Methane-dominated thermochemical sulphate reduction in the Triassic Feixianguan Formation East Sichuan Basin, China: towards prediction of fatal H₂S concentrations   总被引：2，自引：0，他引：2  

Chunfang Cai  Zengye Xie  Richard H. Worden  Guoyi Hu  Lansheng Wang  Hong He 《Marine and Petroleum Geology》2004,21(10):1265-1279

New sour pools have recently found in the Lower Triassic Feixianguan Fm carbonate reservoirs in the East Sichuan Basin in China with H₂S up to 17.4% by volume. A recent blowout from a well drilled into this formation killed hundreds of people as a result of the percentage concentrations of H₂S. In order to assess the origin of fatal H₂S as well as the cause of petroleum alteration, H₂S concentrations and the isotopes, δ³⁴S and δ¹³C have been collected and measured in gas samples from reservoirs. Anhydrite, pyrite and elemental sulphur δ³⁴S values have been measured for comparison. The high concentrations of H₂S gas are found to occur at depths >3000 m (temperature now at 100 °C) in evaporated platform facies oolitic dolomite or limestone that contains anhydrite nodule occurrence within the reservoirs. Where H₂S concentrations are greater than 10% its δ³⁴S values lie between +12.0 and +13.2‰ CDT. This is within the range of anhydrite δ³⁴S values found within the Feixianguan Fm (+11.0 to +21.7‰; average 15.5±3.5‰ CDT). Thus H₂S must have been generated by thermochemical sulphate reduction (TSR) locally within the reservoirs. Burial history analysis and fluid inclusion data reveal that the temperature at which TSR occurred was greater than about 130–140 °C, suggesting that the present depth-temperature minimum is an artifact of post-TSR uplift. Both methane and ethane were actively involved in TSR since the petroleum became almost totally dry (no alkanes except methane) and methane δ¹³C values become significantly heavier as TSR proceeded. Methane δ¹³C difference thus reflects the extent of TSR. While it is tempting to use a present-day depth control (>3000 m) to predict the distribution of H₂S in the Feixianguan Fm, this is an invalid approach since TSR occurred when the formation was buried some 1000–2000 m deeper than it is at present. The likelihood of differential uplift across the basin means that it is important to develop a basinal understanding of the thermal history of the Feixianguan Fm so that it is possible to determine which parts of the basin have been hotter than 130–140 °C.  相似文献   

Analytic Solution of Interaction Between Surface Waves and Floating Elastic Plates with Elastic End-Restraints     

赵存宝张嘉钟  邢海燕黄文虎 《中国海洋工程》2007,21(1):23-38

Based on the dynamic theories of water waves and Mindlin plates,the analytic solution of interaction between surface waves and two-dimensional floating elastic plates with edge-restraint is constructed by use of the Wiener-Hopf technique.Firstly,without regard for elastic edge restraint,the wave-induced responses of elastic floating plate analyzed by the present method are in good agreement with the results from literature and experimental results.Therefore,it can be shown that the present method is valid.Secondly,three end-restraint cases(i.e.,the left-end elastic restraints,the both-end elastic restraints,and the right-end elastic restraints)are proposed to reduce the vibration of floating plates,in which the spring is used to connect the sea bottom and the floating plate's left(or right)edge.The relations between the spring stiffness and the parameters of wave-induced responses of floating plates are discussed.Moreover,the effective method to reduce the vibration of floating elastic plates can be obtained through comparison.  相似文献   

Northward transport of pacific summer water along the Northwind Ridge in the Western Arctic Ocean     

Hiroshi Sumata  Koji Shimada 《Journal of Oceanography》2007,63(3):363-378

The recent sea-ice reduction in the Arctic Ocean is not spatially uniform, but is disproportionally large around the Northwind Ridge and Chukchi Plateau compared to elsewhere in the Canada Basin. In the Northwind Ridge region, Pacific Summer Water (PSW) delivered from the Bering Sea occupies the subsurface layer. The spatial distribution of warm PSW shows a quite similar pattern to the recent ice retreat, suggesting the influence of PSW on the sea-ice reduction. To understand the regionality of the recent ice retreat, we examine the dynamics and timing of the delivery of the PSW into this region. Here, we adopt a two-layer linearized potential vorticity equation to investigate the behavior of Rossby waves in the presence of a topographic discontinuity in the high latitude ocean. The analytical results show a quite different structure from those of mid-latitude basins due to the small value of β. Incident barotropic waves excited by the sea-ice motion with large annual variation can be scattered into both barotropic and baroclinic modes at the discontinuity. Since the scattered baroclinic Rossby wave with annual frequency cannot propagate freely, a strong baroclinic current near the topographic discontinuity is established. The seasonal variation of current near the topographic discontinuity would cause a kind of selective switching system for shelf water transport into the basin. In our simple analytical model, the enhanced northward transport of summer water and reduced northward transport of winter water are well demonstrated. The present study indicates that these basic dynamics imply that a strengthening of the surface forcing during winter in the Canada Basin could cause sea-ice reduction in the Western Arctic through the changes of underlying Pacific Summer Water.  相似文献   

利用臭氧氧化实现复合生物反应器污泥减量   总被引：3，自引：0，他引：3  

王琳  孙德栋  黄海萍 《中国海洋大学学报(自然科学版)》2006,36(5):799-803

采用复合生物反应器,对应用臭氧氧化实现污泥减量进行了研究。2个相同的复合生物反应器平行运行,1个作为对照系统,1个作为氧化系统。反应器内装有半软性填料,投加量为10%。曝气池中悬浮污泥浓度为1 500 mg/L左右,生物膜浓度为2 000 mg/L左右。试验结果表明,随着臭氧氧化污泥比例的增加,污泥表观产率系数也随之降低,当臭氧投量为0.05 g O3/gSS,每天氧化的污泥分别为反应器内污泥的10%,20%,30%时,污泥表观产率系数分别减少28.2%,44.9%,75.8%。虽然随着污泥氧化比例的增大,氧化系统出水CODcr略有增加,但氧化系统仍能保持其生物处理能力,CODcr去除率在92%以上;2个系统之间氨氮的去除率相差不大,氧化系统的硝化能力基本没有受到臭氧氧化的影响。  相似文献   

