Transport of dissolved methoxy-nonafluorobutane through a saturated column     

Kenneth Y. Lee  Jeong-Yub Lee  James J. Mellett 《Environmental Geology》2004,46(6-7):883-889

Solute transport experiments were conducted in a one-dimensional saturated column using dissolved methoxy-nonafluorobutane (HFE-7100), a Novec engineered fluid developed by the 3M Corporation, as the solute. Novec engineered fluids are considered dense non-aqueous phase liquids (DNAPLs) because they are immiscible with water and have a specific gravity greater than one. The HFE-7100 fluid is safer and environmentally friendlier than common DNAPL contaminants such as tetrachloroethylene (PCE) or trichloroethylene (TCE); thus, it is an ideal substitute DNAPL for laboratory groundwater contamination research. Three sets of solute transport experiments were conducted. The first set of experiments was conducted in a glass-bead-packed column using dissolved HFE-7100 as the solute. The second set of experiments was conducted in a sand-packed column using dissolved HFE-7100 as the solute. The third set of experiments was conducted in a sand-packed column using dissolved PCE as the solute. The dissolved HFE-7100 column breakthrough concentrations were compared with dissolved PCE breakthrough concentrations. Results show that the one-dimensional solute transport equation was successful in describing the transport behavior of dissolved HFE-7100. This study demonstrates that the HFE-7100 fluid can be used as a safer substitute DNAPL for groundwater contaminant dissolution and transport research.  相似文献   

Classification and interpretation of piezometer well hydrographs in parts of southeastern peninsular India     

Pradeep Raj 《Environmental Geology》2004,46(6-7):808-819

Well hydrographs from 275 piezometers between 1998 and 2001 in the southeastern parts of peninsular India were used in this study. The area has a monsoon-type climate. Hard rocks cover 85% of the area. The form (shape) of the hydrograph depends upon (1) climatic and hydrogeologic parameters and (2) the scale of the graph. Therefore, hydrographs are drawn to a defined and standardised scale, which allows comparison of hydrographs and helps in bringing out reasons for different forms of the hydrographs. Hydrographs can be divided into seasonal segments and the slope of each segment then used as the basic element of a classification scheme. Slopes are classed as flat (inclination <20°), obtuse (between 20 and 45°), acute (45 and 80°), right angled (80 and 90°) and homoclinal (segments of hydrographs are either rising or falling during one complete water year). Hydrographs are assigned names that are a combination of these classes and begin with the rising segment, such as acute-obtuse. Seventy-six percent of segments were homoclinal-falling in 1999, which had a poor monsoon. Flat segments constitute 27% of all segments in confined Mesozoic aquifer systems. Water table fluctuations suggest an approximate recharge of 120 to 180 mm per annum constituting 18% of the annual precipitation. Cumulative rainfall required to affect a rise in water table is between 45 to 200 mm and lag time varies from 30 minutes to 200 rainy days, which suggests that moisture in the vadose zone holds a part of the annual replenishment for these aquifers.  相似文献   

Environmental impact of an urban landfill on a coastal aquifer (El Jadida, Morocco)     

Amina Chofqi  Abedelkader Younsi  El Kbir Lhadi  Jacky Mania  Jacques Mudry  Alain Veron 《Journal of African Earth Sciences》2004,39(3-5):509

