天然气水合物的地热研究进展   总被引：8，自引：0，他引：8  

金春爽  汪集晻 《地球科学进展》2001,16(4):540-543

天然气水合物的地热研究在以下几个方面都取得了重要进展，热流与似海底反射层的关系，水合物稳定带的研究；水合物热物理参数的确定；水合物形成过程中的热状态；热导率的应用，指出了今后水合物的地热学研究方向。  相似文献   

Zur Bildung von Artefakten und deren Vermeidung bei der Bestimmung leichtflüchtiger Halogenkohlenwasserstoffe in Wasser mittels Headspace-Gaschromatographie unter den Bedingungen der DIN 38407 Teil 5 (DEV-F5). Teil II: Überhöhte Trihalogenmethanbefunde in gechlortem Schwimmbeckenwasser     

J. Koch  P. Vlker 《洁净——土壤、空气、水》1996,24(4):179-184

Formation of Artefacts and its Suppression during the Determination of Volatile Halogenated Hydrocarbons in Water by Means of Headspace Gas Chromatography under the Standard Conditions of DIN 38407-F5. Part II: Increased Trihalomethane Formation in Chlorinated Swimming-pool Water A comparison of two analytical standard procedures for the determination of trihalomethanes (THM) in water (headspace gas chromatography and pentane extraction/gas chromatography) yielded strongly differing results. Under the conditions recommended by the German Standard Method DIN 38407-F5 (60…80°C for at least 60 min) degradation of thermo-labile chlorination products occurs resulting in elevated THM concentrations. The reactions involved are partly pH-dependant, and these can be suppressed by sample acidification. The degradation of trihalogen acetic acids, however, can only be influenced by minimizing the equilibration time and temperature. Other intermediate chlorination products (haloacetonitriles) are also degraded to THM after preceding hydrolysis to the corresponding carboxylic acids. Comparative results obtained with a purge and trap method at ambient temperature, i.e. without thermal stress during the enrichtment step, are lower than with static headspace GC but still high in comparison to the pentane extraction method. Presumably volatile THM-precursors are also trapped and subsequently decomposed upon thermal desorption from the trap. As the static headspace GC is the most rational method of LHKW determination available, the recommended experimental sample handling conditions should be modified in a way that deterioration reactions are reduced as far as possible.  相似文献   

Gas Chromatography for Determination of Pesticides in Aquatic Systems — Analytical Basis Gaschromatographie zur Bestimmung von Pestiziden in aquatischen Systemen — Analytische Grundlagen     

H.-J. Brauch 《洁净——土壤、空气、水》1993,21(2):84-88

High resolution gas chromatography (HRGC) with ECD, NFID and MSD is a very efficient determination method for pesticides in water. Because of their relatively low concentrations in aquatic systems enrichment and preconcentration procedures are essential. Some examples for pesticide determination by GC methods are given. Potentials and limitations of HRGC for pesticide analysis are also discussed. An extensive pesticide analysis in water has to include different methods like HRGC, HPLC and GC/MS.  相似文献   

Natural Gas Hazard (CO2, 222 Rn) within a Quiescent Volcanic Region and Its Relations with Tectonics: The Case of the Ciampino-Marino Area, Alban Hills Volcano, Italy     

L. Pizzino  G. Galli  C. Mancini  F. Quattrocchi  P. Scarlato 《Natural Hazards》2002,27(3):257-287

Groundwater surveys were performed by detailed(around 300 sites) grid-analysis of water temperature, pH, redox potential, electrical conductivity, ²²²Rn, alkalinity and by calculating the pCO₂, throughout the Ciampino and Marino towns in the Alban Hills quiescent volcano (Central Italy). Following several episodes of dangerous CO₂ exhalation from soils during the last 20 years and earlier ashistorically recorded, the work aimed at assessing the Natural Gas Hazard (NGH) including the indoor-Rn hazard. The NGH was defined as the probability of an area to become a site of poisonous peri-volcanic gas exhalations from soils to the lower atmosphere (comprising buildings). CO₂ was found to be a ``carrier' for the other poisonous minor and in trace components (H<sub>s</sub>S, CH<sub>4</sub>, <sup>222</sup>Rn, etc.). This assessment was performed by extrapolating in the aquifer CO<sub>2</sub> and <sup>222</sup>Rn conditions, and discriminating sectors where future CO<sub>2</sub> flux in soils as well as indoor-Rn measurements have to be noted. A preliminary indoor-Rn survey was performed at about 200 sites. The highest values were found in the highest pCO<sub>2</sub> and high <sup>222</sup>Rn values in groundwater. This indicates convection and enhanced permeability in certain sectors of the main aquifer, i.e., along the bordering faults and inside the gas-trap of the Ciampino Horst., where ``continuous gas-phase micro-macro seepage mechanism' is invoked to explain the high peri-volcanic gases flux.  相似文献   

