广东雷州半岛火山岩二氧化碳矿化封存潜力评估     

李鹏春  江静练  程锦辉  赵明辉 《高校地质学报》2023,29(1):76-84

火山岩的矿物固碳作用为减少大气中的二氧化碳(CO₂)提供了一种永久性的封存解决方案,是一种经济、安全的碳捕集封存(CCS)方式。中国火山岩分布广泛,但对火山岩固碳潜力的研究还很欠缺。文章选择广东省雷州半岛火山岩为研究区,利用MapGis软件,建立雷州半岛火山岩厚度分布的矢量地理信息数据库,插值得到三维网格化数据体;基于火山岩矿化封存机制和CO₂矿化封存潜力评估方法,对雷州半岛火山岩CO₂理论矿化封存潜力进行了计算。结果表明,雷州半岛火山岩总面积约3940 km²,总体积约257 km3,CO₂理论矿化封存量在19～459亿吨之间。其中以雷南火山岩区潜力最大,理论封存量为13～326亿吨;其次为雷北遂溪县以东、湛江市西部区域的火山岩区,理论封存量为2～56亿吨;东海岛区域火山岩,理论矿化封存量虽然不大(1.5～35亿吨),但因其与周边工业排放源较近,具有较好的源汇匹配条件,具备CCS潜力。研究结果不仅对于优选封存CO₂火山岩储集区带提供重要依据,同时为未来开...  相似文献   

Genesis of the Maoling gold deposit in the Liaodong Peninsula: Constraints from a combined fluid inclusion,C-H-O-S-Pb-He-Ar isotopic and geochronological studies     

《地学前缘(英文版)》2022,13(4):101379

The large tonnage Maoling gold deposit (25 t @ 3.2 g/t) is located in the southwest Liaodong Peninsula, North China Craton. The deposit is hosted in the Paleoproterozoic metamorphic rocks. Four stages of mineralization were identified in the deposit: (stage I) quartz-arsenopyrite ± pyrite, (stage II) quartz-gold- arsenopyrite-pyrrhotite, (stage III) quartz-gold- polymetallic sulfide, and (stage IV) quartz-calcite-pyrrhotite. In this paper, we present fluid inclusion, C-H-O-S-Pb-He-Ar isotope data, zircon U-Pb, and gold-bearing sulfide (i.e. arsenopyrite and pyrrhotite) Rb-Sr age of the Maoling gold deposit to constrain its genesis and ore-forming mechanism. Three types of fluid inclusions were distinguished in quartz-bearing veins, including liquid-rich two-phase (WL type), gas-rich two-phase (GL type), and daughter mineral-bearing fluid inclusions (S type). Fluid inclusions data show that the homogenization at temperatures 197 to 372 °C for stage I, 126 to 319 °C for stage II, 119 to 189 °C for stage III, and 115 to 183 °C for stage IV, with corresponding salinities of 3.7 to 22.6 wt.%, 4.7 to 23.2 wt.%, 5.3 to 23.2 wt.%, and 1.7 to 14.9 wt.% NaCl equiv., respectively. Fluid boiling was the critical factor controlling the gold and associated sulfide precipitation at Maoling. Hydrogen and oxygen stable isotopic analyses for quartz yielded δ¹⁸O = ?5.0‰ to 9.8‰ and δ D = ?133.5‰ to ?77.0‰. Carbon stable isotopic analyses for calcite and ankerite yielded δ¹³C = ?2.3‰ to ?1.2‰ and O = 7.9‰ to 14.1‰. The C-H-O isotope data show that the ore-forming fluids were originated from magmatic water with meteoric water input during mineralization. Hydrothermal inclusions in arsenopyrite have ³He/⁴He ratios of 0.002 Ra to 0.054 Ra, and ⁴⁰Ar/³⁶Ar rations of 1225 to 3930, indicating that the ore-forming fluids were dominantly derived from crustal sources almost no mantle input. Sulfur isotopic values of Maoling fine-grained granite range from 6.‰1 to 9.8‰, with a mean of 7.7‰, δ³⁴S values of arsenopyrite from the mineralized phyllite (host rock) range from 8.9‰ to 10.6‰, with a mean of 10.0‰, by contrast, δ³⁴S values of sulfides from ore vary between 4.3‰ and 10.6‰, with a mean of 6.8‰, suggesting that sulfur was mainly originated from both the host rock and magma. Lead radioactive isotopic analyses for sulfides yielded ²⁰⁶Pb/²⁰⁴Pb = 15.830–17.103, ²⁰⁷Pb/²⁰⁴Pb = 13.397–15.548, ²⁰⁸Pb/²⁰⁴Pb = 35.478–36.683, and for Maoling fine-grained granite yielded ²⁰⁶Pb/²⁰⁴Pb = 18.757–19.053, ²⁰⁷Pb/²⁰⁴Pb = 15.596–15.612, and ²⁰⁸Pb/²⁰⁴Pb = 38.184–39.309, also suggesting that the ore-forming materials were mainly originated from the host rocks and magma. Zircon U-Pb dating demonstrates that the Maoling fine-grained granite was emplaced at 192.7 ± 1.8 Ma, and the host rock (mineralized phyllite) was emplaced at some time after 2065.0 ± 27.0 Ma. Arsenopyrite and pyrrhotite give Rb–Sr isochron age of 188.7 ± 4.5 Ma, indicating that both magmatism and mineralization occurred during the Early Jurassic. Geochronological and geochemical data, together with the regional geological history, indicate that Early Jurassic magmatism and mineralization of the Maoling gold deposit occurred during the subducting Paleo-Pacific Plate beneath Eurasia, and the Maoling gold deposit is of the intrusion-related gold deposit type.  相似文献   

