溶剂萃取法提硼研究概述   总被引：3，自引：1，他引：2       下载免费PDF全文

高成花  邓小川  张琨 《盐湖研究》2010,18(1):49-52

溶剂萃取法作为一种有效的溶液提硼方法之一,对于硼资源的开发利用、环境保护以及其它化学工业的发展具有重要意义。从萃取剂、萃取工艺和萃取设备3个方面讨论溶剂萃取法提硼的研究进展,并对今后溶液提硼的发展方向进行展望。  相似文献   

Application of major and trace elements as well as boron isotopes for tracing hydrochemical processes: the case of Trifilia coastal karst aquifer,Greece     

G. Panagopoulos 《Environmental Geology》2009,58(5):1067-1082

The Trifilia karst aquifer presents a complex hydrochemical character due to the intricate geochemical processes that take place in the area. Their discernment was achieved by using the chemical analyses of major, trace elements and boron isotopes. Major ion composition indicates mixing between seawater and freshwater is occurring. Five hydrochemical zones corresponding to five respective groundwater types were distinguished, in which the chemical composition of groundwater is influenced mainly due to the different salinization grade of the aquifer. The relatively increased temperature of the aquifer indicates the presence of hydrothermal waters. Boron isotopes and trace elements indicate that the intruding seawater has been hydrothermally altered, as it is shown by the δ¹¹B depleted signature and the increased concentrations of Li and Sr. Trace elements analyses showed that the groundwater is enriched in various metallic elements, which derive from the solid hydrocarbons (bitumens), contained in the carbonate sediments of the Tripolis zone. The concentration of these trace elements depends on the redox environment. Thus, in reductive conditions As, Mn, Co and NH₄ concentrations are high, in oxidized conditions the V, Se, Mo, Tl and U concentration increases while Ni is not redox sensitive and present high concentration in both environments.  相似文献   

南海全新世大暖期海表水的高酸性证据   总被引：1，自引：1，他引：0       下载免费PDF全文

刘羿  刘卫国  彭子成  聂宝符  肖应凯  贺剑峰  刘桂建 《第四纪研究》2009,29(1):73-79

利用正热电离质谱高精度测定了南海化石珊瑚样品的δ¹¹B 比值,定量地重建了中晚全新世以来南海海表水的pH值。结果显示南海海表水pH值并不像预先设想的那样稳定。其中古海水pH值最低为6100aB.P.前的7.91;   最高为4300aB.P.前和1200aB.P.前的8.29。南海海表水pH值从全新世大暖期开始,整体上呈缓慢增加趋势,而到现代以后明显下降。珊瑚δ¹¹B记录表明南海海表水在中晚全新世有两个高酸性的时期,一个发生在全新世大暖期,一个为现代。全新世大暖期时南海出现的高海平面、偏强的东亚夏季风和偏弱的冬季风可能是导致其海表水出现高酸性的原因。现代南海海表水pH值显著偏低,背离了中晚全新世以来南海海表水pH值逐渐增加的趋势,这很可能说明人类大量排放的CO₂确实改变了南海海表水自然变化的规律,南海在变酸。  相似文献   

Life-stage differences in the diet of Parabroteas sarsi (Daday) (Copepoda, Calanoida): A field study     

Marina P. Vega   《Limnologica》1999,29(2):186

The diet of P. sarsi in different life-stages from copepodid I to adult was investigated. Gut contents of copepodid I to II consisted mainly of algae such as diatoms and dinoflagellates. From copepodid III to adult stages the composition of the diet changed towards the inclusion of nauplii, cladocerans and copepods. The importance of the algae on the diet decreased with the inclusion of the prey items. Copepods were the most important components of the diet from C V to adult. Differences in the capture and ingestion of cladocerans and copepods were found. Diet of P. sarsi can be characterized as diverse consisting of diatoms, phagotrophic algae, protozoans, rotifers and nauplii from C I to C III and consisting mainly of carnivorous items from C IV to adult. The ability to eat a variety of food allows the copepods to modify their diet with varying conditions in the food environment. The effect of these diversity in the diet seems to be advantageous, specially in stressed environments imposed by episodes of drying.  相似文献   

胶束增溶增敏分光光度法直接测定海水中的硼   总被引：4，自引：1，他引：3  

史春莲  王渊  陈国华 《中国海洋大学学报(自然科学版)》1999,(Z1)

首次以含量为１５ ％ 的非离子型乳化剂ＯＰ１００ 胶束体系为介质进行硼的分光光度法测定研究,确定最佳实验条件（ 最大吸收波长为５５５ｎｍ ,姜黄素用量为４ｍＬ,酸试剂用量为５ｍＬ,胶束用量为５ｍＬ,显色温度为５０ ℃,显色时间为１５ｍｉｎ） ,改进了现有的姜黄法,此方法适用于海水中硼的水相直接分光光度测定。实验结果表明测定灵敏度显著增加（Ｅ＝ １ ．５ ×１０５） ,线性范围变宽（０ ～１．２μｇ／２５ｍＬ） ,络合物稳定性好,稳定时间长达５０ｈ。  相似文献   