华北平原冬麦田土壤CH4的吸收特征研究   总被引：9，自引：0，他引：9  

张雪松  申双和  李俊  于强 《南京气象学院学报》2006,29(2):181-188

利用静态箱/气相色谱(GC)法,对华北平原冬小麦拔节—成熟期间麦田土壤CH4气体通量进行了测定,得出华北平原典型冬麦田土壤是大气CH4的弱吸收汇。试验期间土壤CH4通量存在明显的季节变化和日变化,麦田拔节—成熟期间土壤CH4通量日平均值为-18.3μg.m-2.h-1,波动范围为-4.3~-24.4μg.m-2.h-1;在土壤CH4通量的日变化中,观测到麦田土壤在午间和夜间都有一个吸收峰,峰值出现的时间因生育期不同而有所不同。试验期间CH4通量日平均值与土壤温度关系不明显,而与土壤水分呈负相关(α=0.01);日变化中土壤CH4通量与地表温度的相关性较差,而与5 cm地温相关密切。麦田拔节—成熟期间土壤CH4通量日平均值随NH4 -N施用量的增加呈递减规律,农田秸秆还田后不利于土壤对CH4的吸收。  相似文献   

南海含天然气水合物地层地震反射特征及可能分布研究   总被引：4，自引：0，他引：4  

徐华宁  李丽青  舒虎  文鹏飞  张宝金 《应用地球物理》2006,3(1):42-47

天然气水合物是当前能源与环境领域的研究热点之一,南中国海是天然气水合物赋存的有利区域。天然气水合物的存在改变了沉积地层的声学特征,这一性质使多道地震勘探成为发现海洋天然气水合物的主要手段。本文首先根据地震成像结果定性分析南海可能含天然气水合物沉积地层的地震反射特征,初步确定天然气水合物存在的可能性并指出地震成像关键技术。在无井条件下,构建虚拟井进行波阻抗反演得到定量的地层速度参数进一步证实这一可能性,最后将反演获得的速度场与ODP184 航次在此区域获得的地球物理、地球化学信息综合分析,可以确定此区域天然气水合物的存在及其空间展布。  相似文献   

华北平原冬麦田土壤CH₄的吸收特征研究          下载免费PDF全文

张雪松  申双和  李俊  于强 《大气科学学报》2006,29(2):181-188

利用静态箱/气相色谱(GC)法,对华北平原冬小麦拔节-成熟期间麦田土壤CH₄气体通量进行了测定,得出华北平原典型冬麦田土壤是大气CH₄的弱吸收汇。试验期间土壤CH₄通量存在明显的季节变化和日变化,麦田拔节-成熟期间土壤CH₄通量日平均值为-18.3μg·m^-2·h^-1,波动范围为-4.3-24.4μg·m^-2·h^-1;在土壤CH₄通量的日变化中,观测到麦田土壤在午间和夜间都有一个吸收峰,峰值出现的时间因生育期不同而有所不同。试验期间CH₄通量日平均值与土壤温度关系不明显,而与土壤水分呈负相关(α=0.01);日变化中土壤CH₄通量与地表温度的相关性较差,而与5cm地温相关密切。麦田拔节-成熟期间土壤CH₄通量日平均值随NH4+-N施用量的增加呈递减规律,农田秸秆还田后不利于土壤对CH₄的吸收。  相似文献   

Scalar Similarity for Relaxed Eddy Accumulation Methods     

Johannes Ruppert  Christoph Thomas  Thomas Foken 《Boundary-Layer Meteorology》2006,120(1):39-63

