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31.
32.
Questions persist about interpreting isotope ratios of bound and mobile soil water pools, particularly relative to clay content and extraction conditions. Interactions between pools and resulting extracted water isotope composition are presumably related to soil texture, yet few studies have manipulated the bound pool to understand its influence on soil water processes. Using a series of drying and spiking experiments, we effectively labelled bound and mobile water pools in soils with varying clay content. Soils were first vacuum dried to remove residual water, which was then replaced with heavy isotope-enriched water prior to oven drying and spiking with heavy isotope-depleted water. Water was extracted via centrifugation or cryogenic vacuum distillation (at four temperatures) and analysed for oxygen and hydrogen isotope ratios via isotope ratio mass spectrometry. Water from centrifuged samples fell along a mixing line between the two added waters but was more enriched in heavy isotopes than the depleted label, demonstrating that despite oven drying, a residual pool remains and mixes with the mobile water. Soils with higher clay + silt content appeared to have a larger bound pool. Water from vacuum distillation samples have a significant temperature effect, with high temperature extractions yielding progressively more heavy isotope-enriched values, suggesting that Rayleigh fractionation occurred at low temperatures in the vacuum line. By distinctly labelling bound and mobile soil water pools, we detected interactions between the two that were dependent on soil texture. Although neither extraction method appeared to completely extract the combined bound and mobile (total water) pool, centrifugation and high temperature cryogenic vacuum distillations were comparable for both δ2H and δ18O of soil water isotope ratios.  相似文献   
33.
东昆仑祁漫塔格山地区夏日哈木镍矿床矿物学特征   总被引:3,自引:0,他引:3  
青海夏日哈木是近年来新发现的超大型镍矿床,大地构造位置处于东昆仑造山带之东昆中花岗—变质杂岩带的隆起区,成矿与镁铁质—超镁铁质小侵入体有关,属岩浆深部熔离贯入型。矿体呈透镜状、似层状,主要产于辉石岩、橄辉岩和苏长岩中;矿石为块状、准块状、海绵陨铁状、浸染状、细脉状和斑杂状构造,粒状结构、交代结构和固溶体分离结构等。矿石金属矿物主要为磁黄铁矿、镍黄铁矿和黄铜矿,含少量和微量紫硫镍矿、马基诺矿、铬铁矿、磁铁矿、黄铁矿、闪锌矿、辉铋矿、钛铁矿和自然铋等;脉石矿物主要有斜方辉石、橄榄石、普通辉石、基性斜长石、镁铁闪石、直闪石、滑石、蛇纹石等。文中对夏日哈木和金川我国两个超大型镍矿的主要地质特征作了对比;与世界上主要同类型硫化物铜镍矿床相比较,夏日哈木镍矿具有不少独特的特征,如其成岩成矿时代相对较年轻,矿石中铜的品位较低、亏损铂族元素等。  相似文献   
34.
点苍山-哀牢山变质杂岩带中北段嘎洒地区出露了多种典型的变沉积岩,其中夕线石榴黑云二长片麻岩和二云母片岩保存多期/多阶段矿物相转变特征,本文通过岩相学和矿物化学的综合分析,并结合传统矿物对温压计的估算结果,限定上述典型变沉积岩峰期角闪-麻粒岩相(M1)阶段、近等温减压-高温剪切变形阶段(M2)和晚期退变质(M3)阶段的矿物组合及变质温压条件。峰期角闪-麻粒岩相(M1)阶段的矿物组合为:石榴石(Grt)+板柱状夕线石(Sil1)+黑云母(Bt1)+钾长石(Kfs)+斜长石(Pl)+石英(Qtz)+钛铁矿(Ilm),变质温度压力条件为t=690~750℃,p=690~810 MPa;近等温减压-高温剪切变形阶段(M2)阶段,稳定矿物组合为:Grt+Sil2+Bt2+Kfs+Pl+Qtz+Ilm,黑云母在强烈走滑剪切作用下发生脱水熔融反应:2 Bt→Sil+6(Mg,Fe)O+K_2O+5 Qtz+2 H_2O,石榴石、黑云母和夕线石等受到剪切变形影响而发生强烈定向,形成的温度压力条件为t=650~720℃,p=450~630 MPa;晚期退变质阶段(M_3)的稳定矿物组合为:Qtz+Bt+Ms+Pl,退变的温度压力条件为t=580~640℃,p=400~500MPa。其变质演化p-T轨迹样式具有近等温减压的顺时针型式,表明点苍山-哀牢山变质杂岩带曾经历了一次明显的俯冲-碰撞造山事件,峰期变质可达到角闪-麻粒岩相;在碰撞后的构造折返过程中,上述变质岩石发生强烈的高温剪切变形作用,并伴随着黑云母等含水矿物的脱水熔融。  相似文献   
35.
