Genesis of the Changba–Lijiagou Giant Pb-Zn Deposit, West Qinling, Central China: Constraints from S-Pb-C-O isotopes     

WEI Ran  WANG Yitian  MAO Jingwen  HU Qiaoqing  QIN Siting  LIU Shengyou  YE Dejin  YUAN Qunhu  DOU Ping 《《地质学报》英文版》2020,94(4):884-900

The extensive Changba-Lijiagou Pb-Zn deposit is located in the north of the Xihe–Chengxian ore cluster in West Qinling. The ore bodies are mainly hosted in the marble, dolomitic marble and biotite-calcite-quartz schist of the Middle Devonian Anjiacha Formation, and are structurally controlled by the fault and anticline. The ore-forming process can be divided into three main stages, based on field geological features and mineral assemblages. The mineral assemblages of hydrothermal stage I are pale-yellow coarse grain, low Fe sphalerite, pyrite with pits, barite and biotite. The mineral assemblages of hydrothermal stage II are black-brown cryptocrystalline, high Fe shalerite, pyrite without pits, marcasite or arsenopyrite replace the pyrite with pits, K-feldspar. The features of hydrothermal stage III are calcite-quartz-sulfide vein cutting the laminated, banded ore body. Forty-two sulfur isotope analyses, twenty-five lead isotope analyses and nineteen carbon and oxygen isotope analyses were determined on sphalerite, pyrite, galena and calcite. The δ34 S values of stage I(20.3 to 29.0‰) are consistent with the δ34 S of sulfate(barite) in the stratum. Combined with geological feature, inclusion characteristics and EPMA data, we propose that TSR has played a key role in the formation of the sulfides in stage I. The δ34 S values of stage II sphalerite and pyrite(15.1 to 23.0‰) are between sulfides in the host rock, magmatic sulfur and the sulfate(barite) in the stratum. This result suggests that multiple S reservoirs were the sources for S2-in stage II. The δ34 S values of stage III(13.1 to 22‰) combined with the structure of the geological and mineral features suggest a magmatic hydrothermal origin of the mineralization. The lead isotope compositions of the sulfides have 206 Pb/204 Pb ranging from 17.9480 to 17.9782, 207 Pb/204 Pb ranging from 15.611 to 15.622, and 208 Pb/204 Pb ranging from 38.1368 to 38.1691 in the three ore-forming stages. The narrow and symmetric distributions of the lead isotope values reflect homogenization of granite and mantle sources before the Pb-Zn mineralization. The δ13 CPDB and δ18 OSMOW values of stage I range from-0.1 to 2.4‰ and from 18.8 to 21.7‰. The values and inclusion data indicate that the source of fluids in stage I was the dissolution of marine carbonate. The δ13 CPDB and δ18 OSMOW values of stage II range from-4 to 1‰ and from 12.3 to 20.3‰, suggesting multiple C-O reservoirs in the Changba deposit and the addition of mantle-source fluid to the system. The values in stage III are-3.1‰ and 19.7‰, respectively. We infer that the process of mineralization involved evaporitic salt and sedimentary organic-bearing units interacting through thermochemical sulfate reduction through the isotopic, mineralogy and inclusion evidences. Subsequently, the geology feature, mineral assemblages, EPMA data and isotopic values support the conclusion that the ore-forming hydrothermal fluids were mixed with magmatic hydrothermal fluids and forming the massive dark sphalerite, then yielding the calcite-quartz-sulfide vein ore type at the last stage. The genesis of this ore deposit was epigenetic rather than the previously-proposed sedimentary-exhalative(SEDEX) type.  相似文献   

Quantitative Morphology Of C/1995 O1 (Hale–Bopp) In February – April 1997     

Vanscheidt  R.  Bleul  H.  Manthey  E.  Jütte  M.  Pohlen  M.  Schmidtobreick  L.  Altmann  M.  Dieball  A.  Geffert  M.  Sanner  J.  Notni  P.  Schmoll  J. 《Earth, Moon, and Planets》1998,81(3):223-231

