Interpreting zirconium‐in‐rutile thermometric results          下载免费PDF全文

K. Taylor‐Jones  R. Powell 《Journal of Metamorphic Geology》2015,33(2):115-122

At first sight, experimental results and observations on rocks suggest that the Zr content in rutile, where equilibrated with quartz and zircon, should be a useful thermometer for metamorphic rocks. However, diffusion data for Zr in rutile imply that thermometry should not, for plausible rates of cooling, give the high temperatures commonly observed in high‐grade metamorphic rocks. It is suggested here that such observations can be accounted for by high‐T diffusive closure of Si in rutile, causing the interior of rutile grains to become insensitive to the thermometer equilibrium well above the temperature of Zr diffusive closure. Paired with comparatively slow grain boundary diffusion and problematic zircon nucleation, this allows for cases of Zr retention in rutile through temperatures where Zr is still diffusively mobile within rutile grains. Other observations that may be accounted for in this context are large inter‐grain ranges of rutile Zr contents uncorrelated with rutile grain size, and flat Zr profiles across individual rutile grains, counter to what would be expected from diffusive closure. A consequence is that it is unlikely that Zr‐in‐rutile thermometry will be useful for estimating rock cooling rates.  相似文献   

Dissolved inorganic carbon evolution in neutral discharge from mine tailings piles          下载免费PDF全文

Hendratta N. Ali  Eliot A. Atekwana 《水文研究》2016,30(13):2079-2091

We measured the concentrations of dissolved inorganic carbon (DIC) and major ions and the stable carbon isotope ratios of DIC (δ¹³C_DIC) in two creeks discharging from carbonate‐rich sulphide‐containing mine tailings piles. Our aim was to assess downstream carbon evolution of the tailings discharge as it interacted with the atmosphere. The discharge had pH of 6.5–8.1 and was saturated with respect to carbonates. Over the reach of one creek, the DIC concentrations decreased by 1.1 mmol C/l and δ¹³C_DIC increased by ~4.0‰ 200 m from the seep source. The decrease in the DIC concentrations was concomitant with decreases in the partial pressure of CO_2(aq) because of the loss of excess CO_2(aq) from the discharge. The corresponding enrichment in the δ¹³C_DIC is because of kinetic isotope fractionation accompanying the loss of CO_2(g). Over the reach of the other creek, there was no significant decrease in the DIC concentrations or notable changes in the δ¹³C_DIC. The insignificant change in the DIC concentrations and the δ¹³C_DIC is because the first water sample was collected 160 m away from the discharge seep, not accessible during this research. In this case, most of the excess CO_2(aq) was lost before our first sampling station. Our results indicate that neutral discharges from tailings piles quickly lose excess CO_2(aq) to the atmosphere and the DIC becomes enrich in ¹³C. We suggest that a significant amount of carbon cycling in neutral discharges from tailings piles occur close to the locations where the discharge seeps to the surface. Copyright © 2015 John Wiley & Sons, Ltd.  相似文献   

Root‐zone moisture replenishment in a native vegetated catchment under Mediterranean climate     

Xiang Xu  Huade Guan  Grzegorz Skrzypek  Craig T. Simmons 《水文研究》2019,33(18):2394-2407

The root‐zone moisture replenishment mechanisms are key unknowns required to understand soil hydrological processes and water sources used by plants. Temporal patterns of root‐zone moisture replenishment reflect wetting events that contribute to plant growth and survival and to catchment water yield. In this study, stable oxygen and hydrogen isotopes of twigs and throughfall were continuously monitored to characterize the seasonal variations of the root‐zone moisture replenishment in a native vegetated catchment under Mediterranean climate in South Australia. The two studied hillslopes (the north‐facing slope [NFS] and the south‐facing slope [SFS]) had different environmental conditions with opposite aspects. The twig and throughfall samples were collected every ~20 days over 1 year on both hillslopes. The root‐zone moisture replenishment, defined as percentage of newly replenished root‐zone moisture as a complement to antecedent moisture for plant use, calculated by an isotope balance model, was about zero (±25% for the NFS and ± 15% for the SFS) at the end of the wet season (October), increased to almost 100% (±26% for the NFS and ± 29% for the SFS) after the dry season (April and May), then decreased close to zero (±24% for the NFS and ± 28% for the SFS) in the middle of the following wet season (August). This seasonal pattern of root‐zone moisture replenishment suggests that the very first rainfall events of the wet season were significant for soil moisture replenishment and supported the plants over wet and subsequent dry seasons, and that NFS completed replenishment over a longer time than SFS in the wet season and depleted the root zone moisture quicker in the dry season. The stable oxygen isotope composition of the intraevent samples and twigs further confirms that rain water in the late wet season contributed little to root‐zone moisture. This study highlights the significant role of the very first rain events in the early wet season for ecosystem and provides insights to understanding ecohydrological separation, catchment water yield, and vegetation response to climate changes.  相似文献   