辽南上达子堡金矿化区黄铁矿标型特征及意义     

李勇 《吉林地质》2015,(2)

上达子堡金矿化区主要出露古元古界辽河群盖县岩组二岩段,是金成矿物质的矿源层。黄铁矿标型特征指示目前区内的剥蚀水平相当于中上部,按黄铁矿垂直分带规律,{210}+{100}、{210}习性晶体向深部有可能逐渐增加,因此,本金矿化区深部含金量可能高于浅部。  相似文献   

华北克拉通辽东半岛新元古代早期基性岩浆活动:辉绿岩墙年代学和岩石地球化学证据     

韩吉龙  王清海 《世界地质》2015,34(4):886-902

华北克拉通辽东半岛地区广泛发育侵位于青白口系不同层位中的辉绿岩(脉)岩墙,对其锆石CL图像、U--Pb定年和岩石地球化学特征研究得出以下结论。锆石类型有三组:前两组锆石具有早期岩浆作用的锆石属性或结晶基底的变质锆石属性,反映该区辉绿岩岩浆上升过程受到了陆壳的混染;第三组锆石多呈自形--半自形短柱状,发育岩浆振荡生长环带结构或条带结构,具原生岩浆成因锆石属性,锆石SHRIMP U--Pb定年显示其加权平均年龄为832.3±8.1 Ma(n=14,MSWD=1.3),可以代表辉绿岩的结晶年龄。岩石地球化学组成,其具有低Si O_2、Al_2O_3,高TFe_2O_3、MgO、Ti O_2的特征,这与拉斑玄武岩特征相似;其稀土元素总量相对较低(ΣREE=71.88×10~-6~129.64×10~-6),且具弱的正Eu异常和铌亏损;略富集轻稀土元素(LREE)、富集大离子亲石元素(LILE:Rb、Pb、Ba)和高场强元素(HFSE:Th、U、Zr、Ti、Hf),而亏损高场强元素(HFSE:Nb、Sm、Gd、P)等;以上特征指示岩浆源区为富集型地幔,且上侵位就位过程中受陆壳不同程度的同化混染。本文对辉绿岩的研究显示华北克拉通辽东半岛地区在新元古代早期存在基性岩浆活动,结合前人对华北克拉通中元古代晚期—新元古代早期构造--岩浆事件的研究成果,进一步证明了华北克拉通东北部在新元古代早期经历了挤压汇聚后的伸展裂解演化过程,这与Rodinia超大陆聚合和裂解事件一致。  相似文献   

东南亚中南半岛锡矿带成矿特征     

陈喜峰  向运川  叶锦华  蔡纲  陈秀法  张振芳  李娜  张新元 《地质通报》2015,34(4):734-745

东南亚中南半岛位于特提斯成矿域和西环太平洋成矿域的相交地带,在印支—喜山期发生了多期次俯冲、碰撞造山成矿作用,发育多个与中酸性岩浆活动密切相关的锡(钨)岩浆热液成矿系统,形成了世界著名的东南亚中南半岛锡矿带。研究区自西向东依次可划分为抹谷—毛淡棉—德林达依—普吉锡矿带、景栋—清莱—清迈锡矿带和越北—长山—昆嵩—大叻锡矿带三大锡矿带及7个锡矿亚带,锡矿化花岗岩多为高度分异演化的重熔型铝过饱和花岗岩类,具有多硅、富碱、多挥发分、高钾、87Sr/86Sr初始比值高、Rb/Sr值高、相对明显富集Be、Bi、Cu、Mo、Pb、Sn、Y、Zn等元素的特点。锡矿体主要分布于S型花岗岩与围岩的内、外接触带。锡矿床成矿类型主要有热液脉型、矽卡岩型、锡石—硫化物型、云英岩型、伟晶岩—细晶岩型等。从海西晚期到喜山早期都有锡的成矿事件发生,以燕山期锡成矿作用为主,成矿构造环境主要为岛弧环境和大陆边缘碰撞造山环境。  相似文献   

