Changes to cadmium associations in canal sediments on drying and oxidation     

Samantha R. Cook John M. Chamock Andrew Parker 《中国地球化学学报》2006,25(B08):247-247

The mainly 19th Century canal system in the UK, largely managed by British Waterways, has been increasingly brought back into operation over the last few decades, and is now widely used for both leisure, and, increasingly, transport. Both initial and routine dredging of the canal sediment is carried out and these sediments are generally disposed of to land. Because many of the canals were connected with primary industries, their sediments can locally be significantly contaminated with heavy metals, and the behaviour of these metals under differing redox conditions, when introduced into a new environment （i.e., on land） is of importance for environmental risk-assessment purposes. Canal sediments are often rich in sulfidic mineral phases, and we have attempted to quantify the influence of these sulfidic phases on the release and retention of metals in dredged canal sediments, using a combination of traditional chemical techniques （e.g. sequential extraction） and X-ray absorption spectroscopy （XAS）. Sediment samples have been collected from urban fresh-water canals, one in the British Midlands and one in Northern France. It appears from XAS that Cd is largely associated with oxygen in air-dried sediment, and with sulphur in vacuum-dried sediment.  相似文献   

Origin and three-dimensional fluorescence spectrum of the chromophoric dissolved organic matter in Yangtze estuary, East China     

Fan YANG Qinghui HUANG Jianhua LI Xiaomin ZHU 《中国地球化学学报》2006,25(B08):262-262

Dissolved organic matter （DOM） is an important chemical component in natural water. Chromophoric dissolved organic matter （CDOM）, a fraction of optical properties, plays art important role in the biogeochemical cycle of nutrients in aquatic environment. People realized that DOM cycle is crucial in the global carbon and nitrogen flux, and also is inherently related to nutrients and trace metal elements. Therefore, CDOM was concerned by scientists in global oceanography and limnology fields. Water samples were collected from three sections （North Channel, South Channel and Zhuyuan） of the Yangtze （Changjiang River） estuary in March 2006 Three-dimensional excitation emission matrix （3-DEEM） fluorescence spectra were analyzed for those filtrates through Whatman GF/F filters. Dissolved organic carbon （DOC） was also measured by TOC analyzer. The tidal variety was also taken into account. The 3-D EEM fluorescence scans suggested the fluorescence characteristics of humic acid （Ex=332-344 nm, Em=439-451 nm） and fulvic acid （Ex=250-254 nm, Em=472-478 nm） were obvious, and the fluorescence group of protein-like and tyrosine （Ex=230 nm, Em=283 nm） was also found. They are mainly composed of CDOM in the Yangtze estuary. Further data analysis, especially the fluorescence index （f 450/500）, showed that terrestrial signal was rather strong （1.41-1.65） in the surface water, however, some terrestrial CDOM signals of bottom water showed excursions （1.28-1.39）. On the other hand, anthropogenic sign was impressed in the waters of Zhuyuan, which is one of the main drain outlets of Shanghai Metropolis. DOC concentrations ranged from 2.2 mg/L to 3.4 mg/L in Zhuyuan and South Channel, and from 2.0 mg/L to 2.4 mg/L in North Channel. The tide effect played a role in the composition of the CDOM measured by 3-D fluorescence scan technology.  相似文献   

Effect of particles on the photodegradation of PAHs in natural waters-A case study for the Yellow River     

Xinghui XIA 《中国地球化学学报》2006,25(B08):263-263

Photodegradation of chrysene, benzo （a） pyrene and benzo （g, h, i） perylene in natural water of the Yellow River was studied using simulation sunlight. The effects of particulates on the photodegradation were explored. Several results arose from this study. （1） The photodegradation of PAHs can be fitted with first-order kinetics when no particulate exists in water system, and the first-order constant increases with decreasing of initial concentration of PAHs. The photodegradation rates of the three PAHs are related to their molecule absorption spectrum. （2） The existence of loess exerts two kinds of effects on the photodegradation of PAHs, including the inner filter effects and the photosensitizing effects of humic substance in loess. These two contrary effects lead to the difference of net effects among different contents of loess. When the loess contents are 0.1 and 5.0 g/L, the existence of loess stimulates the photodegradation of chrysene, benzo （a） pyrene. When the loess content is 5.0 g/L, the existence of loess stimulates the photodegradation of benzo （g, h, i） perylene. In addition, the photodegradation of PAHs can be fitted with the second-order kinetics when there is loess in the water system. （3） The soluble humic substances in loess can accelerate the photodegradation of PAHs while the in soluble part cannot. （4） Since the soluble humic substances in the suspended solids of the river have been dissolved in water,  相似文献   

