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41.
E. J. Palin M. T. Dove S. A. T. Redfern C. I. Saniz-Díaz W. T. Lee 《Physics and Chemistry of Minerals》2003,30(5):293-304
As part of a wider study of the nature and origins of cation order–disorder in micas, a variety of computational techniques
have been used to investigate the nature of tetrahedral and octahedral ordering in phengite, K2
[6](Al3Mg)[4](Si7Al)O20(OH)4. Values of the atomic exchange interaction parameters J
n
used to model the energies of order–disorder were calculated. Both tetrahedral Al–Si and octahedral Al–Mg ordering were studied
and hence three types of interaction parameter were necessary: for T–T, O–O and T–O interactions (where T denotes tetrahedral
sites and O denotes octahedral sites). Values for the T–T and O–O interactions were taken from results on other systems, whilst
we calculated new values for the T–O interactions. We have demonstrated that modelling the octahedral and tetrahedral sheets
alone and independently produces different results from modelling a whole T–O–T layer, hence justifying the inclusion of the
T–O interactions. Simulations of a whole T–O–T layer of phengite indicated the presence of short-range order, but no long-range
order was observed.
Received: 8 August 2002 / Accepted: 14 February 2003
Acknowledgements The authors are grateful to EPSRC (EJP) and the Royal Society (CIS) for financial support. Monte Carlo simulations were performed
on the Mineral Physics Group's Beowulf cluster and the University of Cambridge's High Performance Computing Facility. 相似文献
42.
Philippe Machetel 《Comptes Rendus Geoscience》2003,335(1):91-97
The numerical models of mantle convection agree to depict avalanches behaviour according to the level of endothermicity of the spinel → perovskite phase change. Their potential effects on the global thermal and dynamical states of the mantle have been computed thanks to a numerical code, which takes into account both the 400-km exothermic and the 660-km endothermic phase changes. The cycle followed by the avalanches is: local layering, destabilization of the 660-km thermal layer, travelling and spreading on the core, and reappearing of the local layering. Therefore, mantle convection is characterized by quiet periods of partial layering embedded in catastrophic events. During the avalanche, the amplitude of the surface velocity is multiplied by two, which would imply an enhanced plate tectonic and ridge activities. The global thermal effects of the avalanche are compatible with a high mantle temperature and an acceleration of Earth's rotation during the Cretaceous. They also offer a coherent explanation to locate the origin of mantle plumes both within the CMB and just below the transition zone. 相似文献
43.
黄金水 《武汉大学学报(信息科学版)》1997,(4)
将重力场内蕴几何结构的研究引入到正常椭球内部场的研究中,深入探讨了内蕴几何量及其与内部物理量之间的关系,并据此建立了弱平衡条件下的基本微分方程,进而给出确定椭球内部内蕴几何量与场源密度分布的方法。研究表明,平衡形状理论中的Wavre公式和Clairaut方程可由内蕴几何与内部物理量之间的关系导出,它们是在平衡假设下取椭球近似的结果。 相似文献
44.
45.
从系统辨识的原理出发,给出了确定精密重力仪相位滞后的一种方法,即记录精密重力仪在阶跃信号作用下的输出数据,利用这些数据对仪器的传递函数进行辨识,从而确定重力仪对各潮汐波产生的相位滞后角度.用这种方法对ET-21地潮重力仪进行了相位滞后的确定,并给出这台仪器对15个主要潮汐波的相位滞后角度. 相似文献
46.
根据相空间嵌入定理,按照Grassberger和Procaccia提出的计算分数维的方法,利用近百年来南、北半球地面气温资料,估算了气候吸引子的分数维,计算结果表明:气候吸引子的分数维南半球为3.3~3.7,北半球为3.2~3.7。它提供了气候吸引子的自相似结构的基本信息,表明模似气候系统最少需要4个独立变量。另外,还讨论了气候噪声对估算维数的影响。 相似文献
47.