The relaxed eddy accumulation (REA) method allows the measurement of trace gas fluxes when no fast sensors are available for eddy covariance measurements. The flux parameterisation used in REA is based on the assumption of scalar similarity, i.e., similarity of the turbulent exchange of two scalar quantities. In this study changes in scalar similarity between carbon dioxide, sonic temperature and water vapour were assessed using scalar correlation coefficients and spectral analysis. The influence on REA measurements was assessed by simulation. The evaluation is based on observations over grassland, irrigated cotton plantation and spruce forest.Scalar similarity between carbon dioxide, sonic temperature and water vapour showed a distinct diurnal pattern and change within the day. Poor scalar similarity was found to be linked to dissimilarities in the energy contained in the low frequency part of the turbulent spectra ( < 0.01 Hz).The simulations of REA showed significant change in b-factors throughout the diurnal course. The b-factor is part of the REA parameterisation scheme and describes a relation between the concentration difference and the vertical flux of a trace gas. The diurnal course of b-factors for carbon dioxide, sonic temperature and water vapour matched well. Relative flux errors induced in REA by varying scalar similarity were generally below ± 10%. Systematic underestimation of the flux of up to − 40% was found for the use of REA applying a hyperbolic deadband (HREA). This underestimation was related to poor scalar similarity between the scalar of interest and the scalar used as proxy for the deadband definition.  相似文献   

西气东输管道工程中卫黄河穿越隧道场地工程地质条件评价     

曹兴山  卿春和 《工程地质学报》2007,15(3):338-345

西气东输工程中卫黄河穿越隧道长1197.77m,高4.3m,宽5.6m。隧道入口高于黄河水位28m,出口高于黄河水位45m。隧道顶板高程为1130m。位于黄河水下100m。隧道场地围岩为寒武系磨盘井组灰绿色、银灰色浅变质中厚层细粒长石石英砂岩、千枚状板岩、绢云母化千枚岩。围岩为弱风化Ⅲ～Ⅳ类岩石。透水率为4～67Lu,纵波波速为500～3300m.s-1。BQ为300～400。变形模量为6.11～9.22GPa。泊松比（）0.14～0.24。内摩擦角（）为42.1～44.7。地下水为基岩裂隙水。含水层为寒武系浅变质岩,受大气降水渗入补给,单井涌水量为1.0～50m3.d-1。隧道轴线穿越区岩体较完整较破碎,未有全新活动断层。隧道位置选择和开挖深度设计是可行的。施工和长期运营是安全的。  相似文献   

Control and prevention of gas outbursts in coal mines, Riosa–Olloniego coalfield, Spain     

María B. Díaz Aguado  C. Gonzlez Nicieza 《International Journal of Coal Geology》2007,69(4):253-266

Underground coal mines have always had to control the presence of different gases in the mining environment. Among these gases, methane is the most important one, since it is inherent to coal. Despite of the technical developments in recent decades, methane hazards have not yet been fully avoided. This is partly due to the increasing depths of modern mines, where methane emissions are higher, and also to other mining-related circumstances, such as the increase in production rates and its consequences: difficulties in controlling the increasing methane levels, increasing mechanization, the use of explosives and not paying close attention to methane control systems.The main purposes of this paper are to establish site measurements using some critical parameters that are not part of the standard mining-control methods for risk assessment and to analyze the gas behavior of subvertical coal seams in deep mines in order to prevent gas incidents from occurring. The ultimate goal is the improvement in mining conditions and therefore in safety conditions.For this purpose, two different mines were instrumented for mine control and monitoring. Both mines belong to the Riosa–Olloniego coalfield, in the Asturias Central Basin, Spain and the areas instrumented are mined via subhorizontal sublevels at an actual depth of around 1000 m under the overburden of Mount Lusorio.During this research, a property favoring gas outbursts was site measured for the first time in an outburst-prone coal (8th Coalbed), gas pressure and its variations, which contributed to complete the data available from previous characterizations and to set some guidelines for assessing the potential outburst-prone areas. A gas-measurement-tube set has been designed for measuring gas pressure as well as its variation over time as a result of nearby workings and to calculate permeability.The paper establishes the effect of overlapping of works, but it also shows the efficacy of two preventive measures to be applied: high pressure water infusion and the exploitation of a protective coal seam (7th Coalbed), that must be mined preferably two complete sublevels before commencing the advance in the outburst-prone coalbed. Both measures constitute an improvement in the mining sequence and therefore in safety, and should be completed with a systematic measurement to control the risk: gas pressure in the 8th Coalbed in the area of influence of other workings, to establish the most suitable moment to renew the advance. Further researches could focus on ascertaining the permeability, not only in mined areas but also in areas of the mine that are still not affected by mining work and on tuning more finely the ranges of influence of overstress time and overlap distance of the workings of the 7th Coalbed in the 8th Coalbed.  相似文献