环溪河流域土壤氮素含量及影响因素分析     

黄海峰邓良基  胡玉福高雪松 郑小佳 《山地学报》2006,24(B10):98-102

根据67个随机格网样点和分层抽样样点的耕层土壤氮素含量，在ArcGIS9．0平台上运用地统计学等方法研究了环溪河流域土壤氮素含量及其影响因素。结果表明，环溪河流域土壤全氮和碱解氮的平均含量分别为0．60g／kg和53．31mg／kg。研究区土壤全氮含量总体上呈条带状和团块状分布，其低值中心区（〈0．5g／kg）位于团结村不规则三角形区域，并以此为中心向四周增加；高值中心区（〉0．8g／kg）主要位于走马村椭圆状区域。区内土壤碱解氮其高值区（〉75mg／kg）主要分布在深弯村以西，低值区（〈33mg／kg）主要分布于窝窝店村和杨柳村一带。影响区内土壤氮素含量空间分布的因素主要是成土母质、土壤质地、土地利用方式、地貌和坡度。  相似文献   

本刊影响因子再创新高     

《云南地理环境研究》2006,18(6):97-97

据日前“中国科学文献计量评价研究中心”提供的最新《中国学术期刊综合引证年度报告（2006）》（统计源刊6182种），本刊影响因子再创新高，达0．961，五年影响因子0．815，在云南省的全部期刊中名列第一，并遥遥领先!（全国排名尚未查到）。  相似文献   

西藏昌都镇地质灾害发育特征及防治对策   总被引：1，自引：1，他引：1  

汤明高  许强  马和平  成民  杜先兴 《中国地质灾害与防治学报》2006,17(4):11-16

昌都镇位于澜沧江上游“三河一江”地带(即昂曲、扎曲、色曲、澜沧江)。地质构造条件复杂,气候较恶劣,昼夜温差大,物理风化强烈,植被稀疏,地质灾害发育。该区是藏东的政治、经济、文化中心。随着地区的经济发展,其城镇建设与地质灾害之间的矛盾日益突出。调查研究显示昌都镇发育地质灾害33处,其中崩塌16处,占灾害点总数48.5%,主要发育于路堑边坡和河流下切侧蚀形成的自然边坡;滑坡13处,占灾害点总数的39.4%,且90%为土质滑坡,多与人类工程活动有关;泥石流4处,占灾害点总数的12.1%,以中小型为主。文章总结了昌都镇崩塌、滑坡和泥石流灾害的发育分布特征,地质灾害与地层岩性、空间位置和人类工程活动等之间的关系,以及对昌都城镇建设和发展的影响。结合调查分析提出了昌都镇地质灾害防治的总体策略———治灾、设防、治水、治坡、生态建设和加强环保意识。  相似文献   

淮北煤田孙庄勘探区煤层气赋存规律及影响因素分析     

樊爱英 《中国煤田地质》2006,18(5):25-27

通过对淮北煤田孙庄勘探区地质构造、沉积特征、煤层煤质及煤层气赋存特征的分析，研究认为有利于本区煤层气赋存的主要因素是较大的埋藏深度、较高的壳质组＋镜质组、较高的变质程度、较大的煤层厚度、低透气性的盖层、较缓的地层倾角和封闭性较好的构造条件，推测煤田深部可能具有一定工业价值的煤层气资源。  相似文献   

GPS高差在滑坡监测中的应用研究   总被引：6，自引：0，他引：6  

赵超英  张勤  王利 《测绘通报》2005,(1):39-41

在分析GPS水准研究的现状及应用成果的基础上,推导基于站心地平直角坐标系的GPS坐标,其中Z分量即为GPS高差.主要分析影响GPS高差及其变化的误差,即GPS定位误差、垂线偏差以及坐标框架不一致等的影响,最后应用实例进行验证.  相似文献   

城市水环境初探     

李中艳 《地下水》2005,27(6):475-476

本文从人口和经济实业集结与硬化工程集中两方面,分析了影响城市水环境的客现成因;从缺失负责任的社会主体与水务工程的设计、施工方式的缺陷两方面,分析了影响城市水环境的主观成因;对城市水环境的改善、管理进行了初步探讨,提出了相应的对策和建议.  相似文献   

盛源盆地南部铀成矿水文地球化学条件分析     

石平 《铀矿地质》2005,21(1):38-44,51

本文阐述了盛源盆地南部铀成矿的地质、水文地质和水文地球化学条件 ,分析了区内放射性水异常的产出、分布特征和控制因素 ,认为坝口等地段水的循环深度大 ,深部氧化 还原过渡带发育 ,大面积、交互叠加的放射性水异常是寻找大型隐伏铀矿床的重要标志。  相似文献