X. Lee H.H. Neumann G. Hartog R.E. Mickle J.D. Fuentes T.A. Black P.C. Yang P.D. Blanken 《Boundary-Layer Meteorology》1997,84(3):383-398
In this paper we report the results of the analysis of two 60-min wave events that occurred in a boreal aspen forest during the 1994 BOREAS (Boreal Ecosystems-Atmosphere Study) field experiment. High frequency wind and temperature data were provided by three 3-D sonic anemometer/thermometers and fourteen fine-wire thermocouples positioned within and above the forest. Wave phase speeds, estimated from information revealed by spectral analysis and linear plane wave equations, are 2.2 and 1.3 m s-1 for the two events. The wavelengths are 130 m and 65 m respectively and are much larger than the vertical wave displacements. There is strong evidence from the present analysis and from the literature supporting our postulate that these waves are generated by shear instability. We propose that wind shear near the top of the stand is often large enough to reduce the gradient Richardson number below the critical value of 0.25 and thus is able to trigger the instability. When external conditions are favorable, the instability will grow into waves. 相似文献
48.
49.
Disequilibrium for Ca during growth of pelitic garnet 总被引:14,自引:1,他引:14
Compositional zoning in hundreds of almandine-rich garnets in amphibolite by facies micaceous quartzites from the Picuris Range, north-central New Mexico USA, indicates that although Mn, Mg and Fe achieve chemical equilibrium at hand-sample scale during garnet growth, Ca does not. Instead, Ca concentrations at the surface of growing garnets appear to depend strongly on kinetic factors that govern the local chemical environment, yielding disequilibrium for Ca at scales larger than the region immediately surrounding an individual porphyroblast. Detailed zoning profiles were obtained for 371 garnet crystals in a small volume of a single sample of garnetiferous quartzite, and core analyses were made of 97 additional crystals. Each analysis was made on a section that passed precisely through the morphological centre of the crystal, located by means of 3-D imagery from computed X-ray tomography. The data reveal strong correlations between crystal size and concentrations of Mn, Mg and Fe (but not Ca) in garnet cores; a relationship between crystal size and isolation; rigorous cross-correlations among concentrations of Mn, Mg and Fe (but not Ca); and systematic variations in Ca concentrations as a function of crystal size and core composition that are anomalous in comparison to the behaviour of the other divalent cations. We interpret these observations as the result of thermally accelerated diffusion-controlled garnet growth, in circumstances that promoted rapid intergranular diffusion and thus rock-wide equilibration of Mn, Mg and Fe, but that prevented equilibration at similar scale for Ca because of its more sluggish intergranular diffusion. The anomalous behaviour of Ca is made evident in these garnets by the presence of sharp spikes in Ca concentration, which are demonstrably not a consequence of any simultaneous rock-wide event, such as a change in pressure, temperature, or some other intensive parameter. Instead, Ca concentrations probably reflect the local extent of reaction in the immediate vicinity of each porphyroblast. To the degree that such kinetic factors introduce departures from chemical equilibrium for Ca, thermobarometric estimates that involve grossular contents of pelitic garnet will be in error. 相似文献
50.
A ternary solid solution model for omphacite with the end-members jadeite (NaAlSi2 O6 ), diopside (CaMgSi2 O6 ) and hedenbergite (CaFeSi2 O6 ) was derived from experimental data from the literature. The subregular solution model, fitted by linear programming, is best suited to omphacites with very little aegirine component in common eclogites. Applying this solution model to the calculation of equilibrium phase diagrams of eclogites from the Adula nappe (Central Alps, Switzerland) results in large stability fields for common eclogite assemblages (garnet+omphacite+quartz+H2 O±kyanite). Within this field the compositions of garnet and omphacite show very little variation. A precise determination of the peak-pressure and temperature is not possible. The occurrence of amphibole, overgrowing the peak-pressure assemblage in fresh eclogite, suggests retrograde re-equilibration, still under eclogite facies conditions. The computation of isopleths for garnet and pyroxene end-members allows the estimation of the pressure and temperature conditions of this re-equilibration event (19–21 kbar, c . 700 °C). 相似文献