复合加载条件下吸力式沉箱基础承载特性数值分析   总被引：2，自引：0，他引：2  

王志云  王栋  栾茂田  范庆来  武科 《海洋工程》2007,25(2):52-56,71

吸力式沉箱基础的承载特性是海洋工程结构设施建造与设计中的一个关键问题。这种新型的深水海洋基础型式,通常承受竖向上拔荷载与水平荷载的共同作用,其工作性能与设计理论远远不能满足工程实践的需要。本文采用有限元分析方法对吸力式沉箱基础的极限承载特性进行数值计算。以大型通用有限元分析软件ABAQUS为平台,通过二次开发,数值实现了Swipe试验加载方法和固定位移比分析方法,针对不同的沉箱长径比、土的强度折减系数,探讨了沉箱基础在垂直上拔荷载和水平荷载单调联合作用下的极限承载力,通过对不同荷载组合的数值计算构造了复合加载条件下沉箱基础破坏包络面。  相似文献   

重力辅助惯性导航中重力归算的垂直梯度计算     

李姗姗  吴晓平  陈少明 《测绘科学》2008,33(2):10-12

重力辅助惯性导航技术是利用地球物理特征信息数据—重力来完成水下运动载体的辅助导航与定位。为了实现水下运动载体上重力传感器输出的实测重力信息与重力数据库中存储的重力信息之间的匹配,首先必须将这两类数据归算到一个平面。本文研究分析了重力归算中重力垂直梯度求解的各种方法;探讨了不同数值积分区域对扰动重力垂直梯度精度的影响;并通过计算分析,提出了可以直接以重力异常垂直梯度代替扰动重力垂直梯度来求取重力垂直梯度。  相似文献   

江西省地质灾害-气象预警预报系统研究   总被引：4，自引：1，他引：3  

周玉才  雷万荣  余广文  唐春梅  程志华 《中国地质灾害与防治学报》2008,19(2):67-71

论文采用了降雨特征（用降雨诱发指数表征）与地质环境条件（以地质灾害敏感性指数表征）进行叠加、分析,确定预警预报等级,建立地质灾害-预警预报模型的方法;提出了预警产品制作与发布、多普勒雷达跟踪、应急指导、反馈信息收集、灾情调查的地质灾害气象预警预报工作程序。对近几年江西省地质灾害-预警预报效果分析,总结了地质灾害-预警预报成功与失败的经验教训,提出今后的工作设想与建议。应用基于GIS的地质灾害预警预报系统已在近几年的地质灾害-气象预警预报中不断完善,预警预报精度得到提高,防灾减灾效果明显,对保护人民生命财产安全发挥了重要作用。  相似文献   

锦屏一级水电站引渠内侧自然边坡的稳定性   总被引：1，自引：1，他引：0  

王东  伍法权  任爱武 《工程地质学报》2008,16(6):793-797

层状岩体顺层滑动但却存在反倾的后缘结构面的边坡稳定性研究尚未见到具体讨论。本文采用了数值模拟方法对锦屏一级水电站引渠内侧边坡的稳定性进行了分析,通过结构面参数折减法,求得该边坡稳定性系数为1.191,后端岩体对前端不稳定体不存在推力。通过数值分析方法和极限平衡法对结构面相关参数的敏感性进行了分析对比,对比表明采用参数折减法的数值分析方法结果可靠。本文为类似复杂岩体边坡稳定性判定提供参考。  相似文献   

生物气CO_2还原途径中碳同位素分馏作用研究及应用   总被引：2，自引：0，他引：2  

李谨  胡国艺  张英  杨贵芳  崔会英  曹宏明  胡须龙 《地学前缘》2008,15(5):357

地质历史中,CO2/H2还原产甲烷作用对生物气的形成具有十分重要的意义。中国柴达木盆地第四系生物气主要为CO2/H2还原型生物气。笔者以CO2/H2还原生气理论为指导,进行不同初始碳同位素值和不同赋存状态碳源的生物模拟实验,研究CO2/H2还原产气过程中发生的碳同位素分馏作用。实验结果表明,产物中δ13CH4值与底物的δ13C值呈很好的正相关关系;在反应母质过量的情况下,碳源的赋存状态可以影响产物甲烷的碳同位素组成。以游离形式CO2还原产生的甲烷δ13C值,相对于以HCO3-、CO23-离子形式产生的甲烷δ13C值轻。通过柴达木盆地东部第四系生物气田实例分析,探讨了该区生物气的主要底物CO2的来源及赋存状态,对评价盆地生物气资源和有利勘探区预测有重要的参考价值。  相似文献   

首都减灾圈的思考与建议     

张少泉  吕庆书 《地震》1993,(5):47-61

首都减灾圈,系首都减轻自然灾害预测防治圈。1991年12月20—21日在北京召开了《首都圈自然灾害及其减灾对策研讨会》。本文根据这次会议所提供的材料,在从整体上实现减灾的思想指导下,就首都减灾圈的“成灾背景”、“首都减灾圈的组成”、“首都减灾圈的灾害预测与防治状况”、“首都减灾圈的灾害关联性分析”、“首都减灾圈的减灾实效预估”和“首都减灾圈的减灾对策与实施”等六个带有共同性的问题,进行了讨论。供制定首都圈减灾方案时参考。  相似文献