Decompression and H<Subscript>2</Subscript>O exsolution driven crystallization and fractionation: development of a new model for low-pressure fractional crystallization in calc-alkaline magmatic systems     

James Gerald Brophy 《Contributions to Mineralogy and Petrology》2009,157(6):797-811

Magma ascent, decompression-induced H₂O exsolution and crystallization is now recognized as an important process in hydrous subduction zone magmas. During the course of such a process calculations suggest that the ascent rate of a degassing and crystallizing mafic magma will be greater than crystal settling velocities. Thus, any crystals formed as a consequence of volatile exsolution will remain suspended in the magma. If the magma erupts before the percentage of suspended crystals reaches the critical crystallinity value for mafic magma (~55 vol.%) it will produce the commonly observed crystal rich island arc basalt lava. If the magma reaches its critical crystallinity before it erupts then it will stall within the crust. Extension of compaction experiments on a 55 vol.% sand-Karo syrup suspension at different temperatures (and liquid viscosities) to the likely viscosities of interstitial andesitic to dacitic liquid within such a stalled magma suggest that small amounts (up to ~10%) can be expelled on a time scale of 1–10 years. The expelled liquid can create a new intermediate to silicic body of magma that is related to the original mafic magma via fractional crystallization. The short time scale for liquid expulsion indicate that decompression-induced H₂O exsolution and crystallization can be an important mechanism for fractional crystallization. Based on this assumption a general model of decompression-induced crystallization and fractionation is proposed that explains many of the compositional, mineralogical and textural features of Aleutian (and other andesites).  相似文献   

云南腾冲全新世火山岩岩浆演化和岩石成因     

杨逸云  赵志丹  雷杭山  武精凯  苗壮  张双全  陈玲  季宏伟 《岩石学报》2019,35(2):472-484

腾冲火山岩区是我国全新世以来记载火山喷发的少数地区之一,该地区岩浆作用的性质与成因是揭示青藏高原东缘的现今侧向生长过程与深部作用的重要依据。本文对腾冲火山岩区的马鞍山、黑空山、打鹰山全新世火山岩开展了矿物化学和岩石地球化学研究,以期揭示岩石成因和深部动力学过程。腾冲全新世火山岩主体岩性为高钾钙碱性系列的玄武粗安岩和粗安岩。岩石的Ca O、Fe_2O_3~T、Ti O_2与Si O_2负相关,而K_2O与Si O_2正相关,表明岩浆演化过程中可能存在橄榄石、辉石和斜长石的分离结晶作用。岩石中存在酸性斜长石(更长石,An=28)大颗粒捕掳晶,其边部发育了基性斜长石(拉长石,An=65)增生边;在大颗粒石英捕掳晶的边部发育了辉石的反应边,这些结构表明在岩浆上升到地壳浅部时,曾受到了花岗岩围岩的混染,但岩石的Th/Nb值均小于1.16,表明地壳混染总体不显著。腾冲全新世火山岩大离子亲石元素富集、高场强元素相对亏损,高Th/U、低Ba/La,富集Sr-Nd同位素,其岩浆源区应为经历过洋壳沉积物交代后的富集地幔。腾冲火山岩属于大陆板内环境,是印度与亚洲大陆碰撞后岩浆作用的产物。火山岩是沿着腾冲盆地南北向展布,且熔岩分布面积有限。由于高原侧向生长过程中的区域性走滑断裂会引起局部的伸展,腾冲火山岩产出可能与富集岩石圈地幔的减压熔融有关。  相似文献   

Mineral chemistry,crystallization conditions and magma mixing‐mingling at Orduzu volcano (Malatya), Eastern Anatolia,Turkey     

