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191.
High-resolution clay mineral records combined with oxygen isotopic stratigraphy over the past 190 ka during late Quaternary from core MD01-2393 off the Mekong River in the southern South China Sea are reported to reconstruct a history of East Asian monsoon evolution. The dominating clay mineral components indicate a strong glacial-interglacial cyclicity, with high glacial illite, chlorite, and kaolinite contents and high interglacial smectites content. The provenance analysis indicates the direct input of clay minerals via the Mekong River drainage basin. Illite and chlorite derived mainly from the upper reach of the Mekong River, where physical erosion of meta-sedimentary rocks is dominant. Kaolinite derived mainly from active erosion of inhered clays from reworked sediments in the middle reaches. Smectites originated mainly through bisiallitic soils in the middle to lower reaches of the Mekong River. The smectites/(illite+chlorite) and smectites/kaolinite ratios are determined as mineralogical indicato  相似文献   
192.
The aim of this paper is to determine a relationship between the wavenumbers of the first OH-stretching overtones (W2OH) and the wavenumbers of the OH-stretching fundamentals (WOH) to help to interpret the near-infrared (NIR) spectra. The first overtone (2OH) bands appear at wavenumbers less than twice those of the fundamental bands (OH), due to the anharmonic character of vibrations, X = W2OH/2 - WOH, with X being the anharmonicity constant. Talc samples with various crystal chemistries are used to solve the equation and the experimental data are well fitted with X = –85.6 cm–1. As far as the authors are aware, it is the first time that the anharmonicity constant for the OH-stretching vibrations is determined for phyllosilicates. The anharmonicity constant remains almost unchanged for several types of clay samples. Therefore the relation, established from talc samples because their absorption bands are narrow and their wavenumber range of OH vibrations is wide, can be used for any other clay minerals.  相似文献   
193.
An integrated approach of petrographic analysis, whole rock geochemistry and microprobe analysis has been applied to obtain information on the geodynamic development and the provenance for Ordovician to Permian siliciclastic successions exposed within the Carnic Alps (Austria). Sandstone detrital mode and geochemical results refine previous geodynamic interpretations. Late Ordovician samples indicate a stable craton and recycled orogenic and, possible, extensional setting. The Early Carboniferous is interpreted to represent a compressional environment, followed by a Late Carboniferous molasse-type foreland basin, and a Permian extensional geodynamic setting. Contrasting geochemical patterns of post-Variscan and Permian sequences suggest a rift setting. Electron microprobe data of detrital white mica also indicate changes in the provenance. Compositional data reflect a shift from low- to medium-grade metamorphic (Ordovician) to high-grade metamorphic (Carboniferous) to low- to medium-grade metamorphic and plutonic source rocks (Permian). Additionally, our data show that various chemical discrimination diagrams do not include all possible ranges of sandstones, and that high contents of detrital mica and ultra-stable heavy minerals may cause misclassification. Consequently, we propose the use of multi-method approach for provenance studies, including the control of geochemical data by modal analysis and heavy mineral investigations.  相似文献   
194.
Ninety-eight clay mineral samples from the YSDP102 core were analyzed by x-ray diffractometer to study the four clay minerals: illite, chlorite, kaolinite and smectite. Twenty-eight samples had been analyzed on the laser particle-siz eanalyzer to reveal the particle features of the sediments. Distribution of the clay minerals and the particle characteristics in the YSDP102 core show that the core experienced three different depositional periods and formed three different sedimentary intervals due to different sediment sources and different depositional environments. Features of the clay minerals and the heavy minerals in the YSDP102 core indicate that coarse-grained sediments and fine-grained sediments result from different sources. The Yellow Sea Warm Current has greatly influenced the sedimentary framework of this region since the current‘s formation.  相似文献   
195.
为了海洋粘土的开发应用,利用FTIR和XRD衍射对其进行了矿物成分分析。结果表明,海洋粘土样品中粘土矿物含量较高,其主要矿物组成为伊/蒙混层和伊利石并含有少量其它矿物,同时证实样品中有磁铁矿和赤铁矿存在。粘土沉积物的化学成分分析显示,粘土中Fe2O3质量分数较高,约为7%。采用酸溶氢气还原法对东太平洋的粘土样品进行了化学增白试验,并探讨了酸种类及其浓度、药剂用量、反应时间、煅烧温度等因素对除铁增白效果的影响,优选出最佳除铁增白方案,使海洋粘土的白度由原来的23.8%提高到73.1%。另外,对增白前后样品的粒度、比表面积和分散性的测试表明,在增白的同时样品的活性也得到了提高。  相似文献   
196.