Extensive widefield CCD direct imaging of C/1995 O1 (Hale-Bopp) at UBVRI was carried out at Hoher List Observatory with the 1.06 m telescope (field of view 20′ × 20′) and at Potsdam Observatory with the 0.70 m telescope (field of view 8′ × 8′). The corresponding spatial resolution is 850–1000 km pix^-1and 525–590 km pix^-1, respectively. The data covers 25 nights from February 20 to April 21, 1997. In order to quantify the various features in the apparent inner coma we introduce a new tomographic method that minimizes the morphological bias caused by image processing. The tomographic analysis leads to quantitative maps refering to the position and intensity of the dust ejections for each image frame. Variability and periodicity within the inner coma can be thoroughly deduced due to various sets of consecutive nights in the observation period mentioned above. The results are compared with applications of adaptive Laplace filtering. This revised version was published online in July 2006 with corrections to the Cover Date.  相似文献   

栖霞金矿矿物、流体和同位素特征及意义   总被引：11，自引：2，他引：9  

翟建平  徐光平  胡凯 《矿床地质》1998,17(4):307-313

栖霞金矿床伴生的黑钨矿是低温热液的产物。成矿流体的成分与典型的大气降水热液组分相类似,其δ１８Ｏ约为－３．６‰～４．５‰,δＤ约为－５６‰～－９５‰,变化范围较大,但这些氢、氧同位素值很好地反映了大气降水在不同温度和Ｗ／Ｒ比值条件下与胶东群变质岩交换后的分布特征,成矿作用以Ｗ／Ｒ比值较低为特点。金矿床的Ｒｂ－Ｓｒ等时线年龄为１２５．８×１０６ａ,与胶东群变质岩系和混合花岗岩的时差较大,矿化物质的Ｓｒ同位素初始比高达０．７１６８,大气降水深循环对流作用是形成栖霞金矿床的主要原因。  相似文献   

中国东部新生代碱性玄武岩中的流体组成及其碳,氧同位素地球化学特征   总被引：16，自引：2，他引：14  

张铭杰  王先彬 《地球化学》1998,27(5):452-457

利用热分解质谱法测定了中国东部新生代碱性玄武岩中流体挥发分的组成,并对不同温度段释放出的ＣＯ２气体测定了Ｃ,Ｏ同位素值,流体组成和ＣＯ２的Ｃ,Ｏ同位素值表明中国东部上地幔源区的不均一性,与其中所含幔源岩捕体相比,碱性玄武岩浆发育在相对氧化的环境中,并有外来流体组分的加入。  相似文献   

K–Ar ages from seamount chains in the back-arc region of the Izu–Ogasawara arc     

OSAMU  ISHIZUKA  KOZO  UTO  MAKOTO  YUASA & ALFREDG.  HOCHSTAEDTER 《Island Arc》1998,7(3):408-421

The Izu–Ogasawara arc contains, from east to west, a volcanic front, a back-arc extensional zone (back-arc knolls zone), and a series of across-arc seamount chains that cross the extensional zone in an east-northeast and west-southwest direction and extend into the Shikoku Basin. K–Ar ages of dredged volcanic rocks from these across-arc seamount chains and extension-related edifices in the back-arc region of the Izu–Ogasawara arc were measured to constrain the volcanic and tectonic history of the arc since the termination of spreading in the Shikoku Basin. K–Ar ages range between 12.5 and 1 Ma. Andesitic to dacitic rocks of 12.5–2.9 Ma occur mainly on the western part of the chains. The western part of the chains are the locus of volcanism behind the front which erupted mainly calc-alkaline andesitic lavas. The youngest rocks (< 2.8 Ma), characterized by cpx-ol basalt, occur along the western margin of the back-arc knolls zone. Basaltic rocks of 12.5–2.9 Ma have relatively high concentrations of Na₂O (> 2.0 wt%), Zr (> 50 p.p.m.) and Y (> 20 p.p.m.) and low CaO (< 12 wt%). On the other hand, basalts of 2.8–1 Ma have lower Na₂O (< 1.8 wt%), Zr (< 50 p.p.m.) and Y (< 20 p.p.m.), but significantly higher CaO (> 12 wt%). The age inferred for the initiation of back-arc rifting (∼ 2.35–2.9 Ma: Taylor 1992 ) behind the current volcanic arc coincides with the time that basalt chemistry changed drastically (eruption of the low-Na₂O and high-CaO basalt). This implies that post-2.8 Ma volcanism in the back-arc knolls zone is associated with rifting. Similarly, the change in chemical composition might be explained by a different type of source mantle following rift initiation. Volcanism in the western seamounts ceased after the onset of rifting at ∼ 2.8 Ma.  相似文献   

