Seasonal and photochemical changes of DOM in an acidified forest lake and its tributaries   总被引：1，自引：0，他引：1  

Petr?PorcalEmail author  Josef?Hejzlar  Ji?í?Kopá?ek 《Aquatic Sciences - Research Across Boundaries》2004,66(2):211-222

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The eastern continuation of the Cadomian orogen: U–Pb zircon evidence from Saxo-Thuringian granitoids in south-western Poland and the northern Czech Republic     

Żelaźniewicz  Andrzej  Dörr  Wolfgang  Bylina  Paweł  Franke  Wolfgang  Haack  Udo  Heinisch  Helmut  Schastok  Janina  Grandmontagne  Klaus  Kulicki  Cyprian 《International Journal of Earth Sciences》2004,93(5):773-781

We report U–Pb single zircon ages from three pre-Variscan granitoids in the NE part of the Bohemian Massif. The Platerówka granodiorite from the Lausitz-Izera Unit, the Polish Sudetes, has been dated at 533±9 Ma. The Bitouchov granite form the SW part of the South Krkonoe Unit, the Czech Sudetes, gave an age of 540+11/–10 Ma, and the Wdroe granodiorite in the Fore-Sudetic Block yielded 548±9 Ma. All these latest Vendian/Early Cambrian granitoids represent the post-tectonic expression of a late Proterozoic Cadomian orogenic cycle and demonstrate the eastward extent of the Cadomian basement into the Variscan orogen. Granodiorites of similar age have so far been reported from Brittany and especially from the Saxo-Thuringian Terrane to the NE and SW of the Elbe Fault Zone. We conclude that the Saxo-Thuringian Terrane extends across the Elbe and Sudetic Marginal Fault Zones into the Fore-Sudetic Block.  相似文献   

Low-grade metamorphic rocks from the Pulur complex,NE Turkey: implications for the pre-Liassic evolution of the Eastern Pontides     

Gültekin?Topuz  Rainer?AltherrEmail author  Muharrem?Sat?r  Winfried?H.?Schwarz 《International Journal of Earth Sciences》2004,93(1):72-91

In the Pulur complex (Sakarya Zone, Eastern Pontides, Turkey) a low-grade tectonometamorphic unit (Doankavak) is exposed in three tectonic windows beneath a complex medium-pressure high-temperature metamorphic unit of late Carboniferous age. The thrust plane between both units is transgressively covered by Liassic conglomerates. The Doankavak unit comprises a sequence of metabasites with MORB-type chemical compositions and phyllites, with subordinate calcareous phyllites, marbles, quarzofeldspathic schists and metacherts. This sequence is interpreted as a former accretionary complex related to the consumption of the Palaeotethys. Mineral parageneses in the metabasites allow for the distinction of two domains with slightly different peak metamorphic conditions, i.e. 375–425 °C/0.5–0.8 GPa (greenschist facies) and 400–470 °C/0.6–1.1 GPa (albite-epidote amphibolite facies). The age of metamorphism is constrained at ~ 260 Ma (early Late Permian) by two Rb-Sr mineral-whole rock ages (hornblende, phengite) and one ⁴⁰Ar/³⁹Ar single step total fusion age (phengite). In conjunction with previous data on other accretionary complexes in the Sakarya zone in Northern Turkey, the data presented in this study suggest a continuous subduction of the Palaeotethys at least from Early/Late Permian to Late Triassic and a discontinuous preservation of accretion complexes in both space and time.  相似文献   

腈菌唑在茶园土壤中的对映体选择性降解与碳同位素分馏     

刘冰月  张冬冬  何玲  朱优峰 《地学前缘》2019,26(6):13-18

运用对映体分馏分析(EFA)与单体同位素分析(CSIA)技术研究了三唑类杀菌剂腈菌唑在4种不同种植年限茶园土壤中的对映体选择性降解规律。腈菌唑的降解符合一级反应动力学方程,半衰期为28.4~70.5 d。4种茶园土壤中均表现为(+)腈菌唑优先降解,并均有碳同位素富集,表明发生了显著的微生物降解。腈菌唑在茶园土壤中的降解半衰期和对映体比在50年茶园土中最小,显著低于100年、20年和2年茶园土壤(P<0.05)。降解半衰期与砂粒含量显著相关(P<0.05),对映体选择性与粉粒含量显著相关(P<0.05)。运用Rayleigh方程计算各土壤中腈菌唑的碳同位素富集因子,并建立生物降解评估模型。应用两种方法评估生物降解所得结果与总降解率趋势相同。  相似文献   

