Surface chemical analysis in coal preparation research: complementary information from XPS and ToF-SIMS     

A. N. Buckley  R. N. Lamb 《International Journal of Coal Geology》1996,32(1-4)

The application of X-ray photoelectron spectroscopy (XPS) to coal surface characterisation for preparation research is described. Progress towards the acquisition of complementary surface chemical information by time-of-flight secondary ion mass spectrometry (ToF-SIMS) is also discussed. Surface-based beneficiation techniques such as flotation are assuming greater importance as the proportion of fines in raw coal increases due to the proliferation of high capacity mining methods. A necessary condition for the floatability of a coal particle is adequate hydrophobicity, and the degree of hydrophobicity of the flotation concentrate is one factor influencing the ease with which its dewatering can be affected. The hydrophobicity of a coal is very difficult to measure directly because of microporosity, and it is often necessary to deduce the degree of hydrophobicity from a knowledge of the surface chemistry. XPS is able to provide sufficient analytical data to allow relative levels of hydrophobicity to be estimated. In principle, ToF-SIMS should be able to supply additional information enabling refinement of such estimates; however, there are insufficient data at present to allow the ionic fragments detected to be related to specific functional groups at the coal surface.  相似文献   

矿物材料合成的直流弧光法   总被引：1，自引：0，他引：1  

陈素纯  傅慧芳 《大地构造与成矿学》1996,20(2):186-187

阐述了Ａｒ＋Ｈ２＋ＣＨ４气体体系中直流弧光放电过程，及其在金刚石膜等矿物材料合成中的应用。  相似文献   

湖北郧西六斗金矿床地质地球化学及矿床成因研究     

田云华 《华北地质》1997,(3)

郧西县六斗石英脉一破碎蚀变岩型金矿床，是鄂西北地区近年新发现的金矿床之一。通过对金矿床产出地质背景、控矿地质条件、围岩蚀变、矿石矿物、包体物理化学、同位素地球化学等的研究，阐述了六斗金矿床的形成机理和成矿物质来源。确定了该矿床成因类型为与韧性剪切变形变质作用有关的中一低温热液矿床。  相似文献   

山西铝土矿床成矿物质来源     

卢静文  彭晓蕾  徐丽杰 《吉林大学学报(地球科学版)》1997,(2)

山西铝土矿矿石中鲕、豆、碎屑等组构均具红土性质，结合化学成分特征、稀土元素特征、氧同住素特征、锆石等副矿物特征及含矿岩系底部岩层与下伏中奥陶纪灰岩关系和矿床分布与古陆、古岛的依赖关系等方面分析，铝土矿的成矿物质多是异源的，多为古陆上的铝硅酸盐岩红土风化产物，经流水以机械碎屑形式被搬运至海盆，沉积成矿  相似文献   

青海德令哈巴音郭勒河断裂带的新活动特征   总被引：3，自引：0，他引：3       下载免费PDF全文

刘小龙  袁道阳 《地震工程学报》2004,26(4):303-308

在青海德令哈巴音郭勒河北侧山前冲洪积扇上新发现了一条长约60km的逆断裂带,属于本区NNW-NWW向的柴达木盆地北缘活动断裂系内的一条次级挤压构造。断裂在地貌上表现为明显的挤压逆冲断层陡坎,晚更新世晚期以来的平均垂直滑动速率为0.41±0.27mm/a。探槽剖面确定了三次古地震事件,其年代分别为距今约32.7±1.45ka、15.54±1.32ka和3.2±0.33ka。  相似文献   

论江苏若干矿产资源开发利用的新方向     

尚培颖王浩  翁志华 《江苏地质》2004,28(3):183-187

江苏泥炭大多数为低有机质分解较强的低位泥炭，适于制作肥料或制成腐肥使用；江苏硅质原料丰富，一种以硅为主的化肥——硅肥正日益显示其重要性；湖泊淤泥具有颗粒微细、含砂量少、可塑性高、结合力强、干燥敏感性好和收缩率较大等特点，是生产空心砖的最佳原料；高家边组泥页岩和坟头组底部细粉砂质泥岩及泥质粉砂岩是良好的陶粒原料、砖瓦、陶瓷建材以及水泥用粘土质原料；利用矿泉水与茶的结合能够生产出高、中、低多效应的复合型新产品。上述尚未被利用或利用程度不够的矿产资源有着广泛的开发利用前景。  相似文献   

