‐49 is coarse‐, medium‐ and fine‐grained and shows two types of zonation patterns. In pattern I, X_grs is constant as X_py rises, and in pattern II X_grs decreases as X_py rises. Phase equilibrium modelling in the NC(K)MnFMASH system with Thermocalc 3.25 indicates that pattern I can be formed during progressive metamorphism in lawsonite‐stable assemblages, while pattern II zonation can be formed with further heating after lawsonite has been consumed. Garnet growth in Q5‐49 is consistent with a continuous progressive metamorphic process from ～14.5 kbar at 470 °C to ～22.5 kbar at 560 °C. Garnet in sample Q5‐12 develops with pattern I zonation, which is consistent with a progressive metamorphic process from ～21 kbar at 540 °C to ～23.5 kbar at 580 °C with lawsonite present in the whole garnet growth. The latter sample shows the highest P–T conditions of the reported chloritoid–glaucophane‐bearing assemblages. Phase equilibrium calculation in the NCKFMASH system with a recent mixing model of amphibole indicates that chloritoid + glaucophane paragenesis does not have a low‐pressure limit of 18–19 kbar as previously suggested, but has a much larger pressure range from 7–8 to 27–30 kbar, with the low‐pressure part being within the stability field of albite.  相似文献   

Probabilistic aspects of micropaleontologic assemblage zones     

Isamu Hattori 《Mathematical Geology》1985,17(2):167-175

A micropaleontologic assemblage zone is defined by occurrence of some characteristic species among many coeval species. When number of assemblage-defining species and total number of species observed are designated as Aand N,respectively, the ratio, A/N,is strongly dependent on duration of the assemblage. Theoretical consideration on the basis of a micropaleontologic cohort model shows that, when origination rate and extinction rate of species are obtained, the most reasonable ratio (A/N) and duration of the assemblage can be determined. The probabilistic model described in this paper provides a theoretical relation between the ratio and the duration. Inaccuracy in correlating micropaleontologic data to certain assemblage zones established can not be avoided because of many natural sorting and artificial biases. Ambiguity arising when data with a small number of characteristic species are correlated with a certain assemblage is numerically estimated.  相似文献   

富钴结壳中矿物组成对稀土元素分布的制约     

张平萍  初凤友  李小虎 《海洋学报》2015,37(5):136-147

为探讨富钴结壳中矿物组成对稀土元素分布的制约,对约翰斯顿岛富钴结壳中矿物组成及稀土元素特征进行了研究。依据主要矿物组成,富钴结壳可以分为3种类型,分别命名为A、B、C。由A到C,水羟锰矿含量逐渐降低,B类中磷灰石含量最高,C类中水钠锰矿和钙锰矿含量最高。A类结壳中富集REE3+、Ce,B类结壳中富集Ce和Y。A类富钴结壳中,REE3+、Y以专属吸附的方式富集在铁氧化物上,Ce3+氧化成Ce4+与其他REE分离,吸附在锰矿物上。B类结壳中,稀土元素主要以独立矿物的形式存在,另有部分Ce、LREE3+吸附于铁相中,部分Y存在于磷灰石中。C类结壳中,稀土元素主要赋存在锰矿物中,部分Y存在于磷灰石中。  相似文献   

