不同方法评价喀斯特煤矿区农田土壤重金属生态风险比较     

刘品祯  贾亚琪  程志飞  杨珍  杜启露  吴迪 《中国岩溶》2018,37(3):371-378

采用TCLP法、内梅罗综合污染指数、嵌入Igeo综合污染指数法等方法对贵州织金县某煤矿区周边农田土壤重金属进行评价。土壤中Cd、Cr、Cu、Ni、Hg和Zn的含量范围分别为0.79～2.08 mg·kg-1、144.20～464.40 mg·kg-1、91.63～187.50 mg·kg-1、48.13～104.47 mg·kg-1、0.14～2.33 mg·kg-1、144.35～265.89 mg·kg-1,所有土壤样点的Cd、Cr、Cu和Ni含量均已超过国家土壤环境质量二级标准,部分土壤样点的Hg和Zn含量超过二级标准。TCLP法评价结果所有土壤样点均未受到重金属污染;内梅罗综合污染指数法评价结果为农田土壤重金属生态风险处于安全水平;嵌入Igeo综合污染指数法评价结果表明,90%的土壤达到中度污染以上,其中65%的土壤处于中度污染,25%的土壤受到中度至重度污染;潜在生态危害指数法评价表明,所有土壤样点重金属均处于轻微生态风险水平。针对不同评价方法得出的结果存在差异的情况,在评价土壤重金属污染状况时,应根据评价目标的差异选择合适的评价方法。   相似文献   

青藏高原东部暴雨的中尺度有效位能收支分析          下载免费PDF全文

Kuo Zhou  Lingkun Ran  Yi Liu  Xiuxia Tian 《大气和海洋科学快报》2021,14(2):53-59

针对2018年7月10-11日青藏高原东部一次暴雨过程,利用模式模拟资料分析了有效位能分布特征,成因及其对降水发展演变的影响.结果表明,有效位能主要分布在对流层低层4km以下和高层8-14km,高层有效位能和降水有更好的对应性西北冷平流和降水粒子下落的蒸发作用是低层有效位能高值中心的主要成因,而降水过程释放潜热带来的热力扰动叠加高原大地形造成的位温扰动是导致高层有效位能高值的主要原因.有效位能收支分析表明,有效位能的通量输送项以及与动能间的转换项是主要源汇项.低层有效位能的经向通量输送和动能向有效位能的转化补给了有效位能的耗散;高层有效位能向垂直动能转化增强垂直运动是促进降水发展演变的主要因素.高层有效位能与垂直运动之间的正反馈过程使得两者相关性较强;低层较长时间内均存在垂直动能向有效位能的转化,削弱了垂直运动,而西北冷平流使得低层有效位能有增强的趋势,因此二者相关性较弱.  相似文献   

川西九龙地区锂铍矿区土壤重金属分布特征及生态风险评价   总被引：1，自引：0，他引：1  

于沨  王伟  于扬  王登红  刘善宝  高娟琴  吕秉廷  刘丽君 《岩矿测试》2021,(3):408-424

川西九龙地区是近年来中国关键矿产资源勘查的热点地区之一,区内锂铍等稀有金属矿产资源优势突出,有望逐步发展成为国家级大型资源基地。作为长江上游生态保护屏障,该区生态环境脆弱,面对矿业开发的巨大机遇,在当前"环保优先"的现实情况下,急需摸清该区环境家底,支撑国家能源战略发展。本文用ICP-MS方法检测了该区352件土壤样品中7种重金属元素(Cd、As、Pb、Cr、Cu、Ni、Zn)的含量,运用地累积指数法、污染负荷指数法、潜在生态风险指数法和健康风险评价模型,结合GIS空间分析,综合研究了该区土壤中重金属的空间分布特征和生态风险。结果表明:(1)研究区土壤7种重金属元素浓度的平均值均没有超过国家农用土壤污染风险筛选值。As和Pb平均含量低于四川省土壤背景值,Cd、Cr、Cu、Ni和Zn含量高于背景值,分别是背景值的2.44、1.04、1.15、1.28和1.17倍。(2)Cd、Pb、Cr、Cu、Ni和Zn六种重金属元素浓度的空间分布特征明显受到区内黑云母花岗岩的影响,Pb的高浓度中心以及Cr、Cu、Ni和Zn的低浓度中心与岩体的空间位置对应关系明显。(3)地累积指数法评价结果显示,研究区土壤区域整体上不存在重金属异常累积;污染负荷指数法评价结果显示污染负荷指数均小于1,不存在重金属的污染;除Cd存在轻微的潜在生态风险外,其余6种元素均不存在潜在生态风险。(4)健康风险评价模型分析结果显示,空间上,Cd元素的单元素潜在生态风险指数空间分布规律与岩体存在一定联系,无生态风险区域与黑云母花岗岩岩体位置对应。土壤中的重金属可以通过手口、呼吸和皮肤直接接触三种途径进入人体,其中手口途径是产生健康风险的最主要途径。在全部重金属元素产生的健康风险中,除Cr的手口途径会产生可以接受的正常的自然致癌风险外,其余元素均不存在致癌性和非致癌性。研究表明,当前研究区土壤不存在重金属污染,潜在危害程度较低,且不存在非致癌和致癌性风险。但基于土壤中重金属存在一定的累积效应,在今后矿业开发过程中要密切关注土壤重金属浓度的变化,防止重金属污染带来的风险。  相似文献   

