Factors influencing the oxidation,reduction, methylation and demethylation of mercury species in coastal waters     

Lindsay Whalin  Eun-Hee Kim  Robert Mason 《Marine Chemistry》2007

The objective of this study was to examine the redox reactions and other transformations of mercury (Hg) species in surface waters, and the factors determining the rates of these reactions. For the redox studies completed at the Chesapeake Biological Laboratory (CBL), two isotopes (¹⁹⁹Hg^II and ²⁰²Hg⁰) were added into different types of filtered water (fresh to seawater) to examine the oxidation and reduction reactions. Further studies of both the redox reactions and methylation/demethylation reactions of Hg were conducted with unfiltered water on board research vessels during cruises in May and July 2005 on the Chesapeake Bay and shelf. While CH₃¹⁹⁹Hg^II was added to allow the examination of demethylation, ²⁰¹Hg^II was used to examine both reduction and methylation, and ²⁰²Hg⁰ was used to examine oxidation. Overall, the results showed that both Hg oxidation and reduction were simultaneously occurring and were photochemically mediated in the waters investigated. In contrast to the previously assumed “unreactive” nature of Hg⁰, the studies found that the magnitude of the rate constant for Hg⁰ oxidation was greater than that for reduction, indicating its importance in estuarine and coastal waters. In addition, both experiments at CBL and on board ship showed that Hg^II reduction was similar in magnitude, suggesting that biotic processes were relatively unimportant. While no measurable methylation occurred during the incubation period during the on board studies, concentration of CH₃¹⁹⁹Hg^II decreased over the time during the experiments. It appeared that the demethylation processes were not dominantly photochemically driven, but could be microbially mediated. Further studies are needed in order to help better understand Hg redox and transformations in natural water systems.  相似文献   

Modeling erosion of sedimentary coasts in the western Russian Arctic     

I. O. Leont'yev   《Coastal Engineering》2003,47(4):413-429

Morphodynamic modeling is employed in the present work to predict the long-term evolution (over the next 100 years) of typical sedimentary coasts in the western Russian Arctic. The studied objects are the coasts of Varandey (the Barents Sea), Baydaratskaya Bay and Harasavey (the Kara Sea). The model developed takes into account both the short-term processes (storm events) and long-term factors (for example, changes in sea level, inter-annual variations in gross sediment flux, lack or excess of sediment supply). Predicted and observed morphological changes in coastal profiles are shown to agree well for time scales ranging from weeks to decades. It is revealed that under given environmental conditions, the morphological evolution is strongly influenced by storm surges and associated wind-driven circulation. The water level gradient created by a surge generates a seaward flow at the bed. This outflow is shown to be an important destructive mechanism contributing to the erosion and recession of Arctic coasts. The rate of change is found to depend on both the exposure of the coast (relative to the direction of dominant winds) and its height above the sea. The open coast of Varandey is expected to retreat as much as 300–500 m over 100 years, while recession of the less exposed coasts of Baydaratskaya Bay would not exceed about 100 m/century. If long-term sediment losses are insignificant, the rate of erosion decays with time and the morphodynamic system may tend toward equilibrium. It is concluded that the expected relative sea-level rise (up to 1 m over the nearest 100 years) is non-crucial to the future coastal evolution if an erosion activity is already high enough.  相似文献   

鲫鱼(Carassius auratus)在微冻保鲜过程中的质量变化   总被引：2，自引：0，他引：2  

曾名勇  黄海  李玉环  黄叶锋 《中国海洋大学学报(自然科学版)》2001,31(3):351-355

该文研究鲫鱼 ( Carassius auratus)在微冻 ( - 3℃ )保鲜过程中的质量变化规律。以感官评价、细菌总数、T- VBN值、p H值、ATPase活性、K值等作为质量指标。实验结果表明 ,微冻可以明显抑制细菌总数的增长 ,维持较低的 T- VBN和 K值。但是 ,微冻条件下鲫鱼的 ATPase活性下降速度较快  相似文献   

Modelling morphological processes in the vicinity of shore-parallel breakwaters     

Julio A. Zyserman  Hakeem K. Johnson 《Coastal Engineering》2002,45(3-4)

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A Functional Analysis of the Benthic Macrofauna of the São Sebastião Channel (Southeastern Brazil)     

Emilia Arasaki  Pablo Muniz  & Ana Maria S. Pires-Vanin 《Marine Ecology》2004,25(4):249-263