青藏高原盐湖水化学及其矿物组合特征   总被引：23，自引：1，他引：22  

郑绵平  刘喜方 《地质学报》2010,84(11):1585-1600

青藏高原湖泊的矿化度与其湖泊演化所处的自然环境,特别是与气候条件关系密切,根据取得盐湖数量和卫片解译,本区湖泊矿化度在空间上变化的总趋势是由北、西北向南、东南趋向下降,大体上与现代高原年干燥度(年蒸发量/年降水量)呈同步变化。高原盐湖的pH值既与水化学类型有关,又与湖水矿化度有关,即由碳酸盐型→硫酸钠亚型→硫酸镁亚型→氧化物型,其pH值趋于下降,而湖泊的pH值与矿化度大体呈反相关。根据库尔纳可夫—瓦良什科分类法及作者对碳酸盐型的细分,对青藏高原盐湖水化学进行了全面细致划分,从而取得了清晰的规律性认识:本区盐湖水化学具有南北分带,东西分区的特点。不同的盐湖水化学类型,具有不同的专属性,碳酸盐型代表性成矿组合为硼砂(三方硼砂)或硼砂—扎布耶石,以及碱—芒硝组合;硫酸钠亚型代表性成矿组合为芒硝(无水芒硝)—石盐以及镁硼酸盐(库水硼镁石、柱硼镁石等)—钠硼解石—芒硝;硫酸镁亚型代表性成矿组合为硫酸镁盐(泻利盐、白钠镁矾)—石盐、镁硼酸盐—芒硝、芒硝—软钾镁矾—石盐以及大量石膏;氯化物型代表性成矿组合则为光卤石—水氯镁石—石盐、光卤石—石盐,个别盐湖共生南极石。由此可见,青藏高原各类型盐湖矿物组合基本上具有冷相组合特征,芒硝及与其共生的冷相盐类矿物,可成为研究古气候变化的重要标志物。目前已检出青藏高原盐湖水含有59种元素,其中B与Li、Cs、K、Rb有密切共生关系,其含量随湖水矿化度增长大致呈正相关;B、Li、Cs、K、Rb最高正异常落在羌南碳酸盐型带(Ⅰ2)西段—昂拉陵湖区为中心地区;并与本区中新世火山沉积岩系和地热水B、Li、Cs、Rb等高值区并行不悖。以上有力证明B、Li、Cs等特殊元素物质与深部来源有关。据近期大量地球物理和火山岩岩石地球化学研究,其成因与印度—欧亚陆陆碰撞引起的重熔岩浆作用有密切成因联系。南美科迪勒拉高原硼锂(铯)盐湖即生成于活动大陆边缘,两者均说明全球特定的活动构造带是造成天然水B、Li、Cs(K、Rb)高丰度及其成矿作用的主因。  相似文献   

西藏札达盆地晚上新世—早更新世孢粉组合及其地质意义   总被引：2，自引：0，他引：2  

江尚松  向树元  徐亚东 《地质科技情报》2010,29(4)

札达盆地位于青藏高原西南隅的阿里地区,是在中新世晚期约9.6 Ma B.P.形成的一个NW—SE向断陷盆地。该盆地在上新世—早更新世发育一套完整的河湖-冲积扇相地层。在札达县香孜乡西北约1 km处精细实测了上上新统—下更新统香孜剖面。根据前人的古地磁及ESR年龄数据确定下更新统香孜组年龄为2.60~1.67 Ma B.P.。根据孢粉学研究把香孜剖面自下而上划分为3个孢粉组合带(8个孢粉组合),并据此将札达盆地2.75 Ma B.P.以来的气候变化划分为3个阶段:(1)孢粉组合带Ⅰ(孢粉组合1~2),植被为温暖偏湿的常绿与落叶针阔叶混交林,2.67 Ma以后气候逐渐向干旱转变,地层对比时代为晚上新世(2.75~2.60 Ma);(2)孢粉组合带Ⅱ(孢粉组合3~5),发育温凉偏湿的亚高山落叶针阔叶混交林,并在约2.38 Ma逐渐变为针叶林,气候趋向变冷,地层对比时代为早更新世(2.54~2.16 Ma);(3)孢粉组合带Ⅲ(孢粉组合6~8),发育寒冷干旱的高山针叶林,并存在高寒灌丛草甸草原,低海拔处零星分布落叶针阔叶混交林,指示较强的地势差异,地层对比时代为早更新世(2.13~1.86 Ma)。  相似文献   

不同石漠化等级的孢粉组合特征及其生态指示意义——以花江实验区为例   总被引：1，自引：1，他引：0  

赵增友  袁道先  罗伦德  石胜强  郝秀东 《中国岩溶》2010,29(2):113-119

以贵州省关岭县南部北盘江试验示范为例,分析了不同等级石漠化土地上的表土孢粉组合特征,揭示了孢粉组合特征与石漠化等级的相互关系。结果显示:石漠化地区的孢粉组合具有鲜明的特征,乔木与灌木合占16.1%,草本与蕨类植物合占58.9%,这反映了石漠化地区以草蕨类植物为主的植被状况;孢粉组合与石漠化等级呈良好的相关性,草蕨类植物随石漠化等级的升高比重由41%增加到77.6%,种类由14种增加到27种,乔木花粉所占比重由6.9%降到2.6%,植物种类不变;孢粉组合反映出三出凤尾蕨等蕨类植物对岩溶石漠化生态环境的适应性和代表性。  相似文献   

A geochemical survey of trace elements in agricultural and non-agricultural topsoil in Dexing area,China   总被引：2，自引：0，他引：2  

Yanguo Teng  Shijun Ni  Jinsheng Wang  Rui Zuo  Jie Yang 《Journal of Geochemical Exploration》2010