2015年11月沈阳地区一次PM2.5重污染过程综合分析     

杨磊  陈传雷  曹世腾  孙丽  崔曜鹏  蒋超  黄海亮  陈宇  杨雪 《气象与环境学报》2019,35(3):37-44

利用多源观测资料综合分析了2015年11月沈阳地区一次PM2.5 重污染天气的气象条件、垂直风场演变、大气边界层特征以及污染物的来源。结果表明:本次重污染过程中,沈阳市区PM2.5浓度长达81h超过250μg · m^-3 ,其中峰值浓度达到1287μg · m^-3 ,重污染期间PM2.5 /PM10 的比例最高为90%。受地面倒槽和黄淮气旋影响,近地面层持续存在的逆温层、高相对湿度和弱偏北风为颗粒物吸湿增长和长时间聚集提供有利的天气条件。风廓线雷达风场资料显示在重污染期间,近地面层存在弱风速区、凌乱风场和弱下沉气流。利用风廓线雷达资料计算了边界层通风量(Ventilation Index,VI)和局地环流指数(Recirculation,R),边界层通风量VI和PM2.5 存在明显的负相关,非污染日VI是重污染日的2倍,局地环流指数R在重污染天气前大于0.9,而在污染期间部分空间R小于0.8。通过后向轨迹模式和火点监测资料分析发现,沈阳上空300m高度气团来自于生物质燃烧区域,而且沈阳地区NO2和CO浓度的变化与PM2.5一致,说明本次重污染过程也可能和生物质燃烧有关。  相似文献   

双雷达风场反演拼图在登陆台风“莫兰蒂”(1614)强降水精细预报中的同化应用试验   总被引：4，自引：2，他引：2  

王叶红  赵玉春  罗昌荣  韩颂雨 《气象学报》2019,77(4):617-644

利用福建龙岩、漳州、泉州新一代多普勒天气雷达和厦门海沧双偏振雷达探测资料,采用动态地球坐标系下双雷达三维风场反演与拼图技术,基于天气研究和预报模式（Weather Research and Forecasting,WRF）及其资料同化系统,对登陆台风“莫兰蒂”（1614）引起的2016年9月14—15日福建强降水过程进行了双雷达风场反演拼图资料检验及其三维变分同化对强降水精细预报影响的数值试验,结果发现:（1）动态地球坐标系下双雷达反演风场能合理反映实际风场分布状况,其误差相对较小。相较厦门翔安风廓线雷达及厦门探空秒级测风数据,反演风风向（风速）平均绝对误差分别为7.8°（2.6 m/s）及3.4°（1.1 m/s）;（2）反演风场水平方向稀疏化对同化及预报结果极为重要,过密的反演风场资料会给同化及预报结果带来负效果。文中采用18、6、2 km 3重嵌套,在3重嵌套区域均进行同化以及仅在2 km区域进行同化两种情况下,均表现为当反演风场资料水平分辨率提高到0.1°时,同化分析及预报的台风环流开始受到负影响;且当反演风场资料水平分辨率越高时,负效果越明显。敏感性试验结果显示,分辨率取0.2°时数值预报效果最好;（3）以美国国家环境预报中心全球预报系统（National Centers for Environmental Prediction/Global Forecast System,NCEP/GFS）0.5°×0.5°分析场为初值,基于3个不同起报时刻（2016年9月14日14时、20时及15日02时）（北京时,下同）模拟的福建省境内台风内核雨带和螺旋雨带逐时演变、台风路径与强度、逐时降水TS评分和空间相关差异显著,其中14日14时起报试验效果最好;而14日20时起报试验效果最差,这与该试验初始台风大风轴风速明显偏大有关;（4）在上述3个不同起报时刻试验基础上,分别增加双雷达反演风场资料的三维变分同化后,福建境内地面风场和台风内核雨带、螺旋雨带逐时分布、逐时降水TS评分和空间相关、台风环流结构以及U、V风垂直廓线分布均有明显改善,最大正影响时效可达24 h;但仅对1—6 h时效内台风路径有改善。   相似文献   

海南澄迈地区风化壳型钽铌矿的发现及找矿意义     

吕昭英  袁勤敏  刘兵  马波  林义华  魏昌欣  胡在龙 《地质论评》2024,70(S1):77-78

  相似文献   

Spatial and temporal distributions of nitrogen, phosphorus and heavy metals in the intertidal sediment of the Chang jiang River Estuary in China   总被引：2，自引：0，他引：2  

