Astrophysical molecules of AlH and CaH: RKR potential and dissociation energies     

B. Narasimhamurthy  N. Rajamanickam 《Journal of Astrophysics and Astronomy》1983,4(1):53-58

The true potential energy curves for the electronic ground states of astrophysically important AlH and CaH molecules are constructed by the Rydberg-Klein-Rees method. Empirical potential functions, of three-parameters by Lippincott, of five-parameters by Hulburt and Hirsch-felder and, of electronegativity by Szöke and Baitz, are examined for the adequacy to represent the true curve. From the best-fitting function, the dissociation energiesD ₀ ⁰ of AlH and CaH molecules are estimated to be 2.99 ± 0.08 and 2.72 ± 0.06 eV respectively. The force constants indicate that these values are of correct magnitude.  相似文献   

火试金法测定铜精矿中金含量结果的不确定度评定   总被引：2，自引：0，他引：2  

江水英  肖化云  吴声东  吴波  秦云和 《岩矿测试》2008,27(4):299-301

对火试金法测定铜精矿中金含量的结果进行不确定度评定。分析了铜精矿样品称量、铜精矿样品的不均匀性和配料处理,以及金粒称量等因素对金含量测量结果不确定度的影响,并得出火试金法测量铜精矿中金含量的扩展不确定度。  相似文献   

Gouging abrasion test for rock abrasiveness testing     

V.A. Golovanevskiy  R.A. Bearman 《International Journal of Mineral Processing》2008

Wear parts of many mineral processing and mining equipment are often subjected to high stress loads applied at high speeds and at varying angles of incidence, where the prevalent mode of wear is high-stress gouging/sliding impact abrasion. Examples include crusher liners, wear liners in hoppers and chutes, picks on roadheaders, discs on tunnel boring machines and ground engaging tools. Abrasion under these conditions is characterised by a high material removal rate and thus has a direct bearing on wear rates and service life of the equipment concerned. However, at present there appears to be no method for rock abrasiveness assessment under these conditions. This paper describes a new Gouging Abrasion method and apparatus for testing abrasivity of rocks under high-stress gouging/sliding impact wear. A Gouging Abrasion Index (Gi) is introduced, which can be used for prediction and assessment of component life expectancy and efficiency of mineral processing and materials handling equipment. Experimental data from Gouging Abrasion testing of numerous Australian rock types are presented. It is suggested that the results of Gi testing can be used for wear rate predictions for a variety of mineral processing and materials handling equipment working under high-stress gouging/sliding impact abrasion conditions.  相似文献   

沉积盆地有机质自由基热演化特征及其作为古温标的探索   总被引：1，自引：0，他引：1  

徐二社  邱楠生  秦建中  郑伦举 《地质学报》2008,82(3):413-419

恢复沉积盆地热历史的方法主要有古地温指标法和动力学模拟法两类.古温标法中最常用的为有机质成熟度和矿物裂变径迹,动力学模拟法中最常用的是盆地的拉张模型和挤压模型.本文针对Ⅰ型有机质自由基浓度作为沉积盆地古温标进行了探索研究.分析了自然演化系列Ⅰ型有机质的自由基的热演化特征;根据自然演化系列的Ⅰ型有机质自由基浓度及时间-温度指数(TTI)数据,对热模拟实验下的Ⅰ型有机质自由基浓度及时间-温度指数(TTI)值进行校正,由校正后的数据初步建立了Ⅰ型有机质的自由基浓度(Ng)与时间-温度指数(TTI)的定量模型.  相似文献   