杨晓勇 《地质学报》2009,83(8):1167-1177
砂岩型铀矿床是一种具有重要经济价值的铀矿类型,受到世界各国地质勘探部门的高度关注。本文应用电子探针和高分辨分析型电镜联合研究鄂尔多斯盆地砂岩型铀矿铀的赋存状态;对砂岩中铀、钍及稀土含量的分布进行了线扫描分析,观察到铀矿物微粒主要分布在砂岩的主要造岩矿物裂隙中及其胶结物中。铀矿物主要存在形式是以铀石微粒(UO2)的形式存在, 以微粒吸附形式存在(小于1 微米)。铀物微粒一般富集砂岩中的钾长石、微斜长石、白云母裂隙和解理缝或胶结物中,分析数据显示氧化铀的含量可达1~3.46%,在石英和方解石颗粒裂隙或解理缝中比较低。应用高分辨的电镜还观察到少数呈较大铀石微粒集合体形式存在, 最大可达200 微米。从电子探针分析数据上看,UO2 含量可以从0~几个百分含量,一般来说含铀高的部位,其对应的稀土元素、ThO2含量也较高。本文的研究对含油气盆地的铀矿质的沉淀、运移和富集的认识具有重要意义,同时对鄂尔多斯盆地铀矿开发过程的选冶工艺的确定,具有借鉴价值。  相似文献   
197.
The Qilian Orogen of north western China records mid-Paleozoic collisional suturing of arc and continental blocks onto the south western margin of the North China craton. Silurian strata from the retroarc foreland basin mark the transition from ocean closure and northward subduction to the initiation of collision suturing. Detrital zircons were analysed from the western and eastern parts of the basin and show a spectrum of ages from Archean to Paleozoic with major age concentrations at around 2.5 Ga, 1.6 Ga, 1.2 Ga, 0.98 Ga, 0.7 Ga and 0.45 Ga. Archean age grains are derived from the North China craton, whereas the Central Qilian Bloc, which lies to the south provides the likely source for the bulk of the Proterozoic detritus. Paleozoic grains are restricted to Early Silurian samples from the western part of the basin and are considered to have been derived from the magmatic arc related to ocean closure and ultimate collision of the Central Qilian Belt with the North China craton.  相似文献   
198.
基于黄河下游流域考古遗址中第一次发现的黄泛地层,对苏北梁王城遗址T3902探方南壁剖面上部自然淤积层采样,结合考古断代,并参照历史资料,通过分析重砂矿物和粒度两方面的实验结果,揭示出考古遗址中黄泛地层的沉积物特征。旨在为今后环境考古中对黄泛地层的判别和对比提供可靠的科学依据,特别是为在黄河下游洪泛区考古遗址中疑似黄泛层的确认提供依据。  相似文献   
199.
云南剑川金河岩体中地幔流体交代特征及其成矿意义   总被引:5,自引:0,他引:5  
云南剑川金河岩体中的硅化霓辉正长斑岩含有较多的镁铁-超镁铁质深源岩石包体.岩相学研究表明,伴随交代蚀变,其主岩和各类包体岩石中普遍发育沿矿物粒间和矿物晶体裂隙或解离纹贯入或穿插的呈网状和细脉浸染状分布的黑色不透明物质.对该物质进行了电子探针及扫描电镜和能谱分析,发现其组成以微晶硅酸盐矿物为主,含少量微晶石英,尤其是含有微晶地幔标型矿物--含钛磁铁矿(或镜铁矿)和含铬自然铁;后两者与硅酸盐矿物构成超显微熔离结构交生.研究认为,这种物质组成和特征,是具超临界和熔浆性质的地幔流体的微观表现,其活动所引发的交代蚀变表现为硅化、钠化及深源包体中的暗色矿物由辉石→角闪石→黑云母的退变序列.这一地幔流体作用微观踪迹的揭示,对于分析和论证滇西地区新生代多金属成矿的深部地质作用规律具有重要的理论和现实意义.  相似文献   
200.
对鲁西隆起北侧博兴洼陷新生界碎屑重矿物组份和稳定性组合的研究发现:古近纪孔店组沉积期、沙河街组四段沉积晚期和沙河街组二段沉积期金红石、电气石、锆石和白钛矿等稳定碎屑莺矿物占优势,指示盆-山的构造古地理分异较弱;沙四段沉积早期、沙三段和沙一段沉积期绿帘石、榍石等不稳定碎屑重矿物占优势,表明构造古地理分异强烈.新近纪馆陶组稳定重矿物自下而上逐渐占据优势,表明该时期构造活动逐渐趋缓;明化镇组自下而上不稳定重矿物逐渐占优势,指示构造活动逐渐加强.根据砂岩中自生矿物赤(褐)铁矿的分析,认为其含量较高的孔店组、沙四段、沙段沉积期气候干旱,而含量较低的沙四段沉积末期一沙二段沉积期气候湿润;新近纪里赤(褐)铁矿含量向上增大,可能指示气候干旱程度加剧.  相似文献   
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