Understanding the undrained strength of fine-grained soils has been of interest to geotechnical researchers from many practical considerations. In several civil engineering applications, water content of soil is quite high being near or above the liquid limit of soils, and understanding the factors responsible for imparting the strength of soil at high water contents is of great significance. Recently, it has been reported in the literature that the shear strength of soils at these limiting water contents has significant variation. However, the reasons and the factors that probably influence for this variation have not been reported in the literature. This experimental investigation is an attempt in the direction of understanding the reasons for the variation in the undrained strength at higher limiting water content, namely liquid limit considering the various influencing factors like clay mineralogy and fine-sand content present in soil used for determining liquid limit. The results from this study are quite revealing and have been explained based on the mechanisms controlling the undrained strength at liquid limit.  相似文献   
36.
王凯凯  刘传朋  邓俊  梁成  刘同 《地球学报》2021,42(6):771-784
基性-超基性岩脉群通常形成于伸展构造背景,是示踪地幔源特征以及大陆和超大陆破裂的重要标志.鲁西地区角闪石岩为研究古元古代岩浆源和构造演化提供了一个窗口.本文对鲁西地区角闪石岩进行了岩相学、全岩地球化学及角闪石、黑云母电子探针原位分析.角闪石岩具板内构造环境,来自富集地幔.通过角闪石、黑云母成因分析,均具有幔源成因,角闪石结晶温度为702~781℃;结晶压力为29.8~228.8 MPa,结晶深度1~7.5 km,结晶时氧逸度变化范围在NNO+2.68到NNO+3.35之间.结合本次获得角闪石岩磷灰石U-Pb年龄为(1817±35)Ma,认为鲁西地区(1817±35)Ma处于板内拉伸环境,存在幔源岩浆上侵,已进入大陆裂解阶段.  相似文献   
37.
东秦岭商丹地区蛇绿岩中的角闪石研究   总被引:1,自引:0,他引:1  
东秦岭蛇绿岩主要分布在北秦岭南缘、商丹断裂带以北的狭窄地带,断续逶迤呈带状作近东西向展布。分布于商丹地区的蛇绿岩是东秦岭蛇绿岩带的重要组成部分并具有代表性。 本文着重论述了商丹地区蛇绿岩中广泛分布的主要造岩矿物之一,角闪石的主要特征组份、微量元素、晶胞参数、阳离子占位度等成因矿物学特点。并据此说明了该蛇绿岩中的角闪石属于区域正变质的产物;形成的物质来源具有同源性,原岩为超镁铁质-镁铁质的岩浆岩和火山熔岩;形成的热力学条件基本相同,变质程度为绿帘角闪岩相或角闪岩相,变质温度为610℃左右,压力大于5×10~8Pa。 此外,根据商丹地区蛇绿岩中角闪石成因矿物学特征之相同性所提供的信息表明,东秦岭蛇绿岩带是华北和扬子两个板块俯冲、碰撞的构造边界变质带。  相似文献   
38.
Summary Intimate intergrowths of ferrotantalite and ferrotapiolite occur in a pegmatite in Spittal a.d. Drau, Carinthia. They are associated with muscovite, albite, smoky quartz, cassiterite, and microscopic uranmicrolite, zircon and uraninite. An assemblage of secondary uranium minerals is also present, generated by extensive alteration and leaching of the uranmicrolite and zircon. Textures of the ferrotantalite-ferrotapiolite intergrowths suggest considerable recrystallization that obliterated most of their primary features; neither coprecipitation nor exsolution can be recognized with certainty. Despite intersecting tielines indicating disequilibrium, the ferrotantalite and ferrotapiolite compositions show very restricted ranges (Mn/(Mn + Fe) 0.08–0.11, Ta/(Ta + Nb) 0.53–0.57 for ferrotantalite, and 0.01–0.04, 0.84–0.89 for ferrotapiolite, respectively), particularly in comparison with compositions from other localities featuring primary textures. A degree of compositional equilibration could have been attained during recrystallization. This process may also explain the high level of structural order characterizing both minerals; they are considerably disordered in other localities. Extensive deformation typical of pegmatites in the southern Ostalpen in general, and specifically of the Spittal pegmatite, is probably responsible for the recrystallization phenomena in the Ta, Nb, Sn-bearing mineral assemblage.