海相碳酸盐岩层系不整合量化研究及其意义——以四川盆地北部二叠系为例   总被引：2，自引：1，他引：1  

李儒峰  郭彤楼  汤良杰  陈国飞 《地质学报》2008,82(3):407-412

本文以四川盆地北部二叠系为例,将层序地层分析和沉积盆地波动过程分析相结合,提出了运用沉积波动过程分析研究沉积记录不完整性的量化方法,该方法可以相对准确地定量描述盆地形成演化过程中的升降运动,恢复无地层"记录"中的沉积-剥蚀过程,进而定量分析盆地的沉积-剥蚀过程、计算沉积间断(不整合)内的地层剥蚀量、认识其时空分布规律.同时,通过实际钻井及"人工井"的波动过程分析,结合地震剖面解释成果,可以作出主要不整合的空间分布图、各层位的剥蚀厚度图和原始厚度图、各期构造的剥蚀量分布图等重要基础图件,为盆地进一步系统分析及盆地模拟打好基础,结合沉积相研究及构造样式分析还可分析盆地沉积中心、生油层、盖层、储层等在时空中的变化规律.由于沉积盆地的升降波动过程直接影响着盆地的埋藏史、热史和生、排烃史,因此通过沉积波动过程的系统分析不仅能正确建立盆地演化的地质模型,还可以正确认识油气形成与分布规律,有效指导油气勘探.  相似文献   

Delineation of groundwater protection zones by the backward particle tracking method: theoretical background and GIS-based stochastic analysis   总被引：1，自引：0，他引：1  

Konstadinos N. Moutsopoulos  Alexandra Gemitzi  Vassilios A. Tsihrintzis 《Environmental Geology》2008,54(5):1081-1090

The backward particle tracking method, an effective and powerful tool that can be used to delineate groundwater protection zones, is presented. The theoretical background and insights on the applicability of this method are provided. Moreover, the present work enriches the backward particle tracking method with an uncertainty analysis concerning the porosity values, applying a Monte Carlo (MC) approach, coupled with the use of geographical information systems (GIS). As an application example, a wellfield in the Komotini area, Greece, is investigated. The present study may serve as a potential guideline for wellfield delineation, particularly in areas like Greece where lack of data related to the hydrogeological system is often a problem.  相似文献   

Distribution of Cd,Pb, Zn and Cu and their chemical speciations in soils from a peri-smelter area in northeast China   总被引：2，自引：0，他引：2  

Ping Du  Nandong Xue  Li Liu  Fasheng Li 《Environmental Geology》2008,55(1):205-213

An exploratory study on soil contamination of heavy metals was carried out surrounding Huludao zinc smelter in Liaoning province, China. The distribution of total heavy metals and their chemical speciations were investigated. The correlations between heavy metal speciations and soil pH values in corresponding sites were also analyzed. In general, Cd, Zn, Pb, Cu and As presented a significant contamination in the area near the smelter, comparied with Environmental Quality Standards for Soils in China. The geoaccumulation index showed the degree of contamination: Cd > Zn > Pb > Cu > As. There was no obvious pollution of Cr and Ni in the studied area. The speciation analysis showed that the dominant fraction of Cd and Zn was the acid soluble fraction, and the second was the residual fraction. Pb was mostly associated with the residual fraction, which constituted more than 50% of total concentration in all samples. Cu in residual fraction accounted for a high percentage (40–80%) of total concentration, and the proportion of Cu in the oxidizable fraction is higher than that of other metals. The distribution pattern of Pb and Zn was obviously affected by soil pH. It seemed that Pb and Zn content in acid solution fraction increased with increasing soil pH values, while Cd content in acid soluble fraction accounted for more proportion in neutral and alkaline groups than acidic one. The fraction distribution patterns of Cu in three pH groups were very similar and independent of soil pH values. And the residual fraction of Cu took a predominant part (50%) of the total content.  相似文献   

The double solid reactant method: II. An application to the shallow groundwaters of the Porto Plain,Vulcano Island (Italy)     

Matteo Lelli  Roberto Cioni  Luigi Marini 《Environmental Geology》2008,56(1):139-158