A. nal 《Geological Journal》2008,43(1):95-116

The Middle Miocene Orduzu volcanic suite, which is a part of the widespread Neogene Yamadağ volcanism of Eastern Anatolia, consists of a rhyolitic lava flow, rhyolitic dykes, a trachyandesitic lava flow and basaltic trachyandesitic dykes. Existence of mafic enclaves and globules in some of the volcanic rocks, and microtextures in phenocrysts indicate that magma mingling and mixing between andesitic and basaltic melts played an important role in the evolution of the volcanic suite. Major and trace element characteristics of the volcanic rocks are similar to those formed in convergent margin settings. In particular, incompatible trace element patterns exhibit large depletions in high field strength elements (Nb and Ta) and strong enrichments in both large ion lithofile elements (Ba, Th and U) and light rare earth elements, indicating a strong subduction signature in the source of the volcanic rocks. Furthermore, petrochemical data obtained suggest that parental magmas of rhyolite lava and dykes, and trachyandesite lava and basaltic trachyandesite dykes were derived from subduction‐related enriched lithospheric mantle and metasomatized mantle (± asthenosphere), respectively. A detailed mineralogical study of the volcanic suite shows that plagioclase is the principal phenocryst phase in all of the rock units from the Orduzu volcano. The plagioclase phenocrysts are accompanied by quartz in the rhyolitic lava flows and by two pyroxenes in the trachyandesitic lava flows and basaltic trachyandesitic dykes. Oxide phases in all rocks are magnetite and ilmenite. Calculated crystallization temperatures range from 650°C to 800°C for plagioclase, 745°C–1054°C for biotite, 888°C–915°C for pyroxene and 736°C–841°C for magnetite–ilmenite pairs. Calculated crystallization pressures of pyroxenes vary between 1.24–5.81 kb, and oxygen fugacity range from −14.47 to −12.39. The estimates of magmatic intensive parameters indicate that the initial magma forming the Orduzu volcanic unit began to crystallize in a high‐level magma chamber and then was stored in a shallow reservoir where it underwent intermediate‐mafic mixing. The rhyolitic lava flow and dykes evolved in relatively shallower crustal magma chambers. Copyright © 2007 John Wiley & Sons, Ltd.  相似文献   

碳酸氢钠冷却结晶动力学          下载免费PDF全文

蒋士姣 《盐湖研究》2021,29(2):50-57

碳酸氢钠(NaHCO_3)俗称小苏打,其产品质量取决于颗粒的大小,晶体的形貌和样品的纯度等诸多因素。本论文基于连续稳态MSMPR结晶器原理,研究了不同停留时间下,碳酸氢钠从碳酸钠溶液中冷却结晶过程动力学。利用实验数据建立了NaHCO_3的结晶动力学操作模型。实验和计算结果表明,随停留时间的增加,NaHCO_3过饱和度降低,晶体生长速率和成核速率均减小,相应的平均粒径增加,细颗粒含量减小;适当延长停留时间是制取高品质小苏打产品的有效途径。冷却结晶过程可有效增加小苏打产量,小苏打收率维持在55%左右。此外,一定Na_2CO_3存在下冷却结晶碳酸氢钠晶体形态由细长的针状变为规整的片状。  相似文献   

t-BAMBP/磺化煤油萃取体系从盐湖卤水中萃取铷的动力学研究          下载免费PDF全文

黄东方  郑红  宝阿敏  刘泽宇  段东平  王舒娅  李波  王斌  杨晋生  范承亮 《盐湖研究》2017,25(1):49-56

采用上升单液滴法,进行盐湖卤水中萃取铷的动力学研究,主要考察了比界面积、水相铷浓度和油相(t-BAMBP/磺化煤油)浓度对萃取速率的影响。通过比界面积的研究发现,t-BAMBP萃取铷的过程由界面化学反应和相内化学反应共同控制;通过对实验数据的非线性拟合,得到了萃取体系的动力学方程,R=9.936×10-7[Rb+]1.134[t-BAMBP]2.190,萃取速率对铷的反应级数为a=1.134,对t-BAMBP反应级数b=2.190,实验值和计算值的均方根误差为1.735%。  相似文献   