MATLAB在碎屑沉积岩矿物含量计算中的应用     

刘飞  陈岳龙  蒋丽婷 《沉积学报》2006,24(2):229-234

岩石学与地球化学研究中,岩石中矿物含量的确定是一项重要的基础工作,传统测定主要依赖偏光显微镜镜下观察统计或进行编程计算,效率较低。通过实例介绍了使用MATLAB工具箱中非负线性最小二乘法根据岩石化学与镜下观察到的矿物种类对碎屑沉积岩中矿物含量进行定量计算的应用。计算结果表明,使用这种计算方法对岩石矿物含量的计算结果明显比显微镜下统计的更准确、快速,值得推广应用。在使用同时,也要注意合适的矿物化学组成的正确选取,以保证计算的真实有效。  相似文献   

沉积硼酸盐矿物硼同位素组成特征及控制因素研究          下载免费PDF全文

彭章旷  马云麒  彭齐鸣 《盐湖研究》2022,30(3):112-121

硼资源主要来自沉积硼酸盐矿床,其硼同位素组成携带着丰富的成矿及蚀变信息。通过室内模拟实验及统计全球沉积硼酸盐矿物δ¹¹B值,分析发现硼酸盐矿物δ¹¹B值主要受硼源、硼酸盐结构、pH值、后期蚀变及瑞利过程影响。不同试剂合成及不同盐湖产出的硼酸盐矿物δ¹¹B值存在显著差异,说明硼源是决定δ¹¹B值的第一要素。同一矿床及全球沉积硼酸盐矿物间δ¹¹B值均表现出钠硼酸盐(硼砂、三方硼砂、贫水硼砂)>钠—钙硼酸盐(钠硼解石、硼钠钙石)>镁硼酸盐(多水硼镁石、柱硼镁石、库水硼镁石)>钙硼酸盐(硬硼钙石、板硼石、白硼钙石、三斜硼钙石)>钙—镁硼酸盐(砷硼镁钙石、水方硼石),这与硼酸盐矿物中BO₃/BO₄比值及卤水pH值有关。原始沉积硼酸盐后期埋藏过程经历的蚀变反应会改变δ¹¹B值：(1)次生硼酸盐矿物δ¹¹B值比原生硼酸盐矿物低2‰～4‰,这是由于脱水反应中¹¹...  相似文献   

重庆中坝遗址地层Na-Ca元素含量揭示的制盐业兴衰史     

朱诚  姜逢清  马春梅  徐伟峰  黄林燕  郑朝贵  李兰  孙智彬 《地理学报(英文版)》2008,18(3):328-340

Based on dynastic period division and AMS ^14 C dating performed on the sedimentary layers at Zhongba and Yuxi sites,and also the analysis of Na,Ca and Mg of 201 sedimentary samples from Zhongba site and that of Ca and Na in 47 sedimentary samples from Yuxi by using an inductively coupled plasma-mass spectrometry（ICP）,we found that there were 35 time periods when the contents of Ca and Na were reversely correlated,i.e.whenever the content of Ca was the highest,the content of Na was the lowest,and vice versa. Among them,there were 21 time periods when the content of Ca was the highest,and Na was the lowest,indicating that there were about 21 prosperous periods of ancient salt production at Zhongba site since 3000BC.Other 14 time periods with the peak values of Na while the low values of Ca indicate 14 declined periods of salt production at Zhongba site since 3000BC.The conclusion obtained from the reverse relationship between Ca and Na contents in this paper is consistent with that＂the salt production at Zhongba site started in the new stone age,developed in the Xia and Shang dynasties,reached at the heyday in periods from the Western Zhou to the Han Dynasties,maintained stable to develop in the Tang and the Song dynasties,and gradually declined after the Song Dynasty because the sea salt were conveyed into Sichuan region,however,still had production in the 1970s-1980s＂,educed from archeological exploration.All the above mentioned results indicate that there is a reverse relationship obviously between the contents of Na and Ca in sediments at Zhongba site for ancient salt production,which can be used to reveal the process of rise and decline of ancient salt industry at Zhongba site.  相似文献   

关于黄土含水量划分的讨论     

徐洪安  张玲 《地球科学与环境学报》1991,(2)

黄土含水量高低,通常能反映出黄土中含水量的变化规律和土性特点。本文对黄土含水量高低的划分和命名做了初步尝试,并对其划分和命名所考虑的因素和依据做了简要讨论。  相似文献   

广西典型高砷高硫浮选金精矿的矿物学研究     

韦丛中  邱美珍 《南方国土资源》2002,15(4):77-79

文章阐述了广西高砷高硫金精矿的矿物组成及砷、硫、金的赋存状态  相似文献