This paper presents an example of application of the double solid reactant method (DSRM) of Accornero and Marini (Environmental Geology, 2007a), an effective way for modeling the fate of several dissolved trace elements during water–rock interaction. The EQ3/6 software package was used for simulating the irreversible water–rock mass transfer accompanying the generation of the groundwaters of the Porto Plain shallow aquifer, starting from a degassed diluted crateric steam condensate. Reaction path modeling was performed in reaction progress mode and under closed-system conditions. The simulations assumed: (1) bulk dissolution (i.e., without any constraint on the kinetics of dissolution/precipitation reactions) of a single solid phase, a leucite-latitic glass, and (2) precipitation of amorphous silica, barite, alunite, jarosite, anhydrite, kaolinite, a solid mixture of smectites, fluorite, a solid mixture of hydroxides, illite-K, a solid mixture of saponites, a solid mixture of trigonal carbonates and a solid mixture of orthorhombic carbonates. Analytical concentrations of major chemical elements and several trace elements (Cr, Mn, Fe, Ni, Cu, Zn, As, Sr and Ba) in groundwaters were satisfactorily reproduced. In addition to these simulations, similar runs for a rhyolite, a latite and a trachyte permitted to calculate major oxide contents for the authigenic paragenesis which are comparable, to a first approximation, with the corresponding data measured for local altered rocks belonging to the silicic, advanced argillic and intermediate argillic alteration facies. The important role played by both the solid mixture of trigonal carbonates as sequestrator of Mn, Zn, Cu and Ni and the solid mixture of orthorhombic carbonates as scavenger of Sr and Ba is emphasized.

Luigi Marini (Corresponding author)Email:

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A new method of estimating the ratio between in situ rock stresses and tectonics based on empirical and probabilistic analyses   总被引：1，自引：0，他引：1  

L.I. Gonzlez de Vallejo  T. Hijazo 《Engineering Geology》2008,101(3-4):185-194

This paper describes a new procedure for assessing the ratio between in situ stresses in rock masses by means of K (K = σ_H / σ_v, being σ_H and σ_v principal stress) and tectonics for purposes of engineering geology and rock mechanics. The method combines the use of the logic decision tree and the empirical relationship between the Tectonic Stress Index, TSI, and a series of K in situ values obtained from an extensive database. The decision tree considers geological and geophysical factors affecting stress magnitudes both on the regional and local scale. The TSI index is defined by geological and geomechanical parameters. The method proposed provides an assessment of the magnitude of horizontal stresses of tectonic origin. Results for several regions of Europe are presented and the possible applications of the procedure are discussed.  相似文献   

Mapping ambivalence: Exploring the geographies of community change and rails-to-trails development using photo-based Q method and PPGIS   总被引：5，自引：0，他引：5  

Timothy Hawthorne  John Krygier 《Geoforum》2008,39(2):1058-1078

As the literature on trail development suggests, recreational trail projects can generate conflicts and controversies, particularly when built on abandoned rail corridors through developed areas. These conflicts are often understood as “not in my back yard” (NIMBY) reactions, suggesting a spatial proximity to conflict which increases as one draws closer to the proposed trail. This research seeks to understand local residents’ perceptions and reactions to recreational trail development in the City of Delaware (Ohio, USA). It addresses two spatially infused questions: Does the potential for conflict related to trail development increase as people live closer to a potential trail (the NIMBY factor)? Can important qualitative factors about favorable and unfavorable land uses including potential recreational trail sites be defined using a participatory methodology and then represented in GIS? The study used a mixed-method approach to collect and analyze qualitative data from a group of local residents. Each participant was interviewed and asked to sort 19 pictures related to trail development. After each of the sorts, participants were asked to explain why they ranked the pictures the way they did. Results of the picture sorts were then analyzed using Q method and mapped with GIS. The results show that spatial proximity matters in the context of trail development and potential NIMBY reactions to trails. Significant differences were found in the picture sorts that reveal the importance of proximity and location, although in a manner contrary to the assumptions in the writings on rails-to-trails. Through combining qualitative methods, Q analysis and PPGIS analysis, the research shows that qualitative place-based studies are capable of generating insights about the complexities of situated geographic change such as recreational trail development.  相似文献