Abstract.  The major problem in coastal areas of developing countries is disturbance caused by anthropogenic influence. This disturbance can be quantified by analysing the distribution and composition of marine communities using uni- and multivariate techniques and the biotic index. A study of benthic macrofauna was carried out along the São Sebastião Channel, northern coast of São Paulo State, Brazil, in an area with a submarine outfall, a petroleum terminal and a commercial harbour. Sampling was undertaken seasonally, by means of a van Veen grab (0.1 m²) at 15 oceanographic stations, from November 1993 to August 1994. A total of 392 species were identified (129 Polychaeta, 127 Mollusca, 98 Crustacea, 28 Echinodermata and 10 other phyla). The sedimentary pattern recorded for the São Sebastião Channel is very heterogeneous, influenced mainly by strong wind-driven currents, and differs from nearby shelf areas. The study area could be divided into three regions based on sediment texture and fauna: one region dominated by medium and coarse sand with low values of organic carbon; a second area where pelitic fractions were dominant with high values of organic carbon and nitrogen; and a third region characterised by fine and very fine sand, presenting intermediate organic carbon values. No temporal significant variation in abundance and species composition was found, except in autumn. The use of the 'marine Biotic Coefficient' showed the same ecological trend as the faunal abundance and demonstrated that the central continental region of the channel is affected by human activities.  相似文献   

Using benthic macrofauna to assess environmental quality of four intertidal mudflats in Hong Kong and Shenzhen Coast   总被引：4，自引：0，他引：4  

Cai Lizhe  Nora F. Y. Tam  Teresa W. Y. Wong  Ma Li  Gao Yang  Yuk-Shan Wong 《海洋学报(英文版)》2003,22(2):309-319

Abstract-Intertidal zone is a significant wetland between land and ocean. It plays an important rolein maintaining local ecological balance. Both Mai Po and Futian intertidal mudflats are located in Shen-zhen Bay and are important "refueling" point along the East Asian/Australian flyway of migratory birds.The environmental quality of Mai Po and Futian mudflats have aroused great concern due to rapid eco-nomic developments in Hong Kong and Shenzhen in recent decades. Microinfauna of Mai Po and Futianmudflats was investigated in December 2000 and the faunal data were used to assess their environmentalquality. Two other mudflats, namely Ma Wan Typhoon Shelter (a more disturbed area) and Luk Kengintertidal mudflat (a place with relatively less human disturbance), were also sampled for macroinfaunaand used as reference mudflats. Shannon-Weaver species diversity index (I_(sd)), biotic coefficient (C_b)and macrofaunal pollution index (I_(mp)) of the macrofauna community on four intertidal mudflats wereused to  相似文献   

Sea Grant in Latin America?: Adapting the US Sea Grant model of linked applied research,extension, and education to a Latin American Context—Is there a fit?     

S. Matthew Wilburn  James Tobey  Jill Hepp  Stephen Olsen  Barry Costa-Pierce 《Marine Policy》2007

This paper explores the application of the US Sea Grant model of applied research, extension, and education to two case studies in Latin America: Coastal Ecuador and the Gulf of Fonseca. The analysis is based on a series of meetings and roundtables with in-country partners and leaders of the US Sea Grant program. We conclude that the Sea Grant model provides an institutional structure that Latin America lacks and the model's features would improve governance of marine and coastal resources through more effective linkages between coastal communities, universities, and policy/decision makers at local, national, and international levels.  相似文献   

Heavy metals in marine sediments of Taranto Gulf (Ionian Sea, Southern Italy)   总被引：5，自引：0，他引：5  

Alessandro Buccolieri  Giovanni Buccolieri  Nicola Cardellicchio  Angelo Dell'Atti  Antonella Di Leo  Antonella Maci 《Marine Chemistry》2006,99(1-4):227

Al, Cr, Cu, Fe, Hg, Mn, Ni, Pb, Ti and Zn concentrations have been determined in surface sediment samples collected in the Taranto Gulf (Ionian Sea, Southern Italy) in order to evaluate their levels and spatial distribution in this important area of the Mediterranean Sea. For various metals, the geoaccumulation index has been calculated as a criterion to assess if their concentrations represent contamination levels or can be considered as background levels. The results show that metals concentrations in sediments can be considered near the background levels found in the Mediterranean Sea.Analytical results have been elaborated by using a Geographical Information System (GIS) software to show metals accumulation areas. Using multivariate statistical analysis, we evaluate the possibility to distinguish the sampling stations, in relation to their geographical position. Results have showed metals distribution in the Taranto Gulf is principally influenced by industrial and urban wastes, located mostly in the northern coastal area of the Ionian Sea. Rivers in the Basilicata region and prevailing anticlockwise marine currents are further factors influencing metal accumulation in sediments.  相似文献   

An Assessment of Surface – Dynamics Observed Offshore Ancona with HF Radar     

Giorgio Budillon  Federica Grilli  Annalisa Ortona  Aniello Russo  Marco Tramontin 《Marine Ecology》2002,23(S1):21-37

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海岸带专题地图编绘相关问题     

顾燕  张鹰 《海洋技术学报》2004,23(2):103-106

海岸带是影响人类活动的重要地带，海岸带专题地图能够详细表示出海岸带的特性。随着海洋经济的发展，海岸图的需求日益增加。从地图的数学要素出发，提出目前海岸图绘制存在的问题，并从地图学、海洋学、遥感地学的角度，对地图投影的选择、坐标系转换、比例尺对海岸图编绘的影响及控制点的确定等问题进行了综合分析。  相似文献