南海北部东沙天然气水合物区浮游植物生物量和生产力粒级结构特征及其环境影响分析     

康建华  梁前勇  王建军  林毅力  何雪宝  夏真  郑新庆  王雨 《海洋学报(英文版)》2018,37(1):97-107

本文讨论了2013年5月南海东沙天然气水合物区浮游植物生物量和生产力粒级结构特征及其环境影响因素。结果表明，研究海域表现出典型的低营养盐、低叶绿素a、低生产力特征，浮游植物叶绿素a和初级生产力具有明显的次表层最大值现象。东沙海域生物量和初级生产力粒级结构差异性显著，从生物量和生产力贡献度来看，表现为微微型浮游植物> 微型浮游植物> 小型浮游植物。生物量的垂直分布结果表明，春季不同粒级类群浮游植物在真光层内的分布存在明显不同，比如小型浮游植物在真光层内分布较均匀；微型浮游植物则主要分布于近表层或真光层中部，而微微型浮游植物则主要分布于真光层中部和底部。微微型浮游植物在纬度较低的热带贫营养海区之所以能够占主导优势，最主要的原因是其极小的细胞体积和较大的表面积使其有利于营养竞争。相关性分析表明，南海东沙浮游植物各粒级生物量与温度、pH显著正相关，与硅酸盐、磷酸盐显著负相关；浮游植物各粒级生产力与温度显著正相关，与盐度、磷酸盐显著负相关。磷酸盐含量是影响东沙海域浮游植物粒级结构差异的重要因素之一，同时，光辐照度和水体的真光层深度对东沙天然气水合物区不同粒径浮游植物的垂直分布起着更为重要的调控作用。  相似文献   

Calibration of oxygen isotope fractionation and calcite-corundum thermometry in emery at Naxos,Greece     

Rachelle B. Turnier  Yaron Katzir  Kouki Kitajima  Ian J. Orland  Michael J. Spicuzza  John W. Valley 《Journal of Metamorphic Geology》2020,38(1):53-70

Corundum (Crn), including sapphire, occurs in emery pods surrounded by marble on the island of Naxos, Greece. The emery formed from bauxite deposited in karst that was metamorphosed to 400–700°C at 20–15 Ma. Many of these rocks initially appeared well suited for refractory accessory mineral (RAM) thermometry, which uses oxygen isotope fractionation between a RAM – corundum – and a modally dominant phase with faster diffusion of oxygen – calcite (Cc) – to determine peak metamorphic temperatures. However, previous attempts at oxygen isotope thermometry were confounded by highly variable fractionations (Δ¹⁸O) measured at mm-scale and the uncertain calibration of Δ¹⁸O(Cc-Crn) versus temperature. Secondary ion mass spectrometry (SIMS) permits in situ analysis of δ¹⁸O in corundum and calcite at the 10-μm scale in adjacent grains where textures suggest peak metamorphic equilibrium was attained. SIMS analyses of adjacent mineral pairs in eight rocks yield values of Δ(Cc-Crn) that systematically decrease from 7.2 to 2.9‰ at higher metamorphic grade. Pairing these data with independent temperature estimates from mineral isograds yields an empirical calibration of 1,000 lnα(Cc-Crn) = 2.72 ± 0.3 × 10⁶/T² (T in K). The new fractionations (2.7‰ at 1,000 K) are significantly smaller than those calculated from the modified increment method (6.5‰ at 1,000 K; Zheng, Geochimica et Cosmochimica Acta, 1991, 55:2299–2307; Zheng, Mineral Mag, 1994, 58A:1000–1001), which yield unreasonably high temperatures of 630 to 1,140°C when applied to the new Naxos data. The new calibration of Δ(Cc-Crn) can be combined with published fractionations to calculate A-factors for corundum versus a range of 14 other minerals. These new fractionation factors can be used for thermometry or to constrain the genesis of corundum. A compilation of gem corundum δ¹⁸O values shows that many igneous sapphires, including important deposits of basalt-associated sapphire, are mildly elevated in δ¹⁸O relative to the calculated range in equilibrium with mantle values (4.4–5.7‰) and formed from evolved magmas.  相似文献   

树轮纤维素中氧同位素温度意义     

陈拓  秦大河  任贾文 《冰川冻土》1999,(3)

