库伦滴定法测定岩矿试样中氯     

候磊  金秉慧 《岩矿测试》1990,9(3):178-183

本文提出用电生Ag~ 库伦滴定岩矿样品中痕量氯的方法。经对电解液组成、不同电解电流下的电流效率、干扰元素的分离等进行了实验研究,确定了最佳分析条件。实验结果表明:当测定氯量≥100μg时,回收率达99.5～99.9％,相对标准偏差0.33～0.03％;测定氯量≥10μg,回收率为98.6～98.9％;相对标准偏差2.5～0.58%;方法准确,重现性好,操作简便。用岩石和土壤一级标准物质检验及参加建材一级标准物质协作定值,结果满意。  相似文献   

山地冰川与湖泊萎缩所指示的亚洲中部气候干暖化趋势与未来展望   总被引：67，自引：1，他引：67  

施雅风 《地理学报》1990,(1)

天山北坡乌鲁木齐河1号冰川与土尤克苏冰川物质平衡观察表示80年代比以前出现大的亏损。青海湖与伊赛克湖在近百年一直处于萎缩状态。从小冰期最盛时以来,乌鲁木齐河谷中冰川面积已缩去44％。上述及其他冰川与湖泊变化证据清楚地指示本世纪气候干暖化趋势增强了,并可能延续到下世纪初。但如由于CO_2及其他痕量气体增加所致的温室效应使下世纪重现全新世早、中期那样的高温,则亚洲中部有可能转为潮湿。  相似文献   

配位滴定法同时测定金属离子浓度的研究     

乔延江  王英华  刘友谊 《吉林大学学报(地球科学版)》1994,(3)

将多元校正分析法应用于配位滴定中，以ＥＤＴＡ为滴定剂，玻璃电极为指示电极，饱和甘汞电极为参比电极。依据电位滴定原理，对混合三组分：Ｃｕ￣（２＋）、Ｃｄ￣（２＋）、Ｚｎ￣（２＋）、及Ｃｕ￣（２＋）、ＣＯ￣（２＋）、Ｎｉ￣（２＋）进行测定，各金属离子之间的△ｌｏｇＫ在０．０４～２．３４之间，计算误差一般小于土１０％。  相似文献   

Depositional environment and sedimentary of the basinal sediments in the Eibiswalder Bucht (Radl Formation and Lower Eibiswald Beds), Miocene Western Styrian Basin,Austria     

K. Stingl 《International Journal of Earth Sciences》1994,83(4):811-821

The Eibiswald Bucht is a small subbasin of the Western Styrian Basin exposing sediments of Lower Miocene age. In the past the entire sequence exposed in the Eibiswalder Bucht has been interpreted as being of fluvial/lacustrine origin; here, results are presented of detailed sedimentological investigations that lead to a revision of this concept. The lowermost siliciclastic sedimentary unit of the Eibiswalder Bucht sequence is the Radl Formation. It is overlain by the Eibiswald Beds, which are subdivided into the Lower, Middle and Upper Eibiswald Beds. The Radl Formation and the Lower Eibiswald Beds are interpreted as a fan delta complex deposited along NNW-SSE striking faults. Based on the sedimentary facies this fan delta can be subdivided into a subaerial alluvial fan facies group, a proximal delta facies group and a distal delta/prodelta facies group. The Radl Formation comprises the alluvial fan and proximal delta facies groups, the Lower Eibiswald Beds the distal delta/prodelta facies group. The alluvial fan and the proximal delta consist of diverse deposits of gravelly flows. The distal delta/prodelta consists of wave-reworked, bioturbated, low density turbidites intercalated with minor gravelly mass flows. The prodelta can be regarded as as the basin facies of the small and shallow Eibiswalder Bucht, where marine conditions prevailed. The basin was probably in part connected with the Eastern Styrian Basin, the contemporary depositional environment of the Styrian Schlier (mainly turbiditic marine offshore sediments in the Eastern Styrian Basin). Analysis of the clast composition, in conjunction with the paleotransport direction of the coarse delta mass flows of the Radl Formation, shows that the source rocks were exclusively crystalline rocks ranging from greenschists to eclogites.  相似文献   

Determination of nitrophenols,diaminotoluenes, and chloroaromatics in ammunition wastewater     

P. Mußmann  R. Eisert  K. Levsen  G. Wünsch 《洁净——土壤、空气、水》1995,23(1):13-19

Methods for the determination of three compound classes, i. e. diaminotoluenes, nitrophenols, and chloroaromatics in groundwater of a former ammunition plant are reported. Diaminotoluenes were extracted by discontinuous liquid/liquid-, nitrophenols by continuous liquid/liquid-extraction using dichloromethane, and chloroaromatics by solid-phase extraction. These compound classes may be analyzed by gas chromatography (GC) or gas chromatography coupled to mass spectrometry (GC/MS) without derivatization or after derivatization with N-methyl-bis(trifluoroacetamide) (MBTFA) or heptafluorobutyric anhydride (HFBA) in the case of diaminotoluenes and HFBA or acetic anhydride in the case of nitrophenols. An atomic emission detector (AED) coupled to a gas chromatograph may be employed for the analysis of chloroaromatics. High selectivity can be achieved using the characteristic wavelengths of chlorine. A variety of these compounds were identified and quantified in a groundwater sample from the former ammunition plant Elsnig (Saxony, Germany). Concentrations were in the lower ppb range. Thus, dichlorobenzenes which may have been used as substituents at the end of World War II could be identified in groundwater samples at this site.  相似文献   