江西庐山─星子地区早前寒武纪片麻岩基底的初步研究   总被引：3，自引：1，他引：2  

吴根耀 《大地构造与成矿学》1998,22(2):138-147

庐山-星子地区原称的混合花岗岩和混合岩实为以奥长花岗质片麻岩为主体的灰色片麻岩（TTG岩套）和花岗质片麻岩．后者是前者经钾质成分改造交代的结果。其常量元素和微量元素特征与早前寒武纪低铝型灰色片麻岩一致,构成扬子克拉通的晚太古代基底。其上的星子群属表壳岩,与赣北片麻岩一起构成花岗-绿岩地体,因燕山运动和新构造而出露地表。  相似文献   

滇西马厂箐铜钼多金属矿床成矿流体来源及演化过程——来自石榴子石原位微量元素及H- O同位素组成的限定     

吉彦冰  杜丽娟  陈军  黄智龙  李波  李鑫正  刘林林  杨再风 《地质学报》2023,97(4):1140-1156

滇西马厂箐铜钼多金属矿床位于三江特提斯成矿域,是一个与喜马拉雅期富碱斑岩侵入有关的多金属矿床。前人研究表明,马厂箐铜钼多金属矿床形成于斑岩-矽卡岩成矿系统,但由于缺乏系统矿物学研究,目前对矽卡岩矿化过程和成矿效应仍不清楚,限制了对该矿床成矿过程的全面认识。因此,本文以马厂箐矿床矽卡岩型矿化中的石榴子石为研究对象,利用H-O同位素、电子探针(EPMA)以及LA-ICP-MS原位微区技术开展了同位素及成分分析,限定成矿流体来源以及反演成矿流体演化过程。石榴子石可分为早期自形石榴子石(Grt I)和晚期他形石榴子石(Grt II)。Grt I与辉石共生,并伴有黄铁矿、黄铜矿等金属矿物组合,属于钙铝-钙铁榴石固溶体(And_{49.37～99.58}Gro_0～49.79);Grt II更富Fe,属钙铁榴石系列(And_{67.50～99.85}Gro_0～31.84)。两期石榴子石均富含Th、U、Nd,亏损Ba、Sr、Hf、Nb,富轻稀土。基于石榴子石矿物化学特征认为,Grt I可能是在弱酸性、氧化、低水岩比(W/R)条...  相似文献   

南秦岭钡成矿带重晶石与毒重石成矿特征   总被引：4，自引：1，他引：3  

吴胜华  刘家军  张鼐  柳振江 《现代地质》2010,24(2)