树轮作为自然档案中的一种, 其同位素研究是较为新颖的领域文章比较系统地从树轮纤维素的提取、氧的来源、植物体内氧的分馏、与温度变化的关系等４ 个方面评述了树轮纤维素氧同位素组成的气候学意义已有的研究结果表明, 树轮纤维素氧同位素组成的变化是温度变化的良好载体, 但在定量恢复古温度变化时遇到了不少限制, 有待于进一步完善分馏模型  相似文献   

Controlling factors on the charging process of oil and gas in the eastern main sub-sag of the Baiyun Sag,Zhujiang River (Pearl River) Mouth Basin     

Cong Chen  Xiangtao Zhang  Guangrong Peng  Zulie Long  Baojun Liu  Xudong Wang  Puqiang Zhai  Bo Zhang 《海洋学报(英文版)》2023,42(3):189-200

The eastern main sub-sag (E-MSS) of the Baiyun Sag was the main zone for gas exploration in the deep-water area of the Zhujiang River (Pearl River) Mouth Basin at its early exploration stage, but the main goal of searching gas in this area was broken through by the successful exploration of the W3-2 and H34B volatile oil reservoirs, which provides a new insight for exploration of the Paleogene oil reservoirs in the E-MSS. Nevertheless, it is not clear on the distribution of “gas accumulated in the upper layer, oil accumulated in the lower layer” (Gas_upper-Oil_lower) under the high heat flow, different source-rock beds, multi-stages of oil and gas charge, and multi-fluid phases, and not yet a definite understanding of the genetic relationship and formation mechanism among volatile oil, light oil and condensate gas reservoirs, and the migration and sequential charge model of oil and gas. These puzzles directly lead to the lack of a clear direction for oil exploration and drilling zone in this area. In this work, the PVT fluid phase, the origin of crude oil and condensate, the secondary alteration of oil and gas reservoirs, the evolution sequence of oil and gas formation, the phase state of oil and gas migration, and the configuration of fault activity were analyzed, which established the migration and accumulation model of Gas_upper-Oil_lower co-controlled by source and heat, and fractionation controlled by facies in the E-MSS. Meanwhile, the fractionation evolution model among common black reservoirs, volatile reservoirs, condensate reservoirs and gas reservoirs is discussed, which proposed that the distribution pattern of Gas_upper-Oil_lower in the E-MSS is controlled by the generation attribute of oil and gas from source rocks, the difference of thermal evolution, and the fractionation controlled by phases after mixing the oil and gas. Overall, we suggest that residual oil reservoirs should be found in the lower strata of the discovered gas reservoirs in the oil-source fault and diapir-developed areas, while volatile oil reservoirs should be found in the deeper strata near the sag with no oil-source fault area.  相似文献   

苏北盐城凹陷天然气与凝析油的成因机制   总被引：3，自引：0，他引：3  

常象春  刘宝珺  张金亮  毛凤鸣 《海洋地质与第四纪地质》2004,24(4):95-100

盐城凹陷天然气中甲烷含量高,碳同位素具有正分布系列,主体具有高成熟腐泥型气特征,伴随产出的凝析油则体现出与本区湖相原油和海相原油既相似又相区别的特征。不同组分间存在成熟度差异,轻质组分反映高成熟,中等组分体现出未熟低熟,重质组分表现出成熟特征。母源分析对比表明天然气与凝析油主要源自古生界海相腐泥型源岩,混有泰州组少许贡献,造成组分差异和成熟度变化的重要原因是大量气体注入配以长期发育断裂引起的运移分馏和不同成熟度油气混合所致。  相似文献   

不同氮源对海洋微藻氮同位素分馏作用的影响   总被引：2，自引：2，他引：0  

俞志 明  Waser N A D  Harrison P J 《海洋与湖沼》2004,35(6):524-529

以海链藻(Thalassiosira pseudonana)为研究对象,分别考察了以硝酸盐、铵盐和尿素为氮源的氮同位素分馏作用。在建立相应理论模型基础上,分别计算出各个实验体系的ε值。结果表明,在藻类生长初期,δ^15N均较低,其δ^15N的积累主要发生在指数增长期,在稳定期达到最高,与氮源的初始δ^15N相同;不同氮源的氮同位素分馏作用也不相同,其中以铵盐最强,硝酸盐次之,尿素最弱。考虑到实际情况下氮化合物并非单一存在,作者还进一步考察了上述3种氮源混合后对其同位素分馏作用的影响,发现混合氮源体系的表观ε值介于单一氮源时的最大与最小ε值之间,该结果较好地解释了Montoya等(1991)在Chesapeak湾的现场实验结果。  相似文献