广西新型矿物材料发展方向初探     

李艺 《矿产与地质》2004,18(1):42-45

新材料是发展高新技术产业的基础。根据广西的矿产资源优势和在矿物材料方面的研究基础和技术力量，提出了加强工艺矿物学研究，大力发展广西新型矿物材料的研究开发方向，特别提出了超细改性矿物粉体材料、环保矿物材料、节能保温矿物材料、高技术陶瓷材料和合成矿物晶体材料等材料体系中的重点开发方向。  相似文献   

Analysis of Sediments and Soils by X-Ray Fluorescence Spectrometry Using Matrix Corrections Based on Fundamental Parameters   总被引：2，自引：0，他引：2  

Jacinta Enzweiler  Maria Aparecida Vendemiatto 《Geostandards and Geoanalytical Research》2004,28(1):103-112

Wavelength dispersive X-ray fluorescence spectrometry (WD-XRF) is widely used for the analysis of soils and sediments using well characterised procedures. However, difficulties can occur with samples such as unknowns containing small amounts of ore materials and samples collected from contaminated sites where trace elemental concentrations can exceed the concentration range for routine analysis. We studied the performance of a commercially available method, based on fundamental parameters (FP) to correct matrix effects. The spectrometer was originally calibrated with elemental or simple compound calibrants. Samples were analysed as pressed powder pellets. Eighteen sediment and soil reference materials, three of them with certified values for some of their constituents, were used to evaluate accuracy, by comparing results with recommended values and their standard deviations (RV ± 2s) or certified values and their confidence intervals (CV ± Cl). When results fell systematically outside these intervals, calibrations were refined with geochemical reference materials. The best agreement of results with recommended and certified values was obtained when the contents of H₂O and C in each sample were included as matrix constituents during calculations. The detection limits of trace elements tended to be relatively high, because the measuring conditions employed were not maximised for sensitivity. The main advantage of the method tested was that it enabled the analysis of samples with high concentrations of trace elements and the determination of elements such as F, Bi, Sb and W, which are not commonly included in quantitative XRF analysis of geological samples.  相似文献   

A Reflection on Mg, Cd, Ca, Li and Si Isotopic Measurements and Related Reference Materials   总被引：6，自引：1，他引：6  

Jean Carignan  Damien Cardinal  Anton Eisenhauer  Albert Galy  Mark Rehkamper  Frank Wombacher  Nathalie Vigier 《Geostandards and Geoanalytical Research》2004,28(1):139-148

This contribution aims to report the reflections we had with the scientific community during two international workshops on reference materials for stable isotopes in Davos (2002) and Nice (2003). After evaluating the isotopic homogeneity of some existing reference materials, based on either certificates, literature data or specific inter-laboratory rounds, we confirm these as primary reference materials or propose new ones relative to which stable isotope compositions should be reported. We propose DSM-3 for Mg, NIST SRM 915a for Ca, L-SVEC for Li and NBS28 for Si. Cadmium does not yet have a well identified delta zero material, although three commercial mono-elemental Cd solutions have yielded the same isotopic composition relative to one another. In order to scale the linearity of any mass spectrometer, some secondary reference materials are also proposed: Cambridge-1 solution for Mg, the "Münster-Cd" and JEPPIM Cd solutions for Cd and the "Big Batch" silicate for Si. The team from Nancy propose to prepare a mixed spike solution for Li isotopes. Well-characterised natural samples such as ocean or continental waters, diatoms, sponges, rocks and minerals are needed to validate the entire analytical procedure, particularly to take into account the effect of sample mineralisation and of chemical manipulations for elemental separation prior to analysis.  相似文献   

Precise/ Small Sample Size Determinations of Lithium Isotopic Compositions of Geological Reference Materials and Modern Seawater by MC-ICP-MS   总被引：6，自引：1，他引：6  

Alistair B. Jeffcoate  Tim Elliott  Alex Thomas  Claudia Bouman 《Geostandards and Geoanalytical Research》2004,28(1):161-172

The Li isotope ratios of four international rock reference materials, USGS BHVO-2, GSJ JB-2, JG-2, JA-1 and modern seawater (Mediterranean, Pacific and North Atlantic) were determined using multi-collector inductively coupled plasma-mass spectrometry (MC-ICP-MS). These reference materials of natural samples were chosen to span a considerable range in Li isotope ratios and cover several different matrices in order to provide a useful benchmark for future studies. Our new analytical technique achieves significantly higher precision and reproducibility (< ± O.3%o 2s) than previous methods, with the additional advantage of requiring very low sample masses of ca . 2 ng of Li.  相似文献