在我国扬子地块北缘南秦岭一带的早古生代硅质岩建造中,存在一大批重晶石矿床和毒重石矿床,构成世界上极为罕见的大型钡成矿带。根据流体包裹体显微测温分析,重晶石流体包裹体均一温度峰值低于毒重石流体包裹体峰值。这些矿床中重晶石的3δ4S值比同期海水3δ4S值高(除去文峪矿区重晶石一个3δ4S值与同期海水3δ4S值接近),表明当时细菌对硫酸盐的还原作用引起了重S的富集。各钡矿床中的毒重石有各自的1δ3C和1δ8O值范围,毒重石中的C来自有机质事件反应。根据热力学计算表明,小于162.42℃的温度有利于形成重晶石矿石;在温度高于162.42℃时,海水中积累充足的CO32-(来自有机事件)有利于形成毒重石矿石。在重晶石矿床形成的晚期,如出现贫Ba2+热液,且海水中积累足够的CO32-和温度高于162.42℃,CO32-可以交代重晶石中的SO42-,形成交代成因的毒重石。  相似文献   

Origin of Paleofluids in Dabashan Foreland Thrust Belt:Geochemical Evidence of 13C,18O and 87Sr/86Sr in Veins and Host Rocks     

Zeng Jianhui  Xu Tianwu  Sun Zhanqiang  Zhang Yongwang 《《地质学报》英文版》2010,84(5):1239-1255

In the last ten years, with important discoveries from oil and gas exploration in the Dabashan foreland depression belt in the borderland between Shanxi and Sichuan provinces, the relationship between the formation and evolution of, and hydrocarbon accumulation in, this foreland thrust belt from the viewpoint of basin and oil and gas exploration has been studied. At the same time, there has been little research on the origin of fluids within the belt. Based on geochemical system analysis including Z values denoting salinity and research on δ13C, δ18O and 87Sr/86Sr isotopes in the host rocks and veins, the origin of paleofluids in the foreland thrust belt is considered. There are four principal kinds of paleofluid, including deep mantle-derived, sedimentary, mixed and meteoric. For the deep mantle-derived fluid, the δ13C is generally less than ?5.0‰PDB, δ18O less than -10.0‰PDB, Z value less than 110 and 87Sr/86Sr less than 0.70600; the sedimentary fluid is mainly marine carbonate-derived, with the δ13C generally more than ?2.0‰PDB, δ18O less than ?10.0‰PDB, Z value more than 120 and 87Sr/86Sr ranging from 0.70800 to 0.71000; the mixed fluid consists mainly of marine carbonate fluid (including possibly a little mantle-derived fluid or meteoric water), with the δ13C generally ranging from ?2.0‰ to ?8.0‰PDB, δ18O from ?10.0‰ to ?18.0‰ PDB, Z value from 105 to 120 and 87Sr/86Sr from 0.70800 to 0.71000; the atmospheric fluid consists mainly of meteoric water, with the δ13C generally ranging from 0.0‰ to ?10.0‰PDB, δ18O less than ?8.0‰PDB, Z value less than 110 and 87Sr/86Sr more than 0.71000. The Chengkou fault belt encompasses the most complex origins, including all four types of paleofluid; the Zhenba and Pingba fault belts and stable areas contain a simple paleofluid mainly of sedimentary type; the Jimingsi fault belt contains mainly sedimentary and mixed fluids, both consisting of sedimentary fluid and meteoric water. Jurassic rocks of the foreland depression belt contain mainly meteoric fluid.  相似文献   

CaCl_2对KAlSi_3O_8-CaSO_4-CaCO_3反应体系的影响研究     

石林  曾小平  罗汉金 《矿物岩石》2010,30(1)

通过CaCl2添加剂对KAlSi3O8-CaSO4-CaCO3体系研究反应温度和反应时间的影响研究,结果表明:随着CaCl2加入量的增多,体系的反应温度下降,反应时间缩短,当CaCl2的加入量为10%时,反应温度可降至1000℃,反应时间降至25min,此时KAlSi3O8的转化率仍可高达83.24%。研究CaCl2的加入对KAlSi3O8-CaSO4-CaCO3反应体系动力学过程的影响,得出反应体系符合金斯特林格动力学方程:FK(G)=1-2/3G-(1-G)2/3=KKt,反应受扩散过程控制,计算出当CaCl2的加入量为10%时,体系的表观活化能可从原来的128.921kJ/mol下降至58.320kJ/mol。  相似文献