Frequency analysis of nonstationary annual maximum flood series using the time‐varying two‐component mixture distributions          下载免费PDF全文

Lei Yan  Lihua Xiong  Dedi Liu  Tiesong Hu  Chong‐Yu Xu 《水文研究》2017,31(1):69-89

The most popular practice for analysing nonstationarity of flood series is to use a fixed single‐type probability distribution incorporated with the time‐varying moments. However, the type of probability distribution could be both complex because of distinct flood populations and time‐varying under changing environments. To allow the investigation of this complex nature, the time‐varying two‐component mixture distributions (TTMD) method is proposed in this study by considering the time variations of not only the moments of its component distributions but also the weighting coefficients. Having identified the existence of mixed flood populations based on circular statistics, the proposed TTMD was applied to model the annual maximum flood series of two stations in the Weihe River basin, with the model parameters calibrated by the meta‐heuristic maximum likelihood method. The performance of TTMD was evaluated by different diagnostic plots and indexes and compared with stationary single‐type distributions, stationary mixture distributions and time‐varying single‐type distributions. The results highlighted the advantages of TTMD with physically‐based covariates for both stations. Besides, the optimal TTMD models were considered to be capable of settling the issue of nonstationarity and capturing the mixed flood populations satisfactorily. Copyright © 2016 John Wiley & Sons, Ltd.  相似文献   

Estimation of instantaneous peak flow from maximum mean daily flow by regionalization of catchment model parameters          下载免费PDF全文

Jie Ding  Uwe Haberlandt 《水文研究》2017,31(3):612-626

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Generation of continuous surface soil moisture dataset using combined optical and thermal infrared images          下载免费PDF全文

Pei Leng  Xiaoning Song  Si‐Bo Duan  Zhao‐Liang Li 《水文研究》2017,31(6):1398-1407

Surface soil moisture (SSM) is a critical variable for understanding water and energy flux between the atmosphere and the Earth's surface. An easy to apply algorithm for deriving SSM time series that primarily uses temporal parameters derived from simulated and in situ datasets has recently been reported. This algorithm must be assessed for different biophysical and atmospheric conditions by using actual geostationary satellite images. In this study, two currently available coarse‐scale SSM datasets (microwave and reanalysis product) and aggregated in situ SSM measurements were implemented to calibrate the time‐invariable coefficients of the SSM retrieval algorithm for conditions in which conventional observations are rare. These coefficients were subsequently used to obtain SSM time series directly from Meteosat Second Generation (MSG) images over the study area of a well‐organized soil moisture network named REMEDHUS in Spain. The results show a high degree of consistency between the estimated and actual SSM time series values when using the three SSM dataset‐calibrated time‐invariable coefficients to retrieve SSM, with coefficients of determination (R²) varying from 0.304 to 0.534 and root mean square errors ranging from 0.020 m³/m³ to 0.029 m³/m³. Further evaluation with different land use types results in acceptable debiased root mean square errors between 0.021 m³/m³ and 0.048 m³/m³ when comparing the estimated MSG pixel‐scale SSM with in situ measurements. These results indicate that the investigated method is practical for deriving time‐invariable coefficients when using publicly accessed coarse‐scale SSM datasets, which is beneficial for generating continuous SSM dataset at the MSG pixel scale.  相似文献   

Reevaluating suitability estimates based on dynamics of cropland expansion in the Brazilian Amazon     