In China, soil pollution is very serious, which has jeopardized the ecology, food safety, the people's health, and even the sustainable development of agriculture. In order to investigate the soil pollution situation, a total of 874 agricultural and non-agricultural topsoil samples were collected from Dexing area, northeast of Jiangxi Province, China. The total elemental concentrations of 17 elements (As, Hg, Mo, Cd, Cr, Zn, Cu, Mn, Ti, Pb, Fe, Ca, K, Si, Al, Mg, and Na) were determined. The geochemical background and threshold was predicted with the method of the median ± median absolute deviation (MAD). The agricultural soil median concentration of trace elements was similar to that of the non-agricultural soil. In contrast to Jiangxi soil background of trace elements, the geochemical background of the study area was obviously higher. The maps of the pollution indices for As, Cd, Cr, Cu, Hg, Mn, Mo, Pb, Ti and Zn of non-agricultural soil and agricultural soils in the study area, showed that the highest level of pollution is distributed near and along the Lean River, especially in the neighboring and surrounding Dexing and Leping mining area.  相似文献   

海拉尔盆地查干诺尔凹陷扎赉诺尔群孢粉组合   总被引：3，自引：0，他引：3  

薛云飞  王丽岩 《中国煤炭地质》2010,(1):6-14

内蒙古自治区呼伦贝尔盟地区海拉尔盆地查干诺尔凹陷扎赉诺尔群自下而上划分为4个孢粉组合。云杉粉Piceaepollenites sp.-单束松粉Abietineaepollenites sp.-三角粒面孢Granulatisporites sp.组合,分布于大磨拐河组一段;罗汉松粉Podocarpidites sp.-双束松粉Pinuspollenites sp.-无突肋纹孢Cicatricosisporites sp.组合,分布于大磨拐河组二段;无突肋纹孢Cicatricosisporites sp.-刺毛孢Pilosisporite sp.-水龙骨单缝孢Polypodiaceaesporites sp.组合,分布于伊敏组一段;有突肋纹孢Appendicisporites sp.-桫椤孢Cyathidites sp.-星粉Astropollis sp.组合,分布于伊敏组二、三段。上述孢粉组合研究证明,大磨拐河组地质时代为早白垩世凡兰吟期—欧特里夫期(Valanginian-Hauterivian),尽管没有出现最原始的被子植物花粉,但也不排除部分进入巴列姆期(Barremian)的可能,伊敏组的地质时代为早白垩世巴列姆期-阿普第期(Barremian-Aptian)。据此认为扎赉诺尔群地质时代为早白垩世凡兰吟期—阿普第期(Valanginian-Aptian)。  相似文献   

云南剑川地区象鼻洞遗址孢粉组合和古环境   总被引：1，自引：0，他引：1  

张继效  王伟铭  高峰 《地球科学与环境学报》2014,(4)

为了解云南剑川旧石器时代中晚期植被和气候变化特点以及当地环境与人类活动的关系,选取象鼻洞遗址各地层的13个土样进行孢粉分析。结果表明:该遗址堆积时期孢粉植物群以亚热带和温带成分为主,类型相对丰富,呈温暖期气候特征,但气候存在小的波动,呈现出早期温暖湿润、中期短暂干旱、晚期又逐渐暖湿的特点;木本植物花粉在孢粉总量中占绝对优势,说明当时人类活动对自然环境的影响不明显;可作为食物来源的植物很少,因此,当时居住在象鼻洞的人类主要食物应来源于捕捞或狩猎;对照邻近地区已有的研究成果,推测该遗址气候变化与季风活动有关。  相似文献   

柴达木盆地西部大浪滩梁中矿区软钾镁矾沉积的矿物组合特征   总被引：1，自引：1，他引：0  

樊启顺  程怀德  冉广芬 《盐湖研究》2014,(3):9-14

柴达木盆地西部大浪滩梁中矿区是一个以液体钾矿为主、固液并存的大型钾镁盐矿田。通过对梁中矿区大浪滩凹地钾镁盐矿点实地考察,以兴元钾肥厂开挖的固体钾盐(软钾镁矾、钾石盐和杂卤石等矿物)剖面为研究载体,采集73件固体盐样。通过XRD矿物组成分析,发现梁中凹地盐类呈石盐+泻利盐—石盐+泻利盐+软钾镁矾—石盐+泻利盐+钾石盐—石盐+钾石盐+光卤石—石盐+水氯镁石矿物组合变化。其中,在Ⅱ阶段(5.3².6 m)沉积了层状的固体钾盐矿物(包含软钾镁矾、钾石盐和光卤石)。地层中沉积的软钾镁矾,结晶良好。通过对比分析认为,软钾镁矾的形成条件:1)外来水体的混入,溶滤了地表盐滩中可溶性钾;2)(全新世)相对较高的温度条件,芒硝等矿物的溶解,会使湖表卤水中硫酸盐含量明显增加,卤水组成点易落在25℃介稳相图的白钠镁矾相区,有利于软钾镁矾结晶析出;3)干旱的气候条件。  相似文献