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141.
含粘粒砂土抗液化性能的试验研究   总被引:20,自引:1,他引:20  
通过对含粘粒砂土所作的试验研究, 包括: 粘粒矿物成分不同、粘粒含量不同的重塑土样所作的室内动三轴试验; X光衍射试验, 试验结果对比分析后, 得出了含粘粒砂土抗液化性能的特性。并得出以下结论: (1)粘粒矿物成分不同, 也引起砂土动力稳定性的变化; (2 )动剪应力强度与粘粒含量并非呈单调增加关系, 而呈抛物线型, 并给出回归方程; (3)含粘粒的砂土, 其抗液化能力最低点总是在粘粒含量 8.5~ 9.5 %之间。  相似文献   
142.
The OECD soil, which is standardised for use in the sediment toxicity with the midge Chironomus riparius revealed inhibition of the nematode Caenorhabditis elegans in body growth length and egg production of 41.0% and 84%, respectively. 18 formulated sediments were tested to optimise the sediment composition for growth and reproduction of C. elegans. Their components were chosen to simulate native sediments, whereby different quantities and different clay minerals were tested. The mixture that we found to be optimal in our experiments consisted of 5% sphagnum peat, 70% calcitic sand, 0.5% dolomite limestone, 4.5% iron(III) oxide, and a clay combination of 1.5% chlorite and 18.5% aluminium(III) oxide. When applying this mixture to C. riparius, the new formulated sediment improved also growth in comparison to the OECD sediment.  相似文献   
143.
The heat capacity of natural chamosite (XFe=0.889) and clinochlore (XFe=0.116) were measured by differential scanning calorimetry (DSC). The samples were characterised by X-ray diffraction, microprobe analysis and Mössbauer spectroscopy. DSC measurements between 143 and 623?K were made following the procedure of Bosenick et?al. (1996). The fitted data for natural chamosite (CA) in J?mol?1?K?1 give: C p,CA = 1224.3–10.685?×?103?×?T ??0.5???6.4389?× 106T ??2?+?8.0279?×?108?×?T ??3 and for the natural clinochlore (CE): C p,CE = 1200.5–10.908?×?103T ??0.5?? 5.6941?×?106?×?T ??2?+?7.1166?×?108?×?T ??3. The corrected C p-polynomial for pure end-member chamosite (Fe5Al)[Si3AlO10](OH)8 is C p,CAcor = 1248.3–11.116?× 103?×?T ??0.5???5.1623?×?106?×?T ??2?+?7.1867?×?108×T ??3 and the corrected C p-polynomial for pure end-member clinochlore (Mg5Al)[Si3AlO10](OH)8 is C p,CEcor = 1191.3–10.665?×?103?×?T ??0.5???6.5136?×?106?×?T ??2?+ 7.7206?×?108?×?T ??3. The corrected C p-polynomial for clinochlore is in excellent agreement with that in the internally consistent data sets of Berman (1988) and Holland and Powell (1998). The derived C p-polynomial for chamosite (C p,CAcor) leads to a 4.4% higher heat capacity, at 300?K, compared to that estimated by Holland and Powell (1998) based on a summation method. The corrected C p-polynomial (C p,CAcor) is, however, in excellent agreement with the computed C p-polynomial given by Saccocia and Seyfried (1993), thus supporting the reliability of Berman and Brown's (1985) estimation method of heat capacities.  相似文献   
144.
INTRODUCTIONItisanacknowledgedfactthataragonite,ahigh pressurepolymorphofCaCO3 ,occurswidelyasanindexmineralofhigh pressureandlow temperaturemetamorphism (glaucophaneschistfacies)withinthegeodynamiccontextofsubduction obductionandcontinentalcollision (Liou…  相似文献   
145.
Previous research by our group (e.g., [Chem. Geol. 132 (1996) 25; Geochim. Cosmochim. Acta 64 (2000) 1363]) has shown that an aerobic Pseudomonas mendocina bacterium enhances Fe(hydr)oxide dissolution in order to obtain Fe under Fe-limited conditions. The P. mendocina is incapable of utilizing Fe as a terminal electron acceptor and requires several orders of magnitude lower Fe concentrations than do dissimilatory Fe reducing bacteria. The research reported here compared the effects of the P. mendocina on dissolution of well and poorly ordered Clay Minerals Society Source Clay kaolinites KGa-1b and KGa-2, respectively, under Fe-limited conditions. KGa-1b and KGa-2 contain 0.04 and 0.94 bulk wt.% Fe, respectively, and their surface Fe/Si atomic RATIOS=0.008 and 0.012. Following strong cleaning of the kaolinites in 5.8 M HCl at 85 °C, the surface Fe/Si atomic ratios decreased to 0.004 and 0.008, respectively. Both kaolinites also developed a Si-enriched surface precipitate upon strong cleaning.