The El Jadida landfill is one among many uncontrolled dumping sites in Morocco with no bottom liner. About 150 tons/day of solid wastes from mixed urban and industrial origins are placed directly on the ground. At the site of this landfill, the groundwaters circulate deeply (10–15 m) in the Cenomanian rock (calcareous–marl), which is characterised by an important permeability from cracks. The soil is sand–clay characterized by a weak coefficient of retention.The phreatic water ascends to the bottom of three quarries, which are located within the landfill. These circumstances, along with the lack of a leachate collection system, worsen the risks for a potential deterioration of the aquifer.To evaluate groundwater pollution due to this urban landfill, piezometric level and geochemical analyses have been monitored since 1999 on 60 wells. The landfill leachate has been collected from the three quarries that are located within the landfill. The average results of geochemical analyses show an important polluant charge vehiculed by landfill leachate (chloride = 5680 mg l⁻¹, chemical oxygen demand = 1000 mg l⁻¹, iron = 23 000 μg l⁻¹). They show also an important qualitative degradation of the groundwater, especially in the parts situated in the down gradient area and in direct proximity to the landfill. In these polluted zones, we have observed the following values: higher than 4.5 mS cm⁻¹ in electric conductivity, 1620 and 1000 mg l⁻¹ respectively in chlorides and sulfate (), 15–25 μg l⁻¹ in cadmium, and 60–100 μg l⁻¹ in chromium. These concentrations widely exceed the standard values for potable water.Several determining factors in the evolution of groundwater contamination have been highlighted, such as (1) depth of the water table, (2) permeability of soil and unsaturated zone, (3) effective infiltration, (4) humidity and (5) absence of a system for leachate drainage. So, to reduce the pollution risks of the groundwater, it is necessary to set a system of collection, drainage and treatment of landfill leachates and to emplace an impermeable surface at the site of landfill, in order to limit the infiltration of leachate.  相似文献   

Groundwater and geotechnical aspects of deep excavations in Hong Kong     

R. A. Forth   《Engineering Geology》2004,72(3-4):253-260

Consideration of groundwater is a key element in almost every construction project. The design of deep excavations for basements or underground railway station concourses below the water table require that the water pressures are taken into account. Whilst these can be considered to be hydrostatic in soil, the decreasing permeability of rock with depth and the fact that groundwater flow is invariably along discrete fractures means that the water pressure is unlikely to be hydrostatic at depth.

Groundwater control for deep excavations can be achieved by a number of methods such as grouting, pumping or structural walls or a combination of these. For tunnelling projects grouting is extensively used, but the development of sophisticated tunnelling machines has led in many cases to the demise of compressed air as a means of groundwater control.  相似文献   

Timing and intensity of groundwater movement during Egyptian Sahara pluvial periods by U-series analysis of secondary U in ores and carbonates     

J.K Osmond  Adel A Dabous 《Quaternary Research》2004,61(1):85-94

Wet climatic episodes are known to have prevailed in the Egyptian Sahara several times during the late Quaternary, most recently during the Holocene 8000 yr ago. Earlier wet episodes have been recognized as having occurred during the past 300,000 yr and have been dated by U-series methods in speleothems and in lake travertines. We show here that the times of enhanced groundwater movement can also be determined by ²³⁰Th/²³⁴U dating of secondary U in ores of uranium, iron, and phosphate. We also present evidence that such acceleration of groundwater movements is indicated by relatively low ²³⁴U/²³⁸U activity ratios in the secondary uranium. Our new data show that pluvial periods in Egypt occurred during marine oxygen isotope stages 4, 5, 6, and 7 and therefore are consistent with the view that the wet episodes are the results of migration of the tropical monsoonal belt driven primarily by the 23,000-yr precession cycle of the Milankovich curve, modulated by the 100,000-yr eccentricity cycle.  相似文献   

The influence of floodplain geohydrology on the distribution of Sarcocornia pillansii in the Olifants Estuary on the West Coast, South Africa     

Thomas G. Bornman  Janine B. Adams  Guy C. Bate 《Journal of Arid Environments》2004,56(4):603

The distribution of Sarcocornia pillansii (Moss) A.J. Scott was determined by water-table depth and electrical conductivity (EC) of the groundwater. Where the groundwater was accessible (<1.5 m) and had a low EC (<80 mS cm⁻¹), S. pillansii extended its roots down to the water-table where a suitable water potential gradient was shown to exist between the soil and roots. In areas where the groundwater was too deep and/or hypersaline, the plants grew on hummocks. The unconfined aquifer below the floodplain is linked to the estuary and although diurnal tidal waves were dampened, water-table level fluctuations were recorded between tidal events. The complex geomorphology of the floodplain influences groundwater flow, in turn affecting the distribution of the salt marsh vegetation.  相似文献   

Use of time series analysis for the identification of tidal effect on groundwater in the coastal area of Kimje, Korea     

Ji-Hoon Kim  Jeongho Lee  Tae-Jin Cheong  Rak-Hyeon Kim  Dong-Chan Koh  Jong-Sik Ryu  Ho-Wan Chang   《Journal of Hydrology》2005,300(1-4):188-198