Eine Ferrotantalit-Ferrotapiolit Verwachsung von Spittal a.d. Drau, Kärnten, österreich
Zusammenfassung In einem Pegmatit von Spittal a.d. Drau, Kärnten, treten enge Verwachsungen von Ferrotantalit und Ferrotapiolit auf. Diese werden von Muskovit, Albit, Rauchquarz, Zinnstein sowie-in mikroskopischem Masstab-von Uranmikrolith und Zirkon begleitet. Die Textur der Verwachsungen lässt Rekristallisation erheblichen Ausmasses erkennen, die die primären Merkmale weitgehend auslöscht. Weder eine gemeinsame Auskristallisation der beiden Mineralphasen noch eine Bildung durch Entmischung kann mit Sicherheit erkannt werden. Trotz einander kreuzender Verbindungslinien, die einen Hinweis auf Ungleichgewicht darstellen, zeigen die Zusammensetzungen des Ferrotantalits und des Ferrotapiolits lediglich geringe Schwankungsbreiten: Mn/(Mn + Fe) 0,08–0,11, Ta/(Ta + Nb) 0,53–0,57 für den Ferrotantalit beziehungsweise 0,01–0,04 und 0,84–0,89 für den Ferrotapiolit. Dies gilt insbesondere für den Vergleich mit Zusammensetzungen solcher Mineralphasen mit jenen von Fundarten, die primäre Verwachsungstrukturen aufweisen. Bis zu einem gewissen Ausmass ist diese homogene Zusammensetzung möglicherweise auf die Rekristallisation zurück zuführen. Diese Rekristallisation könnte auch den hohen strukturellen Ordnungsgrad der beiden Mineralphasen erklären. An anderen Fundorten zeigen diese Minerale strukturell merklich geringeren Ordnungsgrad. Intensive metamorphe überprägung, wie sie für die Pegmatite in den südlichen Ostalpen und insbesondere für jenen von Spittal typisch sind, kann wahrscheinlich als Ursache der Rekristallisationsphänomene der Ta-Nb-Sn Mineralparagenese angenommen werden.
  相似文献   
39.
本文从超高压变质作用的矿物学、P-T-t轨迹和超高压地体抬升、保存机制三个方面总结了近年来超高压变质作用研究所取得的重要进展和存在的问题。超高压变质作用的矿物学研究正在向深入发展,其P-T-t轨迹具有三种成因类型。而其超高压地体的抬升、保存机制则是争论的焦点,其中增生楔模式(Platt,1987)和连续俯冲─仰冲机制较好地解释了抬升过程,但也存在一些问题需进一步研究。  相似文献   
40.
Results of the first detailed study of the climate proxy record in the loess-palaeosol sequence at Xining-one of the few palaeoclimate sites in the currently arid western Loess Plateau of China-illustrate the importance of making many types of rock-magnetic measurements other than susceptibility. A multiparameter approach yielded confirmation that here, as elsewhere in the Loess Plateau, the susceptibility enhancement in palaeosols was caused primarily by ultrafine magnetite and maghaemite. Nevertheless, magnetic enhancement was caused not exclusively by changes in relative grain size, but also by variations in concentration and mineralogy of the magnetic fraction.
The effects of concentration variations were removed through normalization of susceptibility and anhysteretic remanence with saturation magnetization and saturation remanence, respectively. the resulting signal was ascribed more confidently to variation in magnetic grain size, which in turn was interpreted as a better proxy of pedogenesis than simple susceptibility. Variations in magnetic mineralogy were also determined to constrain interpretations further. the data were then used to discuss climate history at Xining. Finally, results from Xining were compared with other western sites and contrasted with eastern sites.
In summary: (1) data is presented from a new Loess Plateau site which also appears to yield a global climate signal; (2) a demonstration is made of a more rock-magnetically robust way to separate concentration, composition and grain-size controls on susceptibility and other magnetic parameters; and (3) models are provided for inter-regional comparisons of palaeoclimate proxy records.  相似文献   
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