Because the P. mendocina take up Fe, we could not measure Fe release from the kaolinite directly, but rather had to monitor it indirectly by comparing microbial populations sizes under Fe-limited growth conditions. We found that microbial growth on uncleaned, weakly cleaned, and strongly cleaned kaolinites increased with the amount of Fe readily available to organic ligands as estimated by dissolution in 0.001 M oxalate (pH 3). This suggests that it is the amount of readily accessible Fe that controls Fe acquisition and hence microbial growth. The trend is based on only a relatively small range of kaolinite Fe contents, and the research thus needs to be expanded to include kaolinites with a broader range of bulk and surface Fe concentrations.

Significant enhancement of Al release was observed in the presence of the bacteria, along with generally some enhancement of Si release. This enhancement of kaolinite dissolution could be related to an observed pH increase from 7–8 to 9 in the presence of the bacteria and/or to production of Al chelating agents. The P. mendocina produce a variety of organic exudates, including siderophores [Chem. Geol. 132 (1996) 25; Geomicrobiology (2001b)], and further studies into the effects of the siderophores on Al complexation and on kaolinite dissolution are ongoing.  相似文献   

146.
Partitioning of heavy metals on soil samples from column tests   总被引:3,自引:0,他引:3  
In this study, column tests were used to determine the retention capability of three types of estuarine alluvia collected adjacent to landfill sites in South Wales. Selective sequential extraction (SSE) was used to study the retention mechanisms of heavy metals in the soil columns obtained from leaching experiments. Acid digestion was later used to check the validity of the SSE results. Breakthrough curves show good retention of heavy metal ions (Pb, Cu, and Zn) by all soils, where almost 99% of heavy metals were retained with the Ce/Co values in the order of 10−3. The retention strength of these soils was observed to be constant up to five pore volumes (PV). This corresponds with the pH of the effluents and pore water of soil slices, which also show good buffering capacity against very acidic leachate up to 5PV. The heavy metal extraction profiles from SSE show very similar trends with the retention profiles from the leaching experiments, where heavy metals were retained mainly at the top part where the leachate entered the column. SSE indicates qualitatively that heavy metals precipitated with carbonates and amorphous materials (oxides/hydroxides) are higher than heavy metal retention via exchangeable mechanisms. The mass balance calculation gives range of deviation of 1–16% of the total soil extraction. The distribution of the heavy metals with various soil constituents are ranked in the following order: Carbonates>Amorphous oxides hydroxides>Organic matter>Exchangeable phases.  相似文献   
147.
陕北鄂尔多斯盆地埋藏变质作用研究   总被引:11,自引:2,他引:11  
张立飞 《地质学报》1992,66(4):339-349
本文系统地研究了陕北鄂尔多斯盆地的埋藏变质作用。砂岩胶结物在成岩到变质作用转化过程中经历了如下4个阶段:1.粘土胶结阶段;2.压溶长石、石英再生长阶段;3.碳酸盐胶结阶段;4.生成浊沸石阶段。泥岩中粘土矿物组合在埋藏变质过程中出现如下转化:早期蒙皂石、高岭石组合,随埋深的增加转化为伊利石和镁铝蛇纹石混合阶段;进一步埋深出现了伊利石和绿泥石混层阶段;最后转化为分散状的伊利石和绿泥石。  相似文献   
148.
An improvement on the new method of Intervalhalving-Scanning (INS) proposed by the senior author for derivation of thermodynamic properties of minerals from reversed experiment (REP) data has been made in the present work. The treatment of the REP data of 6 reactions in the system MgO-SiO_2-H_2O and the derivation of △_(?)H(?) (298. 15K) for minerals Talc,Forsterite and Anthophyllite are chosen as an example for demonstration of the application of the method.INS is quite different from all the methods for the derivation in the literature and throughout based on thermodynamic principles and equations so that its thermodynamical validity is thoroughgoing.  相似文献   
149.
我国一些铜镍硫化物矿床主要金属矿物的特征   总被引:7,自引:0,他引:7  
镍、铜共生的铜镍硫化物矿床是镍矿也是铜矿的重要矿床类型。磁黄铁矿,镍黄铁矿、黄铜矿是这类矿床的主要金属矿物。它们的某些矿物学特征,特别是微量元素Co/Ni比值,与其他铜矿类型明显不同,这三种矿物组成不同于任何其他铜矿类型的典型矿物共生组合, 形成特殊的海绵损铁状、球滴状构造。  相似文献   
150.
在瑞典,硫化物矿尾矿污染水的淋滤造成巨大的环境污染问题。本文概述一项利用天然土覆盖尾矿、最大限度地减少淋滤水的调查报告。研究表明,天然土渗水性是如此之高,以致于起不到明显的隔水效果。天然土盖层只能减少高降雨量期或迅速化雪期的渗水量,而且只对淋滤水峰值有作用。但是,作为一种蓄水体,位于尾矿顶部的密封盖层具有重要意义,它可以增加蒸腾损失。  相似文献   
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