Reconsideration of the age of blueschist facies metamorphism on the Seward Peninsula, Alaska, based on phengite ⁴⁰Ar/³⁹Ar results     

K. A. HANNULA  M. O. McWILLIAMS 《Journal of Metamorphic Geology》1995,13(1):125-139

Abstract ⁴⁰Ar/³⁹Ar step-heating and single-grain laser fusion ages from phengites from the polydeformed and polymetamorphosed blueschist-greenschist facies Nome Group fall into two groups. Samples from the upper part of the structural section that have experienced a relatively weak metamorphic and deformational post-blueschist facies overprint and one sample from the Cape Nome orthogneiss yield plateau ages of 116-125 Ma. More intensely overprinted samples yield hump-shaped spectra with minimum ages of 123 Ma and maximum ages of 334 Ma. Samples with hump-shaped spectra are derived from a greater structural depth than most samples with plateau ages. Unreasonably old maximum ages from some of the disturbed spectra suggest that the hump-shaped spectra result from the incorporation of excess ⁴⁰Ar. This interpretation conflicts with previous interpretations of similarly disturbed spectra from the Brooks Range, which have been argued to provide minimum ages for blueschist facies metamorphism. Since the maximum temperatures achieved by all samples were probably above the blocking temperature of Ar in phengite, the 116-125 Ma plateau ages are a minimum age for blueschist facies metamorphism on the Seward Peninsula, Alaska.  相似文献   

Processing and Inversion of Long-Period Surface-Wave Data Collected In the Iberian Peninsula   总被引：3，自引：0，他引：3  

J. Badal  V. Corchete  G. Payo  J. A. Canas  L. Pujades  F. J. Serón 《Geophysical Journal International》1990,100(2):193-202

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雷州半岛人工增雨研究与应用   总被引：3，自引：0，他引：3  

张羽  徐峰 《广东海洋大学学报》2006,26(1):57-61

通过对雷州半岛云水资源气候分布、云的宏观动力学和微观物理学、降水形成机制、人工增雨机制、冷云催化剂与暧云催化剂、播云方式与催化方法的研究和对外场试验的总结，表明：雷州半岛空中具有丰富的云水资源。有暖云降水机制、冷云降水机制和混态云“播种一供水”降水增强机制。人工增雨可进行静力催化和动力催化，使用的冷云催化剂为冰核和致冷剂，暖云催化剂为吸湿性巨核。适宜的人工增雨作业工具为飞机、火箭、地面蚶丙酮溶液燃烟发生器、气球携带AgI焰弹、增雨炮艇等。37高炮不适宜在雷州半岛使用。  相似文献   

乔治王岛菲尔德斯半岛的地温特征和岩石热物理性质          下载免费PDF全文

杨淑贞  张文仁  沈显杰 《极地研究》1989,1(3):43-51

1985—1986年度和1986—1987年度在菲尔德斯半岛对地面温度进行了测量,共获得129个数据,并对带回的样品进行了岩石热导率测量,共获得210个数据。本文在分析和归纳这些数据的基础上对菲尔德斯半岛的地温特征和岩石热物理性质进行了初步探讨。  相似文献   

Fluid evolution in the Rushan lode gold deposit of Jiaodong Peninsula, eastern China   总被引：2，自引：0，他引：2  

Fang-Fang Hu  Hong-Rui Fan  Ming-Guo Zhai  Cheng-Wei Jin 《Journal of Geochemical Exploration》2006,89(1-3):161

The Rushan gold deposit in the Jiaodong Peninsula is currently the largest lode gold in China. Gold occurs mainly in pyrite- and polymetallic sulfide–quartz vein/veinlet stockworks. Fluid inclusions in the deposit are divided into three main types, namely CO₂–H₂O, H₂O–CO₂ ± CH₄ and aqueous ones. Microthermometric data show that the pre-gold fluids were CO₂-dominant (X_CO2 up to 0.53), and the total homogenization temperatures fall in the range of 298377 °C. These fluids, modified by fluid/wallrock reactions, gradually evolved into fluids with less CO₂ (X_CO2 = 0.010.19) in the main ore-forming stage, and the total homogenization temperatures range from 170 to 324 °C. Hydrogen and oxygen stable isotope data suggest that ore-forming fluids were mixture of magmatic and meteoritic origin. Co-occurrence of gold and sulfides implies that gold was most likely transported in the form of gold–sulfide complexes. The wide distribution of CO₂ inclusions means that the pH variation during gold transportation was controlled by CO₂ buffering.  相似文献