QUAN Weimin  SHI Liyan  HAN Jindi  PING Xianyin  SHEN Anglv  CHEN Yaqu 《海洋学报(英文版)》2010,29(1):108-115

Spatial and temporal distributions of nutrients (N and P) and heavy metals (Cu, Zn, Pb and Cd) in the intertidal sediments at Dongtan wetland of the Changjiang River (Yangtze River) Estuary were examined by laying one transect running seaward to landward during January, April, June, August and October of 2005. Total nitrogen (TN) and heavy metal concentrations in the intertidal sediment showed an increasing trend from open bare °at to the high marsh, with the maximum concentrations in the high marsh and the minimum values in open bare °at. In contrast, sediment total phosphorus (TP) concentrations changed little among sampling sites. One-way ANOVA found that there were signiˉcantly temporal variations of nutrients and heavy metals concentrations in the intertidal sediment (P <0.05). The concentrations of heavy metals generally showed an increasing trend from January to October. As compared with other large estuaries, heavy metal contamination in the intertidal sediment of the Changjiang River Estuary was relatively low.  相似文献   

Towards developing sediment quality assessment guidelines for aquatic systems: An Australian perspective     

A. V. Arakel 《Australian Journal of Earth Sciences》2013,60(4):335-369

Sediment at the sediment‐water interface of natural and man‐made waterways forms an integral part of the ecosystem because it is affected by a continuous flux of physical, chemical and biological components between the sediment, interstitial water and the overlying water column. Aquatic sediments contain records of past and present urban and rural runoff, chemical discharges and spills. In recent years sediment quality has received increasing attention following identification of the role of sediment as both a sink for pollutants and as a contaminant source with potential impacts on the quality of receiving waters. Research has indicated that the processes leading to remobilization of contaminated sediments in upstream reaches of a waterway may, through time, exert a significant influence on water quality in the downstream reaches. This, together with the cumulative effects due to contaminant input from point and non‐point source discharges, have dramatic effects on water quality and thus on ecosystem structure and functioning.

The problems associated with elevated concentrations of many hazardous organic and inorganic compounds have resulted in the establishment of aquatic sediment quality criteria and management guidelines in many overseas countries, with the objectives being the reduction and elimination of adverse environmental effects and human health risks associated with contaminated sediments. Whereas more than 70% of the Australian population is clustered around the coastal waterways, little is known about the role of sediments as a repository of environmental pollutants and/or as a source of adverse impacts on water quality and the health of our rivers. The paucity of knowledge on the quality of aquatic sediment highlights the need for the development of coherent guidelines for sediment quality assessment and management of contaminated sites, which are consistent with Australian environmental conditions and land use features.

A comparative evaluation of sediment quality information from eight coastal rivers along the east coast of Australia, presented in this paper, indicates the possibility for establishing a framework for regional sediment quality assessment. This may be achievable by using textural and compositional attributes of bottom sediments in depositional areas to develop databases on the loading and concentration trends of nutrients and contaminants. Regional variability in sediment quality determinants are shown to reflect the influence of catchment hydrology, lithology and land use on nutrient and contaminant concentration trends. Locally, the loading and partitioning behaviour of sediment‐bound contaminants is largely controlled by the nature and the extent of interactions occurring at the sediment‐water interface within individual depositional units.

The concept of ‘Sediment Effect Zone’ is introduced to provide a compartmental approach to the characterization of aquatic sediments and depositional environments in different hydrologic zones. This approach offers a rational basis for follow‐up chemical and biological assessments to establish sediment quality standards and management guidelines. Because of the complex influences of environmental, methodological and statistical factors on defining the sediment variability, the need for implementing proper quality control measures from early stages of design of a sediment quality assessment program is highlighted.  相似文献   

长江口泥沙的来源分析与数量计算的研究   总被引：3，自引：0，他引：3  

林承坤 《地理学报》1989,44(1):22-31

本文根据地学原理，建立了长江口泥沙的来源分析与数量计算的模式。定量分析了长江口泥沙来源，计算了泥沙的数量。通过验证表明沙量的计算值与验证值两者十分吻合。  相似文献   

Mercury,arsenic, antimony,and selenium contents of sediment from the Kuskokwim River,Bethel, Alaska,USA   总被引：1，自引：0，他引：1  

Harvey E. Belkin  Harold M. Sparck 《Environmental Geology》1993,22(2):106-110

The Kuskokwim River at Bethel, Alaska, drains a major mercury-antimony metallogenic province in its upper reaches and tributaries. Bethel (population 4000) is situated on the Kuskokwim floodplain and also draws its water supply from wells located in river-deposited sediment. A boring through overbank and floodplain sediment has provided material to establish a baseline datum for sediment-hosted heavy metals. Mercury (total), arsenic, antimony, and selenium contents were determined; aluminum was also determined and used as normalizing factor. The contents of the heavy metals were relatively constant with depth and do not reflect any potential enrichment from upstream contaminant sources.  相似文献