Variation in element release rate from different mineral size fractions from the B horizon of a granitic podzol     

Mark E. Hodson 《Chemical Geology》2002,190(1-4):91-112

Far-from-equilibrium batch dissolution experiments were carried out on the 2000–500, 500–250, 250–53 and 53–2 μm size fractions of the mineral component of the B horizon of a granitic iron humus podzol after removal of organic matter and secondary precipitates. The different size fractions were mineralogically and chemically similar, the main minerals present being quartz, alkali and plagioclase feldspar, biotite and chlorite. Specific surface area increased with decreasing grain size. The measured element release rates decreased in the order 53–2>>>2000–500>500–250>250–53 μm. Surface area normalised element release rates from the 2000–500, 500–250 and 250–53 μm size fractions (0.6–77×10⁻¹⁴ mol/m²/s) were intermediate between literature reported surface area normalised dissolution rates for monomineralic powders of feldspar (0.1–0.01×10⁻¹⁴ mol/m²/s) and sheet silicates (100×10⁻¹⁴ mol/m²/s) dissolving under similar conditions. Element release rates from the 53–2 μm fraction (400–3000×10⁻¹⁴ mol/m²/s) were a factor of 4–30 larger than literature reported values for sheet silicates. The large element release rate of the 53–2 μm fraction means that, despite the small mass fraction of 53–2 μm sized particles present in the soil, dissolution of this fraction is the most important for element release into the soil. A theoretical model predicted similar (within a factor of <2) bulk element release rates for all the mineral powders if observed thicknesses of sheet silicate grains were used as input parameters. Decreasing element release rates with decreasing grain size were only predicted if the thickness of sheet silicates in the powders was held constant. A significantly larger release rate for the 53–2 μm fraction relative to the other size fractions was only predicted if either surface roughness was set several orders of magnitude higher for sheet silicates and several orders of magnitude lower for quartz and feldspars in the 53–2 μm fraction compared to the other size fractions or if the sheet silicate thickness input in the 53–2 μm fraction was set unrealistically low. It is therefore hypothesised that the reason for the unpredicted large release rate from the 52–3 μm size fraction is due to one or more of the following reasons: (1) the greater reactivity of the smaller particles due to surface free energy effects, (2) the lack of proportionality between the BET surface area used to normalise the release rates and the actual reactive surface area of the grains and, (3) the presence of traces quantities of reactive minerals which were undetected in the 53–2 μm fraction but were entirely absent in the coarser fractions.  相似文献   

矿产资源资产与市场优化配置     

郑锡泉 《江苏地质》2003,27(4):242-245

将土地资产的理论与经验引进矿产资源管理，探讨建立和完善社会主义矿产资源市场经济制造，指出实现矿产资源性资产的市场机制是资源优化配置的一种十分重要的手段。它能够通过各级政府规划或者指导对资源的形势研究，预测其供求、价格和竞争之间的相互作用和影响。推动资源的科学利用与有效保护，合理流动与分配，提高资源利用率，从而促进社会经济的可持续发展。探讨和创建矿产资源性资产与产权管理的新机制，其实质是采矿权人根据国家法律，按统一的技术规定、规程、标准和要求，对其占用的资源储量进行定期或不定期的检测，编制相应的动态报表、年度报告和统计报表。国家根据矿种类型，通过省市县建立不同层次的矿产资源储量数据库进行产权管理。政府的监督管理主要由矿产资源储量登记与统计及核查机制组成。  相似文献   

基于GIS技术的矿产资源信息系统   总被引：8，自引：3，他引：8  

蔡洪春  张春明  姜绍飞  陈为公  寇大明 《地质与资源》2003,12(2):111-114

地质资料基本上可以分为空间数据和属性数据两大类.它们是地学数据不可分割的两方面,客观上要求统一进行管理.采用地理信息系统技术,可以彻底解决两种类型数据统一管理问题.结合正在开展的辽宁省矿产资源勘查、开发与利用规划工作,论述了建立基于GIS技术的辽宁矿产资源信息系统实现数据可视化和空间模型分析的思路和实现方法.它为今后矿产资源管理工作实现全面科学化管理提供了现代化手段,也为制定行业发展规划以及进行生产决策提供了支持,进而促进地质找矿和矿产开发的工作部署朝思维可视化及思路多样化的方向发展.  相似文献   

青海东昆仑肯德可克金-有色金属矿床矿物特征研究   总被引：4，自引：0，他引：4  

王力  孙丰月  陈国华  李碧乐  迟效国 《世界地质》2003,22(1):50-56

肯德可克贵金属-有色金属矿床有多种元素达到工业要求，矿物组成复杂，本文在详细的光、薄片鉴定和电子探针分析的基础上，分析研究了该矿床的矿物组成特征，并根据成矿地质特征、矿物组合特点和矿物间的穿插关系，划分了成矿期次，进而确定该矿床为-多期成矿作用叠加的叠生型金-有色金属矿床。  相似文献   

