Simulation Chamber Studies of the Atmospheric Oxidation of 2-Methyl-3-Buten-2-ol: Reaction with Hydroxyl Radicals and Ozone Under a Variety of Conditions     

N. Carrasco  J. F. Doussin  M. O’Connor  J. C. Wenger  B. Picquet-Varrault  R. Durand-Jolibois  P. Carlier 《Journal of Atmospheric Chemistry》2007,56(1):33-55

This article presents a complete study of the diurnal chemical reactivity of the biogenic volatile organic compound (BVOC), 2-methyl-3-buten-2-ol (MBO) in the troposphere. Reactions of MBO with OH and with ozone were studied to analyse the respective parts of both processes in the global budget of MBO atmospheric reactivity. They were investigated under controlled conditions for pressure (atmospheric pressure) and temperature (298 ± 2 K) using three complementary European simulation chambers. Reaction with OH radicals was studied in the presence of and in the absence of NO _x . The kinetic study was carried out by relative rate study using isoprene as a reference. The rate constant found for this reaction was molecule⁻¹ cm³ s⁻¹. FTIR spectroscopy, DNPH- and PFBHA-derivatisation analyses were performed for reactions with both OH radicals and ozone. In both reactions, the hydroxycarbonyl compound, 2-hydroxy-2-methylpropanal (HMPr) was positively identified and quantified, with a yield of in the reaction with OH, and a yield of and 0.84 ± 0.08 in the reaction with ozone under dry (HR < 1%) and humid conditions (HR = 20%–30%). A primary production of two other carbonyl compounds, acetone , and formaldehyde was found in the case of the dry ozonolysis experiments. Under humid conditions, only formaldehyde was co-produced with HMPr as a primary carbonyl compound, with a yield of . For the reaction with OH, three other carbonyl compounds were detected, acetone , formaldehyde and glycolaldehyde . In addition some realistic photo-oxidation experiments were performed to understand in an overall way the transformations of MBO in the atmosphere. The realistic photo-oxidation experiments were conducted in the EUPHORE outdoor simulation chamber. It was found that this compound is a weak secondary aerosol producer (less than 1% of the carbon balance). But it was confirmed that it is a potentially significant source of acetone, Δ[Acetone]/Δ[MBO] = 0.45. With our experimental conditions ([MBO]₀ = 200 ppb, [NO]o = 50 ppb), an ozone yield of Δ[O₃]/Δ[MBO] = 1.05 was found.  相似文献   

临沂中尺度数值预报系统及应用   总被引：5，自引：1，他引：4  

裴洪芹  邰庆国  吴君  张京英  王庆华 《气象科技》2007,35(4):464-469

介绍了临沂中尺度数值预报系统及预报产品的释用和模式系统应用雷达资料情况,并对2005年6~10月的业务运行结果进行了检验,对小雨和中雨预报效果较好,TS评分较高,对夜间温度预报平均值绝对误差在1.52~2.52℃之间,平均均方根误差在2.01~2.93℃之间。该系统降水预报质量较高,气温预报误差小,准确率高,对定时、定点、定量的精细化预报具有较高的参考价值。应用自主开发的SDAF软件包,对系统的预报产品进行释用,研制了暴雨、空气质量、极端气温、干热风等预报方法。将多普勒雷达回波强度加入模式,改变模式水汽场,明显改进了预报。对径向速度反演降水系统内部风场进入中尺度模式进行了初步试验,得出了一些有益结论。  相似文献   

添加剂对KAlSi_3O_8-CaSO_4-CaCO_3体系反应表观活化能的影响   总被引：2，自引：0，他引：2  

石林  曾小平  柴妮  杨国友 《岩石矿物学杂志》2010,29(1):90-94

首先测定了KAlSi3O8-CaSO4-CaCO3体系在不同焙烧条件下钾长石转化成可溶性氧化钾的转化率,进而通过模拟计算表明:KAlSi3O8-CaSO4-CaCO3体系的固相扩散动力学过程符合金斯特林格动力学方程,反应表观活化能Ea为128.92kJ/mol。并着重考察了4种添加剂Na2SO4、Na2SO3、NaCl和NaF对KAlSi3O8-CaSO4-CaCO3体系的影响,结果表明:向体系中分别加入占反应物总质量3%的Na2SO4、Na2SO3、NaCl和1%的NaF后,体系的反应表观活化能Ea从原来的128.92kJ/mol依次下降至87.15、98.71、117.38和126.14kJ/mol,这表明4种添加剂中Na2SO4的效果最好,它能较大程度上降低反应表观活化能,从而降低反应温度和提高固相反应速率。  相似文献   