《Global Environmental Change》2016

Agricultural suitability maps are a key input for land use zoning and projections of cropland expansion. Suitability assessments typically consider edaphic conditions, climate, crop characteristics, and sometimes incorporate accessibility to transportation and market infrastructure. However, correct weighting among these disparate factors is challenging, given rapid development of new crop varieties, irrigation, and road networks, as well as changing global demand for agricultural commodities. Here, we compared three independent assessments of cropland suitability to spatial and temporal dynamics of agricultural expansion in the Brazilian state of Mato Grosso during 2001–2012. We found that areas of recent cropland expansion identified using satellite data were generally designated as low to moderate suitability for rainfed crop production. Our analysis highlighted the abrupt nature of suitability boundaries, rather than smooth gradients of agricultural potential, with little additional cropland expansion beyond the extent of the flattest areas (0–2% slope). Satellite-based estimates of the interannual variability in the use of existing crop areas also provided an alternate means to assess suitability. On average, cropland areas in the Cerrado biome had higher utilization (84%) than croplands in the Amazon region of northern Mato Grosso (74%). Areas of more recent expansion had lower utilization than croplands established before 2002, providing empirical evidence for lower suitability or alternative management strategies (e.g., pasture–soya rotations) for lands undergoing more recent land use transitions. This unplanted reserve constitutes a large area of potentially available cropland (PAC) without further expansion, within the management limits imposed for pest management and fallow cycles. Using two key constraints on future cropland expansion, slope and restrictions on further deforestation of Amazon or Cerrado vegetation, we found little available flat land for further legal expansion of crop production in Mato Grosso. Dynamics of cropland expansion from more than a decade of satellite observations indicated narrow ranges of suitability criteria, restricting PAC under current policy conditions, and emphasizing the advantages of field-scale information to assess suitability and utilization.  相似文献   

Modelling the flow of self‐compacting concrete     

S. Kulasegaram  B. L. Karihaloo  A. Ghanbari 《国际地质力学数值与分析法杂志》2011,35(6):713-723

A Lagrangian particle‐based method, smooth particle hydrodynamics (SPH), is used in this paper to model the flow of self‐compacting concretes (SCC) with or without short steel fibres. An incompressible SPH method is presented to simulate the flow of such non‐Newtonian fluids whose behaviour is described by a Bingham‐type model, in which the kink in the shear stress vs shear strain rate diagram is first appropriately smoothed out. The viscosity of the SCC is predicted from the measured viscosity of the paste using micromechanical models in which the second phase aggregates are treated as rigid spheres and the short steel fibres as slender rigid bodies. The basic equations solved in the SPH are the incompressible mass conservation and Navier–Stokes equations. The solution procedure uses prediction–correction fractional steps with the temporal velocity field integrated forward in time without enforcing incompressibility in the prediction step. The resulting temporal velocity field is then implicitly projected on to a divergence‐free space to satisfy incompressibility through a pressure Poisson equation derived from an approximate pressure projection. The results of the numerical simulation are benchmarked against actual slump tests carried out in the laboratory. The numerical results are in excellent agreement with test results, thus demonstrating the capability of SPH and a proper rheological model to predict SCC flow and mould‐filling behaviour. Copyright © 2010 John Wiley & Sons, Ltd.  相似文献   

Influence of heterogeneity on unsaturated hydraulic properties: (1) local heterogeneity and scale effect     

Pen‐Yuan Chen  Chu‐Hui Chen  Nien‐Sheng Hsu  Cheng‐Mau Wu  Jet‐Chau Wen 《水文研究》2012,26(23):3593-3603

Spatial heterogeneity is ubiquitous in nature, which may significantly affect the soil hydraulic property curves. The models of a closed‐form functional relationship of soil hydraulic property curves (e.g. VG model or exponential model) are valid at point or local scale based on a point‐scale hydrological process, but how do scale effects of heterogeneity have an influence on the parameters of these models when the models are used in a larger scale process? This paper uses a two‐dimensional variably saturated flow and solute transport finite element model (VSAFT2) to simulate variations of pressure and moisture content in the soil flume under a constant head boundary condition. By changing different numerical simulation block sizes, a quantitative evaluation of parameter variations in the VG model, resulting from the scale effects, is presented. Results show that the parameters of soil hydraulic properties are independent of scale in homogeneous media. Parameters of α and n in homogeneous media, which are estimated by using the unsaturated hydraulic conductivity curve (UHC) or the soil water retention curve (WRC), are identical. Variations of local heterogeneities strongly affect the soil hydraulic properties, and the scale affects the results of the parameter estimations when numerical experiments are conducted. Furthermore, the discrepancy of each curve becomes considerable when moisture content becomes closer to a dry situation. Parameters estimated by UHC are totally different from the ones estimated by WRC. Copyright © 2012 John Wiley & Sons, Ltd.  相似文献   

基于NGM(1,1,k,c)模型和改进切线角的危岩变形预测     

刘富有  陈鹏宇  余宏明 《测绘与空间地理信息》2016,(6):8-10

针对危岩变形预测问题,本文以非齐次指数序列的灰色模型(NGM)作为危岩变形预测的基本模型,通过对望霞危岩变形的分析结果显示,NGM(1,1,k,c)模型拟合效果明显优于GM(1,1)模型,说明危岩变形趋势更接近于非齐次指数序列。利用NGM(1,1,k,c)模型结合改进切线角可对危岩变形趋势进行分析预测,可作为危岩稳定性和发展趋势的评估依据。  相似文献