中国金银矿产资源现状成矿环境及开发前景   总被引：5，自引：0，他引：5  

朱桂田 《矿产与地质》1997,(6):368-373

中国金银矿产具有类型齐全的共同特点，其资源和开发前景表现为金矿优于银矿。金矿成矿环境有利，成矿时代及资源分布广泛。但是，储量在１００吨以上的超大型矿床不多，富矿少，资源利用程度高，且浪费严重，存在重开发、轻勘查等问题。银矿虽然是世界上资源丰富的国家之一，但仍然是我国资源保证程度较低的矿种之一，也存在特大型矿床少、探明储量不足的问题。  相似文献   

Genesis and distribution of mineral waters as a consequence of recent lithospheric dynamics: the Rhenish Massif,Central Europe     

Franz May  Stephan Hoernes  Horst J. Neugebauer 《International Journal of Earth Sciences》1996,85(4):782-799

Three major, interdependent processes control the genesis and distribution of mineral and thermal waters in the Rhenish Massif, Central Europe: (a) Magmatic processes in the upper mantle provide most of the CO₂ to produce bicarbonate waters in shallow aquifers. (b) Extension of the brittle upper crust enables the ascent of sodium chloride waters. (c) Uplift and erosion shape the massif's relief, which determines the extent of flow systems and the distribution of thermal springs. The chemistry of mineral waters further depends on the aquifers' mineral composition. A comprehensive set of hydrological, chemical, tectonic and geophysical data on the Rhenish Massif has been compiled. It was used to classify the mineral waters and to map the spatial distribution of water properties. The composition of cuttings from several representative wells producing different water types shows that the hydrothermal alteration of the aquifer rocks consists mainly of kaolinization of chlorite and dissolution of feldspar. Numerical transport simulations favour two modes of groundwater flow: topography-driven flow and the pressure-driven ascent of basement brines along active faults. Thermal convection is less important.  相似文献   

Metamorphic evolution of oceanic gabbros: recrystallization from subsolidus to hydrothermal conditions in the MARK area (ODP Leg 153)     

L. Gaggero  L. Cortesogno 《Lithos》1997,40(2-4):105-131

The 117.38 m of gabbroic core drilled during the Ocean Drilling Program (ODP) Leg 153 at Sites 921 to 924 in the Mid-Atlantic Ridge (MAR) between 23 °N and the Kane Fracture Zone, exhibits a remarkable primary compositional heterogeneity, such as magmatic layering, intrusive contacts and late magmatic veining, which express a succession of magmatic events. Textural indicators suggest that the cooling of the crystal mush occurred in a dynamic environment, with infiltration of progressively evolved liquids. Magmatic features include random shape fabric and magmatic lamination; the subsequent deformational overprint occurred in subsolidus conditions. The ductile deformation, generally concentrated in discrete domains of the gabbro, is associated with continuous re-equilibration of the metamorphic assemblages of (1) olivine + clinopyroxene + orthopyroxene + plagioclase + ilmenite + Ti-magnetite, (2) olivine + clinopyroxene + plagioclase + ilmenite + Ti-magnetite + red hornblende. At lower temperatures brittle deformation prevails and subsequent fractures control the development of metamorphic assemblages: (3) clinopyroxene + plagioclase + red brown hornblende + Ti-magnetite + magnetite (?) + ilmenite, (4) plagioclase + brown hornblende + Ti-magnetite + magnetite + hematite + titanite ± Ti-oxide, (5) plagioclase + green hornblende + magnetite + titanite, (6) plagioclase + actinolite + chlorite + titanite + magnetite, (7) albite + actinolite + chlorite + prehnite ± epidote ± titanite and (8) albite + prehnite + chlorite ± smectite. Assemblages 1 to 8 express increasing water/rock ratios and decreasing degrees of recrystallization.

During the ductile phase, red hornblende is stable and its abundance increases with deformation intensity, possibly as an effect of the introduction of hydrous fluids. During the brittle phase, water diffusion controls the development of the fracture-filling mineral assemblages and re-equilibration of the adjacent rock; temperatures decrease further, as demonstrated by mineral zoning and incompletely re-equilibrated assemblages. The lowest temperatures correspond to the development of hydrothermal assemblages.