水平长导线源瞬变电磁三维积分方程模拟     

刘昱  李云哲  黄子莹 《现代地质》2010,24(2)

以体积分方程法模拟三维电磁正演问题的原理为基础,利用数值滤波方法实现了时间域水平长导线源的瞬变电磁三维问题的模拟,对电阻率、极化率、时间常数和频率相关系数的变化分别进行了三维数值模拟。为了提高计算的精度,变换过程中采用双精度数值滤波方法。利用偶极源的解析解和数值解的对比来检验数值滤波方法的可靠性。数值模拟结果表明,此种数值滤波方法精度高,结果稳定。高精度数值滤波结果为瞬变电磁法在石油、矿产、地热以及其他方面的应用提供了理论指导。  相似文献   

微量水δ(~(17)O)和δ(~(18)O)CoF_3法线外同时测试新技术     

余婷婷  甘义群  刘存富  李小倩  刘运德  蔡鹤生  周爱国  周建伟 《地质科技情报》2010,29(1)

三氧同位素(16O、17O、18O)组成特征可有效示踪天然水循环及其环境效应,微量水δ(17O)和δ(18O)CoF3法同时测试新技术的建立,可为三氧同位素定量研究提供有效的分析手段,特别是能够捕捉到像光合作用、呼吸作用等生物过程中发生的同位素分馏现象。在国内首次建立了微量水δ(17O)和δ(18O)CoF3法线外同时测试新技术,样品量仅需2μL,整个制样时间约40min。采用在质谱测试前对待测样品在100℃下预热10 min,待O2完全解吸后再进行质谱测试的方法,避免了制样和测试过程中的记忆效应及分馏效应,δ(17O)和δ(18O)的分析精度分别达到±0.07‰和±0.14‰。该法使用固体试剂CoF3替代了剧毒的气态氟化物BrF5,使得制样流程更加安全可靠且样品量少,适用性强,具有很大的推广应用价值。  相似文献   

Morphology and Histology of Lattice-like Ossified Epaxial Tendons in Psittacosaurus (Dinosauria: Ceratopsia)     

ZHOU Chang-Fu  GAO Ke-Qin  and Richard C. FOX 《《地质学报》英文版》2010,84(3):463-471

<正>Epaxial tendons play an important role in the study of the musculoskeletal system and locomotory style of dinosaurs.Although the ossified epaxial tendon lattice is fairly well known in Iguanodontoidea,only recently has knowledge of this complex been extended to ceratopsians.This study concerns the gross morphology and microstructure of the tendon lattice in Psittacosaurus,a basal ceratopsian.As in the neoceratopsian Chasmosaurus,the ossified tendons of Psittacosaurus form a three-layered, lattice-like structure.The microstructure of the tendons in large psittacosaur individuals retains an early stage of ossification,as in juvenile birds and nestling hadrosaurs,suggesting a slow developmental rate of ossification of the tendons in psittacosaur ontogeny.Comparative study indicates that a lattice-like arrangement of three-layered epaxial tendons is widely distributed in Cerapoda.This pattern also extends to Ankylosauria,implying a similar pattern of the epaxial muscles through the ornithischian clade.In addition,comparison with crocodiles implies that the different morphology of ossified tendons in dinosaurs may be associated with adaptive aspects of their paleobiology,not simply a side effect of skeletal ossification.In contrast to the short tendons in quadrupedal Chasmosaurus and Protoceratops,the elongated tendons in Psittacosaurus may be related to the bipedal locomotion characteristic of this taxon.  相似文献   

Origin of Paleofluids in Dabashan Foreland Thrust Belt:Geochemical Evidence of 13C,18O and 87Sr/86Sr in Veins and Host Rocks     

Zeng Jianhui  Xu Tianwu  Sun Zhanqiang  Zhang Yongwang 《《地质学报》英文版》2010,84(5):1239-1255