Mass movements in cave sediments: investigation of a ∼40,000-year-old guano mudflow inside the entrance of the Great Cave of Niah, Sarawak, Borneo     

A. P. Dykes 《Landslides》2007,4(3):279-290

The West Mouth of the Great Cave at Niah in Sarawak, northwest Borneo and the North Passage that leads to the West Mouth contain large deposits of guano. The main deposit, several metres thick in places, forms the sloping floor of the entire North Passage. A mass movement deposit identified in the West Mouth, having a volume of 600 m³, originated as a guano mudflow up the North Passage in the order of 40,000 years ago. This failure of the guano slope was investigated to determine whether particular conditions or events could be identified as the most likely causes. The physical, hydrological and geotechnical properties of samples of the material were determined so that the stability of the slope could be assessed. Stability analyses showed that shearing failure of the slope would require inputs of water to the slope in quantities for which no feasible explanation can be suggested. However, the properties of the guano are similar to those of loess, indicating a high susceptibility to ‘hydrocollapse’. Very shallow failure of the slope, possibly as several smaller mudflows, could therefore have occurred due to additional water in quantities that could realistically be supplied as rainwater spray, possibly with a seismic trigger. The climate must therefore have been wetter than it is at present. These findings have implications for the interpretation of sediment deposits in other relict caves.  相似文献   

Effective macroscopic transport parameters between parallel plates with constant concentration boundaries     

D.R. Webster  D.S. FeltonJ. Luo 《Advances in water resources》2007

A macroscopic transport model is developed, following the Taylor shear dispersion analysis procedure, for a 2D laminar shear flow between parallel plates possessing a constant specified concentration. This idealized geometry models flow with contaminant dissolution at pore-scale in a contaminant source zone and flow in a rock fracture with dissolving walls. We upscale a macroscopic transient transport model with effective transport coefficients of mean velocity, macroscopic dispersion, and first-order mass transfer rate. To validate the macroscopic model the mean concentration, covariance, and wall concentration gradient are compared to the results of numerical simulations of the advection–diffusion equation and the Graetz solution. Results indicate that in the presence of local-scale variations and constant concentration boundaries, the upscaled mean velocity and macrodispersion coefficient differ from those of the Taylor–Aris dispersion, and the mass transfer flux described by the first-order mass transfer model is larger than the diffusive mass flux from the constant wall. In addition, the upscaled first-order mass transfer coefficient in the macroscopic model depends only on the plate gap and diffusion coefficient. Therefore, the upscaled first-order mass transfer coefficient is independent of the mean velocity and travel distance, leading to a constant pore-scale Sherwood number of 12. By contrast, the effective Sherwood number determined by the diffusive mass flux is a function of the Peclet number for small Peclet number, and approaches a constant of 10.3 for large Peclet number.  相似文献   

Capillary pressure for the sand–CO₂–water system under various pressure conditions. Application to CO₂ sequestration     

W.-J. Plug  J. Bruining 《Advances in water resources》2007

Accurate modeling of storage of carbon dioxide (CO₂) in heterogeneous aquifers requires experiments of the capillary pressure as function of temperature and pressure. We present a method with which static drainage and imbibition capillary pressures can be measured continuously as a function of saturation at various temperature (T) and pressure (P) conditions. The measurements are carried out at (T, P) conditions of practical interest. Static conditions can be assumed as small injection rates are applied. The capillary pressure curves are obtained for the unconsolidated sand–distilled water–CO₂ system. The experimental results show a decrease of drainage and imbibition capillary pressure for increasing CO₂ pressures and pronounced dissolution rate effects for gaseous CO₂. Significant capillary pressure fluctuations and negative values during imbibition are observed at near critical conditions. The measurement procedure is validated by a numerical model that simulates the experiments.  相似文献   

黑龙江盘古-碧水韧性剪切带中段构造地球化学特征   总被引：3，自引：0，他引：3       下载免费PDF全文

李仰春  赵寒冬  韩伟民  李永秀  朱春艳 《地质科学》2001,36(2):144-151

盘古-碧水韧性剪切带中段糜棱岩的叠加强度和质量平衡分析表明:剪切带在变形过程中组分发生了显著的交换。糜棱岩类总体CaO、K₂O、SiO₂大量带入,TiO₂、MnO、FeO是带出的。随着糜棱岩化程度的提高,SiO₂、K₂O、MnO明显带入,CaO少量带出。以Al₂O₃守恒为限制条件,整个剪切带质量和体积增加了16.87%。大规模的物质带入带出发生在糜棱岩阶段。  相似文献   

质量平衡法——定量恢复新生代青藏高原造山作用   总被引：2，自引：0，他引：2  

向芳  王成善 《地球科学进展》2001,16(2):279-283

青藏高原的形成演化及其对东亚地形，水文分布，季风起源，全球气候变化，海洋化学组分改变等的影响，一直是全球地质学家关注的热点，然而由于定量研究方法的缺乏，一些关键性的问题一直悬而未决，质量平衡法的提出为解决这一困境提供了新思路，阐述了质量平衡法的原理，并以Metivier等对西藏高原地区，东亚，印度支那和印度板块地区的研究为例，介绍了质量平衡法的应用，同时对存在的问题进行了较为详细的讨论，为进一步研究指明了重点。  相似文献