Compared with oceanic gabbros from fast-spreading transform environments, high-temperature ductile phases (granulite and amphibolite) are well developed, whereas brittle phases are widespread, as microcracks, prevalent on fracturing associated with discrete veins.  相似文献   

未定名矿物(Bi38CrO60)的矿物学研究   总被引：2，自引：0，他引：2  

周新春  袁周伟  贾小梅  王开崎  李广文  李成玉  刘良  舒桂明  徐平  翟明国 《黄金地质》2004,10(4):45-54

人工合成立方晶体Bi38CrO60在自然界首次发现于中国陕西省洛南县驾鹿金矿床中,暂称之为未定名矿物.其共生和伴生矿物有黄铁矿、自然金、碲金矿、含氧金矿物等.常呈不规则粒状集合体,偶见立方体微晶(粒径小于0.05 mm),棕黑色,金属光泽;HV=232.78 kg/mm2 ,HM=4.15;D=14.10(3)g/cm3,Dx=14.08(2)g/cm3,n=3.14(3).EPM8100探针分析Bi2O3为98.854%、CrO3为1.111%,合计99.965%,化学式为Bi38.009Cr0.995O60;CAMEBAX-SX51探针分析Bi2O3为98.862%,CrO3为1.112%,合计99.974%,化学式为Bi38.008Cr0.996O60.均可写为Bi38CrO60.X射线粉晶分析主要强度线d(I)(hkl)分别为0.321 5(100),(310);0.272 11(72),(321);0.171 45(40),(530);0.169 6(30),(600);0.165 1(30),(611);0.160 8(30),(620);0.294 11(25),(222);0.359 6(22),(220);0.217 1(20),(332);0.150 3(20),(631),等轴晶系,可能的空间群为Im3m;a=1.018 1(1)nm,c/a=1,晶胞体积v=1.055 29(1)nm3,z=1.1-Kp/Kc=0.019.Cr6 ,Bi3 ,O2-.未定名矿物和人工晶体的化学成分与X射线粉晶数据基本一致.  相似文献   

Tracing the protolith, UHP metamorphism, and exhumation ages of orthogneiss from the SW Sulu terrane (eastern China): SHRIMP U–Pb dating of mineral inclusion-bearing zircons     

Fulai Liu  Zhiqin Xu  Huaimin Xue 《Lithos》2004,78(4):411-429

Orthogneisses are the major country rocks hosting eclogites in the Sulu UHP terrane, eastern China. All of the analyzed orthogneiss cores from the main drilling hole of the Chinese Continental Scientific Drilling Project (CCSD-MH) have similar major and trace element compositions and a granite protolith. These rocks have relatively high LREE/HREE ratios, strong negative Eu anomalies (Eu/Eu*=0.20–0.39), and negative Ba anomalies (Ba/Ba*=0.25–0.64). Coesite and coesite-bearing UHP mineral assemblages are common inclusions in zircons separated from orthogneiss, paragneiss, amphibolite, and (retrograded) eclogite of the CCSD-MH. This suggests that the eclogite, together with its country rocks, experienced in situ ultrahigh-pressure (UHP) metamorphism. Laser Raman spectroscopy and cathodoluminescence (CL) images show that zircons from the orthogneisses are zoned and that they have distinct mineral inclusions in the different zones. Most zircons retain early magmatic cores with abundant low-pressure mineral inclusions, which are mantled with metamorphic zircon-containing inclusions of coesite and other UHP minerals. The outermost rims on these grains contain low-pressure mineral inclusions, such as quartz and albite. SHRIMP U–Pb dating of the zoned zircons gives three discrete and meaningful groups of ages: Proterozoic ages for the protolith, 227±2 Ma for the coesite-bearing mantles, and 209±3 Ma for the amphibolite facies retrograde rims. The widespread occurrence of UHP mineral inclusions in zircons from the Sulu metamorphic belt dated at about 227 Ma suggests that voluminous continental crust experienced late Triassic subduction to depths of at least 120 km and perhaps more than 200 km. Eighteen million years later, the terrane was rapidly exhumed to midcrustal levels, and the UHP rocks were overprinted by amphibolite facies metamorphism. The exhumation rate deduced from the zircon age data and previously obtained metamorphic P–T data is estimated to be 5.6–11.0 km/Ma. Such rapid exhumation of the Sulu UHP terrane may be due to the buoyancy forces produced by subduction of low-density continental material into the deep mantle.  相似文献   

The magmatic to hydrothermal transition and its bearing on ore-forming systems   总被引：1，自引：0，他引：1  

Werner E. Halter  James D. Webster 《Chemical Geology》2004,210(1-4):1-6

The exsolution of volatile phases from silicate magmas controls physical and chemical magma properties and influences large-scale geologic phenomena and processes having major societal and economic implications including the release of climate-altering gases to the atmosphere, the explosivity of volcanic eruptions, hydrothermal alteration, and the generation of magmatic–hydrothermal mineralization. These volatile phases exsolve from a wide variety of magmas and cover a very broad spectrum of compositions.

The transition from the orthomagmatic to the hydrothermal stages has important bearing on these fundamentally important geologic phenomena, and this report summarizes the published results of a dozen scientific investigations on the magmatic–hydrothermal transition as applied to volcanic eruption and magmatic–hydrothermal mineralization. These studies involve a variety of analytical and experimental methodologies, and many focus on fluid and melt inclusions from mineralized magmatic systems. A primary goal of each study is to better understand the role of magmatic volatiles and the importance of the magmatic–hydrothermal transition on these geologic processes.  相似文献