In the last ten years, with important discoveries from oil and gas exploration in the Dabashan foreland depression belt in the borderland between Shanxi and Sichuan provinces, the relationship between the formation and evolution of, and hydrocarbon accumulation in, this foreland thrust belt from the viewpoint of basin and oil and gas exploration has been studied. At the same time, there has been little research on the origin of fluids within the belt. Based on geochemical system analysis including Z values denoting salinity and research on δ13C, δ18O and 87Sr/86Sr isotopes in the host rocks and veins, the origin of paleofluids in the foreland thrust belt is considered. There are four principal kinds of paleofluid, including deep mantle-derived, sedimentary, mixed and meteoric. For the deep mantle-derived fluid, the δ13C is generally less than ?5.0‰PDB, δ18O less than -10.0‰PDB, Z value less than 110 and 87Sr/86Sr less than 0.70600; the sedimentary fluid is mainly marine carbonate-derived, with the δ13C generally more than ?2.0‰PDB, δ18O less than ?10.0‰PDB, Z value more than 120 and 87Sr/86Sr ranging from 0.70800 to 0.71000; the mixed fluid consists mainly of marine carbonate fluid (including possibly a little mantle-derived fluid or meteoric water), with the δ13C generally ranging from ?2.0‰ to ?8.0‰PDB, δ18O from ?10.0‰ to ?18.0‰ PDB, Z value from 105 to 120 and 87Sr/86Sr from 0.70800 to 0.71000; the atmospheric fluid consists mainly of meteoric water, with the δ13C generally ranging from 0.0‰ to ?10.0‰PDB, δ18O less than ?8.0‰PDB, Z value less than 110 and 87Sr/86Sr more than 0.71000. The Chengkou fault belt encompasses the most complex origins, including all four types of paleofluid; the Zhenba and Pingba fault belts and stable areas contain a simple paleofluid mainly of sedimentary type; the Jimingsi fault belt contains mainly sedimentary and mixed fluids, both consisting of sedimentary fluid and meteoric water. Jurassic rocks of the foreland depression belt contain mainly meteoric fluid.  相似文献   

CaCl_2对KAlSi_3O_8-CaSO_4-CaCO_3反应体系的影响研究     

石林  曾小平  罗汉金 《矿物岩石》2010,30(1)

通过CaCl2添加剂对KAlSi3O8-CaSO4-CaCO3体系研究反应温度和反应时间的影响研究,结果表明:随着CaCl2加入量的增多,体系的反应温度下降,反应时间缩短,当CaCl2的加入量为10%时,反应温度可降至1000℃,反应时间降至25min,此时KAlSi3O8的转化率仍可高达83.24%。研究CaCl2的加入对KAlSi3O8-CaSO4-CaCO3反应体系动力学过程的影响,得出反应体系符合金斯特林格动力学方程:FK(G)=1-2/3G-(1-G)2/3=KKt,反应受扩散过程控制,计算出当CaCl2的加入量为10%时,体系的表观活化能可从原来的128.921kJ/mol下降至58.320kJ/mol。  相似文献   

沿海地区地下水模拟优化管理模型   总被引：4，自引：0，他引：4       下载免费PDF全文

高玉芳  陈耀登  张展羽 《水科学进展》2010,21(5):622-627

针对中国一些沿海地区地下水超采及由此带来的海水入侵问题,将地表水补给、抽水量及地下水位等相嵌在一起,建立了沿海地区地下水模拟优化管理模型。将人工鱼群算法和基于MODFLOW2000的变密度地下水流及溶质运移模型耦合起来,对沿海地区地下水模拟优化管理模型进行求解。以山东省威海市节水示范区为例,验证模型的有效性和可靠性。结果表明,10、11、12月份抽水量最大,以后至第2年5月份依次是减少的;从区域分布上看,在临海区域1号井处抽水量是3500～1120m3/月,在其它井处是6540～2920m3/月;与现行方案相比,增加总有效供水1990m3,地下水平均水位升高0.29m,海水入侵问题能够得到解决。计算结果合理可行,为沿海地区地下水资源的科学管理和持续利用提供可靠依据。  相似文献   

三维地震资料在圈定煤层结构变化上的应用     

方庆水  王云  姚磊 《安徽地质》2010,20(3):216-218

随着煤炭开采机械化程度的不断提高,煤层结构的变化对采掘工作的影响日益突出。三维地震资料不仅能够控制落差3~5m以上的断层和幅度大于5m的褶曲,而且还可以利用三维资料所包含的丰富地质信息,包括煤层反射波振幅能量强弱的变化、波阻抗反演等对煤层结构的变化情况进行圈定,以提供煤层结构方面的地质资料。  相似文献