基于数学形态学方法的街道数据提取算法     

刘洋 《北京测绘》2007,(3):5-8

数学形态学用具有一定形态的结构元素去度量和提取图像中的对应形态以达到对图像分析和识别的目的。其中细化是处理线状二值图像的一种重要技术,它可以把二值图像区域缩成线条,以逼近区域的中心线,极大地减少图像中的冗余信息量,以便进一步分析和识别。本文研究了通过击中变换实现的骨架线提取算法,并将其应用于城市居民地的街网数据提取,取得了较好的实验效果。  相似文献   

萃取法制取磷酸二氢钾工艺研究   总被引：2，自引：0，他引：2       下载免费PDF全文

肖学英  孟瑞英  宋明礼 《盐湖研究》1999,7(3):36-41

本文研究改进了萃取法制取磷酸二氢钾的工艺路线,确定了较适宜的工艺条件,萃取在常温下进行,一次反应得到磷酸二氢钾。产品纯度高,能耗低,有望成为大规模工业生产该产品最经济的路线之一。  相似文献   

论CILa/CISm—CILa图解     

万渝生 《现代地质》1990,4(3):81

通过对分离结晶作用和批式熔融作用C_l^y/C_l^x-C_l^y图解的数学分析,笔者认为,虽然C_l^La/C_l^sm-C_l^La图解在一定程度上能区分这两种不同岩浆作用过程,但是,Treuil等的解释是不完全的。直线的斜率和截距还极大地受参数C_o^x,C_o^y,D_x,D_y的影响。该图解并非总是有效。本文还给出了一般式C_l^y/C_l^x-C_l^y在其它方面的可能应用。  相似文献   

岩浆结晶与成矿作用模拟     

马鸿文 《地学前缘》1994,1(3):0-0

本文回顾了８０年代以来国际上关于岩浆结晶及成矿作用过程的计算机模拟这一领域的研究进展,主要包括镁铁质干岩浆体系、长英质湿岩浆体系的岩浆结晶作用模拟,以及有关的岩浆矿床成矿作用、岩浆热液成矿作用的模拟。基于对这一领域研究现状和发展趋势的分析,笔者首次提出了模拟岩石学的概念。预测在今后５～１０年内,模拟岩石学将得到突飞猛进的发展,并将对现代岩石成因理论、实验岩石学与矿物学、实验地球化学、矿床成因理论和矿产预测及勘察理论产生重要影响。  相似文献   

Spectroscopic Characterization of Organic Structures and Organic‐Inorganic Interactions in Paper Mill Sludge     

Claudia M. B. F. Maia  Fabio Simonelli  Antinio S. Mangrich 《洁净——土壤、空气、水》2001,28(7):372-377

The organic composition and organic‐inorganic interaction in paper mill sludge (PS) solvent extracts (hexane, ethyl acetate, acetone and ethanol) and humic fractions, humic acid (HA) and humin (HU) were studied by electron paramagnetic resonance spectroscopy (EPR), proton and carbon‐13 nuclear magnetic resonance spectroscopy (¹H NMR; ¹³C NMR), Fourier‐transformed infrared spectroscopy (FTIR), and ultraviolet‐visible spectroscopy (UV‐vis). The strategy of fractionating the PS, sequentially, with organic solvents of increasing polarity is a reliable analytical procedure for humic substance sample separation because it results in more purified fractions. FTIR, ¹H NMR and ¹³C NMR results showed that hexane extract consisted mainly of aliphatic hydrocarbon structures. Their contents in the extracts decreased as the polarity of the extracting solvent increased and the content of oxygen functional groups increased. Carboxylic and carboxylate functional groups were found in the acetone extract, and ester and ether functions were predominantly found in the ethanol extract. EPR spectra revealed some Fe³⁺ complexes with rhombic structure (g₁ = 4.3; g₂ = 9.0) in the humic fractions and in all solvent extracts, except hexane. Quasi‐octahedral Fe³⁺ complexes (g = 2.3; ΔH_pp ≤ 400 G) were found in the HU fraction and in the acetone extract. The organic free radical content in the HA fraction was higher than the non‐fractionated PS sample and HU fraction.  相似文献