The purpose of this study is to apply time series analysis to investigate whether the groundwater quality in the coastal area is affected by the tide. Continuous and regular in situ monitoring data of electrical conductivity (EC) and groundwater level, and tidal level data measured by the National Oceanographic Research Institute were used for the time series analysis. Through the time series analysis, it is known that EC and groundwater level conspicuously fluctuate with two periodicities (15.4 and 0.52-day), which is very similar to those of the tide. Also the behaviors of their fluctuations vary in accordance with the tidal period. These indicate that the groundwater quality has been mainly controlled by the tidal level, and the strength of tidal effect on the groundwater quality is different according to the tidal period.  相似文献   

Origin of the high variability of water mineral content in the bedrock aquifers of Southern Madagascar     

V. Rabemanana  S. Violette  G. de Marsily  H. Robain  B. Deffontaines  P. Andrieux  M. Bensimon  A. Parriaux 《Journal of Hydrology》2005,310(1-4):143-156

This study assesses the causes of the high spatial variability of the mineral content of groundwater in crystalline bedrock of Southern Madagascar. Although many kilometres from the coast and at a mean altitude of 400 m a.s.l, wells drilled in this area produce water with electrical conductivities in the range of 300–30,000 μS cm⁻¹ with a high spatial variability. Chemical and isotopic data are used to identify the processes involved in the groundwater mineralization. It is shown that the chemical composition of the groundwater in this region has its origin in (i) normal silicate and carbonate weathering reactions and (ii) input of marine salts, probably via rainfall recharge, modified by evapo-concentrative processes probably including precipitation and re-dissolution of secondary evaporites in the unsaturated zone. To obtain a better understanding of the spatial salinity distribution, well parameters such as yields, weathered zone thickness, weathered materials and morphological positions (upper slope, mid-slope, lower slope or valley bottom) are scrutinized.

A correlation was found between high salinity and low flow, shallow groundwater environments (flat hill tops, valley bottoms, weakly developed and clayey weathered zones) and between low salinity and high flow environments (granular, well-developed weathered zones and situation on valley slopes).  相似文献   

Application of Characteristics of Seismogenic Structures in the Determination of Parameter of Potential Seismic Source Areas     

Zhou Bengang 《中国地震研究》2005,19(4):430-441

INTRODUCTIONThe method of probabilistic seismic risk analysis was proposed by Cornell in1968(Cornell,1968).After more than30years development,it has become the main method for seismic riskassessment of engineering sites and seismic zonation,and has been u…  相似文献   

Groundwater vulnerability mapping: A GIS and fuzzy rule based integrated tool   总被引：8，自引：0，他引：8  

B. Dixon   《Applied geography (Sevenoaks, England)》2005,25(4):327-347

Contamination of groundwater has become a major concern in recent years. Since testing of water quality of all domestic and irrigation wells within large watersheds is not economically feasible, one frequently used monitoring strategy is to develop contamination potential maps of groundwater, and then prioritize those wells located in the potentially highly contaminated areas for testing of contaminants. However, generation of contamination potential maps based on groundwater sensitivity and vulnerability is not an easy task due inherent uncertainty. Therefore, the overall goal of this research is to improve the methodology for the generation of contamination potential maps by using detailed landuse/pesticide and soil structure information in conjunction with selected parameters from the DRASTIC model. The specific objectives of this study are (i) to incorporate GIS, GPS, remote sensing and the fuzzy rule-based model to generate groundwater sensitivity maps, and (ii) compare the results of our new methodologies with the modified DRASTIC Index (DI) and field water quality data. In this study, three different models were developed (viz. DI_fuzz, VI_fuzz and VI_{fuzz_ped}) and were compared to the DI. Once the preliminary fuzzy logic-based (DI_fuzz) was generated using selected parameters from DI, the methodology was further refined through VI_fuzz and VI_{fuzz_ped} models that incorporated landuse/pesticide application and soil structure information, respectively. This study was conducted in Woodruff County of the Mississippi Delta region of Arkansas. Water quality data for 55 wells were used to evaluate the contamination potential maps. The sensitivity map generated by VI_{fuzz_ped} with soil structure showed significantly better coincidence results when compared with the field data.  相似文献